1124 質均小考

 考試時間 10:20-11:10
 滿分 100，缺考、未交卷為 0 分
 During the problem solving process, consider at least two decimal places
 記得寫名字、寫工整 學號: 姓名:

一、Please define the following statements(20%)

1 Write balanced reaction equations for the C9H18 and oxygen to form carbon
dioxide and water(10%)
1 C9 H 18+ 13.5O2 →9 C O 2 +9 H 2 O
2 How many kilograms of CO2 will be produced as product if 10 kg of C 7H16
react completely with the stoichiometric quantity of O 2? Please carefully
write the conversion factor(15%)
1 kg mole C 7 H 1 6 kg mole C O2 kg C O2
10 kg C 7 H 1 6 ÷100 ×7 × 44 =30.8 kg
kg C7 H 1 6 kg mole C7 H 1 6 kg mole C O2
3 Pease carefully define extent of reaction(15%)

4 NADH (nicotinamid adenine dinucleotide) supplies hydrogen in living cells

for biosynthesis reactions such as
CO2 + 4H → CH2O + H2O
If you saturate 1 L of deaerated water with CO2 gas at 20 oC (the solubility
is 1.81 g CO2 /L) and add enough NADH to provide 0.057 g of H into a
bioreactor used to imitate the reactions in cells, and obtain 0.7 g of CH 2O,
what is the extent of reaction for this reaction? Use the extent of reaction to
determine the number of grams of CO2 left in solution.(20%)
1 g mol C H 2 O
N C H O final=0.7 g of C H 2 O × =0.0233 g mol C H 2 O
2
30.02 g C H 2 O
1 g mol C H 2 O
N C H O initial =0 g of C H 2 O × =0 g mol C H 2 O
2
30.02 g C H 2 O
 ¿−¿ 0 ( 0.0233−0 ) g mol C H 2 O
ζ= =
vi 1 g mol C H 2 O/moles reacting
1 g mol C O 2
N C O initial =1.81 g C O 2 × =0.041 g mol C O 2
2
44 g C O 2
N C O final =0.041+(−1)(0.0233)=0.0177 g mol C O2
2

44 g C O 2
M C O final=0.0177 g mol C O2 × =0.78 g C O 2
2
1 g mol C O2
5 In the combustion of heptane with oxygen, CO 2 is produced. Assume that
you want to produce 1350 kg of dry ice per hour, and that 63% of the CO 2
can be converted into dry ice, as shown in Figure E5.2. How many
kilograms of heptane must be burned per hour?(20%)

1 kg C O 2 formed 1 kg mole C O 2 1 kg mole C 7 H 16 100.1 kg C 7 H 16

1350 kg dry ice × × × × =696.43 kg C
0.63 kg dry ice 44 kg C O 2 7 kg mole C O 2 1 kg mole C 7 H 16
6 For the reaction equation used in question 5, if 18.8 kg of CO2 are formed in
the reaction of 10 kg of C7H16 , please calculate the percent of the C7H16 that
is converted to CO2 (reacts)(20%)
1 kg mole C O 2 1 kg mole C 7 H 16
18.8 kg C O 2 × × =0.061 kg mole C7 H 16
44 kg C O 2 7 kg mol C O 2
1 kg mole C 7 H 16
10 kg C 7 H 16 × =0.0999 kg mole C7 H 16
100.1 kg C 7 H 16
0.061 kg mole reacted
% conversion= ×100 %=61.06 %
0.0999 kg mole feed