CHEMISTRY – XI

(Numericals From Past 25 – Years Papers)

NEWTON’S INN COACHING CENTRE

CHAPTER # 01
(INTRODUCTION TO FUNDAMENTAL CONCEPT OF CHEMISTRY)
DEFINITIONS
 Molar Volume 2014, 2006, 2004
 Limiting Reactant 2014, 2013, 2008, 2005
 Stoichiometry 2014, 2013, 2006, 2004
 Avogadro’s number 2013
 Significant Figure 2013, 2008, 2006, 2004
 Exponential Notation 2006
 Empirical Formula 2006, 2005
 Molecular Formula 2006
 Atomic Mass 2005
 Mole 2005
 Random Error 2005, 2004
DIFFERENTIATE BETWEEN
 Empirical Formula and Molecular Formula 2012, 2004
 Exponential Notation and Significant Figures 2011
NUMERICALS
Number of Moles and Avogadro’s Number:
(1): From 2000
The Atomic mass of Na is 23 a.m.u;
(I): Calculate the Number of Moles in 460 grams of Na.
(ii): Calculate the Number of Atoms 4.6 grams of Na
(iii): Calculate the mass of
(2): From 2002 (Pre – Medical)
(a): Calculate the Number of Moles and Number of Molecules present in 9.0 grams of C6H12O6.
(b): The mass of is 1.6 grams. [Fill in the Blanks]
(3): From 2003 (Pre – Medical)
(a): Calculate the Number of Moles in 3800 grams of:
(I) Ca (OH)2 (ii) SO2 (iii) H2 [Ca = 40, S = 32]
(b): Calculate the mass in grams
(4): From 2003 (Pre – Engineering)
Fill in the blanks:
(I): 8.8 grams of CO2 contains Molecules.
(ii): The mass of 1000 Molecules of H2O is grams.
(iii): 4.48 dm3 of N2 at S.T.P weighs 5.6 grams.
(5): From 2004
The Atomic mass of Na is 23 a.m.u;
(I): Calculate the mass of
(ii): Calculate the Number of Moles of
(6): From 2005
Fill in the blanks: 64 grams of SO2 contains Molecules.
(7): From 2006
What is the weight in grams of ?
(8): From 2007
What is the mass of ?
(9): From 2011
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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
In a Collection of , what is the Number of Moles? (Atomic
Masses: C = 12, O = 16, H = 1)
(10): From 2012
Find the Mass and the Number of Molecules in 18000 cm3 of H2S gas at S.T.P.
Significant Figures, Scientific Notations & Simple Algebra:
(1): From 2000
Solve by rules of Significant Figure:
(2): From 2000
Reduce 432.196 to one significant figure and to four significant figures
(3): From 2001
Express the followings as Power of 10: (I): 50000 (ii): 53.24 (iii): 0.0005 (IV): 54321
(4): From 2001
Solve by using the rules of Significant Figure:
(5): From 2002 (Pre – Medical)
How many Significant Figures are there in 732.020? Convert it to three and two Significant Figures.
(6): From 2002 (Pre – Engineering)
(I): 43.01 have 4 Significant Figures.
(ii): 2.32 × 10-3 can be written as 0.00232 in decimal.
(iii): In Log System, the Characteristics of 1000 is 3.
(7): From 2005
(I): The Significant Figure in 5.734 is 4.
(ii): The Decimal Fractional Part of Log is called Mantissa.
(8): From 2006
Give the Significant values of the followings: (I): 685 (ii): 9000 (iii): 0.58 (IV): 0.004
(9): From 2007
Multiply: According to Multiplication Rule
(10): From 2007
How many Significant Figures are there in 0.0821?
(11): From 2008
Simplify according to the rule of Significant Figure:
(12): From 2011
Simplify the following by using Exponential Notation:
(13): From 2014
The mass of a substance is 18.8865 grams and its volume is 7.9 cm3. What will be its Density
considering Significant Figure and Rounding Off the above obtained?
Empirical Formula & Molecular Formula:
(1): From 2000
A compound contains C = 40%, H = 6.66% by mass. Its Molecular Mass is doubles than its
Empirical Formula Mass. Find its Molecular Formula.
(2): From 2001
An organic compound contains C = 51.80%, H = 13.12% and O = 35.08%. Determine the Empirical
Formula of the compound.
(3): From 2002 (Pre – Engineering)
A Hydrocarbon has 20% of Hydrogen and 80% of Carbon. Find the Empirical Formula and
Molecular Formula of the compound if Molecular Mass is 30.
(4): From 2003 (Pre – Medical)
Acetic Acid contains C; H and O. 2.14 grams of sample of acetic acid on complete combustion gave
3.105 grams of CO2 and 1.27 grams of water. The molecular mass of Acetic Acid is 60. Find its
Empirical and Molecular Formulae.

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
(5): From 2005
The Molecular Mass of a Compound is 180 and its Empirical Formula is CH2O; find the Molecular
Formula.
(6): From 2006
An Organic Compound contains 67.7% of C, 7.41% of H and 25.90% of N. The Molecular Mass of
Compound is 108. Determine the Empirical and Molecular Formula of the Compound.
(7): From 2007
Diethyl Zinc is a Chemical used in the Library to product the books from worms. Its composition is
53% Zinc, 38.9% C and 8.1% H. Determine the Empirical Formula of the Compound.
(8): From 2008
Organic Compound producing air pollution contains 8.73% Carbon, 77.45% Chlorine and 13.82%
Fluorine. Find the Molecular Formula of the Compound if Molecular Mass of Compound is 137.5.
(Atomic masses; C=12, Cl=35.5, F=19)
(9): From 2010
What is the Molecular Formula of a Compound that contains 80% of Carbon and 20% of Hydrogen?
Its Molecular mass is 30.
(10): From 2012
An Organic Compound contains Carbon, Hydrogen and Oxygen has 26.7% C, 2.2% H by weight.
Find the Molecular Formula of the Compound if Molecular Mass of Compound is 90 a.m.u.

(11): From 2014

Combustion of 0.5 gram of Hydrocarbon produced 1.515 grams of CO2 and 0.77 Gram of H2O. If the
Molecular Mass of the Compound is 58 a.m.u; determine the Molecular Formula.
Stoichiometry:
(1): From 1999, 2005
54 grams of Di – Nitrogen Penta Oxide (N2O5) is decomposed on heating as under:

Find out the Volume of NO2 and O2 at S.T.P.

(2): From 2000
Calculate the Volume of O2 at N.T.P required burning 30 grams of CH4 as shown in the reaction:

(3): From 2001

Find the Mass, Number of Moles, Number of Molecules and Volume of Carbon Dioxide Gas at
S.T.P obtained by burning 6.0 grams of C. Give the Equation also.
(4): From 2003 (Pre – Engineering)
73.5 grams of KClO3 is decomposed on heating as:
Calculate the Mass of KCl formed and Volume of O2 at S.T.P.
(5): From 2004
30 grams of Lime Stone (CaCO3) was heated. Write the Equation of the Reaction. Calculate the
mass of CO2 produced and calculate the volume of CO2 at S.T.P.
(6): From 2006
100 grams of KNO3 are heated to redness. What volume of Oxygen at 39 ᵒC and 765 mm pressure
will evolve?
(7): From 2007
Find the mass of KClO3, required to prepare 3.2 grams of O2:

(8): From 2008

Zinc reacts with H2SO4 (Diluted) as given:

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
(I): Calculate the mass of ZnSO4 (ii): Calculate the Volume of H2
(iii): Calculate the Number of Molecules of H2
If H2 will be produced by reacting 163.5 grams of Zn with H2SO4 at S.T.P
(9): From 2010
Complete combustion of CH4 gives the reaction:

Calculate the Mass and the Volume of CO2 gas produced at S.T.P by the combustion of 9.6 grams of
CH4.
(10): From 2013
Find the weight of Barium Sulphate precipitated on adding a solution containing 82 grams of
Potassium Sulphate to a solution containing 82 grams of Barium Chloride.

Limiting Reactant:
(1): From 2002 (Pre – Medical)
You are provided with 6.0 grams Carbon and 100 grams of O2. Calculate the amount of CO2
prepared by reacting them. Which of them is the Limiting Reactant?
(2): From 2007
At high temperature, Sulphur (S) combines with Iron (Fe) to form Brown – Black Iron Sulphide
(FeS):
In an experiment, 76.2 grams of Fe are allowed to react with 86.7 grams S. Which of the two is Limiting
Reactant? Calculate the mass of FeS obtained. (S = 32, Fe = 56)
(3): From 2009
For the reaction:
1.5 grams of Mg and 1.5 grams of Nitrogen react together. What are the 4 actual amounts of Mg3N2
formed and which element is the Limiting Reactant?
(4): From 2012
What is the minimum mass of Al (OH)3 that can be obtained by the reaction of 13.4 grams of AlCl3
with 10 grams of NaOH according to the following equation:

(5): From 2014

ZnCl2 is prepared by the reaction:
6.54 grams of Zn reacts with 73 grams of HCl. Find the Limiting Reactant and the Mass of ZnCl2
produced.
CHAPTER # 02 (THREE STATES OF MATTER)
DIFFERENTIATE BETWEEN
 Crystalline Solid and Amorphous Solid 2003, 2005, 2006, 2010, 2014
 Isomorphism and Polymorphism 2011, 2000
SHORT NOTES
 Viscosity 2007, 2008, 2009, 2010
 Surface Tension 2005, 2007, 2009
 Vapor Pressure 2005
LAWS
 Dalton’s Law of Partial Pressure and its Application 2004, 2006, 2012, 2013, 2014
 Avogadro’s Law 2013
 Graham’s Law of Diffusion 2003, 2004, 2005, 2010, 2013
 Charles’s Law 2003, 2004, 2006, 2012, 2013
 Boyle’s Law 2003, 2006, 2012
SCIENTIFIC REASONS
 A falling drop of liquid is always spherical. 2004, 2007, 2010, 2011, 2012

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
 Glycerin is distilled at a reduced pressure. 2004
 NaF and MgO are isomorphous compound. 2004
 Evaporation is a cooling process. 2005, 2011
 A drop of ink spreads on a blotting paper. 2005, 2013
3 3
 100 cm of O2 and 100 cm of NH3 contain the same number of molecules at S.T.P. 2008
 The rate of diffusion of CO2 and C3H8 gases are same. 2008
 FeSO4.7H2O and ZnSO4.7H2O are isomorphous. 2008
 A liquid is less viscous at high temperature. 2011
 Pressure cooker is used for rapid cooking. 2011
 Ethyl Alcohol (C2H5OH) has greater viscosity than Diethyl Ether (C2H5 – O – C2H5). 2012
 The Liquid has capillary action. 2009
 Water expands when cooled below 4 ᵒC. 2007
DESCRIPTIVE TYPE QUESTIONS
 What is an Ideal Gas? What are the causes of deviation of real gases from ideal behavior?
2008, 2014
 Explain the causes of non ideal behavior of gases especially at high pressure and low temperature.
2009
 The process of diffusion occurs most rapidly in gases less rapidly in liquid and very slowly in solids.
2005, 2011
 Derive General Equation by combining gas laws. 2003, 2006, 2012
 Explain evaporation in liquid and deformity in solids in terms of KMT.
2007
 Explain any one STATE OF MATTER on the basis of Kinetic Theory. 2011
 Write the postulates of Kinetic Molecular Theory of Gases. 2003, 2005, 2008
 Give the Unit Cell of a Cubic Or Orthorhombic System. 2008
 Name the Crystal System which has the following Axes and Angels: 2009
(I):
(ii):
(iii):
(iv):
 Calculate the value of R for One Mole of Gas having volume 0.0224 m3 at 273 K and 101300 Nm-2
Pressure. 2006
 Calculate the value of R at Atmospheric Pressure. 2009
 Calculate the value of the gas constant in two different units. 2003
NUMERICALS
Gas Equations:
(1): From 1993
2.273 grams of Gas at 27 ᵒC and 900 Torr Pressure has Volume 1400 ml. Calculate its Molecular
Mass.
(2): From 1993
Calculate the Number of Moles of Hydrogen Gas present in 1.12 dm3 volume container at 27 ᵒC and
0.1 ATM Pressure.
(3): From 1996
A sample of Chlorine Gas at S.T.P has a volume of 800 cm3; calculate
(i): The Number of Moles of Chlorine
(ii): The Mass of the Sample
(iii): The Number of Chlorine Molecules in the sample
(4): From 1997
13.2 grams of Gas occupies a volume 0.918 dm3 at 25 ᵒC and 8 ATM Pressure. Calculate the
Molecular Mass of the Gas.

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
(5): From 1999
A quantity of a Gas measures 500 ml at 35ᵒC and 600 mm pressure. What would be the volume of
the gas at 45ᵒC and 800 mm pressure?
(6): From 2000
1.40 dm3 volume of a Gas measured at temperature of 27 ᵒC and 900 Torr Pressure was found to
have a mass of 2.273 grams. Calculate its Molecular Mass.
(7): From 2001, 2007
Correct the given statement by giving the name of respective law:
 The volume of a gas at 27ᵒC doubles at 54ᵒC
(8): From 2002 (Pre – Medical)
What is the volume of 2.5 Moles of N2 at S.T.P?
(9): From 2002 (Pre – Medical)
A given mass of a gas occupies 76 cm3 at 16ᵒC and 760 Torr Pressure. Calculate its Volume at
S.T.P.
(10): From 2002 (Pre – Engineering)
Calculate the Number of Moles, the Number of Molecules and volume in cm 3 of 0.32 grams at
S.T.P: (i) CH4 (ii) SO2
(11): From 2003 (Pre – Engineering)
At what temperature in ᵒC does a certain volume of a gas at 27 ᵒC becomes doubled?
(12): From 2003 (Pre – Medical)
A Given Mass of a Gas occupied 76 cm3 at 16 ᵒC and 760 Torr Pressure. Calculate its Volume at
S.T.P.
(13): From 2004
What is the Density of Methane (CH4) at 127 ᵒC and 3.5 Atmospheres?
(14): From 2005
What will be the Volume occupied by 14 Grams of Nitrogen at 20 ᵒC and 740 Torr Pressure?
(15): From 2006
Calculate the value of R for One Mole of Gas having volume 0.0224 m3 at 273 K and 101300 Nm-2
Pressure.
(16): From 2006
100 grams of KNO3 are heated to redness. What volume of Oxygen at 39 ᵒC and 765 mm Pressure
will evolve?
(17): From 2012
1.4 dm3 Volume of a Gas collected at a Temperature of 27 ᵒC and Pressure of 900 Torr was found to
have Mass 2.273 grams. Calculate the Molecular Mass of the Gas.
(18): From 2014
Calculate the volume of Nitrogen Gas produced by heating 800 Grams of Ammonia at 21 ᵒC and 823
Torr Pressure.

(19): From 2014

The Density of a certain gas is 1.43 gram/dm3 at 608 Torr and 27 ᵒC. Find the Molecular Mass of the
Gas.
Dalton’s Law of Partial Pressure:
(1): From 1992
A 5.0 Liter vessel contains 2.0 grams of H2 and 28.0 grams of N2 at 30 ᵒC. Find the Pressure of
container.
(2): From 1994
A 12 dm3 vessel at 30 ᵒC contains 0.2 Moles of H2 and some He Gas. Find the Partial Pressure of
each gas where the total pressure of the container is 2 ATM.
(3): From 1996

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
The volume of Oxygen Gas collected over water at 24 ᵒC and 762 mm Pressure is 128 ml. Calculate
the Mass in Grams of Oxygen Gas obtained. The Pressure of water at 24 ᵒC is 22 mm.
(4): From 2000
Three containers of equal volume are filled as follows:
(i): 2 Moles of H2 at 0ᵒC
(ii): 1 Mole of N2 Gas at 273 K
(iii): 3 Moles of O2 Gas at 27ᵒC
Which of the container is at the lowest pressure and which has the largest number of molecules?
(5): From 2002 (Pre – Medical)
380 cm3 H2 were collected over water at 23ᵒC and 613 Torr. Find the volume of Dry Hydrogen at
S.T.P. (Vapour Pressure of water at 23 ᵒC is 21 Torr)
(6): From 2002 (Pre – Engineering)
A mixture of 0.2 moles of a Gas “A” and 1.1 grams of another Gas “B” (Molecular Mass = 4.4)
exerts a pressure of 750 Torr. Calculate the Partial Pressure of the Two Gases.
(7): From 2003 (Pre – Engineering)
A 500 cm3 vessel contains H2 as at 400 Torr and another 1 dm3 vessel contains O2 Gas at 600 Torr.
If these Gases are transferred to 2 dm3 Empty Vessel; calculate the Total Pressure of the Mixture of
the Gas.
(8): From 2006
A 100 cm3 Gas Cylinder filled with Chlorine under 160 Torr Pressure is connected by stopcock with
another Cylinder of 400 cm3 filled with Nitrogen under Pressure of 200 Torr. What will be the Total
Pressure when stop cock is opened?
(9): From 2008
A 500 cm3 vessel contains 2 grams of He and 8 grams of CH4. What is the total Pressure of the
Mixture of these Gases at -3 ᵒC?
(Atomic Masses: He = 4, C = 12, H = 1)
(10): From 2013
At 30 ᵒC, 500 cm3 of H2 at 400 Torr Pressure and 1 dm3 of N2 at 600 Torr Pressure are transferred
into 1500 cm3 flask; calculate the TOTAL PRESSURE of the Mixture of Gases.
Graham’s Law of Diffusion of Gas:
(1): From 1990
Calculate the density of Gas “A” if the density of Gas “B” is 35.5 gm/cm3 and the rate of diffusion
of Gas “A” is twice than that of Gas “B”.
(2): From 1991
75 cm3 of Gas “A” and 175 cm3 of Gas “B” diffuse at the same time. If the relative Molecular Mass
of Gas “A” is 16, find out the relative Molecular Mass of Gas “B”.
(3): From 1998
400 cm3 Helium Gas effuses from a porous container in 20 seconds. How long will SO2 Gas take to
effuse from the same container?
(4): From 1999
Compare the rate of diffusion of the following pairs of gases:
(i): H2 and D2 (ii): CH4 and He (iii): SF6 and SO2
(5): From 2001, 2007
Correct the given statement by giving the name of respective law:
 H2 Gas takes more time to diffuse than O2 Gas.
(6): From 2002 (Pre – Medical)
Calculate the Molecular Mass of a Gas whose rate of diffusion is twice as that of CH4.
(7): From 2002 (Pre – Engineering)
CH4 takes 36 minutes to effuse from a container. How long will He Gas take to effuse from the
same container under the same conditions?

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
(8): From 2003 (Pre – Engineering)
200 cm3 of Gas “A” diffuses in the same time as 300 cm3 of Gas “B”. If the Molecular Mass of Gas
“B” is 32, calculate the Molecular Mass of Gas “A”.
(9): From 2009
Helium takes 5 Seconds to effuse from a hole of 10 dm3 container. How long would it take for
Oxygen to effuse from the same container at the same temperature and pressure?
(10): From 2010 (Failure)
Calculate the Relative Rate of Diffusion of O2 and SO2 Gases at constant temperature and pressure.
(Atomic Mass of O = 16, Atomic Mass of S = 32)
(11): From 2010
At certain Temperature and Pressure, NH3 diffuses 1.48 times more than HCl. If the Density of NH3
is 0.66 gram/liter; find the Density of HCl.

CHAPTER # 03 (ATOMIC STRUCTURE)

DIFFERENTIATE BETWEEN
 Lyman Series and Balmer Series 2003 (PE), 2012
 Natural Radioactivity Artificial Radioactivity 2004
 Principle and Azimuthal Quantum Number 2005
 Line Spectrum and Continuous Spectrum 2005, 2008, 2013
 α – Rays and β – Rays 2006
 Electronegativity and Electron Affinity 2008, 2014
 Orbit and Orbital 2011
SHORT NOTES
 X – Rays and Atomic Number 2000, 2003 (PM), 2007
 Ionization Potential 2002 (PE)
 Line Spectrum 2002 (PE)
 Quantum Number 2003 (PM), 2010
 Electron Affinity 2003 (PM)
 Electronegativity 2003, 2006, 2013
 Plank’s Quantum Theory of Radiation 2009
LAWS & PRINCIPLES
 Pauli’s Exclusion Principle 2000, 2002 (PM), 2005, 2012
 Hund’s Rule 2002 (PM)
 Heisenberg Uncertainty Principle 2002 (PE)
 2005
DESCRIPTIVE TYPE QUESTIONS
Faraday’s Experiment and Crooke’s Tube Experiment (Discharge Tube Experiment)
 What happens when a current of very high voltage is passed through gas at low pressure in discharge
tube? Prove that these rays:
(i) Travel in Straight Lines (ii) Are material in nature (iii) Are Electrons Years: 2001
 Describe the Experiment, explaining the passage of electricity through gases at low pressure.
2003 (PM)
 Define Cathode Rays. 2002 (PM), 2003 (PE), 2005, 2013
 Describe the properties of Cathode Rays. 2002 (PM), 2003 (PE), 2005, 2013
 How Cathode Rays are produced? 2002 (PM), 2013
 What conclusions were drawn from the properties of Cathode Rays? 2013
 How are positive rays generated in Cathode Rays Tube? 2007, 2009
 Did Positive Rays depend upon the nature of the gas filled in Cathode Rays Tube?
2009

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
Natural Radio Activity
 Compare the properties of α, β and γ – rays. 2002 (PE)
 What is Radioactivity? Describe the three types of radiation with characteristics of each. How were
they discovered? 2006
 A Radioactivity substance emits three types of radiation. Write their names along with their
properties. 2010
 Define Radioactivity? Describe the characteristics of Alpha and Beta Particles. 2012

Artificial Radioactivity and Chadwick Experiment (Discovery of Neutron)

 Complete: 2000, 2005
 Complete the following Nuclear Reaction: 2006

 How were Neutron discovered? Give the Reaction 2002 (PE)

Spectrum and Hydrogen Spectrum

 How does Bohr’s Theory account for Hydrogen Spectrum? 2000
 Write down the names of Spectral Lines of Hydrogen Atom 2001

Bohr’s Theory
 Bohr’s Postulates 2000, 2005, 2008, 2011, 2013
 Derive the expression for the Radius of Bohr’s Orbit
2002 (PM), 2004, 2007, 2009, 2013
 Derive the expression for the Energy of Electron in nth Orbit
2000, 2003 (PE), 2005, 2006
 Derive the expression for the Frequency of radiation. 2010, 2012
 Derive the expression for the Wave Number of radiation. 2010, 2012, 2014
 Bohr’s Model of Atom is contracted by Heisenberg’s Uncertainty Principle 2008

Rutherford’s Atomic Model

 Defects of Rutherford’s Atomic Model
2001, 2002 (PE), 2003 (PM), 2006, 2008, 2012, 2014
 Basic assumptions of Rutherford’s Model 2003 (PM), 2006, 2014
 Limitations of Rutherford’s Model 2009, 2014
 Give the experimental evidence for the presence of very small positively charged Nucleus containing
most of the mass of the Atom. Write also weakness of this Atomic Model.
2012

Shape and Size of Orbital and Energy Level

 Draw the Shape of S and P Orbital 2001
 What are the shapes of orbital for which n = 2 and ℓ = 2 2002
 What are the shapes of orbital for which n = 0 and ℓ = 1 2004
 The Size of Cl-1 is _________ than that of Chlorine Atom. 2002 (PM)
 Na+ (Z = 11) has radius _________ than that of Mg2+ (Z = 12). 2002 (PM)
 The number of orbitals in the second energy level is _________. 2005
 The value of IP _________ with the increase of Atomic Size 2006
 What are the shapes last Sub – Shell of Na and B? 2010
 What is the Shape of Orbital for the Second Energy Level? 2013
Electronic Configuration Atomic Structure & Quantum Numbers

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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
 Write Electronic Configuration of Mg2+ ions (Mg = 12) 2000
 Write Electronic Configuration of the following:
(i): (ii): (iii): 2002 (PM)
 Write Electronic Configuration of the following:
(i): 13Al+3 (ii): 29Cu (iii): 17Cl-1 2005
 Write Electronic Configuration of 2009
 Write Electronic Configuration of the following:
(i): (ii): 2010
 Write Electronic Configuration of the following:
(i): (ii): (iii): 2012
 Write Electronic Configuration of the following:
(i): (ii): 2013
 Write Electronic Configuration of the following:
(i): (ii): 2014
 Give the number of Protons, Electrons and Neutrons for the following:
(i): (ii): (iii): 2001
 The total numbers of Neutrons in is_________. 2008
 Give the number of Protons, Electrons and Neutrons for the following:
(i): (ii): 2002 (PM)
 Give the number of Protons and Electrons for the following:
(i): (ii): (iii): 2012
 Which rule and principle is violated in writing the following electronic configuration:
1s ᶺ ᵛ, 2s ᶺ ᵛ, 2px ᶺ ᵛ, 2py ᶺ ᵛ, 2pzᵒ 2000, 2005
 Which principle is violated in writing the following electronic configuration?
1s2, 2s1, sp5 1s2, 2s3, sp5 2008
 Write the values of all quantum numbers for both the electrons of He atom. 2008
 If the configuration of is written as: 1s2, 2s2, 2px2, 2py1, _____ is violated.
2002 (PM), 2007
 The (n + ℓ) value of 3d orbital is_____ 2007
 Make the correct sequence of the orbital for the electronic configuration according to (n + ℓ) rule:
4P, 4S, 3d, 5S, 5P 2002 (PM), 2011
 Arrange the orbital in order of ascending energy according to (n + ℓ) rule:
4d, 7S, 4f 2009
 What are the value of n and ℓ for the last Sub – Shell of Na and B? 2010
 Arrange the orbital in order of ascending energy according to (n + ℓ) rule:
3d, 4S, 4P, 4d, 5S, 6S, 5P 2012
SCIENTIFIC REASONS
 The value of ionization potential DECREASES DOWN THE GROUP 2005
 The value of ionization potential DECREASES with the INCREASE of Atomic Size 2006
 The ionization energy of 4Be is MORE than 3Li. 2007
 In the following parts, one item is different from the others. Locate the item and give the reason for
it: Aufbau, Thomson, Rutherford, and Bohr 2008
+
 Na ion is smaller in size than Na Atom 2012
 Mg+ ion is smaller in size than Mg Atom 2014
NUMERICALS
Radius of Hydrogen Atom:
(1): From 2003 (PE)
Calculate the radius of the 3rd orbit of Hydrogen Atom using
Bohr’s Radius
(2): From 2006
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 CHEMISTRY – XI
(Numericals From Past 25 – Years Papers)
Bohr’s Radius is . Find radius of 2nd orbit of Hydrogen Atom.
(3): From 2000, 2007, 2011
Bohr’s Radius is . Find radius of 3rd orbit of Hydrogen Atom.
Wave Number of Radiation:
(1): From 2003 (PE)
Calculate the Wave Number of radiation emitted in Lyman Series by Hydrogen Atom when Electron
jumps from 2nd orbit to 1st orbit.
(2): From 2008
Calculate the Wave Number of an Electron when it jumps from n = 5 to n= 1.
(3): From 2011
Calculate the Wave Number of Spectral Line of Hydrogen Gas when the Electron jumps from n = 4
to n= 2.
(4): From 2012
Calculate the Wave Number of the Line in Lyman Series when an Electron jumps from 3rd orbit to 1st
orbit.
Angular Momentum:
(1): From 2003 (PE)
Calculate the Angular Momentum of Electron in the First Energy Level of Hydrogen Atom.

Electronic Configuration:
(1): From 2000
Write Electronic Configuration of Mg2+ ions (Mg = 12)
(2): From 2002 (PM)
Write Electronic Configuration of the following:
(i): (ii): (iii):
(3): From 2005
Write Electronic Configuration of the following:
(i): 13Al+3 (ii): 29Cu (iii): 17Cl-1
(4): From 2009
Write Electronic Configuration of
(5): From 2010
Write Electronic Configuration of the following:
(i): (ii):
(6): From 2012
Write Electronic Configuration of the following:
(i): (ii): (iii):
(7): From 2013
Write Electronic Configuration of the following:
(i): (ii):
(8): From 2014
Write Electronic Configuration of the following:
(i): (ii):

To Find Number of Electrons, Protons & Neutrons:

(1): From 2001
Give the number of Protons, Electrons and Neutrons for the following:
(i): (ii): (iii):
(2): From 2002 (PM)
Give the number of Protons, Electrons and Neutrons for the following:
(i): (ii):

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 CHEMISTRY – XI
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(3): From 2008
The total numbers of Neutrons in is_________.
(4): From 2012
Give the number of Protons and Electrons for the following:
(i): (ii): (iii):

CHAPTER # 04
MCQZ, TRUE AND FALSE, REASONS AND FILL IN THE BLANKS
(1):Write whether the following statements are true or false: (1.5 marks) (98)
i) Hydrogen bond is a primary bond
ii) A coordinate covalent bond is formed by mutual sharing of electrons.
iii) Water is a polar molecule.
(2): Fill in the blanks with correct answer (3 marks) (99)
i) The bond length in CH=CH is ……………….. than that in CH2=CH2.
ii) The bonding molecular orbital has ………………… energy than anti-bonbing molecular
orbital
iii) Sigma bond is …………… reative than pi bond.
(3): CO2 has zero dipole moment because of its …………… structure(2003 P.M)
(4): The shape of BF3 molecule is …………………. 2004
(5): Write true or false for the following (2004)
i) S-S sigma bond is stronger than P-P sigma bond
ii) In NH3, the nitrogen atom is SP3 hybridized.
(6) SO2 molecule has ………………………. Geometrical shape (2005)
(7) Write whether the following ststements are true or false (2006)
i) CCl4 has zero dipole moment because of its symmetrical structure
ii) Hydrogen bond is stronger than covaleny bond..
(8): Fill in the blanks: 2006
i) The melting and boiling points of ionic compounds are ……………
ii) SO2 molecule has ……………….. geometrical shape..
(9) Water expands when cooled below 4 OC WHY? 2007
(10)Choose the correct answer for each from the given option.2008
i) ………………………….. bonds are present in one molecule of ethane(C2H6)
a)four sigma two pi b)Two sigma four pi c)seven sigma
ii) The bond distance b/w C-C single bond is………………….
a)1.54 oA b)1.34 oA c) 1.20 oA

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iii) In hydrogen halides ……………………… posses the largest ionic character
a)HF b)HCl c) HBr
(11) Choose the correct answer for each from the given option. 2009
i) Which atomic orbital is always involved in sigma bonding???
a)S-orbital b)P-orbital c)d-orbital d) None of these
ii) In ethene(C2H2) molecule there are:
a)four sigma two pi b)Two sigma four pi c)seven sigma d) four sigma and one pi
iii) When gaseous cations and anions are brought closer, the energy involved:
a)Electron affinity b)Lattice energy c) Electronegativity d)Ionization potential
iv) Which of the following compounds has Sp2 hybridization?:
a)NH3 b)C2H2 c) C2H4 d)H20
(12) Choose the correct answer for each from the given option. 2010
i) Which bond is non polar?
a)Cl-Cl b)N-Cl c)C-Cl d) H-Cl
ii) The Sp2 hybrid orbitals are:
a)Non-planar b)Co-planar c)Linear d) Non of these
(13) Choose the correct answer for each from the given option. 2011
i) The angle b/w Sp3 hybrid orbital is:
a)120o b)180 o c)109.5 o d) 107.5 o
ii) The single bond in a covalent molecule is called:
a)pi-bond b)Sigma bond c)co-ordinate covalent bond d) Non of these
(14) Choose the correct answer for each from the given option. 2012
i) The strength of sigma bond is highest for???
a)S-S overlap b)S-P overlap c)p-p overlap d) Sp3-s overlap
ii) The Dipole moment of Cl2 molecule is :
a)0.00 D b1.O3 D c) 1.85 D d)1.67 D
(15) Choose the correct answer for each from the given option. 2013
i) The bond formed in fluorine molecule is due to this overlap of orbital:
a)S-S b)S-P c)p-p d) none of these
ii)Bond energy of carbon carbon tripple bond as compare to that of carbon carbon double bond :
a)Greater bLesser cSame d)None of these
iii) The angle b/w Sp3 orbital is:
a)120o b)180 o c)109.5 o d) 107.5 o
(16) Choose the correct answer for each from the given option. 2014

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 CHEMISTRY – XI
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i) Diamond is very hard because of:
 Sp2-hybridization
 Vander waal’s forces
 Close packing of carbon atoms and large no of covalent bonds
 Large amount of energy required to break the bond;

ii) In pi-bonds electron density lies:

 Only above the nodal plane
 Only below the nodal plane
 On the nodal plane
 Both above and below the nodal plane
iii) The presence of hydrogen bond in a liquid:
 Decrease the vapour pressure
 increase the vapour pressure
 Decrease the viscosity
 Cause no effects in the physical properties of liquids
iv) The presence of hydrogen bond is in b/w:
 10-20 KJ/mole
 20-40 KJ/mole
 40-50 KJ/mole
 50-60 KJ/mole
DIFFERENTIATE BETWEEN
 Sigma and pi bond 97,99,2003 P.E, 04,05,08
 Polar bond and ionic bond(3 marks) 98,
 Bonding and antibnding molecular orbital 98,
 Covalent bond and co ordinate covalent bond 99,
 polar and non polar bond 99,2003P.M
 Atomic and Molecular orbital 99,2004
 Shape of water molecule and carbondioxide molecule 99,
 SP3 and SP2 hybridization 2003 P.E
 VBT and MOT 2005

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 CHEMISTRY – XI
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CHAPTER # 05
(2): What is an ionic bond? Explain the formation of NaCl. (5 marks) 97,01,2006,2010
(3): Discuss Dative bond with examples. (4 marks) (98,
(4): Describe the energy changes in the formation of NaCl from sodium and chlorine.
(5marks) 99,
(5): Define hydrogen bondind.(1.5 marks)(99,2011
(6): What is hydrogen bond? What is its importance in biological processes? How does it effect the
physical properties of compounds? (4marks) (99
Hydrogen bonding plays a crucial role in many biological processes hydrogen bonding is also important in
the water transport system of plants,secondary and tertiary protein structure, and DNA base pairing. This
mechanism allows plants to pull water up into their roots

(7): Discuss Co-ordinates or Dative bonds.Show how ammonium ion NH4+ is formed
(2+2 marks) (2000)
(8): Differentiate b/w sigma bond and pi bond with with emamples and one figure for each
(2+2 marks) 2001
(9): Explain why water has a high B.P than hydrogen fluoride although fluorine is
more electronegative than oxygen.(1-Marks) 2001 ,2011
(10): What do you know about ionic character of covalent bond.(03) 2003-p.m,05,09
(11): State and explain covalent bond with suitable examples.(03) 2003P.M
(12): What is Co-ordinate covalent bond? Explain the formation of POCl3 molecule.(04) 2004

(13): Explain the following. 2007, 1997 (ii),

I) The chemical bonding in NH4Cl ii) Polar is stronger than non-polar covalent bond.

(14): Define bond energy. 2008

(15): Do as directed in the following.2008

i. Covalent bond in ethyn (C2H2) Draw the Lewis structure.
ii. Co-Ordinate covalent bond in ammonium ion( Draw the Lewis structure)
iii. Association of water molecules through hydrogen bond( Draw diagram only)
iv. Metallic bond in the atomic crystals of metals (Draw diagram only).

Shapes, Geometry AND HYBRIDIZATION:

(1): Predict the shape of the following molecules on the basis of electron pair repulsion theory.
I) H20 ii) C2H4 (4 marks) (97, 2011

(2): Predict the shape of NH3 molecule according to hybrid orbital model. (2 marks) (98

(2): What do you know about hybridization explain it with examples. (5marks) (99,
(3): Explain the shape of following covalent molecules with the help of Electron pair
Repulsion theory. 2000. (6Marks), 2003P.M (3Marks)
I) H2O ii) CH4 iii) NH3

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 CHEMISTRY – XI
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(4): Draw the Lewis structure and gives shapes of the following molecules
(Explanation not required) (03) 2003 P.E
i) BF3 ii) CS2 iii) NH3

(5): Explain the shape of BeCl2 and H2O molecules in terms of hybrid orbital model. (03)2004

(6): What is hybridization? Give the structure of CH3, C2H4 and BeCl2 molecules in term of hybrid
Orbital model. 2005

(7): Define orbital hybridization. Describe Sp3 hybridization.( 3 marks) (98,2001,2011

(8): Explain the shape of Ethene on the basis of hybridization OR BF3 on the basis of electron pair
Repulsion theory. 2007

(10): Define hybridization. Discuss Sp3hybridization in CH4. 2008

(11): Predict the shape of BeCL2 OR NH3 on the basis of electron pair repulsion theory.2008

(12): Draw dot and cross structures of C2H4 and CHCl3 2009

(13): Explain the shape of Ethene (C2H4) on the basis of hybridization. (2009 detailed)
OR
Explain the structure of NH3 on the basis of Electron pair repulsion theory.
(13): Explain the structure of BF3 and H2O on the basis of Electron pair repulsion Model
(2010 detailed)
(13): Explain Sp3 hybridization in carbon in detail. (2010 detailed)

Short notes and Dipole moment:

(1): CO2 is polar but it has zero dipole moment. 97
(2): Write a detail note on dipole moment. (4-marks) (2000)
(3): Define Dipole moments. Which of the following molecules posse’s dipole moments? 2003P.E
I) PCl3 ii)CS2 iii) H2S iv) CCl4
(4): Write short note on the following 2003P.M
I) Sigma bond ii) Hydrogen Bond
(5) Write a short note on any two of the following 2005
I) Dipole moment ii) H-bonding iii) Co-ordinate bond
(6): Write a short note on any two of the following 2006
I) Covalent bond ii) Bond energy

(7): Define dipole moment. Why does CO2 have zero dipole moment where as SO2 is polar? 2007

(8): Which of the following compounds have dipole moments?

BF3, H20, CO2, CCl4

(9): Briefly explain dipole moments and explain it units. 2009

(10):CO2 is a non polar compound explains. 2009

16 Contact No: 0306-2606923 COMPILED BY Sir Ubaid Ahmed Khan