Expt.No.

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Name: Page No.
CHEMICAL HEACTIONS
LDEHY DE PND KETONES Date: 2201-21
H2N-NHK NO >c=N- NH- Am
>c=0 +
NO Not H %lest lhe phesemce af aldehydic amd
O,N
yellau pbt] kelonic Pnarub.
>c#0 + NaHSO3 so Na
.oH
MaTERIALS KEQUIRED Schi's heagemt,
- s saliin, alcahal, dgNO3 Fehlin
[while bpt 7 salilTicn,
NHOH, NaHS0a. iodine saluticn, dil:
2,4 -DNP NaOH
CH H+ 2g(NH).]'oH -ONH+ 2 Aq + 3NH,
CHa-C-d
THEORY
+Ho 1:Baihaldehydes amd kelanes
camtain
( o )ghaup amd give ohamge pbt uith 2,4-dini
R-C-H+ 2 Cu*+ 50H REO0+ Cuo + 3Ho
Brick e d ppt] Drobhemul hydnagine
2:Libhalic aldehydes amd kelones give
hile bbt due L6 theioisulbhila ccmbaund
lopoFORM TEST uilh sodium biaulbhia
3 Alcehydes give silver mirran wilh Tallezis
CH-H+ 312t 4Na OH CHI, t
CHCOO Na +3NaI hoagemtE hoy ve bink calau uilh schifs n=
lyelowbe] +2H,0 -agent hey lalso give sick ned pbE_uith Feh-
-ling'ssalilicn. kelanesdontgrve lhese lesz.
ExPERIMENT esERVATION INEERENCE
2,4-DNP TEST
TakeImlo auaYellawish-aram.dldehyde
-aus ar alcohalic saiuli-ge þpt. kelane gnaup
-a720aþinchafcomp may be bresent
-aumdamd adA Lml
alcahalic. saluilior
2.4-DNP hydnazine. Boi
Themixtune amd coa.
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Expt. No. Page No. 6
Name Date
EXPERIMENT
SopNUM BISULPHITE TEST
OBSERVATION INEERENCE
Iothe aqueous sa Whik cystaline Aldahydes on
Lulion of ongamic cmppt ketane gmaup
Cumd add 2-3 ml
is bnesemt.
satuwnated satultond
sodium bisulbhibte
im wal Shahe the
mixlure
losoEORM TEST
Ao the qivem ong- Yellaw bht Alde hydes
amic cmpcund,add CHCHan Kelon
iodime saulian amd CH- gncup
a.ueau& NaoHsalulk- nesemtE
an amdheat.
SCHIEES TEST
h lImlaf he ligu Pnk Calaurahb- Aldehyde graup
id camorumd.addd -eahk. Ahesem
4 draha af Schi
HeagemE
ToLLENS TEST
ToLhe givem carn Shiny silver ldehyde g
baund, add follens minhantis fanm- -aus ahesent.
heagemt [ammami -ed.
-calsilven nilnala
satution1
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Expt. No.:
Page No. 63
N a m e :

Date
ExPERIMENT
FEHLINGs TEST
DeSERyATION INEERENCE
Jh Ihe given sau- Bnicked pbt Aldehyde ghcup
lian ndd Iml each pres nt
g Fehligs SatulicnA
amd B. Bail fan 2
mins
NoTE Kelanesgive pasilive 2,4- DNP hydra.
zin lest and nigalive listEwrilhFehlemg
salulian. Schif 's heagent and lallen
eagent Therelone, Ihese iskcam le
used lb dislinguish belasecn aldehsdks
amd kelones
hESULD-- The cambcumd qiving basilive hestulla
an allAix lbslk is comlainiuna aldehs.dic
QHaub amd IhmLamparumd avin bosilkve
esults anly ubtll bst a cemlaims kelo
qhaub.
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