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EQUILIBRIUM
Chemical Eqm
of Egm
"
.
Def
•
Active mass
const
.
Cgm
& Kc
✗
Kp
•
Relation btw Kp Kc
{
◦ &
•
factors affecting K
Application of keg
•
Le chatelier
principle
•
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Aig , g) 9g ,
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✗b
✗
Chemical Egm
rf :B
Cone cone
" nc
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f
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> 0 ° °
1- t 1-
tegm tegan tgmt
1-
Egm
REVISE irreversible
in forward well Can't in both
proceeddirection proceed direction
as
•
Can as •
.
backward .
•
Reaction never Completes .
•
Reaction
goes for Completion
.
Egm=
◦
no
-
Eqm
[ ] Aclireman = Concentration
AA + BB CC t DD
(g) (g) (g) (g)
Kc =
keg =
[c]c[D]d-
a b
[ A) [ B)
= pi pd
kp= keg
%
Relation b/w kpslkc
Ang
<
p
=
Kc (Rt )
Gaseous Reactant
Ang
Gaseous
product
-
-0
kp=kc
ng
-
Kc
Ang > 0
Kp >
Ang <
0 kpskc
factorsaffecliykeg
◦
Reaction Reverse →
Keg Reciprocal
→
◦ Reaction multiply by n →
keg → kn
◦
on adding Rxn
keg gets multiplied
→
.
=
K > 103 Applicalionofkeg
(K product is Stable
if is large more
-
product
Small
if K is
Reactant stable
↳ K < 10-3
product,→
less
Predicting direction
of Reaction .
Qc 5 Kc Reaction backward
Qc = Kc Reaction Egm
towards lower
Poses sure
↑
↑ Rxn moves moles
Pin
"
Pressure ↓ ,
-
higher notes
nt,
⑤ Endothermic Exothermic Dt④
Rxn backward
T ↑ Rxn forward T ↑
Tt .
Rx 's backward T ↑ Rxn forward
?⃝
⑥ Inertgasaddn
at wrist V01 - no
charge
shifts towards
pressure
at Comt
→ Rxn
moles
higher
✓ ↑ .