ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS

ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS

ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS

33. Calculate the ratio of densities if same element undergoes fcc as well as simple cubic packing.
Assume same atomic radius in both crystals.
34.Xenon crystallises in the face-centred cubic lattice and the edge length of the unit cell is
438 2 pm. What is the nearest neighbour distance and what is the radius of xenon atom?

35. A cubic solid is made up of two elements 'A' and 'B'. Atoms 'B' are at the corners of the cube
and 'A' at the body centre. What is the simplest formula of compound?

36. Spinel is a important class of oxides consisting of two types of metal ions with the oxide ions
arranged in CCP pattern. The normal spinel has one-eight of the tetrahedral holes occupied by one
type of metal ion and one half of the octahedral hole occupied by another type of metal ion. Such
a spinel is formed by Zn2+, Al3+ and O2–, with Zn2+ in the tetrahedral holes. Give the formula of
spinel?

37. The density of KBr is 2.38 g cm–3 . The length of the edge of the unit cell is 700 pm. Find the
number of fomula unit of KBr present in the single unit cell.
(NA = 6 ×1023 mol–1 , At. mass : K = 39, Br = 80)

38. Solid AB has NaCl type structure. If the radius of A+ and B– are 0.8 Å and 1.2Å respectively
and formula mass of AB is 48 g/mole, what is the density of AB solid.
Take : Avogadro's number = 6 × 1023

SOLUTIONS
39. 1 mole heptane (V.P. = 92 mm of Hg) is mixed with 4 mole Octane (V.P. = 31 mm of Hg), form
an ideal solution. Find out the vapour pressure of solution?
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
40. At 25°C, the vapour pressure of methyl alcohol is 96.0 torr. What is the mole fraction of
CH3OH in a solution in which the (partial) vapor pressure of CH3OH is 24.0 torr at 25°C?
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
48. The vapour pressure of pure liquid solvent A is 0.80 atm. When a nonvolatile substance B is
added to the solvent its vapour pressure drops to 0.60 atm. What is the mole fraction of
component B in the solution?

56. A 1.2% solution (w/v) of NaCl is isotonic with 7.2% solution (w/v) of glucose. Calculate
degree of ionization and Van’t Hoff factor of NaCl.

57. The vapour pressure of an aqueous solution of glucose is 750 mm Hg at 373 K. Calculate
molality and mole fraction of solute.

58. A solution of crab hemocyanin, a pigmented protein extracted from crabs, was prepared by
dissolving 0.750 g in 125 cm3 of an aqueous medium. At 4°C an osmotic pressure rise of 2.77 mm
of the solution was observed. The solution had a density of 1.013 g/cm3. Determine the molecular
weight of the protein. (g = 10 m/s2)

59. How many grams of sucrose (mol.wt. = 342) should be dissolved in 100 gm water in order to
produce a solution with 105°C difference between the freezing point & boiling point temperature
at 1 atm? (Unit: Kf = 2 K.kg mol–1 ; kb = 0.5 K.kg mol–1)

CHEMICAL KINETICS
61. For the elementary reaction 2A + B2 → 2AB. Calculate how much the rate of reaction will
change if the volume of the vessel is suddenly reduced to one third of its original volume?
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS
ASSIGNMENT ON SOLID STATE, SOLUTIONS, CHEMICAL KINETICS