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Science

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Quarter 4 – Module 1

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Volume and Pressure of a Gas at Constant
Temperature (BOYLE’S LAW)

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Strictly for students use only of the Division of Cebu Province. DO NOT share to other divisions and other teaching or non-teaching personnel. Any violation will be dealt with accordingly. Beta evaluation is still pending.
Science – Grade 10
ADM-Q4 – Module 1: Volume and Pressure of a Gas at Constant
Temperature (BOYLE’S LAW)
First Edition, 2020

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Published by the Department of Education
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Undersecretary: Diosdado M. San Antonio
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MELC: Investigate the relationship between volume and pressure of a
gas at constant temperature S10MT-IIj-20

What I Need to Know


At the end of this module, you should be able to:

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1. describe the relationship between volume and pressure of a gas
at constant temperature;

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2. use Boyle's Law to calculate the volume-pressure relationships of

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a gas; and
3. appreciate the significance of Boyle’s Law to practical situations.

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Before going on, check how much you know about this
topic. Answer the pretest on the next page on a separate
sheet of paper.
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What I Know
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Directions: Choose the letter of the best answer. Write your answer in a
separate sheet of paper.
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1. If temperature is constant, the relationship between volume and


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pressure of a gas is _____________.


A. direct B. equal C. inverse D. unrelated
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2. If pressure is constant, the relationship between temperature and


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volume of a gas is ____________.


A. direct B. equal C. inverse D. unrelated
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3. One way to increase pressure in gas is to ______________________.


A. increase volume
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B. decrease temperature
C. increase the number of gas particles
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D. lower the kinetic energy of the gas molecules


4. How do gas particles respond to an increase in volume?
A. decrease in kinetic energy and decrease in pressure
B. increase in kinetic energy and decrease in temperature
C. increase in temperature and increase in pressure
D. increase in kinetic energy and increase in temperature

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5. Which example has particles that can be drawn closer to occupy
smaller volume?
A. ice cube
B. fruit juice
C. block of wood
D. air inside the syringe
6. If the pressure of a gas is increased and its volume remains
constant, what will happen to its temperature?
A. decreases

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B. increases

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C. remains the same
D. none of the above

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7. The pressure resulting from the collision of air molecules with

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objects is called _______________.
A. atmospheric pressure

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B. kinetic energy
C. sublimation

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D. vapor pressure
8. Which of the following statements does NOT agree with the kinetic
molecular theory of gases?
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A. Gas particles are in constant motion.
B. Gas particles move in predictable patterns.
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C. Gas particles are spaced far apart from each other.
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D. Gas particles move independently of one another.


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9. What happens to the kinetic energy of the particles in a sample of


gas as its temperature increases?
A. It increases, then decreases.
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B. It does not change.


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C. It increases.
D. It decreases.
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10.Which of the following phenomena does NOT involve the


application of gas pressure?
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A. burning fuels
B. falling leaves
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C. vulcanizing tires
D. rising hot air balloons
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How did you find the pretest? What was your score? If
you got 10 items correctly you may skip the module, but
if your score is 9 and below, you must proceed with the
module. Have fun learning!

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What’s In
Sorting Properties of gases
A. Sort the properties of gases into two categories by filling-in the table.

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Choose the word(s) listed below.

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volume density shape
pressure mass temperature
texture diffusability state

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odor expandability number of moles

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compressibility weight

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OBSERVABLE PROPERTIES MEASURABLE PROPERTIES

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B. Match the descriptions in column A with the appropriate gas


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property it illustrates in column B. Write the letter of the correct


answer.
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A B
_____1. the fragrance of perfume spreads a. compressibility
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through the room


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_____2. smog forms over Atlanta during b. diffuses through other


summer days gases
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_____3. a cylinder of oxygen used c. exerts pressure


in a hospital
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_____4. the shrink wrap demonstration d. fills container

_____5. a balloon is inflated with helium e. has mass


_____6. a balloon filled with air weighs more
than an empty balloon

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What’s New

For you to understand the lesson well, do the following


activities as instructed. Have your mind on the activity
below. Have fun and good luck!

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ACTIVITY 1: Getting to Know Gases

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Objective: Prove that gases have the following properties: volume,
temperature and pressure.

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Exploration 1:
When a balloon is full of air, it is said to be inflated. When it has less
air in it, it is said to be deflated.
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Question #1. What will happen when you pump air into the balloon?
Draw a picture or model that explains how the air pump inflates the
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balloon:
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Exploration 2:
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Find a partner in your family. Use an air-filled, sealed syringe:


A. Push the plunger of the syringe as hard as you can.
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B. Record how far you can push the plunger down.


C. Give your partner a turn as well.
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D. Record how far your partner can push the plunger down.
E. Calculate the average of the three trials.
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PARTNER ME

TRIAL 1
TRIAL 2

TRIAL 3

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AVERAGE

Question #2
Were you or your partner able to push the plunger of the syringe until
it reached the bottom? Explain your answer.
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Exploration 3:
Place a marshmallow inside the syringe. Push and pull the plunger of
the syringe and observe what happens to the marshmallow.

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Question #3
A. When I push the plunger of the syringe, the marshmallow

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________________________
B. When I pull the plunger of the syringe, the marshmallow

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________________________
C. Underline the variables involved in the activity.
Temperature Pressure Volume m
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D. Complete this: As__________ increases, ______________ decreases.
E. The relationship between these variables is ___________
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(direct, inverse).
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What is It
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Most gases are invisible. We can name as many solids and liquids
that we see around us but not gases. It is only the very few colored ones
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like the black smoke produced by smoke belchers that can be seen.
Unseen gases are present, to name a few, in a bottle that seems to be
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empty, in the production of food by the plant, and even in playing our
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favorite sports. Can you play your favorite sports like volleyball and
basketball without the ball sufficiently filled with air or gas? Even our
very own existence requires the presence of unseen gases. We take in
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oxygen and we exhale carbon dioxide. Can we survive here on earth


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without the desirable gases which support life?

Gases have different properties. They have indefinite shape and size,
and fit the shape and size of their containers. Gases also have mass,
volume, temperature, and pressure. Volume is the amount of space
occupied by the gases. Temperature is the measure of the coldness or
hotness of the gas. Pressure is the force applied by the gas particles per

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unit area. Gases are fluid, and flow easily, have low density, unless
compressed. Gases diffuse (mix and spread out) and effuse (travel
through small holes).

Kinetic Molecular Theory

By the late 19th century, scientists had begun accepting the atomic
theory of matter started relating it to individual molecules. The Kinetic
Molecular Theory of Gases comes from observations that scientists

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made about gases to explain their macroscopic properties. The following

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are the basic assumptions of the Kinetic Molecular Theory:

A. Gases are composed of molecules. The distances from one molecule

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to another molecule are far greater than the molecules’ dimensions.

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These molecules can be considered as spherical bodies which
possess negligible mass and volume.

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Figure 1. Molecules of gases
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B. Gas molecules are always in constant random motion and they
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frequently collide with one another and with the walls of the
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container. Collision among molecules are perfectly elastic, that is,


energy may transfer from molecule to molecule as the result of
collision but the total energy of all the molecules in the system
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remains the same/constant.


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Figure 2. Molecules of gases in random motion


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C. There is a neither attractive nor repulsive force between or among


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gas molecules.
D. Movement of gas molecules is affected by temperature. The average
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kinetic of the molecules is directly related to the temperature of gas.


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Figure 3. Molecules of gases affected by temperature

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Table 1. Commonly Used Units for Volume and Pressure
VARIABLE SI UNIT METRIC UNIT ENGLISH
UNIT
cubic meter (m )
3 liter (L) quart (qt)
cubic decimeter milliliter (mL) gallon (gal)
VOLUME (dm3)
cubic centimeter
(cm3)

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atmosphere (atm) torr lb/in2
millimeter of (psi)

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PRESSURE Pascal (Pa) mercury (mmHg)
centimeter of

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mercury (cmHg)

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Degree Degree
TEMPERATURE Kelvin (K)
Celsius(ºC) Farenheit(ºF)

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Volume units and their equivalents:

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1 ml = 1cm³ 1 L = 1dm³ 1m³ = 1000 L

Pressure units and their equivalents:


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1 atm = 760 mmHg = 76 cmHg = 760 torr = 101,325 Pa =14.6956 psi
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Temperature units and their equivalents:


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0 ºC = 273.15 K 0 ºC = 32 ºF
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BOYLE’S LAW
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Robert Boyle (1627-1691)


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The relationship between the volume and


pressure of gases at constant temperature was
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first stated by Robert Boyle during the 16th


century. He performed an experiment wherein
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he trapped a fixed amount of air in the J-tube,


he changed the pressure and controlled the
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temperature and then, he observed its effect to


the volume of the air inside the J-tube. He
found out that as the pressure is increased,
the volume decreases. He finally concluded that the volume of a fixed
amount of gas is inversely proportional to its pressure at constant
temperature. As one variable increases in value, the other variable
decreases. An inverse relationship is described in this way.

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Physically, what is happening? The gas molecules are moving and
are at certain distance apart from one another. An increase in pressure
pushes the molecules closer together, reducing the volume. If the
pressure is decreased, the gases are free to move about in a larger
volume.

Formula and Derivation

As per Boyle’s law, any change in the volume occupied by a gas (at

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constant quantity and temperature) will result in a change in the

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pressure exerted by it. In other words, the product of the initial pressure
and the initial volume of a gas is equal to the product of its final pressure

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and final volume (at constant temperature and number of moles). This
law can be expressed mathematically as follows:

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P1V1 = P2V2

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Where,

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• P1 is the initial pressure exerted by the gas


V1 is the initial volume occupied by the gas
P2 is the final pressure exerted by the gas m
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• V2 is the final volume occupied by the gas
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This expression can be obtained from the pressure-volume relationship


suggested by Boyle’s law. For a fixed amount of gas kept at a constant
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temperature, PV = k. Therefore,
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P1V1 = k (initial pressure * initial volume)


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P2V2 = k (final pressure * final volume)


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∴ P1V1 = P2V2
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This equation can be used to predict the increase in the pressure exerted
by a gas on the walls of its container when the volume of its container
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is decreased (and its quantity and absolute temperature remain


unchanged).
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Sample Problem 1
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A fixed amount of a gas occupies a volume of 1L and exerts a


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pressure of 400 kPa on the walls of its container. What would be the
pressure exerted by the gas if it is completely transferred into a new
container having a volume of 3L (assuming the temperature and
quantity of gas remains constant)?

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Given:
Initial volume (V1) = 1L
Initial pressure (P1) = 400 kPa
Final volume (V2) = 3L
As per Boyle’s law, P1V1 = P2V2 ⇒ P2 = P1V1
V2
P2= (1L) (400kPa)
3L

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P2= 133.33 kPa

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Therefore, the gas exerts a pressure of 133.33 kPa on the walls of the 3-

m
liter container.

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Sample Problem 2

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A gas exerts a pressure of 3 kPa on the walls of container 1. When
container 1 is emptied into a 10-liter container, the pressure exerted by

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the gas increases to 6 kPa. Find the volume of container 1. Assume that
the temperature and quantity of the gas remain constant.
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Given:
Initial pressure, P1 = 3kPa
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Final pressure, P2 = 6kPa


Final volume, V2 = 10L
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According to Boyle’s law, V1= P2V2


P1
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V1= (6 kPa) (10L)


(3 kPa)
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V1= 20 L
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Therefore, the volume of container 1 is 20 L.


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What’s More
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Here are some enrichment activities for you to work on to


master and strengthen the basic concepts you have
learned from this lesson.

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Problem Solving Activity

Answer the following problems for a better grasp of the lesson and
provide solutions.

1.Oxygen gas inside a 1.5 L gas tank has a pressure of 0.95 atm.
Provided that the temperature remains constant, how much pressure is
needed to reduce its volume by ½?

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2.A scuba diver needs a diving tank in order to provide breathing gas

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while he is underwater. How much pressure is needed for 6.00 liters of
gas at 1.01 atmospheric pressure to be compressed in a 3.00 liters

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cylinder?

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3.A sample of fluorine gas occupies a volume of 600 mL at 760 torr.
Given that the temperature remains the same, calculate the pressure

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required to reduce its volume by 1/3.

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What I Have Learned


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A. Indicate what happen to the following variables when gas is


compressed in a cylinder by writing “decreases”, “increases” or
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“remains the same” on the space provided.


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1. mass ______________________________.
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2. number of gas molecules ____________________________.


3. pressure ___________________________.
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4. volume __________________________.
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5. the distance between gas molecules ________________________.


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6. density _________________________.
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B. Complete the following statements about the nature of gases as


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presented in the kinetic molecular theory by filling in the appropriate


word(s) listed below.
kinetic energy zero perfectly elastic
Constant random motion potential energy pressure

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1. Gas particles exert ____________________________ on one another.
2. Gas molecules are said to be in ________________________.
3. The volume of gas particles themselves is said to be ____________.
4. The collisions between gas particles are _______________________.
5. The temperature of a gas is a measure of the average _________of
the gas particles.

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What I Can Do

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A. Directions: Identify and underline the possible weakness or flaws in
the postulates of Kinetic Molecular Theory. Write TRUE if the postulate

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is accurate and FALSE if the postulate is flawed.

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1. A gas consists of a collection of small particles traveling in straight
line motion and obeying Newton’s Laws.
2. The molecules in a gas occupy negligible volume. m
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3. Collisions between molecules are perfectly elastic (that is, no energy
is gained nor lost during the collision).
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4. There are negligible, attractive, or repulsive forces between


molecules.
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5. The average kinetic energy of a molecule is constant.


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B. Directions: Write at least 5 examples of practical situations or


activities which you think Boyle’s Law is applied.
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Activities/Situations Properties of gases involved


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1. 1.
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2. 2.
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3. 3.
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4. 4.

5. 5.

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____________________________________________________________________________________________________________________________________________________________________________
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ASSESSMENT

Directions: Select the best answer by writing the letter of the correct
answer in your answer sheet.

1. Jane can still pump air in the party balloon even though it is already

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inflated. What explains this phenomenon?
A. balloons look better if its size is bigger

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B. balloons are made up of plastic
C. the air inside the balloon is hot

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D. air molecules can be compressed

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2. Determine what will happen to the temperature of a confined gas as
the pressure decreases.

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A. the gas temperature stays the same
B. the gas temperature decreases

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C. the gas temperature increases
D. there is no enough data
3. What do you expect to happen to the volume of a gas if its pressure m
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is doubled and its temperature is reduced to half?
A. its volume is increased
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B. its volume is doubled


C. its volume is decreased
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D. its volume remains unchanged


4. Which example has particles that can be drawn closer to occupy
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smaller volume?
A. block of wood C. fruit juice
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B. ice cube D. air inside the syringe


5. Which of the following phenomena does NOT involve the application
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of gas pressure?
A. burning fuel C. vulcanizing tire
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B. falling leaves D. rising hot air balloon


6. Last summer vacation, the Cruz family decided to go to Pagudpod,
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Ilocos Norte to have a beach party. On their way to Ilocos, all of them
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were surprised when the tire suddenly exploded. What is the


probable explanation for the blown out tire during a long summer
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drive?
A. High temperature causes a decrease in volume.
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B. The amount of the gases inside the tire is increased.


C. The mass of the gases inside the tire increases causing a blown
up tire.
D. The volume of gases increases as the temperature increases,
causing a blown up tire.

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____________________________________________________________________________________________________________________________________________________________________________
Strictly for students use only of the Division of Cebu Province. DO NOT share to other divisions and other teaching or non-teaching personnel. Any violation will be dealt with accordingly. Beta evaluation is still pending.
7. How can you possibly prove that gases have negligible mass?
A. put a balloon in a digital balance before and after you fill it with
air
B. feel the weight of the samples on both hands
C. ask two persons to hold a box filled with air
D. support your claim of through equation
8. What kind of movement is exhibited by gas molecules?
A. vibrational movement
B. rotational movement

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C. translational movement

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D. combination of a, b and c
9. What will happen to the gas pressure as the temperature increases,

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if the amount and volume of the gas are kept constant?

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A. the gas pressure remains the same
B. the gas pressure decreases

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C. the gas pressure increases
D. there is no significant effect

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10. What law explains the mechanism of gas compressor?
A. Boyle’s Law C. Charles’ Law
B. Ideal Gas Law D. Combined Gas Law
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Great Job! You are almost done with this


module.
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Additional Activities
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A. Directions: Use Boyle’s Law equation to solve the following problems


below and provide solutions.
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1. A sample of oxygen gas (O2) has a volume of 3.0 L at an initial


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pressure of 760 torr. The same amount of gas at the same temperature
was transferred to a 12.0 L container. What is the pressure the oxygen
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gas(O2) in the new container?

2. A gas tank can hold 25.0 L of helium (He) gas at a pressure of 6.0
atm. How many liters will the gas occupy if the pressure was decreased
to 0.50 atm at constant temperature?

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B. Explain the science behind the following areas/scenarios based on
Boyle’s law. Use not more than five (5) sentences.

1. Invention of syringes
2. Plane travel
3. Popping a balloon
4. Breathing
5. SCUBA diving

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____________________________________________________________________________________________________________________________________________________________________________
Strictly for students use only of the Division of Cebu Province. DO NOT share to other divisions and other teaching or non-teaching personnel. Any violation will be dealt with accordingly. Beta evaluation is still pending.
Strictly for students use only of the Division of Cebu Province. DO NOT share to other divisions and other teaching or non-teaching personnel. Any violation will be dealt with accordingly. Beta evaluation is still pending.
____________________________________________________________________________________________________________________________________________________________________________
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WHAT’S NEW
-Answers may vary
ADDITIONAL ACTIVITIES WHAT’S IN
A. 1. 190 torr A.
2.300 L OBSERVABLE
B. answers may vary PROPERTIES
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-texture
-shape
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WHAT I CAN DO -odor


1.straight line-false -state
2.occupy-false
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-diffusability
3.true -expandability
4.true
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-compressibility
5.true MEASURABLE
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PROPERTIES
ASSESSMENT WHAT I HAVE LEARNED -pressure
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1.D A. -density
2.B 1. remains the same -volume
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3.C 2. remains the same -temperature


3. increases -number of moles
4.D
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4. decreases -mass
5.A
5. decreases -weight
6.D B.
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6. increases
7.A B. 1. B
8.D
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1. pressure 2. B
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9.C 2.constant random motion 3. A
10.A 3. zero 4. C
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4. perfectly elastic 5. D
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5. kinetic energy 6. E

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WHAT’S MORE

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1. P2 = V1P1/V2 WHAT I KNOW
= (1.5L) (0.95 atm) / (0.75 L) 1. C

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P2 = 1.9 atm ( the volume is reduced so the 2. A
pressure will increase) 3. C

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2. P2 = V1P1/V2 4. A
= (6.00L) (1.01 atm) / (3.00 L) 5. D

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=2.02 atm (the volume is reduced so the 6. B
pressure must increased) 7. A

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3. P2=V1P1/V2 8. B
=(600 Ml) (760 torr) / (200 ml ) 9. C
=2280 torr (the volume is reduced so the pressure 10.A
must increased)
Key to Corrections
Book References:

Antonio,R.L., Ole, A.F., Garcia, RJ.G, Laurente, JA.T., (2015).Science for the 21st
Century Learner. Makati City, Philippines: Diwa Learning Systems Inc.

Briones, L.L., Templora, V. F., Tibajares, I. S. Jr. (2010). Chemistry Power Science
and Technology III, vol.2, Manila: St. Mary’s Publishing Corp.

Chang, R. (1998). Chemistry, 6th ed.,Boston:Mc.Graw-Hill

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Davis, R. E., Sarquis, M., Frey, R., Sarquis, J. L., (2009). Modern Chemistry.

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Teacher’s Ed., Orlando: Holt , Rinehart and Winston

LeMay, E.H. Jr., Robblee, K.M., Brower, H., Brower D.C., Beall H. (2000).

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Chemistry Connections to Our Changing World. 2nd ed., New Jersey: Prentice

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Hall, Inc.

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Other References:

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JERRY RATZLAFF (2016).”BOYLE’S LAW”
https://www.piping-designer.com/index.php/properties/fluid-mechanics/228boyle-
s-law

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Kathy Serratore, n.d. “ Changes in Gas Volume/ Gas Laws”
https://www.oercommons.org/courses/changes-in-gas-volume-gas-laws
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Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean
Dupon.”Boyle’sLaw”https://chem.libretexts.org/Bookshelves/Introductory_Chemist
ry/Book%3A_Introductory_Chemistry_(CK-12)/14%3A_The_Behavior_of_Gases/14.0
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https://byjus.com/chemistry/boyle’slaw/

ps://courses.lumenlearning.com/introchem/chapter/kinetic-molecular-theory -and-
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