QNo:1. What mass of a concentrated solution of hydrochloric acid (37.

0% HCl
by mass, specific gravity 1.18) is needed to prepare a 10.0% solution of
HCl by mass?
QNo:2. What Will be molarity of both solution from Q.1
Data:
(%𝐏𝐮𝐫𝐢𝐭𝐲 𝐱 𝐬𝐩 𝐠𝐫𝐚𝐯𝐢𝐭𝐲 𝐱 𝟏𝟎𝟎𝟎)
M=
𝐌𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝟏𝟎𝟎
𝟑𝟕 𝐱 𝟏.𝟏𝟖 𝐱 𝟏𝟎𝟎𝟎
=
𝟑𝟔.𝟓 𝐱 𝟏𝟎𝟎

11.9 moles/L
C1V1 = C2V2
37 x V1 = 10 x 1000
V1 = 270 mL
𝐦
D=
𝐕
𝐦𝐚𝐬𝐬
1.18 =
𝟐𝟕𝟎

1.18 x 270 = 318.6

Molarity of 10% solution
Amount = M x molar mass x volume
𝟑𝟏𝟖𝐠 𝟏𝟎𝟎𝟎
= 8.7M. Ans:
𝟏𝟎𝟎𝟎 𝐱 𝟑𝟔.𝟓

QNo:3. What will be mass of NaOH in 250ml of 10% solution?

Data:
V= 250 ml
w/v= 10%
mass of solute=?
Solution:
 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
Formula: % w/v = x100
𝐯𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝐰/𝐯 𝐱 𝐯𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
= w/v = mass of solute
𝟏𝟎𝟎
𝟏𝟎 𝐱 𝟐𝟓𝟎
Mass of solute =
𝟏𝟎𝟎

Mass of solute = 25g. Ans:

QNo4. What is the molar concentration of Ca 2+ ions in water sample containing

250mg (CaCo3)/L?
Data:
𝟐𝟓𝟎
Convert mg into g = = 0.25 g
𝟏𝟎𝟎𝟎

Molar mass of CaCO3

Ca = 40
C= 12
O = 𝟏𝟔 𝐱 𝟑 =48
=100
100 g of CaCO3 ________ 40 of Ca
𝟒𝟎
1 g of CaCO3 __________ = 0.4g
𝟏𝟎𝟎
𝟎.𝟒
0.25 g Ca _____________ = 0.1g
𝟎.𝟐𝟓
𝐌 𝐱 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐯𝐨𝐥𝐮𝐦𝐞
A=
𝟏𝟎𝟎𝟎
𝐀 𝐱 𝟏𝟎𝟎𝟎
M=
𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐯𝐨𝐥𝐮𝐦𝐞
𝟎.𝟏 𝐠 𝐱 𝟏𝟎𝟎𝟎
M= = 0.0025 M. Ans:
𝟒𝟎 𝐱 𝟏𝟎𝟎𝟎
QNo:5. A solution contains 2.50 % by mass of phenol. if the solution has a
density of 0.995g/ml calculate the molarity of the solution?
Data:
Mass of solute = 2.50 %
Density = 0.995g/ml
Molarity =?
Molar mass of phenol = 34g
Solution:
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐒𝐨𝐥𝐮𝐭𝐞
Formula: M=
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
M=
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧 𝐱 𝐕 𝐢𝐧 𝐋𝐢𝐭𝐫𝐞
𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
OR =
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞
𝟐.𝟓𝟎
No of moles = = 0.073
𝟑𝟒

Moles = 0.073.
𝐌
D=
𝐕
𝐌 𝟑𝟒
V= = = 34.17 ml
𝐃 𝟎.𝟎𝟗𝟗𝟓
𝟎.𝟎𝟕𝟑
M= x 1000
𝟑𝟒.𝟏𝟕

Molarity = 21.47 moles/Liter. Ans:

QNo:6. Calculate the molar concentration of solution containing 5g of Pb(NO2)

in 500 ml of solution?
Data:
Given mass= 5g
Volume = 500 mL
Molar Concentration=?
 Molar mass of Pb(NO3)2 = 538
Solution:
𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
M=
𝐕 𝐢𝐧 𝐋𝐢𝐭𝐫𝐞
𝟓 𝟏𝟎𝟎𝟎
M= x
𝟓𝟑𝟖 𝟓𝟎𝟎 𝐦𝐥
𝟏𝟎
M= = 0.0185 moles/Liter. Ans:
𝟓𝟑𝟖

QNo:7. A 200 mL aqueous solution contains solution 200 mg of NAOH. Express

NaOH concentration in weight percent, parts per million and parts per
billion.
Data:
ppm =?
w/v percent of NaOH =?
Ppb =?
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
(a)w/v % = x100
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐥𝐮𝐭𝐢𝐨𝐧
𝟐𝟎𝟎
w/v % = x 100
𝟐𝟎𝟎

w/v % = 100%. Ans

(b) ppm =?
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
Ppm = x 𝟏𝟎𝟔
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧 𝐢𝐧 𝐋𝐢𝐭𝐫𝐞

1L = 1000 mL
x = 200 mL
x/1000 = 1L x 200 mL
𝐥𝐋 𝐱 𝟐𝟎𝟎 𝐦𝐋
XL =
𝟏𝟎𝟎𝟎
𝟏
200 ml = = 0.2 L
𝟓
 𝟐𝟎 𝐦𝐠
Ppm = x 𝟏𝟎𝟔
𝟎.𝟐

Ppm = 1000 x 𝟏𝟎𝟔

Ppm = 1x𝟏𝟎𝟔 𝐱 𝟏𝟎𝟑
𝐔𝐠 𝐦𝐠
Ppb = =
𝐋𝐢𝐭𝐫𝐞 𝐦𝐋

Ppb =?
𝐮𝐠 𝐧𝐠
Ppb = =
𝐥𝐢𝐭𝐫𝐞 𝐦𝐋

1mg = 1000 ug
200 mg x
200 mg = 𝟐𝐱𝟏𝟎𝟓 ug
𝟐𝐱𝟏𝟎𝟓 𝐮𝐠
Ppb = x 𝟏𝟎𝟗
𝐋𝐢𝐭𝐫𝐞

Ppb = 1x𝟏𝟎𝟔 𝐱 𝟏𝐱𝟏𝟎𝟗

𝐮𝐠
Ppb = 1x𝟏𝟎𝟏𝟒 Ans.
𝐋𝐢𝐭𝐫𝐞

QNo:8. What would be concentration in ppm and ppb of 1.5 x10-3 M of CuCl2?
Data:
1.5 𝐱103 m
Ppm =?
Ppb =?
Ppm = 𝟏. 𝟓𝐱𝟏𝟎−𝟑 𝐱𝟏𝟎𝟔
Ppm = 𝟏. 𝟓𝐱𝟏𝟎−𝟑
Ppb = 𝟏. 𝟓𝐱𝟏𝟎−𝟑 𝐱𝟏𝟎𝟗
Ppb = 𝟏. 𝟓𝐱𝟏𝟎𝟔 .Ans
QNo:9. What is the percentage by mass of a solution made by dissolving 0.5 g
of glucose in 50.00 mL of water?
Data:
V = 50.00 mL
Mass of solute = 0.5g
𝐦𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
w/v% = 𝐱𝟏𝟎𝟎
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝟎.𝟓
w/v = 𝐱𝟏𝟎𝟎
𝟓𝟎.𝟎𝟎

w/v = 1%
𝟎.𝟓
1= 𝐱𝟏𝟎𝟎
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧

1 x volume of solution = 0.5 𝐱 100 = 50 mL

𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
OR = 1 = 𝐱𝟏𝟎𝟎
𝟓𝟎 𝐦𝐋

1𝐱50 = Mass of solute 𝐱 100

𝟓𝟎 𝟏
Mass of solute = = 𝟎. 𝟓𝐠. Ans
𝟏𝟎𝟎 𝟐

QNo:10. Calculate parts per billion concentration of solution containing 10 mg

of KCl in 100 mL of water?
Data:
10 mg of KCl
100 mL water
Ppb =?
𝐮𝐠
Ppb = 𝐱𝟏𝟎𝟗
𝐋𝐢𝐭𝐫𝐞
𝟏𝟎𝟎𝟎𝟎 𝟏 𝐱 𝟏𝟎𝟑 𝐮𝐠
Ppb = = = 𝟏 𝟏𝟎𝟓 . Ans:
𝟎.𝟎𝟏 𝟏𝐱𝟏𝟎−𝟐 𝐋
QNo:11. What will be concentration in ppb And ppm of 0.1M Cu(NO3)2 solution?
Data:
0.1M of Cu(NO3)2
Ppm =?
Ppb =?
𝐮𝐠
Ppm = 0.1𝐱𝟏𝟎𝟔 = 𝟏 𝐱𝟏𝟎𝟓
𝐋
𝐮𝐠
Ppb = 𝟎. 𝟏 𝐱𝟏𝟎𝟗 = 𝟏 𝐱𝟏𝟎𝟖 . Ans:
𝐋

QNo:12. What mass of NH4OH will be needed to prepare 250mL of 2.0 M

solution?
Data:
Given mass =?
Given Volume = 250 mL
M = 2 moles/Liter or 𝐝𝐦𝟑
NH4OH = 14+4+16+1 = 35g Ans
𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞
M=
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐋𝐢𝐭𝐫𝐞
𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
M=
𝐦𝐦 𝐯𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞
𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬 𝟏𝟎𝟎𝟎
M=2= 𝐱
𝟑𝟓 𝟐𝟓𝟎

2 x 35 x 250 = Given mass x 1000

𝟐𝐱𝟑𝟓𝐱𝟐𝟓𝟎
Given mass = = 𝟏𝟕. 𝟓g. Ans:
𝟏𝟎𝟎𝟎
QNo:13. what mass of H2SO is contained in 50.0 ml of 0.8 M solution of sulfuric
acid?
Data:
M = 0.8
Volume = 50.0 mL (Given volume)
Molar mass of H2SO4 = (2+32+64) = 98
Mass =?
𝐌𝐨𝐥𝐚𝐫𝐢𝐭𝐲 𝐱 𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬 𝐱 𝐌𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬
m=
𝟏𝟎𝟎𝟎𝟎
𝟎.𝟏𝟖 𝐱 𝟓𝟎.𝟎 𝐱 𝟗𝟖
m=
𝟏𝟎𝟎𝟎𝟎
𝟒𝟎 𝐱 𝟗𝟖
m=
𝟏𝟎𝟎𝟎
𝟒 𝐱 𝟗𝟖
m=
𝟏𝟎𝟎
𝟐 𝐱 𝟗𝟖 𝟗𝟖
m= =
𝟓𝟎 𝟐𝟓

m = 3.92g. Ans:

QNo:14. how much water you have to add to 0.5kg Na 2SO4 in order to prepare a
5.0 % solution?
Data:
Mass of solute = 0.5 kg
= 0.5 𝐱 1000 = 500
V =?
𝐖𝐞𝐢𝐠𝐡𝐭
W% = 𝐱𝟏𝟎𝟎
𝐯𝐨𝐥𝐮𝐦𝐞
𝟓 𝟓𝟎𝟎
=
𝟏𝟎𝟎 𝐯𝐨𝐥𝐮𝐦𝐞

0.05 𝐱 volume = 500

 𝟓𝟎𝟎
Volume =
𝟎.𝟓
𝟓𝟎𝟎
Volume = = 10000 mL
𝟎.𝟎𝟓
𝟏𝟎𝟎𝟎𝟎
10000 mL into liters = = 10 L. Ans:
𝟏𝟎𝟎𝟎

QNo:15. Calculate Molarity of a 2ppm solution containing compound with molar

mass of 237g/mol?
Data:
Ppm = 2
Mm = 32g/mol
M =?
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
Ppm = 𝐱𝟏𝟎6
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧

Ppm = No of moles 𝐱 106

Ppm = 2 = No of moles 𝐱 106
𝟐
No of moles = = 2 𝐱10-6 moles
𝟏𝟎𝟎

M = 2 𝐱10-6 moles/Liter. Ans:

QNo:16. A 0.16 M solution of NaCl is called a normal saline solution, calculate

the mass of NaCl respectively required to prepare 100 mL and 1000 mL
of normal saline solution.
Data:
M1 = 0.16
V1 = 1000 mL
V2 = 1000 mL
M2 =?
 Mass of NaCl =?
M1V1 = M2V2
0.16 x 100 mL = M2 x 1000
𝟎.𝟏𝟔 𝐱 𝟏𝟎𝟎 𝟎.𝟏𝟔
M2 = = = 0.016 moles/Litre
𝟏𝟎𝟎𝟎 𝟏𝟎𝟎𝟎

𝐌𝟏 𝐱 𝐌𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐍𝐚𝐂𝐥 𝐱 𝐆𝐢𝐯𝐞𝐧 𝐯𝐨𝐥𝐮𝐦𝐞

mass of NaCl =
𝟏𝟎𝟎𝟎
𝟎.𝟏𝟔 𝐱 𝟓𝟖.𝟓 𝐱 𝟏𝟎𝟎 𝐦𝐋
mass of NaCl =
𝟏𝟎𝟎𝟎
𝟏𝟔 𝐱 𝟓𝟖.𝟓
mass of NaCl =
𝟏𝟎𝟎𝟎
𝟏𝟔 𝐱 𝟓𝟖𝟓
mass of NaCl = = 0.936g. Ans
𝟏𝟎𝟎𝟎𝟎

QNo:17. A solution is labeled 2.89ppm and is made with a solute that has molar
mass equal to 522g/mol what is molarity of solution?
Data:
Ppm = 2.89
Mass of salute = 522 g/mol
M =?
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐚𝐥𝐮𝐭𝐞
Ppm = 𝐱𝟏𝟎6
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝟓.𝟐𝟓
2.89 = 𝐱𝟏𝟎6
𝐕
𝟓𝟐𝟐 𝐱 𝟏𝟎𝟔
V=
𝟐.𝟖𝟗

V = 180.6 x 𝟏𝟎𝟔
V = 1.806 x 𝟏𝟎𝟖
𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
M=
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞
 Moles = 1508.5 x 106
Moles = 1.508 x 109
𝟏.𝟓𝟎𝟖 𝐱 𝟏𝟎𝟗
M= = 0.83 x103 = 8.3 x102 mol/sol
𝟏.𝟖𝟎𝟔 𝐱 𝟏𝟎𝟔

QNo:18. What is the ppm concentration of calcium ion in 0.050 M CaCO3?

Data:
0.050 M of CaCO3
ppm =?
ppm = 0.05 x10-6
ppm = 5x10-4. Ans:

QNo:19. how would you prepare 25ppm solution in HCl from 0.5M Stock
solution?
Data:
HCl = 36.5
Ppm= Mx1000xmolar mass
Ppm= 0.5x1000x36.5 =18250 ppm
C1V1 = C2V2
18250 x V1 = 25 ppm x 1000
𝟐𝟓𝟎𝟎𝟎
V1= = 1.36 mL. Ans:
𝟏𝟖𝟐𝟓𝟎

QNo:20. Determine the percent composition by mass of a 100 g salt solution

which contain 20 g salt?
Data:
Mass of solution = 100 g
 Mass of solute = 20 g
Formula:
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
w/w % =
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝟐𝟎
w/w = 𝐱𝟏𝟎𝟎
𝟏𝟎𝟎

w/w % = 20%. Ans:

QNo:21. How would you prepare 1000 mL of 70% v/v alcohol solution?
Data:
V= 1000 mL
v/v % = 70%
Volume of salute =?
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐚𝐥𝐮𝐭𝐞
v/v % = 𝐱𝟏𝟎𝟎
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐚𝐥𝐮𝐭𝐞
70 = 𝐱𝟏𝟎𝟎
𝟏𝟎𝟎𝟎
𝟕𝟎 𝐱 𝟏𝟎𝟎𝟎
= volume of solution
𝟏𝟎𝟎
𝟕𝟎 𝐱 𝟏𝟎𝟎𝟎
Volume of solution =
𝟏𝟎𝟎

Volume of solute = 700 mL. Ans

𝟕𝟎𝟎
70 = 𝐱𝟏𝟎𝟎
𝐯𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝟕𝟎𝟎 𝐱 𝟏𝟎𝟎
Volume of solution =
𝟕𝟎

Volume of solution = 1000 mL. Ans:

QNo:22. What is the molarity of solution made when water is added to 11g
CaCl2 to make 100ml of solution?
Data:
Given mass = 11g of CaCl2
Given volume = 100 mL
Molar Mass of CaCl2 = 111
Molarity =?
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
Molarity =
𝐌𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞
𝟏𝟏 𝟏𝟎𝟎𝟎
Molarity = 𝐱
𝟏𝟏𝟏 𝟏𝟎𝟎
𝟏𝟏𝟎
Molarity = = 0.990 mol/Liter. Ans:
𝟏𝟏𝟏

QNo:23. How many milliliter of 5.5 M NAOH are needed to prepare 300ml of 1.2
M NaOH?
Data:
M1= 5.5 of NaOH
V1 = 300 mL
M2 = 1.2 of NaOH
V2 =?
Solution:
M1 V1 = M 2V2
𝐌𝟏 𝐱 𝐕𝟏
V2 =
𝐌𝟐

𝟓.𝟓 𝐱 𝟑𝟎𝟎
V2 =
𝟏.𝟐
𝟓𝟓 𝐱 𝟕𝟓
V2 =
𝟑

V2 = 55 x25 = 1375 mL. Ans:

QNo:24. Calculate the number of moles of NaOH needed for 0.5M NaOH
aqueous solution?
Data:
M = 0.5
No of moles
V = 0.5 Liter
𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
M=
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞
𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
M = 0.5 =
𝟎.𝟓

No of moles = 0.25. Ans:

QNo:25. A solution has concentration of 1.25g/L. what is its

concentration in ppm?
Data:
Moles = 1.25 g/Liter
Ppm =?
Ppm = mole x 106
Ppm = 1.25 x106
Ppm = 1.25 x106. Ans:

QNo:26. A solution has a concentration of 0.5mg/ml what is the its concentration

in ppm?
Data:
No of moles = 0.5 mg/mL
Ppm =?
 𝟎.𝟓 𝐦𝐠
Ppm =
𝟏𝟎𝟎𝟎

Ppm = 0.5 𝐱 1000

Ppm = 5000 𝐱106
Ppm = 5x108 mg/L. Ans:

QNo:27. A solution has a concentration of 0.033g/kg what is its concentration in

ppm?
Data:
Concentration = 0.033g/kg
Ppm =?
𝟎.𝟎𝟑𝟑 𝐱 𝟏𝟎𝟎𝟎
Ppm =
𝐤𝐠

Ppm = 33x106
Ppm = 3.3x107
Ppm = 33 Ans

QNo:28. A solution has a concentration of 500ug/kg. what is concentration in

ppm?
Data:
Concentration = 5𝐱103 ug/kg
1ppm = 1ug/g
𝟓 𝐱𝟏𝟎𝟑 𝐮𝐠
Ppm = 𝐱𝟏𝟎𝟔
𝟏 𝐱𝟏𝟎𝟑

Ppm = 5
QNo:29. 1.50ml of an aqueous sodium chloride solution contain 0.0045g NaCl.
Calculate the concentration of solution in ppm?
Data:
V= 150 mL
Mass = 0.0045g
Ppm =?
𝟎.𝟎𝟎𝟒𝟓 𝐱 𝟏𝟎𝟎𝟎 𝟎.𝟎𝟎𝟒𝟓 𝐱 𝟏𝟎𝟎𝟎 𝐱 𝟏𝟎𝟎𝟎
Ppm = =
𝟏𝟓𝟎 𝟏𝟓𝟎
𝟒𝟓𝟎𝟎
Ppm =
𝟏𝟓𝟎

Ppm = 30
30 ppm. Ans:

QNo:30. What mass in milligram of KCl is present in 200ml of 1000ppm of KCl

solution?
Data:
1000 ppm
V = 200 mL
Mass =?
𝐦𝐠
Ppm =
𝐋𝐢𝐭𝐫𝐞

Ppm x liter = mg
𝟏𝟎𝟎𝟎 𝐱 𝟐𝟎𝟎
𝟏𝟎𝟎𝟎
Mass = 200 mg. Ans:
QNo:31. What volume of 0.5N stock required to prepare 250ml of normal
solution?
Data:
No: of moles = 0.5 M
Mass of solution = 250 mL
Volume =?
Solution:
𝐍𝐨:𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
Molarity =
𝐕𝐨𝐥𝐮𝐦𝐞 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧 𝐢𝐧 𝐥𝐢𝐭𝐞𝐫𝐬
𝟐𝟓𝟎
= = 0.25 liters
𝟏𝟎𝟎𝟎

V = no: of moles 𝐱 liters

V = 0.5 𝐱 0.25
V = 0.125. Ans:

QNo:32. What volume of 200 ppm in milliliters contains 0.10g of sucrose?

Data:
Ppm = 200
Mass of solute = 0.10g
V =?
= 0.10 x 1000 = 10.00
𝐦𝐠
Ppm =
𝐋𝐢𝐭𝐫𝐞
𝟏𝟎 𝐦𝐠
200 =
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞
𝟏𝟎
V= = 0.05 Litre. Ans:
𝟐𝟎𝟎
QNo:33. A solution contains Cu=2 ions at a concentration of 3𝐱10-4M what is the
Cu=2 concentration in ppm?
Data:
Concentration = 3 x10-4 M
Ppm =?
Ppm = 3x10-4 x106
Ppm = 3 x102 Ans:

QNo:34. The normal level of glucose in the blood usually average

100mg/100ml. Calculate average molarity of glucose in blood (Molar
Mass of Glucose C6H12O6 180g/mol)?
Data:
M =?
Molar mass = 180
Volume = 0.1 liter
Solution:
𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
M=
𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐯𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐞𝐫𝐬
𝟏 𝐱𝟏𝟎𝟑
M= = 0.0055 moles/L
𝟏𝟖𝟎 𝐱 𝟎.𝟏

Ppm = M 𝐱 molecular weight 𝐱 1000

𝐩𝐩𝐦
M=
𝐦𝐨𝐥𝐞𝐜𝐮𝐥𝐚𝐫 𝐰𝐞𝐢𝐠𝐡𝐭 𝐱 𝟏𝟎𝟎𝟎
𝟏𝟎𝟎𝟎
M= = 0.005 moles/L. Ans:
𝟏𝟖𝟎 𝐱 𝟏𝟎𝟎𝟎
QNo:35. How would you prepare 120ml of 0.10M of solution of Potassium
hydroxide in water?
Data:
Given mass = 120 mL
M= 0.10
Given mass =?
K2OH = 55
𝐌𝐨𝐥𝐚𝐫𝐢𝐭𝐲 𝐱 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐠𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
Given mass =
𝟏𝟎𝟎𝟎
𝟎.𝟏𝟎 𝐱 𝟓𝟓 𝐱 𝟏𝟐𝟎
Given mass =
𝟏𝟎𝟎𝟎

Given mass = 0.55 x 12

Given mass = 0.066

𝟎.𝟎𝟔𝟔 𝟏𝟎𝟎𝟎
M= 𝐱
𝟓𝟓 𝟏𝟐𝟎
𝟎.𝟔𝟔 𝐱 𝟏𝟎𝟎
M= = 𝟎. 𝟎𝟏
𝟓𝟓 𝐱 𝟏𝟐

M = 0.01: Ans.

QNo:36. A solution prepared by dissolving 66.0g of urea (NH2)2CO in 950g of

water had density of 1.018g/mol express the concentration of urea in
weight %, molarity, and molality?
Data:
66.0 g of urea (NH2)2Co in 950 g of water.
D = 1.018 g/L
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐞
a. w/w % = 𝐱𝟏𝟎𝟎
𝐌𝐚𝐬𝐬 𝐨𝐟 𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧
𝟔𝟔
w/w % = 𝐱𝟏𝟎𝟎
𝟏𝟎𝟏𝟔
 w/w % = 6.49 Ans

𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
b. M =
𝐕𝐨𝐥𝐮𝐦𝐞 𝐈𝐧 𝐋𝐢𝐭𝐫𝐞
𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
Moles =
𝐌𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬
𝟔𝟔
= = 1.1 moles
𝟔𝟎
𝐌
D=
𝐕
𝐌 𝟔𝟎
V= =
𝐃 𝟏.𝟎𝟖

V = 58.9 Liters
𝟏.𝟏
Molarity = = 0.0186 mol/Litre. Ans:
𝟓𝟖.𝟗

QNo37. Find the number of mg of NaCl per ml of a 0.25M NaCl solution?

Data:
Mass of solution = 0.25 M
Molar mass = 58.5
Mass =?
Solution:
𝐦 𝐠𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
=
𝟏 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐯𝐨𝐥𝐮𝐦𝐞

Given mass = 𝐌 𝐱 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐱 𝐯𝐨𝐥𝐮𝐦𝐞

Given mass = 𝟎. 𝟐𝟓 𝐱 𝟓𝟖. 𝟓 𝐱 𝟏 = 𝟏𝟒. 𝟔𝟐𝟓 𝐠
Given mass = 14.625 g
Convert into mg = 14.625 g = 14.625 𝐱103
Mass = 14.625 𝐱103. Ans:
QNo38. Find the No. of gram of Na2SO4 required to prepare 500 ml of 1.0M
solution?

Data:

Given volume = 1000 mL

Mass of Na2SO4 = 142

M = 0.1

𝐌 𝐱 𝐌𝐦 𝐱 𝐠𝐢𝐯𝐞𝐧 𝐕𝐨𝐥𝐮𝐦𝐞
Given Mass =
𝟏𝟎𝟎𝟎

𝟎.𝟏 𝐱 𝟏𝟒𝟐 𝐱 𝟏𝟎𝟎𝟎 𝐦𝐋

Given mass =
𝟏𝟎𝟎𝟎

Given mass = 14.2 g. Ans:

QNo39. Find the normality of the solution containing 5.277g/L K2Cr2O7 (FW is =
294.90) if Cr+6 is reduced to Cr+3?

Data:

No: of x = 3

m1 = 294.19

m2 = 5.267

Volume in liter = 1

Equivalent weight =?

Normality =?
 Solution:

𝐧𝐨 𝐨𝐟 𝐠𝐫𝐚𝐦 𝐞𝐪𝐮𝐢𝐯𝐚𝐥𝐞𝐧𝐭 𝐰𝐞𝐢𝐠𝐡𝐭

N=
𝐥𝐢𝐭𝐞𝐫

𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
N=
𝐞𝐪𝐮𝐢𝐯𝐚𝐥𝐞𝐧𝐭 𝐰𝐞𝐢𝐠𝐡𝐭 𝐱 𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐞𝐫

𝐠iven mass
Eq: Wt =
x

294.19
Eq: Wt = = 98
3

Given mass
N=
equivalent weight x Volume in liter

5.267
N=
92 x 1

N = 0.053. Ans:

QNo40. A 2.6g sample was analyzed and found to contain 3.6mg zinc find the
concentration of Zinc in ppm and ppb?

Data:

Mass of sample 2.6 g

Mass of solute 3.6 g

Ppm =?

Ppb =?
2.6
Ppm = x106
6.8

Ppm = 4.1 x105

Ppb = 4.1 x108. Ans:

QNo:41. Calculate molarity of a sugar solution of 2L if the solution contains of 2
moles of sugar?

Data:

V = 2L

No of moles = 2

M =?

No of moles
Molarity =
Volume in Litre

2
M = =1. Ans:
2

QNo:42. What is the molarity of solution containing 3moles of solute in 500ml of

solution?

Data:

M =?

No of moles = 3

Given volume = 500 mL

No of moles
M=
Volume in Litre

3
M=
500

3 x 1000
M=
500

30
M=
6

M = 5 mol/Liter. Ans:
QNo:43. How many moles of NaCl are needed to dissolve in water to make one
liter of 2.0M of solution?

Data:

Given volume = 1 liter

M=2

No of moles?

No of moles
M=
Volume in Litre

n = 2x1 = 2

No of moles = 2. Ans:

QNo:44. How many moles of Cu are needed to make 4.5 letter of a 1.5 M Cu
solution?

Data:

No of moles =?

Given volume = 4.5 L

M = 1.5 M

No of moles = MxV

No of moles = 1.5 x 4.5

No of moles = 6.75. Ans:

No:45. Calculate normality of 0.15 M of NaCl?

Data:

M = 0.15 of NaOH

Normality N = n x M

N = 1 x 0.15

N = 0.15. Ans:

N=M

QNo:46. How many waters you have to add to 250ml of a solution 0.025M to
obtain a concentration 0.125M?

Data:

M1 = 0.25

V1 = 250

M2 = 0.125

V2 =?

M2V1 = M2V2
1 1
x 250 = xV2
4 8

1
x250
V2 = 4
1
8

1
x250
V2 = 4
x8
⬚

250
V2 = x8
4
 V2 = 500 mL. Ans:

QNo:47. Calculate the grams of NaCl (MW = 58) contained in 500ml of a 0.25M
solution?

Data:

Given volume = 50 mL

M = 0.25

Mass of NaCl = 58

Given mass =?

Molarity x molar mass x given mass

Given mass =
1000

0.25 x 58 x 50
Given mass =
1000

Given mass = 0.725. Ans:

QNo:48. Calculate W/V Concentration of 0.5M solution of HCl (MW =36)?

Data:

w/v =?

M = 0.5

Mass of HCl = 36

mass of solute
w/v = x100
mass of solution
 mass of solute
w/v = x100
volume of solution

w/v = No of moles x100

w/v = 0.5 x 100

w/v = 50%

No of moles = M x V

No of moles = 0.5 x 1L

No of moles = 0.5. Ans:

QNo:49. The percentage purity of commercial HNO3 is 68% (w/w) and the
specific gravity of the solution is 1.51 g/ml. what is the molarity,
molality and normality of solution?

Data:

w/w = 68% of HNO3

Specific gravity = 1.51g/mL

M =?

m =?

N =?

68% of HNO3 mean 68 g

𝐆𝐢𝐯𝐞𝐧 𝐦𝐚𝐬𝐬
No of moles =
𝐌𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬

𝟔𝟖
No of moles =
𝟔𝟑
No of moles = 1.079

𝐍𝐨 𝐨𝐟 𝐦𝐨𝐥𝐞𝐬
M=
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞

𝟏.𝟎𝟕𝟗
M=
𝐕𝐨𝐥𝐮𝐦𝐞 𝐢𝐧 𝐥𝐢𝐭𝐫𝐞

𝐌
D=
𝐕

𝐌
V=
𝐃

𝟔𝟑
V= = 41.7
𝟏.𝟓𝟏

𝟏.𝟎𝟕𝟗
M= = 0.025. Ans:
𝟒𝟏.𝟕