SKEMA PEMARKAHAN

SMJK CHAN WA
PEPERIKSAAN PERTENGAHAN TAHUN 2021

KIMIA KERTAS 1 4541/1

1 D 11 C 21 D 31 A

2 A 12 B 22 B 32 D

3 C 13 C 23 C 33 C

4 D 14 A 24 B 34 A

5 C 15 A 25 A 35 C

6 A 16 C 26 C 36 A

7 B 17 C 27 B 37 A

8 B 18 A 28 C 38 D

9 A 19 D 29 C 39 B

10 D 20 B 30 B 40 B

KIMIA KERTAS 2 4541/2

Section A
1
 [60 marks]
th
Date : 28 September 2021 (Tuesday)
Time : 9.15 am -11.45 am (2 ½ hours)

SUGGESTED ANSWER MARK

1. a Molecules 1
b Solid 1
c NaCl – ionic bond, Naphthalene – Van der Waals forces. 1+1
Ionic bond is stronger than Van der Waals forces.
d To fill electrical bulbs. OR 1
Provides an inert atmosphere for welding industry.
(any correct answer)
TOTAL 5

2. a i Number of protons in the nucleus of an atom. 1

ii 16 1
b L and M 1+1
Proton number same, number of neutrons different
c i 1 OR one 1
ii 1+1

TOTAL 7

3. a Nucleon number 1
b W : 2, 1 1
c i 4W + O2  2W2O 1 +1
ii 4 mol W ≡ 60 g W2O 1 + 1 +1
∴ 0.05 mol W ≡ 0.05 mol / 4 mol x 60 g
= 0.75 g
TOTAL 7

4. a Molecular formula : a chemical formula that gives the total number of atoms of 1
each element in a molecule of a substance.
b Empirical formula : shows the simplest atomic ratio between the elements in 1+1
the compound.
C2H5
c i X=5 1+1
Y=3
ii 1 mol of C3H8 reacts with 5 mol of O2 1+1
to form 3 mol of CO2 and 4 mol of H2O.
(or interpret using any other chemistry quantity)
TOTAL 7

5. a Iodine or I2 OR 1
Acetamide or CH3CONH2
b Sublimation 1
2
 c i Freezing point : 1
The temperature at which a substance changes state from liquid to solid. OR
The temperature where solid and liquid phase are in equilibrium.
ii 82 o C 1
iii Heat energy that is lost to the surrounding is balanced by the heat energy 1+1
released when the particles attract each other to form solid.
iv After t2 OR at t3 1
d i 1

OR

ii Any figure from 75 o C to 81 o C 1

TOTAL 9

6. a Have 3 shells occupied with electrons 1

b P : 2, 8, 5 1
c Sodium. 1+1
Sodium has the weakest nuclear attraction force towards its electrons.
d Chlorine or Cl2 1
e i Cl is more electronegative. 1
ii Nuclear attraction force of chlorine towards its electrons is stronger. 1
f i Argon has stable octet electron arrangement. 1
ii Aluminium 1
iii Al2O3 1
TOTAL 10

7. a i HCl 1+1
CH3COOH
ii HCl 1
iii HCl (aq)  H+ (aq) + Cl- (aq)
1 mol 1 mol
pH = - log [H+] OR
1 = - log [H+]
[H+] = 0.1 mol dm-3 1+1
b i 2KOH + H2SO4  K2SO4 + 2H2O 1+1
ii 1
Titration I II III
Final reading of burette (cm3) 9.90 19.90 30.00
Initial reading of burette (cm3) 0.00 9.95 19.85
Volume of sulphuric acid used (cm 3) 9.90 9.95 10.15
(written in 2 d.p)
iii 10.00 cm3 1
iv MAVA/a = MBVB/b 1+1
(1.0)(25.0) / 1 = MB (10.00) / 2
MB = 5 mol dm-3
TOTAL 11
8. a Dilution 1
b Mi V i = Mf Vf 1+1
Vi = (100 cm3) (0.2 M) / 1.0 M
Vi = 20 cm3
3
 c 20 cm3 1
d Beaker has low accuracy. 1
e No 1+1
Because pipette is been calibrated to measure the specified volume.

TOTAL 7
63
Max : 60

Section B
[20 marks]
Answer any ONE question from this section

9 a Copper (II) oxide and carbon dioxide 1

4
 (reject formula)

Green colour solid/copper carbonate change to black solid. 1

Limewater turn cloudy. 1

CuCO3 (s)  CuO (s) + CO2 (g) 1+1

(one mark for phases)

1 mol of CuCO3
forms 1 mol of CuO and 1 mol of CO2. 1+1

TOTAL 7
b i
Element C H O 1
Mass (g) 40 6.7 53.3
Mol 40/12 6.7/1 53.3/16
3.33 6.7 3.33
Ratio 1 2 1
Empirical formula : C H2 O 1
Mass C H2 O = 30 g 1
n (30) = 60
n=2 1
Molecular formula = C2 H4 O2 1

TOTAL 5
ii 2 CH3COOH + Mg  (CH3COO)2Mg + H2 1+ 1

24 g Mg ≡ 24 dm3 H2 gas 1
∴ 6 g Mg ≡ 6 g Mg / 24 g Mg x 24 dm3 H2 gas = 6 dm3 H2 gas 1

TOTAL 4
c i Liquid and gas 1

1+1

TOTAL 3
ii 1+1+1

Label axis – 1 M
5
 Shape of curve – 1 M
3 temperature labeled – 1 M

TOTAL 3
TOTAL 22
Max =20

10 a 1. Period 3 4
2. Because R has three shells occupied with electrons.
3. Group 17
4. Because R has seven valence electrons.

b 1. Q atom donates two valence electrons to form a positively-charged ion 7

(cation), Q2+.

2. Q2+ ion achieves a stable octet electron arrangement.

3. Each R atom accepts one electron from the R- ion.

6
 4. Both R- ions achieve stable octet electron arrangements.

5. Q2+ ion and R- ions of opposite charges will attract one another by strong
electrostatic attraction force.

6. Electrostatic attraction forces are known as ionic bonds.

7. An ionic compound, QR2 is formed.

c i CR4 1

ii 2

d 6
(b), QR2 (c), CR4 Mark
Ionic compound. Covalent compound. 1+1

Melting High melting point. Low melting point. 1

point
Strong ionic bond Weak Van der Waals 1
between ions. force between
molecules.
Can conduct electricity Cannot conduct 1
Electrical in molten state and electricity in all states.
conductivity aqueous solution.
Have free moving ions Neutral molecules do 1
that carry charges. not carry any charge.

TOTAL 20

Section C
[20 marks]
Answer ALL questions from this section

11. a LIST OF APPARATUS : 4

1. Electronic balance
2. Filter funnel
3. 500 cm³ volumetric flask
4. Dropper
5. Wash bottle
6. 250 cm³ beaker
7
 7. Glass rod

Two or three apparatus correct – 1 mark

Correct volume of volumetric flask – 1 mark

b DETERMINATION OF MASS OF SODIUM SULPHATE : 3

Formula : Number of mol = Mass/molar mass = MV

Insertion data : Mass/142 = (2.0)(500/1000)

Final answer with unit : Mass = 142 g

c PROCEDURE OF EXPERIMENT : 9

1. Weigh the mass of sodium sulphate calculated using the electronic

balance.

2. Add 100 cm' of distilled water to the solid sodium sulphate in a

beaker.

3. Stir the mixture with a glass rod until all the solid sodium sulphate is
completely dissolved in the distilled water.

4. Transfer the sodium sulphate solution, into a 500 cm3 volumetric

flask using a filter funnel.

5. Rinse the beaker & filter funnel with a little distilled water.

6. Remove the filter funnel. Add distilled water until it approaches the
calibration mark on the volumetric flask.

7. Using a dropper, add distilled water slowly until the meniscus level is
aligned exactly on the calibration mark of the volumetric flask.

8. Close the volumetric flask with a stopper.

9. Shake.

d PRECAUTIONS STEPS THAT SHOULD BE TAKEN IN ORDER TO OBTAIN AN 4

ACCURATE CONCENTRATION OF SOLUTION :

1. Beaker & filter funnel are rinsed with distilled water.

2. Reason : To make sure all the remaining solution is transferred into

8
the volumetric flask.

3. A dropper is used to add distilled water slowly until the meniscus

level is aligned exactly on the calibration mark of the volumetric flask.

4. Reason : A dropper allows you to add liquid in small volumes, which

helps ensure that you add the correct quantity of liquid to the flask.

TOTAL 20

END OF MARKING SCHEME