Name________________________________ Block___________

Unit 7 Test Review-Answer Key will be posted on Synergy

Part A Thermochemistry

• The table shows the specific heat capacity of four substances.

Substance Heat Capacity (J/g °C)

Aluminum 0.900
Glass 0.50
Carbon Dioxide 0.843
Water 4.18

For an equal mass of each substance, which one will require the most amount of heat to raise its temperature from 40
°C to 50 °C?

Water

• Solid magnesium has a specific heat of 1.01 J/g °C. How much heat is given off by a 10.0 gram sample of magnesium
when it cools from 90.0 °C to 70 °C?

200 J

• The temperature of a sample of iron with a mass of 35.0 g changed from 57.4 °C to 32.0 °C with the release of 228 J of
energy. What is the specific heat of iron?

6.256 J/gc

• How many joules of heat are needed to raise the temperature of 27.0 g of aluminum from 44 °C to 77°C if the specific
heat of aluminum is 0.90 J/g °C?

8 x 102 J
 • To what temperature will a 50.0 g piece of glass raise if it absorbs 5275 joules of heat and its specific heat capacity is
0.50 J/g °C? The initial temperature of the glass is 20.0 °C.

231 C

• Define specific heat capacity.

The heat required to raise lg of a substance l C

Part B-Heating and Cooling Curves

• Use the information in the table below to draw the heating curve and determine how much heat is needed to change
9.00 g of H2O at -32.0 °C into a gas at 145 °C.
2.85 x 104 4

H2O
mp = 0 °C
bp = 100 °C
c (ice) = 2.06 J/g °C
c (water) = 4.184 J/g °C
c (steam) = 2.03 J/g °C
molar heat of fusion = 6.02 kJ/mol
molar heat of vaporization = 40.79 kJ/mol

• How much heat is needed to vaporize 7.5 g of H2O at 100 °C?

17kJ
 • How much heat is needed to melt 12.6 g of H2O at 0 °C?
4.22 kJ

• Define heat of fusion and heat of vaporization.

Heat of fusion is the amount of energy needed to turn a Solid Into a Liquid

Heat of vaporization is the amount of energy needed to turn a Liquid into a Gas

Part C-Intermolecular Forces

• If substance X is a liquid, substance Y is a gas, and substance Z is a solid, and all are at the same temperature and
pressure, then the order of decreasing strength of their intermolecular forces would be z>x>y

• At 25 °C, Br2 is a liquid but I2 is a solid. This is most likely due to the what?
It has stronger InterMolecular Forces

• Which of the following should have the lowest boiling point: CH4, CHCl3, H2S, or CH3OH?
CH4 becayse it is a nonpolar molecule that contains only Lonon Dispersion Forces

• Which of the following species exhibits hydrogen bonding: C3H8, H2S, NH4+, or HCN?
NH4+

• Refer to the following four liquids to answer the question, all of which have the molecular formula C 4H10O and which
have the following boiling points: A (571.1 °C); B (92.8 °C); C (64.3 °C); D (59.9 °C). The liquid likely to have the
lowest vapor pressure at 25 °C is ________________.
A

• Which of the following has the highest boiling point: F2, Cl2, Br2, or I2?
I2

• Which of the following has the weakest intermolecular forces: N 2, HCN, or NH3?
:N=N:

• Why does water have several unique properties such as high boiling point, high surface tension, and low vapor
pressure?
 Strongest IMF of hydrogen bonding

• Rank the three types of intermolecular forces in terms of increasing strength.

LDF<Dipole-Dipole<hydrogen

• Fill in the diagram (with high or low) to show how intermolecular forces influence the volatility, vapor pressure, and
boiling point of a substance.

Part D – Vapor Pressure Graphs: Use the graph below to answer the following questions.

1. What is the vapor pressure of CHCl3 at 50C?

68kPa

2.

3. What is the boiling point of H2O when the

external pressure is 30 kPa? 70 C

4. What is the normal boiling point of CCl4? 75 C

5. Which substance has the weakest IMF?

CHCl3

Part E – Heating Curves. Use the heating curve below to answer the following questions.
1. What is the melting point of the substance? 5C

2. What is the boiling point of the substance? 5C

3. Which letter represents heating of the solid? a

4. Which letter represents heating of the vapor? e

5. Which letter represents melting of the solid? b

6. Which letter represents boiling of the liquid? d

Part F – Phase Diagrams. Use the phase diagram for water below to answer the following questions.

1. What is the state of water at 2 atm and 50 C Liquid

2. What phase change will occur if the temperature is lowered from 80 C to -5 C at 1 atm? freezing L>S

3. You have ice at -10 C and 1 atm. What could you do in order cause the ice to sublime?
lower the pressure