㉓ phase

two
system
-

SPlu)→ Cutr du
(
Correlation function E( r )
=
)

Pn( r ) =
Jn ( u )
n (u + r ) du

.
I(
q
)
=
S8 () ei ε idr
nall
=

SRL ) EiEIdT +VDE

@ Define
" "

normolized/ correlation function

Debye

( qx
{()
γ () = ) γ (t ) γ (E)
鍿

0s
=

v <
→
P {( ) R ( = 0 =
V <M

"

⑤ Define In variant "

Q =

JIc 5)
dsidsdoda
)(Iiqidq2
= π☆ JIcEqdq
S [ SE(i ) difds SR
eza 5
Q ( r) dr {( ) V
( )8
<n
= = 0 =
8 Ideal two
modd phase -

assum : I .
two
phase ex .

crystallization or
phase seperation
interface / A

boundary between the 后 phase sharp

2 . is

3 .

isotropic

q>=φ Mi
(
∵<
,
+
kh : M .
=δ .
-

δ>=☆ .
-

(φ ⼼. .
t
φ 0 . .
) =
4 .
0
<

U .
= -

φ ☆ .

V<
>= Q
4 ( δ) + . . . <☆ ] π ( [ q qdq
2

n =√ 4 φ ☆
4

=
k
[
- 4
3^ .
=
,
.
2

@ know . k (
P . ,
Pz degree of
crystallintyculate 結晶度 ) .

expt .
Iq
,
vs . q → ILqE vs . q 1
Q =☆ [ Iqdq =
VQ φ
.
0

bknow 4 ,
a s calculate 8 Ʃ

- s proof 局部相溶

if
fully
0

δ 0 00:
"

: c :

seperation ,

P o

partial miscible 8 , Ʃ< :

P

=
 Porod
lawI
ixqy highq .
assum : 1 .
ideal wo -

phase
2
.

isotropic
3
. flat interface
4 .

high q

methodL from spherical partide in intinted medium

)

= 9Csinx - xcosx
Icq) =
NC08) V
×
6

運⽤ sin 2 X = 2 simxcosxcos2 x
=| - sin =
2
x
= 2 ccsx -

'

R ( 1 + cos 2 ER )
。

ICq ) ≈ N ☆) δπ= 4

q
-

4
→ I α q ,
q →∞

②
method from correlation function

.
R ( )= ( v )+ v + EB ( ) Ps ( r )
R
B
) r +
(

B ( V φ Sr ) n
=

= -

, .

Rs Sr(
-
nip . h 9 R ) +
.
.
 →
Pn ( r )
= V
<y > 正卡了 wherelp =☆

lpqy
8π
.
I(
q
)
=
V(
ns ( Debye Bueche eq )
.
.

when q →∞
2
xq V <n π TcqI
4=

(
= q
)
>
q

袋
)

inhomogeniety
=
4δ
lp =☆ 器 些 ☆
4 .42charactic length
h

= 4

"

SA= 85cos θ ' 85 "cos θ '

=

'
" "

' θ 8s θ
SV l δ A= , ss
cos + cos
= l

. -

SV =Ʃ< cos θ>Ʃ 8 S +< ] =☆< l DS

"

.[ Ʃ 8V
"

Ʃ l >
cos θ >Ʃ 8 s =
Vφ .
.

< l 7
. 454, < l 7 45 .
.
=
.
=

ei =

ei t
a =

4号 ※ +

4 ÷ 片 =

4 .
号4 4
.
@ know 4 4 . ,
.
s
calcl ) .
,
< l .
3 ,

lp

expt .
I(
q)
U. s
. q
> IEv . >
. q
, Q
=☆ ( Iqdq ,
vs .
q

when q
→∞ . ( Ʃ ) < l .
>= 4 ☆ Q .
成 =☆+ ⺠
bKnowf .
, f
= cal . lp .
s ,
( ÷)

[ 在=
( e)
SIE ) “
expt .

ICq ) v . s
.q [ 7

eEidqt ()
= vs …
[( r ) =

{co ) e > {

05 =
p
- 公

S ☆^ 斜率

R [ 03 =
V <作 , 截距

real two phase

model -

fluctuation with
density
D phases due to thermal motion

expt data I ( q = Iid ( q

.
) )

IE
+
(
+I
ICq
) q
)
+

neworrelation empirical ex ,

I .
+ I .
= debq or a+
bq

② Diffuse intertace
boundary
δ ()= Pid ()*
( ) =☆ (u ) ( r - u) du
g
g

品
g (r ) =

( rπj β e
 G qz
A (q ) =
Aid (q ) * G ( q ) gcr ) T
(q =
)
代些
.
q

Iid ( q ) G '( q π
^

e
=2
。
I (
= )

q) 4

eqr
Ixq 4
<

q
=

4 f

Ireal q θ
'

。 … =
2 π☆ S

whem E →0

4
.

Ireal q …
=
2 π S ☆= 截距

d [ adq(
} = 0=
+

c∞ S f )e ] q 斜率
[

2 πC ☆ S
^ '
π 5
'
=

) [ 2
-

鐵斜距
σ==

⼀
Auto correlation Function periodical stacks lamellae
of
板⼼

A (ε) "
∞ (r )
{ 1 .

semiarystallime polymers
zismmetic
diblockpolymer long period
=∞ ( r )eiqrdr A( fpcteiq rdr
*

.
A(
ε)
=
∵
q)

= { staseiq 'indu xfstsetiqndu ffCpa fiqtu

'-u )
∴
ICq )
=

ALE ) A * (ε )

'
) 'd d

let T = tU es tU = rttu
-
' diu dr '

I( )
Ifs ( r + ubca ) eiErdtdu . [( scabtutr )da ]eiqidr ∞C) Eiqrdr
q =J
= =

E
A( )

eiEia'du,fsCa )eiqudu
Define '
auto correlation function E (r ) w

averge
of o 0 cu ) Icqi fota )
=

U
'

ue 5 dadr
fpCptutr fotubtu
=

E (F ) =

) du =
) du
- Ca'
SSoCu
)
du ' du
a

Socilotu du = PE )
=
'

EiE
☆ C)
PCU ☆ C )) ( t )→ % ) = V☆ CD () )
SSC ' ☆C ) fiErdzdu
= (

≥
Sda v
=

wheze γ= 0 [⾃ ⾃) ☆(
SISsta"Dc) du ] iqidr
) V ☆以
0
-
=
vs

=
e
→∞ [ 兩⽯相關 ] ☆ (r) → V ☆3

bC] =
JOCa) Ca ) da
→ I(
q
) =

f . Ecr ) Eiqidr =
VD <) DC } >☆

ICq [ p (r ) eiq rdr

.

“
>=

P 0( ) TIcE ,