ENERGY BALANCE FOR E-102

Stream 8
Stream 7
200°C and 2 atm 410°C and 2atm

Inlet Outlet
Stream
Stream 7 Stream 8
Molar Molar
Component Enthalpy Enthalpy
flowrate flowrate
s (kJ/kmol) (kJ/kmol)
(kmol/hr) (kmol/hr)
O2 130.2 1242.572 130.2 1674.69
N2 936.78 545.2234 936.78 1467.09
SO2 118.9 1242.572 118.9 3446.92
Total nH 2553535 nH 2090518
Q (kW) 2186.771094

Stream In
Stream 7

ΔHSO2
(g, 25˚C, 1atm) (g, 200˚C, 2 atm)
ΔH1 ΔH2
(g, 200˚C, 1atm)

T
Δ H SO 2= ∫ CpdT + ṽΔP
Tref

T
RT
Δ H SO 2= ∫ CpdT + ΔP
Tref P
200˚ C
( 0.0815 kPa. m3 kg . K ) ( 473 K ) kg
Δ H SO 2= ∫
25 ˚C
−3 −5
38.91 x 10 +3.904 x 10 T +(
202.65 kPa
)(64.07
kmol (
) ( 202.65−101.32 )
1k
Δ H SO 2=7.5779+1234.9942

Δ H SO 2=1242.5721 kJ /kmol

kmol kJ
n SO 2 H SO 2 =118.9 x 1242.5721
hr kmol
n SO 2 H SO 2 =147741.8227 kJ /hr

ΔHnitrogen
(g, 25˚C, 1atm) (g, 200˚C, 2atm)
ΔH1 ΔH2
(g, 200˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
 200˚ C
−3 −5 ( 0.0815 kPa .m3 kg . K ) ( 473 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 + 0.2199 x 10 T +( )(28.02 ) ( 202.65−101.32 )
25 ˚ C 202.65 kPa kmol

Δ H nitrogen =5.1183+ 540.1051

Δ H nitrogen =545.2234 kJ / kmol

kmol kJ
n nitrogen H nitrogen =936.78 x 545.2234
hr kmol
n nitrogen H nitrogen =510754.3767 kJ /hr

ΔHoxygen
(g, 25˚C, 1atm) (g, 200˚C, 2atm)
ΔH1 ΔH2
(g, 200˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
200 ˚C
( 0.0815 kPa .m 3 kg . K ) ( 473 K ) kg 1
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
202.65 kPa
)(32
kmol (
) ( 202.65−101.32 )
1 kP
Δ H oxygen=5.3205+616.8224

Δ H oxygen=622.1429 kJ /kmol

kmol kJ
n oxygen H oxygen=130.2 x 622.1429
hr kmol

n oxygen H oxygen=81003.0056 kJ /hr

Stream Out
Stream 8

ΔHO2
(g, 25˚C, 1atm) (g, 410˚C, 2 atm)
ΔH1 ΔH2
(g, 410˚C, 1atm)
 T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
410 ˚C
( 0.0815 kPa . m3 kg . K ) ( 683 K ) kg 1
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
202.65 kPa
)(32
kmol
) ( 202.65−101.32 )
(1 kP
Δ H oxygen=12.1732+890.6760

Δ H oxygen=902.8491 kJ /kmol

kmol kJ
n oxygen H oxygen=130.2 x 902.8491
hr kmol

n oxygen H oxygen=117550.9592 kJ / hr

ΔHnitrogen
(l, 25˚C, 1atm) (l, 410˚C, 2atm)
ΔH1 ΔH2
(l, 410˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
410 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 683 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 202.65−101.32 )
25˚ C 202.65 kPa kmol

Δ H nitrogen =11.3491+779.8981

Δ H nitrogen =779.8981 kJ /kmol

kmol kJ
n nitrogen H nitrogen =936.78 x 779.8981
hr kmol
n nitrogen H nitrogen =730592.9684 kJ /hr
 ΔHSO2
(g, 25˚C, 1atm) (g, 140˚C, 2 atm)
ΔH1 ΔH2
(g, 140˚C, 1atm)

T
Δ H SO 2= ∫ CpdT + ṽΔP
Tref

T
RT
Δ H SO 2= ∫ CpdT + ΔP
Tref P
410 ˚C
( 0.0815 kPa .m3 kg . K ) ( 683 K ) kg
Δ H SO 2= ∫
25 ˚ C
−3 −5
38.91 x 10 +3.904 x 10 T +(
202.65 kPa
)(64.07
kmol (
) ( 202.65−101.32 )
1k
Δ H SO 2=18.2495+1783.3003

Δ H SO 2=1801.5498 kJ /kmol

kmol kJ
n SO 2 H SO 2 =118.9 x 1801.5498
hr kmol
n SO 2 H SO 2 =214204.2655 kJ /hr

Q=∑ noutHout −∑ ninHin

Q=2002224−820279
Q=328.3180 kW