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CHEMICAL

EQUILIBRIUM
Chemical Eqm
of Egm
"
.

Def

Active mass

const
.

Cgm
& Kc

Kp

Relation btw Kp Kc

{
◦ &


factors affecting K
Application of keg

Le chatelier
principle

!
1m11sec
chemicalGM-y.tl
¥6k ✗
,

f- =
%

÷ :-.
- - - -
- - -

⇐ mis: tf
+* + "
Aig , g) 9g ,
g)
✗b

Chemical Egm
rf :B
Cone cone
" nc
100 I "
too

[ ¥ go
:
'

f
'

. : e :
> 0 ° °
1- t 1-
tegm tegan tgmt
1-
Egm
REVISE irreversible
in forward well Can't in both
proceeddirection proceed direction
as

Can as •
.

backward .


Reaction never Completes .

Reaction
goes for Completion
.

Converted Reactants almost 100%



products can be • are

back to Reactant converted to


product
°
contain
Closed container
open
°

Egm=

no
-
Eqm
[ ] Aclireman = Concentration

AA + BB CC t DD
(g) (g) (g) (g)

Kc =
keg =
[c]c[D]d-
a b
[ A) [ B)

= pi pd
kp= keg
%
Relation b/w kpslkc
Ang
<
p
=
Kc (Rt )
Gaseous Reactant
Ang
Gaseous
product
-

-0
kp=kc
ng
-

Kc
Ang > 0
Kp >

Ang <
0 kpskc
factorsaffecliykeg

Reaction Reverse →
Keg Reciprocal

◦ Reaction multiply by n →
keg → kn

on adding Rxn
keg gets multiplied

.

=
K > 103 Applicalionofkeg
(K product is Stable
if is large more
-
product
Small
if K is
Reactant stable
↳ K < 10-3
product,→
less

Predicting direction
of Reaction .

Qc 5 Kc Reaction backward

Qc = Kc Reaction Egm

Qc < Kc Reaction forward


le.chata.1.exptrior-i.pl# P
① Reactant
↑ Rxn forward

② [product ] ↑ Rxn Backward

towards lower
Poses sure

↑ Rxn moves moles

Pin
"

Pressure ↓ ,
-

higher notes

nt,
⑤ Endothermic Exothermic Dt④
Rxn backward
T ↑ Rxn forward T ↑
Tt .
Rx 's backward T ↑ Rxn forward
?⃝
⑥ Inertgasaddn
at wrist V01 - no
charge
shifts towards
pressure
at Comt
→ Rxn
moles
higher
✓ ↑ .

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