Material Safety Data Sheet (MSDS) – Gypsum

HAZARDOUS MATERIALS RATING FOR DRILLING FLUID SYSTEM

Health 1 (Slight)
Flammability 0 (Minimal)
Physical Hazard 0 (Minimal)

GYPSUM
Section 1 – CHEMICAL PRODUCT AND COMPANY INFORMATION
Product Name Gypsum
Synonyms Calcium Sulfate
Chemical Name/Formula Calcium Sulfate, CaSO4.2H2O
Product Function Source of Calcium Ions for Water-Based Fluids
Manufacturer/Source Various
Supplier Egyptian Mud Engineering & Chemicals Co.
Plot No. 196, 2nd City Center
Fifth Settlement, New Cairo, 11835
Cairo, Egypt
Company Phone Number +20 2 26732900
Company Fax Number +20 2 26732920

Section 2 – HAZARD IDENTIFICATION

Main Hazards Nuisance dust. No adverse health effects are expected with normal use
but the product may contain small amounts of crystalline silica, which is
associated with elevated rates of lung cancer following long-term
inhalation of dust particles.
Eyes Dust particles may be an irritant.
Skin Dust particles may be an irritant.
Inhalation Dust particles may be an irritant. Product may contain traces of
crystalline silica quartz, which is associated with an increased risk of lung
cancer.
Ingestion Dust particles may be an irritant. No adverse health effects are expected
if accidentally swallowed in small amounts.

Section 3 – COMPOSITION AND INFORMATION ON INGREDIENTS

The product is an irritant and may contain traces of crystalline silica, which is classified as hazardous. The
Chemical Abstracts Service has assigned the following CAS Registry Number, which is a registered trademark
of the American Chemical Society, to this chemical:
Chemical Name CAS Number % by Weight
Calcium Sulfate Dihydrate 10101–41–4 100%
Crystalline Silica Quartz 14808–60–7 Trace

Section 4 – FIRST AID PROCEDURES

Eyes Immediately flush eyes with saline fluid or clean water for at least 15
minutes, removing contact lenses and lifting upper and lower eyelids to
ensure thorough cleansing. Get medical attention if symptoms persist or
develop.

Tel: +20 (2) 2673 2900

Head Office: Plot No. 196, 2nd City Center, Fifth Settlement, New Cairo, 11835, Egypt www.emec.com.eg
Material Safety Data Sheet (MSDS) – Gypsum

Skin Wash affected area with water. Get medical attention if symptoms
persist or develop.
Inhalation Remove casualty to fresh air. Give artificial respiration if casualty is not
breathing, or give oxygen if breathing is difficult. Get medical attention if
symptoms persist or develop.
Ingestion Do not induce vomiting. Rinse mouth out with clean water and give
casualty plenty of water to drink as this will dilute chemical strength in
the stomach. Get medical attention if symptoms persist or develop.
Additional Comments A copy of this MSDS should be given to the person providing medical
attention. Alkaline chemicals may continue to cause damage after
exposure, so treat casualty according to symptoms and monitor closely
until fully recovered.

Section 5 – FIRE FIGHTING MEASURES

Flammability Not flammable.
Flash Point Not flammbale.
Combustion Hazards Calcium Oxide and Sulfur Oxides.
Explosion Hazards Minimal, but dust particles of any materials at critical concentrations can
be sensitive to ignition by electrostatic discharge.
HMIS Rating (0 to 4) Health = 1 Flammability = 0 Reactivity = 0
NFPA Rating (0 to 4) Health = 1 Flammability = 0 Reactivity = 0
Fire-Fighting Procedures Raise the alarm and then tackle the fire if safe to do so.
Extinguishing Media Material is not combustible. Use fire-fighting equipment that is suitable
for the surrounding fire.
Personal Protection Standard fire-fighting protective equipment and approved self-contained
breathing apparatus, if required.
Additional Comments None.

Section 6 – ACCIDENTAL RELEASE MEASURES

Personal Precautions Wear appropriate personal protective equipment as detailed in Section 8.
Avoid creating and breathing dust particles.
Environmental Precautions Product is not hazardous to the environment.
Spillages If product cannot be reclaimed then sweep up and place in a suitable
waste container for disposal in accordance with regional procedures and
regulations. Flush away any residual spillage material with water.

Section 7 – HANDLING AND STORAGE

Handling Wear standard personal protective equipment and ensure area is well-
ventilated. Avoid creating and inhaling dust particles.
Storage Store in a dry location and ensure that packaging is maintained in
accordance with good warehousing practices.

Section 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Controls Use in a well-ventilated area and minimize airborne dust. An eye-wash
station and safety shower should be located in the mixing and storage
areas.
Eye and Face Protection Standard safety glasses are usually adequate. Wear safety goggles if dust
particles are a nuisance.

Tel: +20 (2) 2673 2900

Head Office: Plot No. 196, 2nd City Center, Fifth Settlement, New Cairo, 11835, Egypt www.emec.com.eg
Material Safety Data Sheet (MSDS) – Gypsum

Hand Protection Standard work gloves are usually adequate. Wear chemical-resistant
gloves if additional protection is required.
Body Protection Standard coveralls are usually adequate. Wear a chemical-resistant apron
or chemical over-suit if additional protection is required.
Respiratory Protection A standard dust mask is usually adequate. Use an approved respirator
fitted with a dust filter for high dust levels or if dust is a nuisance.
Additional Comments Long-term inhalation of dust particles can cause chronic lung problems
and diseases.

Section 9 – PHYSICAL AND CHEMICAL PROPERTIES

Appearance Powder
Color Light brown
Odor Mild
pH Not determined
Flash Point (°C) Not flammable
Vapor Pressure Not applicable
Vapor Density Not applicable
Boiling Point Not determined
Melting Point Not determined
Solubility Partially soluble in water
Specific Gravity 2.3
Pour Point Not applicable

Section 10 – STABILITY AND REACTIVITY

Chemical Stability Stable.
Conditions to Avoid Product is hygroscopic so avoid exposure to moisture during storage.
Chemicals to Avoid Avoid contact with acids and oxidizing agents.
Hazardous Decomposition None known.
Hazardous Polymerization Not applicable.

Section 11 – TOXICOLOGICAL INFORMATION

Toxicity The product may contain small amounts of respirable crystalline silica,
which may cause lung damage (silicosis) as well as being associated with
elevated rates of lung cancer following long-term inhalation of dust
particles.
Acute Toxicity Data LD50 (Oral; Rat) 6,450 mg/kg
Carcinogenicity The product may contain small amounts of respirable crystalline silica,
which is associated with elevated rates of lung cancer according to the
following bodies:
IARC (International Agency for Research on Cancer)
NTP (National Toxicology Program)
OSHA (Occupational Safety and Health Administration)

Tel: +20 (2) 2673 2900

Head Office: Plot No. 196, 2nd City Center, Fifth Settlement, New Cairo, 11835, Egypt www.emec.com.eg
Material Safety Data Sheet (MSDS) – Gypsum

Reproductive Effects Not known to have reproductive effects on humans.

Additional Comments Crystalline silica quartz is only hazardous to health when it is present in
the form of respirable particles.

Section 12 – ECOLOGICAL INFORMATION

Mobility Airborne dust.
Biodegradability No data available.
Persistence No data available.
Bio-Accumulation No evidence of bio-accumulation.
Eco-Toxicity Product is not an environmental hazard.

Section 13 – DISPOSAL CONSIDERATIONS

Product Disposal Dispose in accordance with regional procedures and regulations.
Packaging Disposal Dispose in accordance with regional procedures and regulations.

Section 14 – TRANSPORT INFORMATION

The product is not classified as a hazardous material by leading international transportation regulatory
bodies for road, rail, sea and air (i.e. US DOT, ARD/RID, IMDG, IATA, etc.) and is therefore not subject to
international regulations and restrictions covering the transportation of dangerous goods.
Shipping Name Description Reference Hazard Class Packing Group
– – – – –

Section 15 – REGULATORY INFORMATION

European Labeling in Accordance with EC Directives:
Hazard Statements Causes eye irritation (H320)
May be harmful if inhaled (H333)
Precautionary Statements Protect from moisture (P232)
Avoid breathing dust (P261)
Store in a dry place (P402)

Section 16 – OTHER INFORMATION

MSDS Revision Date November 2018.
Revision No. 3
The NFPA Rating in Section 5 is from the US-based National Fire Protection Association.
The HMIS Rating in Section 5 is from the US-based Hazardous Materials Identification System.

The information contained in this MSDS provides guidelines for safe storage, handling and use of the designated
product, and is based on data that is believed to be accurate. EMEC does not accept liability for any loss or damage
that may result from the use of information contained in this MSDS under conditions beyond our control, and this
includes any failure to comply with regional rules and regulations concerning the disposal of this product.

Tel: +20 (2) 2673 2900

Head Office: Plot No. 196, 2nd City Center, Fifth Settlement, New Cairo, 11835, Egypt www.emec.com.eg