LATIHAN PDPR KIMIA SPM 2021 PADA 21 APRIL

1 Diagram 11 shows the set up of the apparatus of an experiment to investigate the transfer of
electrons at a distance. After a few minutes the brown solution of bromine water turns to
colourless.
Rajah11 menunjukkan susunan radas eksperimen bagi mengkaji pemindahan elekron pada satu
jarak. Selepas beberapa minit, warna perang larutan air bromine bertukar kepada tanpa warna.

Carbon
Karbon Carbon
Karbon

Iron(II) sulphate Bromine water

solution Air bromin
Larutan ferum(II) sulfat
Dilute sulphuric acid
Asid sulfuric cair

Diagram /Rajah 11

(a) State the colour change of iron(II) sulphate solution.

Nyatakan perubahan warna bagi larutan ferum(II) sulfat.

..................................................................................................................................
[1 mark]
(b) Write the half equation for the reaction in (5)(a).
Tulis persamaan setengah bagi tindakbalas di (5)(a).

……………………………………………………………………….......................
[1 mark]
(c) State the change in oxidation number of iron.
Nyatakan perubahan nombor pengoksidaan bagi ferum.

………………………………………………………………………………………
[1 mark]
(d) Referring to the reaction that takes place in bromine water.
Merujuk kepada tindakbalas yang berlaku pada air bromine.

(i) State the type of reaction that occurs.

Nyatakan jenis tindakbalas yang berlaku.

……………………………………………………………………………
[1 mark]
(ii) Write the half equation for the reaction .

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 Tulis persamaan setengah bagi tindakbalas tersebut.

.....................................................................................................................
[1 mark]
(iii) What is the function of bromine water?
Apakah fungsi air bromine ?

……………………………………………………………………………..
[1 mark]

(iv) Name another reagent that is not a halogen that can

replace bromine water ?
Namakan reagan lain yang bukan halogen yang boleh menggantikan air bromin

…………………………………………………………………………….
[1 mark]
(e) Show the direction of the electron flows in the diagram 11.
Tunjukkan arah pengaliran electron pada diagram 11.
[1 mark]
(f) What is the function of dilute sulphuric acid?
Apakah fungsi asid sulfurik cair?

…………………………………………………………………………………….
[1 mark]
(g) State the observation when sulphuric acid is replaced with ethanol in the experiment
Nyatakan pemerhatian apabila asid sulfurik digantikan dengan etanol dalam eksperimen
tersebut.

……………………………………………………………………………………….
[1 mark]

2. Diagram 5 shows the set-up of apparatus to investigate the electrolysis of 0.0001 mol dm─3 of
hydrochloric acid and 1.0 mol dm─3 of potassium iodide using carbon electrodes.

Rajah 5 menunjukkan susunan radas untuk mengkaji elektrolisis 0.0001 mol dm─3 hidroklorik asid
dan 1.0 mol dm─3 kalium iodida dengan menggunakan elektrod karbon.

Electrode X Electrode Y
[Elektrod X] [Elektrod Y]
Electrode Z
Electrode W [Elektrod Z]
[Elektrod W

Hydrochloric acid Potassium iodide solution

[asid hidroklorik] [Larutan kalium iodida]

Diagram /Rajah 5

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(a) (i) Identify all the electrodes which serve as anode and cathode.
Kenalpastikan semua elektrod yang berfungsi sebagai anod dan katod
Anode [anod]:....................................................................................................................

Cathode [katod]:................................................................................................................
[2 marks]
(ii) Name the product that is formed at electrode W.
Namakan hasil yang terbentuk pada elektrod W.

……………………………………………...………………………………………
[1 mark]
(iii) Write the half equation for the reaction that occurs at electrode W.
Tuliskan setengah persamaan bagi tindak balas yang berlaku di elektrod W.

....................................................................................................................................
[ 1 mark]
(b) (i) State the observation at electrode Y.
Nyatakan pemerhatian pada elektrod Y.

……………………………………………………………………………………… ..
[1mark ]
(ii) Name the product formed in b(i)
Namakan hasil yang terbentuk di b(i)

........................................................................................................................................
[ 1 mark ]

(iii) Suggest a test to confirm the product in b(ii).

Cadangkan satu ujian untuk mengesahkan hasil yang terbentuk di b(ii).

………………………...……………………………………………………………

………………….……………………………………………………………………
[2 marks]
─3
(c) In a separate experiment, the 0.0001 mol dm of hydrochloric acid is replaced with 1.0
moldm─3 of hydrochloric acid and electrolysis is carried out.
Dalam experimen yang berlainan, asid hidroklorik yang berkepekatan 0.0001 mol dm─3
digantikan dengan asid hidroklorik yang berkepekatan 1.0 mol dm─3 dan elektrolisis
dijalankan..

(i) State the product that will form at electrode W.

Nyatakan hasil yang akan terbentuk pada elektrod W.

………………………...……………………………………………………………
[1 mark]
(ii) Explain your answer in c(i).
Terangkan jawapan anda dalam c(i).

............................................................................................................................................

.……….………………………………………………………...…………………………

3
 [ 1 mark ]

3 Diagram 3 shows the set-up of apparatus of a voltaic cell.

Rajah 3 menunjukkan susunan radas satu sel kimia.

Zinc
Plate /
Kepingan Copper plate / Kepingan kuprum
zink
Copper (II) nitrate solution /
Larutan kuprum (II) nitrat

DIAGRAM / RAJAH 3.1

Based on Diagram 3 , answer the following questions.

Berdasarkan Rajah 3, jawab soalan- soalan berikut:

(a) What is the energy change that occurs in the voltaic cell?
Apakah perubahan tenaga yang berlaku dalam sel kimia?

..................................................................................................................................
[1 mark]
(b) Write the formula of all ions in copper (II) sulphate solution.
Tuliskan formula semua ion dalam larutan kuprum (II) sulfat.

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[1 mark]
(c) (i) Name the negative terminal of the voltaic cell.
Namakan terminal negatif bagi sel kimia.

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[1 mark]

(ii) Explain your answer in (b)(i).

Terangkan jawapan anda dalam (b)(i).

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[1 mark]

(d) (i) State one observation at copper plate.

Nyatakan satu pemerhatian pada kepingan kuprum.

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 .....................................................................................................................
[1 mark]

(ii) Write the half equation for the reaction occur at the copper plate.
Tuliskan persamaan setengah bagi tindak balas yang berlaku pada kepingan
kuprum.

.....................................................................................................................
[1 mark]

(e) What is the colour change of the copper(II)sulphate solution? Explain your answer.
Apakah perubahan warna larutan kuprum (II) sulfat ? Jelaskan jawapan anda.

..................................................................................................................................

..................................................................................................................................
[2 marks]

(f) Another experiment is carried out by replacing the zinc plate with P , Q and R metals.
Table 3.2 shows the results.
Eksperimen lain dijalankan bagi menggantikan kepingan zink dengan logam P, Q dan R.
Jadual 3.2 menunjukkan keputusannya.

Pair of metal/ Voltage/ Negative terminal/

Pasangan logam Voltan (V) Terminal negative
P/Cu 2.7 P

Q/Cu 2.0 Q

R/Cu 0.5 R

TABLE/ JADUAL 3.2

(i) Arrange P, Q, R and Cu metal in accending order of electropositivity.

Susunkan logam P, Q, R dan Cu mengikut tertib menaik keelektropositifan.

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[1 mark]
(ii) Predict the voltage for pair of Q/R.
Ramalkan nilai voltan bagi pasangan Q/R

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[1 mark]

2 (a) The following is the metal displacement reaction.

Berikut adalah tindak balas penyesaran logam

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 X(s) + CuSO4 (aq) XSO4 (aq) + Cu(s)

Suggest metal X for the reaction and explain the redox reaction in terms of the transfer
of electrons that is occurred.
Cadangkan logam X untuk tindak balas tersebut dan terangkan tindak balas redok yang berlaku
dari aspek pemindahan elektron.
[7 marks]

(b) By using a suitable example and the chemical equation, explain why the neutralization
reaction is not a redox reaction.
Dengan menggunakan contoh dan persamaan kimia yang sesuai, terangkan mengapa
tindak balas peneutralan bukan satu tindak balas redok.
[3 marks]

(c) Diagram 2 shows a few types of the oxidizing agents and reducing agents.
Rajah 2 menunjukkan beberapa jenis agen pengoksidaan dan agen penurunan

Oxidising agent Reducing agent

Agen pengoksidaan Agen penurunan
Acidify potassium manganat(VII) solution, Iron(II) Sulphate solution,
Larutan Kalium Manganat(VII) berasid Larutan Ferum (II) sulfat
KMnO4 FeSO4
Acidify potassium dichromate(VI) solution, Potassium iodide solution,
Larutan kalium dikromat (VI) berasid Larutan kalium iodide,
K2Cr2O7 KI
Chlorine water Potassium bromide
Air Klorin Kalium bromide
Cl2 KBr
Bromine water Hydrogen peroxide
Air bromine Hidrogen peroksida
Br2 H2O2

Diagram /Rajah 2

The electric current is produced by the transfer of electron at a distance from a reducing
agent to an oxidizing agent in a chemical reaction
Arus elektrik terhasil melalui pemindahan electron pada suatu jarak daripada satu agen
penurunan kepada satu agen pengoksiaan dalam satu tindak balas kimia

By using any oxidizing agent and reducing agent given, describe an experiment to prove the
statement above.
Dengan menggunakan mana-mana agen pengoksidaan dan agen penurunan, huraikan
satu eksperimen untuk membuktikan pernyataan di atas.

Your description must include the following;

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 Penerangan anda hendaklah mengandungi perkara-perkara berikut

o set up of the apparatus

susunan radas
o procedure of the experiment
prosedur eksperimen
o observations
semua pemerhatian
o ionic equations
persamaan ion

[10 marks]

9 (a) Dilute ethanoic acid (vinegar) is electrolysed using carbon electrodes. What is produced at the
cathode? Write a half-equation for the reaction.
Elektrolisis asid etanoik cair telah dijalankan menggunakan elektrod –elektrod karbon.
Apakah yang terhasil di katod. Tuliskan setengah persamaan bagi tindak balas tersebut.
[2 marks]

(b) Diagram 9 shows two types of cells.

Rajah 9 menunjukkan dua jenis sel.

Copper
Magnesium Copper
Copper(II)
Magnesium Copper(II) nitrate
chloride solution
nitrate
solution
solution
Cell A Cell B
DIAGRAM 9

Compare and contrast cell A and cell B. Include in your answer the observations and half
equations for the reactions at the electrodes in both cells.
Banding dan bezakan sel A dan sel B. Sertakan dalam jawapan anda pemerhatian dan
setengah persamaan bagi tindakbalas di elektrod-elektrod kedua-dua sel.
[8 marks]

(c) A student intends to electroplate an iron ring with silver.

Seorang pelajar ingin menyadur cincin besi dengan argentum.

(i) State two purposes of electroplating the iron ring.

Nyatakan dua tujuan menyadur cincin besi tersebut.

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 [2 marks]

(ii) Design a laboratory experiment to electroplate the iron ring.

Rancangkan satu eksperimen makmal untuk menyadur cincin besi tersebut.

Your answer should consist of the following

• Procedures of the experiment.
• A labelled diagram showing the set up of apparatus.
• Half equations for the reactions at both electrodes.
• Observations at both electrodes.

Jawapan anda hendaklah termasuk perkara-perkara berikut:

• Langkah-langkah eksperimen.
• Gambar rajah susunan radas berlabel.
• Setengah persamaan bagi tindak balas di kedua-dua elektrod.
• Pemerhatian di kedua-dua elektrod.
[8 marks]