Expt No.01. PageNo Oa.

Date: a1Ot oR

ESTIMATI1ON E FERROUS SULPHATE LEe*).

AIM disselued
Te estimat he amaunt st fenous ulphati
slution velunebically. Fet hb
750 m of qeun unkhown

wih stardardhslutton ot eneus ammanlum

you a qitn a

bulphath CFAS) of nimali o102N and petalum penanganal

bolution a link belutlen.

PRINCLPLE:
huse tihattie Fe lns lfhm enus Aalb) a u
Buing ,

nidbd Mnoz los and'

to Mno lom lum Mn*) z udueed
to Mn2* lon.
Onidatom:e2t 5Fe"t5e
Reduction: Mno t H t 5e
celourlers )
CPink)

Uuall ALaclion A KFe* tMno +8ht Sfe3* +Mn?* +4 H20.

SHORT PROCEDURE

S NO Content Teratin -1 Titatan -I

1: Buette soluin kmny
pipate salultm20m kandasFAS:20ml unkhnn Fesa,
3 Add th_be added 20mloaN Ha So (apps)20ml AN Hs0, Lappta)
Jeespsaaa Jab tempesatas Lab tenpesatus
Indicate- Ssel4- indlatel LkMno) Se-indlcate (kmno,
End pointE Appeasana pemahunt. Appearanu pemanunt
pala pirk colua. pal pink Letasa.
. Eguialent ueht Feso4 21-
TP
 TITRATION -
(Standarl FAs).
V
(LTn KMno)

Buutte cadings. COmcsndant value

valume f
Tnltlal Flnal Cvolume akmno)
SND Standard FAS
mL) Cml)
Cml Cm
1
18 6
18 6

20 8 6

3 18 8

CALCULATION
Volume ot kMno Clik) selutien (v) -186 nml.
selutionNI) =
? N.
Notmaliy kMno [LEnk)
ot standaud FAS Solutibn (Va) =
20 m. =
velume
N.
Noumality o tondard FAS spluticn (Na) =
0.1lo2

ACcORDING T2 NORMALIIY EAVA TION:

V XN| = Va xNa

N = axN
V 8 6
Notmalty t kMno4 {Link) Bolutiion (N) = 20 X0:1102 N.
8 6
N O 1)84 N.
Expt. No.
Date Page No. 04.

PROCEDURE

TITRA TION=1.
CLink mno) Vs CStandard FAs).
Bunette à uashed wih wata, Ainbed with RMnO4
Solution and fled wit ame KMno4 solultio up t e 2e0
hark Exactly 2o ml ot standard FAS solutton Reted put into
he clean, washed cenical Hask. T his FAS selutien, apptoximately
Aoml of aN Sulphualc acl s added. 1his metine 2 ittatid
agalhst kMno Lk seuton pom tu burette kMno4 added dap
se til he appeaiana pemanent pale phk telna. Buutte
nadlng 2 netrd, and he sama pnecadun 2 Apeatrd to get
cOceRdant yalusr

**
 TLTRATION-7
(Link Feso) vs (unkn ewn Fe 50 Sstion)

Burette ALadigs Conesrdant valu

velume
SNO Vnkneum Fes04
Enltal Final Cvelume ot kmno,)
Cm) Cml) tml) Cml)

20 16 5

6 5
16.5
20

16-7
3 20

EALCULATION
solutien V 20 ml.
Velwme t Unknu Feso
? N.
Feso4 Soluuton N
=

thkncun
Noamalty ot
Solulie Va 6 5 ml.
Valunu okMno4 Enk)

dik) 8slutien N2 0. u84N.

Notmali kMnoy

AceORDING T2 NDRMALTY EAUATION

=V xN= Va ANa2
N Va XNa
V
N
&-5Xou34 N
20
The ngimalily ot unknown Fesa Sstutton =0-0977 N.
Expt. No. Page No. 06
Date

TITRATLON -7
Cunknon FesO4 ) Vs (Link KMnO
Bnettes waud wit watea, alnnd wth kMno4
to t u
soluton andEed win same kmn04 8slution up
unknoon olutin splpetted
Feso
mak: Exactly aDml
Concleal Feso Belutlon
lask.To this
ut intsthe clean, warhed
acld s merturu
added Thismeuu
a e m aAaA Sulphurl
appioulmatly
ainst knMno4 LEnk Astution faam the buette
ttated ag
till ta appearanu ot pexmanent pale
kMno4 added drop wise
and Ha am
celoua. Buautte ading 3 neted
puk
Loncordant values
epeatrd to t
WELGHT ALLULA TION

The amount ot Feso = (Nomality) x

disoued n 1 lt ot the selutbn Ceaulvalent wuhat).

The amount ot fesoy disrolued pemalayxeguialent weEghtx 750

in 150ml st te selution o 00

o-0977X 218X750
N Yx a78 x3

20310459.
Expt. No
Date Page No. 03

REPARTI
dinelted a 150 ml ot the
te
he amount o Feso4
Saluton-20.3104q
Expt. No O2
Date 23 0 aoaR
Page No. 10

ESTIMATION GE FERROUS AMMONLUM

SULPHATE CEAS)
AIM
T asttmat the ameunt
disseed oeenous ammenium sulphat
in 15oo ml of the
qin unknwn (FRS)
soutionm
foi this
guen wim a tandard selutien velunmetically
ynu a
ot eneus
ulphali Cfeso) hemality o 10a N and
solutin as lënk selutim.
patamium peunanganat

PRINCIPLE:
ridatiom 5feR+ 5fe3t
:
+5e
Reductiem:5 fea* + Mn0 +8Ht 6Fe 3t +mn* +4Ha0
Sverall Lartien : 5Fe** + MnD +3Ht 5Fe3t tMnt thka0.

SHORT PROLEDURE

3.NO ContentE Ttralton TLatien -T

1: Btt splutin kMn kiana
2. lpjat Beluttnm aeml standal es, 2aml et unkrum £As
2lo aN_H2s04 appina)
TesRaatire lah temperatusa lab_tepezatiu

Tndlats Self-indiats2 Lkmno4) Self-Pndatei tkmno)

G Erd _point Appearana f plnanat| Appealana ot peamarunt
pale plnk ssdaa pale pisk Leles
LEquzalent_ueght EAS 3 4 -
 TUTRATLON -T
(Link kM noa) Vs Cstandard tFesa).

Velune Brutte Aeadis CoALstdant alue

SNO
Standard Fesoum)Lnitial Cml) Final Cm vslune atkmnou) tmt\

1 20 6:3

EALCULA TION:

Velunt et KMno4 ltink) setution V, 6ml.

Nmalt KMno4 lönk) solud N ?N.
velume Standard Fesoy soluion V*2o ml.
Nomality et Fes0 Standard) sotuton Na = 0:l0à+ N

ALCORDING TA NARNOALLTYy EAUATION:

AccoRding noimaliy equaten =V, XN =Va xNg .
N
Va XNa
V
Nlotmaliy otkMn04 Clhk) soluttn (N) 20 X0-1024 N =

6.4
y 0 1248N
xpt. No.
Page No. 1a
ate

PROCEDURE:

TTRATlON -2.
LLink kMno4 )Vs CStandard Fes04).
Brette i3 wahed wi wata, alnsed wim KMnd 8olutien and
with sme Feso Beluton up to tha zep mak. Exacty om
yiled
Standasd Rso4 ppeted ut ith tha lan, uashed cerica lask|
Beluion

hs belulion, approximatly aom aN Aulphui aid added.

T
Link Selulten pom the buntte.
This m2alute i s htatad against kMno4
added drep wi tll the appearanu pemanent pale pink
KMho4 s
ase htud, te Bame paeceduze » kepeatrd to
cgleui. Bwette Beaaling
get cencotdant alues
 ZITRAT/ONL

Vs (Unknown FAs).
(Lak kmno4)

Buaete Acadings Concerdaut

S ND
Valume ot
Unknonom FASDhetal tmt) Fnallm) Cvotuma valua
Chm
I13
1

7.3 I7.3

3 20

CALLULATION
Velume Unknown FASsoluthion V 0 ml.
NGmaliy tUnkhouwn FASSolutton N N.
Vølum t kMnO lnk) solutn Va 7 3 ml.
NAmalila KMO4 link) souttm Na-o-1a48 N.

AccORDING T2 AlORMALLTY CAUATION:

Accetding to nmaliy equalion =
Vj xN =V2 XNg.
N Xx Na
V
N 73Xo248 N.
he
nsmalit Unkhon FAS 20
Soluution 0.I 0 79 N
Expt. No.
Date
Page No. 1t

TITRATIOA -
lUnkrown FAS) Vs lLhk kMno4)
Buuette washad wit uwatir, ainsl
with kmno4 olut
and led with same
kMn04selultlm
aoml nknown EAS solutin 2
tt he
the zero hnask Exactls
up
up .

plpetted eutintó the clean,

washed2 conicalHark. T tho FAS Botutlon approlmately Roml o
aN Sulphurie ald 3 added. This mertie s titatid agalnst
kmno nk 3olulien homthe buette. kMnoy B added dsep wise
b heappearane ot pelmanunt pale pink csleur Buette Aadina
nsted and the kame pAbcedue s aapeattd to get _conmeidont
values.
 CALCULA TION:
LELGHI

The amount ot FAS disolued (Nomality) x

in 1 t ohesolaton (eguivalent wight).
The amouwrt ot FAS disound Nomalty 1equANalent weaht x1500
n 1500ml ot the solutin 1000

X 392 X150Q 0OT1x 392 xis0e

l000
63 9a
 REPORTI:

Thepmeunt ot FAS dssowed n 1500 ml t the

the
sslutiey63:44g
Expt No. O3.
Date 30 Ol0A1
Page No. 8

EsTIMATION F
DXALIC AcID
AlM
TO estimat tha ameunt st oxalie ald disslved n as0 ml
the given unknour 8olutien obt
standard Selutton
volumetltally FoR His you ase2 gen with a
ot HcLBstution ot
uydrocide belutiom nsmalit4 0.1010 N and sodium
as lnk selution.

PRINCIPLE:
Neutalizaton ot Sodlum hydaolde ty
indicati t end
Hcl s gen belnw. T
point, phundphthalein uwrd as an
ndicatel.
NaDH Hcl Nacl &H20.
Neubializatin ofSoetum ydrmulhe y oxale acld a gln
below. T ndicati h end pelnt, phenslphthalein é wd as a
ndecat
la OH t lcooH) l c o o Na)a taRa0
Conalle arlel)(Socdium onalatu)

SHORT PROCEDURE:

S:NO Content Tratiom- Tetratin T

1 Buatte selulinm HeLCStandand_eltion) bralic acld lunkrmum aluttom)
2 Plpett elutt JaOml NAOH Lk seluton_ AomlNa.OH_tink 3olutim
3 Tnpetatus Lab tempazatse Lab temapeaatiuas
Thdeate. phanetghtkaliu phasedphthali
5. Ehd potnt Lisappeaance ot ibappeaane of
pimk tadaua- pink Celna
LI:Euixalentwslght ali aidsb3:
 TITRA TION-T
(Standard Hcu) Vs (lhk Na Or).

Velume s Burutte cadings Conerdant value

S NO
NadH (ml) Tnltial (ml) Fhal (ml) Calume ot 3td
Hct
ml)

1 20 64

16.5
2 165

20 I6 5

CALLULA TION:

Volume ot Naoh (link) solution 1V ao ml

Nomality NaOH lnk) Bolutien Ni ? N.
Velume ottandard Hct soution V2l6 5 ml.
Noamaldy standd Hcl solutin Na 0-loO N

ACCORDING T2 ALORMALLTY EAUATIDN

ACctding tonomali eualien =
Vi xN= V^x Na
N, 6:5 X.0 l0 1O N.

N =
0-0 833 N.

Nemality NaOH (hk) solution N= 0-8 33 .

Expt. No.
Page No. a0
Date

PROLEURE:

TITRATION-2
Lstandaad Het) Vs link NaoH).
Buete 2s washud u h unter , sensed with Hl solutien ana

Hcl 6olution mark. Exacty 2Dml

Aled wfth
Hlled same up t the zero

This
NaOH pipetted oul into the claan, wvashed conal lask.
Aeulion a t 3hops o phtnalphthalein idiatet 3addid and
Mbated againt Hcd solultn hom the buetteHcl added dsq wie.
Bmtte Aaadin is netd
and
l l the pisk Colou dbappraas completuly.
Anpeatd t get Lrcsidaut yalues.
the same piocedure
 TURATION -U
CLInk NaoH) Vs (Unknoen oxall acll solut
(LInk otutlon)
Volue Buutte seadngs concodant alu
S No NaOH link (M) Ettal Cot)Final Cmt) CVolum o Oxall
auid) (ml)
1 0 18:5

8 7
18 7

18.1

eALCULA TION

Volume o Unknewm 0xalic aid solutien V = 18:7 .

Nsmalib
Notnality ot Unkneum okali aid sslutten N = ? N.
Velume ot NaOH Solutten Va ao m.
Nekmality NaOH 8utten Na0-0833 N.

AccORDING TA AORMALLIY
EaUATION
Accding to nsmalty egpattn V,xN =
=
Va XNa.
N Va xN
Nolmalily Unknouh Oxalic aci sutim
N)
-08 N.
Date:
age No. aa

TITRATLON-.
Lvnknowm nalia
acid vs CLink NaoH).
Bute is washed
and led with bame
with walen Amsed wlth orali arl Belutitn
,

ralie arld solution up tw the z e e mark:

20ml o NaOH solutinn Exacty
pipemd aut lnto he dean, waked cmical
ask. TB hts solutio a b 3
deps ot phunelphthalch deate à
added
added and aiatid _agalnst_omal& arll Bolution m the buurtte. Oxalic
acld
aldbadded drep wlse ha pirkcelou daappeas cmpletely..
Burete sading s hotd and the Aame precedure à apeatt.d o get
cOncsidant values.
LWEGHT CALLULATION

The amont of oralii aid diseved

in
(Noimalily) x
1
tt ot thesslution (equevalt welae)
The amonunt st Okali auid
dissolued n 1a9 ml ot thu solution
AMbmallty xeuivalnt uelqhtxya2
YX63X12 502
= 0: 810x63 X1250

= 7:008 q .
Ext.No.
Date Page No. a 4

REPORT:
dissved 1&SO ml
The amountot ral acld n
tha soluten = T.Do89.