to 1

Compressibility factor 2
It denotes the extent of deviation of gas from ideal
behaviour

Real gas
Ideal gas
p f

VI VR Vr VI
VILUR VI VR
ve deviation ve deviation

I _VR Ideal

Observed Mohar volume

2
Molar Volume of ideal gas

Real Real P PidealVided MRD

Ideal NR
ARTIP
Z
N RT

If Z l VR VI Ideal
gas
2 I Vp VI Positive deviationfrom ideal behevious
2 1 VR VI Negative u n a
 Plots of compressibility feder

A Z Vs Pressure

Ha
ve deviation z I

29 He

men
a am i

Intermelecules
AF attraction Mex
dominant
Ve deviation 2 1

O O p
P

Features
1 For Hz He Z is always higher then 1 at all pressures
show the deviationonly
2 Other gases show ve deviation at low'P ve deviation
at high pressure
3 More the dip in the curve gas molecules here high
attraction forces are more liquefiable
4 curve in area Z I repulsive forces in gases aee

dominent gas is non lifecifiabce

5 Gras with more dip
compale native of gas
 Polar gases have more AF here more dip in were

then non polar gases

If native is more compoee molecular cut As that.wtP
AF increases

Dip for 5oz CH g Nz He Hz

B Z vs P For a gas at different temp

To T3

As 1 A gas approach ideal behaviour

Explanation of deviation by Vanden's eyelids

Lew pressure Modrate temp

Pt a V b RT for Imole

At low P V is very high

In V b b'can be neglected in compassion to