Professional Documents
Culture Documents
Topics:
I. States of matter: Solids, Liquids, and Gases
II. Heating and cooling curve of water
III. Kinetic theory of matter
IV. Diffusion
V. Pure substances and impurities
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ABDELQADER BASHA CHEMISTRY O-LEVEL
I. States of matter
Arrangement
Freezing: the change of state from liquid to solid, it occurs at the freezing point.
Boiling: the change of state from liquid to gas, it occurs at the boiling point.
Evaporation: the change at the surface of a liquid into gas, it occurs at any temperature.
Condensation: the change of state from gas to liquid, it occurs at the condensation point.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
For a particular substance its melting point is the same as its freezing point, also the boiling
point is the same as its condensation point.
Example: water
Water can exist in the 3 states: solid (ice), liquid (water), gas (water vapour/steam).
The melting point of ice is the same as the freezing point of water, 0ºC.
The boiling point of water is the same as the condensation point of steam, 100 ºC.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
Look at the graph below. It shows the temperature change as an ice block is steadily heated.
First, the ice warms up till it reaches its melting point where the particles gain more energy
and vibrate more to break away from their positions. The solid turns into liquid while the
temperature stays the same at 0ºC until all the ice has melted.
Second, the water gets warmer and its temperature rises until it reaches its boiling point
where the particles gain more energy to break the attractive forces between them so they
move freely and far apart. The liquid turns into gas while the temperature stays the same at
100ºC until all the water has boiled.
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As a gas cools, its particles lose energy and slow down. When they collide they do not have
enough energy to bounce back, so they stay close to each other and form a liquid.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
1 The solid and liquid phases of water can exist in a state of equilibrium at 1 atmosphere
of pressure and a temperature of:
2 The table below shows the normal boiling point of four compounds.
a) On the heating curve diagram provided above, label each of the following regions:
Liquid, only
Gas, only
Phase change
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ABDELQADER BASHA CHEMISTRY O-LEVEL
b) For section QR of the graph, state what is happening to the water molecules as heat is
added.
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c) For section RS of the graph, state what is happening to the water molecules as heat is
added.
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4 The graph below represents the heating curve of a substance that starts as a solid
below its freezing point.
a) 30oC
b) 55oC
c) 90oC
d) 120oC
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ABDELQADER BASHA CHEMISTRY O-LEVEL
It states that all matter is made up of particles. These particles vibrate with solids having the
smallest amount of vibration and gases having the most.
IV. Diffusion
Diffusion of gas is much faster than diffusion of liquid, so it is used as an evidence of the
kinetic theory.
https://www.youtube.com/watch?v=1Jtw8g795Us
https://www.youtube.com/watch?v=N9OL6AwyM5I
https://www.youtube.com/watch?v=Y8j6peP5nNg
https://www.youtube.com/watch?v=CldadkIuaC4
Observation:
Conclusion:
The warmer the particles, they have more energy, the faster they diffuse.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
It was observed by the scientist Robert Brown in the 19th century when pollen grains were
observed to move in a random pattern on a water droplet.
It is explained by the collision of water molecules with the pollen in a random pattern of
collision.
https://www.youtube.com/watch?v=4m5JnJBq2AU
https://www.youtube.com/watch?v=hy-clLi8gHg
https://www.youtube.com/watch?v=UDj7BXA1CHU
https://www.youtube.com/watch?v=VDOWS_JBCfw
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ABDELQADER BASHA CHEMISTRY O-LEVEL
Try the following experiment for the reaction between HCl and NH3
https://www.youtube.com/watch?v=-ZUMC3tEL0M
Conclusion:
Temperature
The higher the temperature is, the faster the diffusion of the gas.
When a gas is heated, the particles absorb heat energy and move faster. They collide with
more energy and bounce farther away, so the gas diffuses faster.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
A pure substance has no particles of any other substance mixed with it.
Tap water contains small amounts of many different particles (Ca2+ , Cl ).¯¯
Distilled water is much purer, but not 100% pure, it has gas particles from the air dissolved
in it.
Impurity: is any unwanted substance mixed with the substance you want.
Test of purity
There are many tests to check the purity of a substance for example melting or boiling.
What do you understand if you boil a sample of water and it is boiled above100 oC?
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Each pure substance has a definite melting point and (mp) and boiling point (bp)
When a substance contains an impurity:
a) Its melting point decreases ↓ and its boiling point increases ↑
b) It melts and boils over a range of temperatures, not sharply.
The more impurity it has, the bigger the change in the mp and bp, and the wider the
temperature range over which melting and boiling occur.
Give a reason why do people scatter salt on the snow in the roads during winter
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3 (a) A small amount of liquid bromine is added to a container which is then sealed.
Br2(l) → Br2(g)
Use the ideas of the Kinetic Theory to explain why, after about an hour, the bromine molecules
have spread uniformly to occupy the whole container.
..................................................................................................................................... [3]
(b) The diagrams below show simple experiments on the speed of diffusion of gases.
Complete the following explanations. Diagram 1 has been done for you.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
Diagram 1
There is air inside and outside the porous pot so the rate of diffusion of air into the pot is the same
as the rate of diffusion of air out of the pot. The pressure inside and outside the pot is the same so
the coloured liquid is at the same level on each side of the tube.
Diagram 2
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...........................................................................................................................................
...........................................................................................................................................
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...........................................................................................................................................
..................................................................................................................................... [3]
Diagram 3
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[Total: 9]
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(a) A sample of pure X was slowly heated from –5.0 °C, which is below its melting point, to 90 °C,
which is above its boiling point. Its temperature is measured every minute and the results are
represented on the graph.
(i) Complete the equation for the equilibrium present in the region BC.
....................................................................................................................................... [1]
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(iv) What would be the difference in the region BC if an impure sample of X had been used?
....................................................................................................................................... [1]
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.............................................................................................................................................
....................................................................................................................................... [1]
(ii) What property of a gas molecule affects the speed at which it diffuses?
....................................................................................................................................... [1]
(b) Helium is a gas used to fill balloons. It is present in the air in very small quantities. Diffusion can be
used to separate it from the air.
Air at 1000 °C is on one side of a porous barrier. The air which passes through the barrier has a
larger amount of helium in it.
(i) Why does the air on the other side of the barrier contain more helium?
....................................................................................................................................... [1]
.............................................................................................................................................
....................................................................................................................................... [1]
(c) Most helium is obtained from natural gas found in the USA. Natural gas contains methane and 7%
helium. One possible way to obtain the helium would be to burn the methane.
(iii) Suggest another method, other than diffusion, by which helium could be separated from the
mixture of gases in natural gas.
....................................................................................................................................... [1]
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Topics:
1) Apparatuses used in the lab
2) Hazard symbols
3) Mixtures
4) Solutions
5) Separation techniques
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Safety glasses
(goggles)
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Mixtures
A mixture contains two or more substances that are mixed together physically, not
chemically combined.
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Solutions
A solution is a homogeneous mixture of two or more substances.
Example: sea water, a solution of water and salt, the salt is evenly distributed throughout the
water.
Sea water
Sugary water
Concentration: the amount of solute (in gram or mole) that can dissolve in 1L of a
solvent.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
Solubility: the maximum amount of solute that can dissolve in 100g water at a particular
temperature.
Solubility Curve
Use the solubility curve given below to answer the following questions
What is the solubility of KClO3 at 70ºC?
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ABDELQADER BASHA CHEMISTRY O-LEVEL
What will happen if a solution of KClO3 is cooled down from 70ºC to 30ºC?
There are many factors that can increase the solubility of solids in a liquid such as stirring
and heating.
Mention other factors that can speed up the solubility of solids in a liquid
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There are 3 types of solution based on the amount of the solute dissolved at a specific
temperature:
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https://www.youtube.com/watch?v=JQRIlS9lNdg
https://www.youtube.com/watch?v=d7Qge1QbcaE
Water is not the only solvent; there are many other solvents that are used in industry.
Examples:
a) Ethanol that can dissolve glues, printing ink, also used in perfumes and aftershave.
b) Propanone that can dissolve grease and nail polish.
Separation techniques
There are 3 ways you can use to separate an insoluble solid from a liquid
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ABDELQADER BASHA CHEMISTRY O-LEVEL
1. Decanting: carefully pour the liquid in another container and leave behind the
undissolved solid. It is suitable for separating suspensions such as muddy water.
https://www.youtube.com/watch?v=a0-JcyEVWpE
https://www.youtube.com/watch?v=ZvxaFCR2-bY
3. Filtration: pour the solution on a filter paper; the solid particles will be trapped in the
filter paper (residue) while the liquid portion (filtrate) passes through.
Example: water and sand
https://www.youtube.com/watch?v=pFYG7jxjGHs
https://www.youtube.com/watch?v=OMZpzcItQkc
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1. By evaporation:
To obtain salt from aqueous solution, you need to keep heating the solution to evaporate
the water. When there is only a little water left, the salt will start to appear. Heat carefully
until it is dry.
2. By crystallization:
Many soluble solids tend to be less soluble at lower temperatures, as the temperature
decreases the crystals start to form. This is the reason of crystallization.
https://www.youtube.com/watch?v=QdwKhbtzsug
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a) Heat the solution to evaporate some of the water, the solution becomes concentrated
(saturated). (point of crystallization)
b) Let it to cool down, crystals will start to form.
c) Check that it is ready by placing a drop on a microscope slide; crystals will form quickly
on the cold glass.
d) As the temperatures falls, more crystals will form.
e) Remove the crystals by filtration. Rinse the crystals with distilled water.
f) Dry the crystals with a filter paper not in the oven to avoid water loss of crystallization.
Simple distillation:
https://www.youtube.com/watch?v=gIMtFj2gPs8
https://www.youtube.com/watch?v=0IWy_hdgKJM
https://www.youtube.com/watch?v=eRafdvf1urQ
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a) Heat the solution in the flask, as it boils, water vapour rises into the condenser, leaving
the salt behind.
b) The condenser is cold so the water vapour condenses to water.
c) The water drips into the beaker (distilled water), it is almost pure.
The bulb of the thermometer is placed at the top next to the side arm where the vapour
leaves to measure the boiling point of the liquid at atmospheric pressure.
The condenser has two tubes, inner where the vapour passes through it, and outer where
the cooling water passes through it.
The cooling water passes up the condenser opposite the vapour flow to ensure large and
permanent cold surface and condense all the vapour into liquid.
Anti-bumping granules are added to the flask to prevent splashing the liquid as it smooth
the boiling.
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Fractional distillation: it separates miscible liquids with widely differing boiling points.
https://www.youtube.com/watch?v=vRHk4bOivAk
https://www.youtube.com/watch?v=86WY2mV9jiU
1. Heat the mixture in the flask until 78ºC the ethanol begins to boil. Some water evaporates
too, so a mixture of ethanol and water vapour rises up the column.
2. The vapours condense on the glass beads in the column.
3. When the beads reach about 78ºC, ethanol vapour no longer condenses on them. Only
water vapour does, so water drips back into the flask and the ethanol vapour goes into the
condenser.
4. Ethanol vapour condenses, pure liquid ethanol drips into the beaker.
5. As the temperature rise above 78ºC, all the ethanol has gone and you can stop heating.
Fractions: the different mixtures distil over different temperatures during fractional
distillation.
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IV. Chromatography
To separate different solutes dissolved in a solution.
https://www.youtube.com/watch?v=-XCPPB-sBFU
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ABDELQADER BASHA CHEMISTRY O-LEVEL
https://www.youtube.com/watch?v=uOhefwQBAbI
The dyes separate due to the differences in their solubility. The most soluble moves the
fastest up the paper.
Solvent front: the maximum distance travelled by the solvent.
Chromatogram: the chromatography paper with the coloured rings.
Stationary phase is the paper and mobile phase is the solvent.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
Identification of substances
Example: a mixture X contains 3 pigments (red, blue, yellow) which are all soluble in
propanone.
1) Prepare concentrated solution of the mixture X and the three pigments (red, blue,
yellow) in propanone as shown in the figure below. Place a spot of each along a pencil
line on chromatography paper, label them.
You draw the pencil line because it is not soluble. (ink line is soluble)
2) Stand the paper in a little propanone, in a covered glass tank. The solvent rises up the
paper, when it is near the top, remove the paper.
3) The mixture X has separated into three spots of the same height of the red, blue and
yellow pigments.
a) Identify a substance
b) Separate mixtures of substances
c) Purify a substance, by separating it from its impurities.
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Amino acids are colourless so you have to spray it with a locating agent to make the amino
acids to show up. After spraying, heat the paper in the oven for 10 minutes, the spots turn
purple, now you have a proper chromatogram.
Rf has no unit
Rf is always less than 1, give a reason _____________________________________
https://www.youtube.com/watch?v=jiPd5CkCkkU
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Q7)
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Topics:
1) Atomic structure
2) Isotopes
3) The arrangement of electrons
4) Element & compound
5) Chemical change & physical change
6) Metals & nonmetals
7) Alloy
8) Ions and ionic bonds
9) Molecules and covalent bonds
10) Macromolecules
11) Metallic bonding
12) Names & formulas of compounds
I. Atomic structure
An atom is the smallest particle of a matter that cannot be broken down by any chemical
method.
An atom consists of :
a) Nucleus: at the center and contains two types of subatomic particles
protons: have positive charge and
neutrons: have no charge (neutral)
b) Electrons: exist in a cloud around the nucleus and have negative charge.
All subatomic particles are measured in atomic mass unit because they are very light
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Each element has a unique number of protons, so no two elements can have the
same atomic number.
Complete the table below
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20 Ca
8
3 Li
232
90 Th
II. Isotopes
Isotopes: atoms of the same element that have the same atomic number but have different
masses (different number of neutrons).
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Both types have identical chemical properties because they have the same number of
electrons in their outer shell.
(Same atomic number = same number of protons = same number of electrons)
Radioactive isotopes:
Example: Carbon – 14 is a radioactive isotope, its atoms will break down (decay) naturally
and give off radiation in the form of rays and particles and a lot of energy.
If the radiation enters your body it will kill the body cells. Large dose can cause radiation
sickness. The patient will suffer from vomiting, hair fall, tiredness, and eventually die.
Small and frequent doses of radiation for a long period will cause cancer.
a) Industrial uses:
1. Measure thickness of plastic sheets and papers during productions.
2. Trace the leakage of oil, gas, and water pipes by adding a radioactive isotope to the oil
or the gas then use a device called Geiger counter that can detect the emitted radiation
from the isotope outside the pipe, it indicates the location of the leak.
3. Uranium – 235 is used as a fuel in nuclear power stations.
4. Food preservation and sterilization of equipments
https://www.youtube.com/watch?v=gNgHl2FkswE
https://www.youtube.com/watch?v=WPhBQSZLMS4
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https://www.youtube.com/watch?v=E4B94zCY4ok
b) Medical uses:
1. For diagnosis of diseases. Such as activity of thyroid gland and blood clotting in blood
vessels.
2. For treatment of diseases, such as cobalt – 60 is used to kill cancer cells
3. To sterilize syringes and medical equipments because gamma rays kill bacteria and
germs
4. Measuring the age of fossils using carbon – 12 and the half life method.
I. Arrangement of electrons
Electrons are arranged in shells around the nucleus. The closer the shell to the nucleus is, the
lower the energy level it has. Each shell can hold a certain number of electrons.
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The third level fills up to 8 electrons then the next 2 electrons go to the 4th shell
then the rest of the 3rd shell fills.
The distribution of electrons for the first 20 elements that fill 4 shells can be written as
2,8,8,2 or 2.8.8.2
Solve the distribution of electrons for the first 20 elements in the diagram below
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After the 20th element, calcium, the electron shells fill in a more complex way but you can
deduce the electron distribution for later elements.
Period 5 means there are 5 shells and group 2 means there are 2 valence electrons in the
outer shell. So the electron distribution will be 2, 8,18,8, 2
If you add the number of electrons in the distribution 2+8+18+8+2=38 so your answer is
correct. You have 5 levels and the outer shell has 2 valence electrons.
Elements in group 0 have a very stable arrangement of electrons, the outer shell have 8
electrons except Helium which has 2 electrons because it has only one shell, which is the
reason they are chemically unreactive. They are called inert gases or noble gases.
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ABDELQADER BASHA CHEMISTRY O-LEVEL
Element: is a substance that cannot be broken down into simpler substances by chemical
or physical methods.
An element contains only one kind of atom, for example copper contains only copper
atoms.
Compound: is a pure substance made of two or more elements that are chemically
combined.
A compound is described by the chemical formula which uses the symbol of atoms in it.
Ex: sodium chloride (NaCl), water (H2O), Sulfuric acid (H2SO4)
For each of the previous compounds write the name of the elements that it is composed of
and the number of atoms for each element.
Water
Sulfuric acid
Chemical change: a change that forms a new substance and not easy to reverse. Often it
is exothermic (release heat) such as combustion.
Physical change: a change that does not form a new substance, and easy to reverse.
Often it is endothermic (absorb heat) such as melting.
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Metals Nonmetals
Physical properties
Good conductors of electricity and heat Do not conduct or heat
Have high melting point and boiling point Low melting point and boiling point
Many are solids at room temperature Many are gases at room temperature
Shiny Dull
Hard, do not shatter when you hammer Brittle, can shatter when you hammer the
them solid
Chemical properties
Form positive ions when they react Form negative ions when they react
React with oxygen forming oxides that are React with oxygen forming oxides that are
bases acidic
Some metals are soft and can be cut easily with a knife such as sodium and potassium.
Mercury is a metal that is liquid at room temperature
Hydrogen is a nonmetal but it forms a positive ion H+ like metals
Carbon is a nonmetal, it has many forms, one form (graphite) is good conductor and
another form (diamond) is very hard and has a very high melting point.
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VII. Alloy
An alloy is a mixture of metals or a mixture of a metal and another element.
Brass is a metallic alloy that is made of copper and zinc. The proportions of zinc and copper
can vary to create different types of brass alloys with varying mechanical and electrical
properties.
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Ions: they are atoms or group of atoms that have a positive or negative charge.
Cations Anions
Have positive charge Have negative charge
Formed by losing electrons Formed by gaining electrons
Metals Nonmetal
Protons more than electrons Protons less than electrons
Mg → Mg2+ + 2e- -
F + e- → F
Atoms tend to lose or gain electrons to have a stable electron distribution like noble
gases, group 0.
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Chemical bonding
Atoms form bond with each other in order to have a stable electron arrangement of the outer
shell, similar to group 0, Noble gases.
1) Ionic bond
2) Covalent bond
3) Metallic bond
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Ionic bond
It is a bond that is formed between positive ions and negative ions.
A sodium atom loses its valence electron so the outer shell will have 8 electrons, forming a
positive ion, and the chlorine atom will gain that electron so the 7 valence electrons will
become 8, forming a negative ion. The two ions have opposite charges so they attract
together by a strong ionic bond.
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Give reason why MgO (magnesium oxide) has a higher melting point than NaCl
(sodium chloride). (MgO=2852ºC, NaCl=801ºC)
Because the ions of MgO (Mg2+ and O2-) have more charge than the ions of NaCl
(Na+ and Cl--) so its ionic bond is much stronger.
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