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, Bhagat Panchal Sir

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iii.
 NCERT Ques Pry G
AMIA
•
.
.

Kao 's )
inn .
°
B # Br
"
40,1 24,6 -

Toibrom

Bharat PanchalSir
aniline

By
i

Br
. .

C)
CH
3
-
N
1
-
(
Hg -

CHS (A -

I -2013
)
These are alkyl or
aryl derivatives of Ammonia CHS
H H R R N,N -
Dimethyl
H -
N' -
H R -
N' -
H RAI -
H R -
N' -
R ethan amine

Ammonia Ldamine amine famine c) CHECK -

cu - NH told
,
,

CH3

Structure of Amines But -3 en - -

2- amine .

n, structure trigonal beramidae

Preparation of Amines
qq.gg?Yid7.
-

R *
. R 3 Bond Pair -11 lone Pair
R Reduction Nitro
Hybrid . -7 Sps
-

of compounds -

R NO
-

R -

MHz
•
Nomenclature ,
or
Haired
Non FHL
CH -

Cha -
CH -

NHL propan -
I - amine d- snlteceor A
, ,
'*
Log aniline
CH
; NH CH CH
N.me/hylethanamine Nitrobenzene
-
-

, ,

¥9 EH Reduction of Amides
"

Aniline 2- Amino toluene →

-

R - E -

Mk
R cha- -

NH
,

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 NH HAE
cha MHz
↳ Hs
Gg GHS
-
- -

,
,

Hoffmann Brom amide

Degradation Hoffmann Ammonolysis of Alkyl Halide
.
•

Baby art
tr ×
atria El NIR
tr x R tr R
NIH
x
H Tex
Ny
-

H
Base
- - -

Trick
-
- -

qq.ie?nxR-Y-RR-C0-NHgtBrgt4K0H--iR-NH2
Fantine -
2K Br
U
tamed
-

H + calls U
-

GHS
Ny famine
H 1-
Nh The GHS
H
Tey
- - - -
- - -

kids -

2h20
.

↳ Hs CO NH , + Brat 4 KOH ↳ Hs MHz GHS U GHS N ↳ Hs

Na calls Tna
1-
- -

gits
-
- -
- -

,
. -

747%623110
-

Protean amide Ethan amide Imine GH.sEam

• Gabriel phthalimide synthesis : -

Physical Properties of Amines : -

Trick -
steak Basement £ R X -
MT -

physical State : -

Hao UH I lower amines are

gases and
liquids
but higher amines solids lower aliphatic

I%iniiiR
are .
The

sniffing
amines are with fishy odour
gases
.

X
Aryea mines usually
-

→ are colourless
but coloured
Hoo
get storage due to atmospheric
-

on

oxidation .

NR -12110 →
EIFFEL + R -

MHz -

solubility : .

P.IR lower aliphatic amines are soluble in

water because they can form H Bond with water
amines by this
-

Aromatic prepared
'
I cant be

nip pint
'

because aryl halides

if
do not H
method undergo
H

ou
-

H
- -

H
- -
- - -
-
- - -
-

nucleophilic sub with the anion formed .

by
pnthalimide .

primary and secondary amines are soluble in

Reduction of Nitriles
water due to H
bonding arewhile se amines
-

• !
-
-

insoluble in water .

R -

CEN + Acid R -
CH -
NH
, ,

GHS -
⇐N teens ¥5 ↳ Hs -

cha nine
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 -

The
solubility decrease with increase in size
Amines are basic in nature and seats with
of hydrophobic alkyl part .

acids to form salts .

P TR The solubility of amines is less than that

R.in#ttHx-R-NtOHzX0
-

of alcohol
of comparable molecular mass
Ammonium salt
because alcohols polar than amines
.

are more
and form stronger H - Bond
Order of basic character of amines in
.

gaseous phase
→
By -
Bharat Panchal Sir
Point
Boiling The order of b.pt isomeric amines
C Acc .
to +I effect ]

30 amines > amines > famines > NHS

-
2
se amines 7 a amines 23 amines '

① 3. amines
because
do not
no H -
have
is
intermolecular
attached to N -
atom
Boding
H -

.
R -

ni :
7 R -

Niu : > R -

In :
>
ath :

④ so amines have maximum amount of H

Bonding
-

because two H atoms attached to N atom However in aqueous phase : -

-
are -

is subtle
.

There

MT interplay of Inductive effect, steric effect and

l③asic Character of Amines}

Lemmerman
solvation effect

→ Amines are Fa sic in nature due to the presence

@ Hg Ctg ) -

NH > GHz CHIN ) CHS CH

, MHz > NH,
lone
of pair of eo on
nitrogen atom .

Le zo ye

→
Aliphatic amines
due
stronger bases
are than ammonia
@ Hs) NH 7 CH, -
Nu > CHIN > MHz
to +I
effect of Alkyl group .

, ,

I le 3-
→ Aromatic amines are weaker bases than ammonia
to Resonance in Aniline
Ange group
.

due -
I
effect or .

→ Besides inductive effect , effects like "

ste so
: e :#atia .su#i:oa.nemeectsaressiconance .
a

strength of amines .

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cahuf.7iisst.io'
 Acylation
'

•
Carbylamine
- --
Reaction
mm
NH NH + HU
-

,
t
-

cow → - -
co
Ey
-

R NH + CHU, -13 KOH S R NIC -13kV -13110

¥7
- -

-13150nF ↳ Hs CHS Nff

-

t Coll -7 Ctf -
NH + HCl
GHS NHI
-

CHU, NC -13 Kee

-

t +3110
- - -

-
NH -1 CHU, -13 KOH Is - NC + Skee
-13140
-

Electrophilic Substitution Reaction

, - m m- nv m

Bhlpgiaoatncnd onanism
Brominate on
'

Grignard Reagent
B¥¥?BI3HBr
•
Reaction with
-- -

R NH, - + CHS
-

MGI
mm-

→ Chat
-

R NU- -

MGI
%k+zBr ,
a
we
go
Br
RR> NH +
cuz -

MGI → CHR +
B -
N -

MSI p.FR for monobzomination treat aniline with

Cg Hot
,
NH -1
GHS MgI → NU
MSI acetic anhydride (CH, coho
- -
-
-

Piru Tertiary amines do not

do
react with
contain
Grignard III C÷÷÷ ,
" "
s
""

; fiefs :b
reagents as
they not
active H atoms
MH
-

Nth
.

Mutation
.

+ Hao t's t
Br

'
Br
GHS NH,
-
1- GHS - -
Br j (GHS-72 -

NH

Ciii Nitration -

Ffg (GHA,
ion:-,
+ GHS -

Br N testes . -
Br

EI
no

÷i÷÷:
-1
'

.
no
Hasten '
Br rekaemgeammom.am bromide
.

,
⇐ %) Cat 'D 12%3
IN Ha A"
-
NHA t CHI -5 -
NH - CH
,
+ CHI Es Foi
"
€014 p.gl/kocHgNHu
Go ÷÷o
#
pyridine
@ Hd
'
Nt @
N
HII
-

+ CH I
'
-
-

, , no
,
no
I

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or Sul phonation
T

inHg HS OF
,NHs
Tf
'
→
+ ii. so,
x
1
Aniline Anilinium
Hydrogen Sulphate 505
⇐ Willer ion )
MHz
x
Basic character 2
F- 101
→ Basic character 9 I
Kb

'
SO H Pkn
,

Hingberg Test ( Arrange following in

increasing
)
the the order of
benzene sulbhonyl Chloride
•

P
"
Values :
cc.B.SE 20181
⇐ sq Ce ( Heinsberg )
-

Reagent If NHL ↳ Hs NH Nucky

I. Amines
-
- -

, , ,

solution : -

GHS Ntfs -
-
NH -
CH, s # NH
¥-502 -

Clt tf N
-
R → -

so
,
- NH R -
( soluble em alkali ) ,

famine Give reasons : CCHD.NU is more basic than ( CHIN

2 Amines
' -
in solution (
an
aqueous C B .SE 2018 )
-
-

Are CHINH is more basic than ( CHIN in an

Cinsobk in aqueous solution due to less
E- SEU 1- HN -
R → ⇐ SO -

NR alkali )
,
, , steric hindrance .

2. amine
3. Amines
-

Soga T N -

Rs → No Reaction
3- Amine NH
- L

Piru fried al
because
craft
it form
Rxh are not
salt with anhy
possible for
.
Alas
that is in
used as
catalyst the reaction .

iii. + nice
.
-
Eiji
's
69::ge7eI"Eau .

as
strong deactivating
Gould .

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s

Spatafora

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8%7%34
Mcd of Amines

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 PYQ OF AMINES
✓
✓

y
✓

:
u

n
✓

:
"
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