1.

D
[1]

2. D
[1]

3. C
[1]

4. D
[1]

5. CH3CH(OH)CH2CH3;
Accept more detailed formula.
butan-2-ol;
Accept 2-butanol.
ECF for correct name of another C4 alcohol.

contains a chiral/asymmetric carbon atom/four different groups around one

carbon atom;
(plane of) plane-polarized light rotated in opposite directions; 4
[4]

6. butan-1-ol: butanal;
butanoic acid;
butan-2-ol: butanone;
2 methylpropan-2-ol: no oxidation;
Also accept correct structures. Where both name and structure
given structure must be correct and name largely correct.
[4]

7. A
[1]

1
8. B
[1]

9. B
[1]

10. propan-2-ol;
Accept 2-propanol.
oxidation/redox;
(potassium/sodium) dichromate(VI)/potassium manganate(VII);
 2
Accept just dichromate, permanganate, KMnO4 , Mn O4 , K2Cr2O7, Cr2 O7 .
(sulfuric) acid;
heat under reflux;
[5]

11. (a)
H H

C C ;

H H
Allow CH2=CH2.
a hydrocarbon that contains at least one C=C (or CC)/carbon-carbon
double bond (or triple bond)/carbon to carbon multiple bond; 2
Do not accept just “double bond”.

(b) C2H4 + H2O  C2H5OH;

addition/hydration reaction; 2

(c) heat under reflux;

EITHER
2– +
potassium dichromate(VI)/K2Cr2O7/Cr2O7 and acidified/H ;
orange to green;
OR
–
potassium permanganate/manganate(VII)/KMnO4/MnO4 and
+;
acidified/H
purple to colourless;
Penalize wrong oxidation state, but not missing oxidation state.
ethanoic acid; 4

2
 (d) CH3COOH + C2H5OH  CH3COOCH2CH3 + H2O;
Accept CH3COOC2H5
sulfuric acid/H2SO4/(ortho)phosphoric acid/H3PO4;
ethyl ethanoate;
solvent/flavouring/perfumes/plasticizers;. 4
[12]

12. B
[1]

13. (i)
O

CH 3 C
O C H 2C H 2C H 3 / C H 3C O O C H 2C H 2C H 3 ;
1
(ii) propan-1-ol/1-propanol;
CH3CH2CH2OH;
Accept full structural formula showing all bonds and atoms but
no mark if H atoms missing
ethanoic acid/acetic acid;
CH3COOH; 4
Accept full structural formula penalize missing Hs only once
ECF from incorrect ester in (i) above
[5]

14. (i)
H

CH 3 C CH 3 / C H 3 C H (O H )C H 3 ;

O H
1
Allow bond to HO rather than OH or halfway between the two
(ii) secondary; 1
(iii) CH3COCH3/propanone/acetone; 1
Allow ECF from a different alcohol drawn in (i)
[3]

15. D
[1]

3
16. CH3OH + HCOOH  HCOOCH3 + H2O
Award [1] for both reactants and [1] for both products (accept
C2H4O2).

methyl methanoate; 3
[3]