G11 AP Chemistry Name: Class:

Chapter 5 Gases Homework 2

The Gas Laws & The Ideal Gas Equation &

Gas Stoichiometry & Dalton’s Law of Partial Pressure

1. “The volume of an ideal gas is directly proportional to the number of moles of the

gas at constant temperature and pressure” is a statement of _____________ Law.

A) Charles's B) Boyle's C) Dalton's D) Avogadro's

2. “The pressure of an ideal gas is inversely proportional to its volume at constant

temperature and number of moles” is a statement of __________________ Law.

A) Charles's B) Boyle's C) Gay-Lussac's D) Avogadro's

3. “The volume of an ideal gas is directly proportional to its absolute temperature at

constant pressure and number of moles” is a statement of ________________ Law.

A) Charles's B) Boyle's C) Dalton's D) Avogadro's

4. “The total pressure in a mixture of unreacting gases is equal to the sum of the

partial pressures of the individual gases” is a statement of __________________ Law.

A) Charles's B) Graham's C) Boyle's D) Avogadro's E) Dalton's

5. Which of the lines on the figure below is the best representation of the relationship

between the volume of a gas and its pressure, other factors remaining constant?

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a
b

e
c
d

0
0 Pressure (atm)

6. A sample container of carbon monoxide occupies a volume of 435 mL at a pressure

of 785 torr and a temperature of 298 K. What would its temperature be if the volume

were changed to 265 mL at a pressure of 785 torr?

A) 182 K B) 298 K C) 387 K D) 489 K E) 538 K

7. A carbon dioxide sample weighing 44.0 g occupies 32.68 L at 65°C and 645 torr.

What is its volume at STP?

A) 22.4 L B) 31.1 L C) 34.3 L D) 35.2 L E) 47.7 L

8. What is the density of carbon dioxide gas at –25.2°C and 98.0 kPa?

A) 0.232 g/L B) 0.279 g/L C) 0.994 g/L D) 1.74 g/L E) 2.09 g/L

9. Dr. I. M. A. Brightguy adds 0.1727 g of an unknown gas to a 125-mL flask. If Dr. B

finds the pressure to be 736 torr at 20.0°C, is the gas likely to be methane, CH 4,

nitrogen, N2, oxygen, O2, neon, Ne, or argon, Ar?

A) CH4 B) N2 C) Ne D) Ar E) O2

10. A 250.0-mL sample of ammonia, NH3(g), exerts a pressure of 833 torr at 42.4°C.

What mass of ammonia is in the container?

A) 0.0787 g B) 0.180 g C) 8.04 g D) 17.0 g E) 59.8 g

11. If 0.750 L of argon at 1.50 atm and 177°C and 0.235 L of sulfur dioxide at 95.0

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kPa and 63.0°C are added to a 1.00-L flask and the flask's temperature is adjusted to

25.0°C, what is the resulting pressure in the flask?

A) 0.0851 atm B) 0.244 atm C) 0.946 atm D) 1.74 atm E) 1.86 atm

12. A gas mixture consists of equal masses of methane (molecular weight 16.0) and

argon (atomic weight 40.0). If the partial pressure of argon is 200. torr, what is the

pressure of methane, in torr?

A) 80.0 torr B) 200. torr C) 256 torr D) 500. torr E) 556 torr

13. An unknown liquid is vaporized in a 273-mL flask by immersion in a water bath at

99°C. The barometric pressure is 753 torr. If the mass of the vapor retained in the

flask is 1.362 g, what is its molar mass?

A) 20.4 g/mol B) 40.9 g/mol C) 112 g/mol D) 154 g/mol E) 184 g/mol

14. A gas consists of 85.7 % carbon and 14.3 % hydrogen, by weight. A sample of this

gas weighing 0.673 g occupies 729 mL at a pressure of 720.0 mmHg and a

temperature of 77°C. Calculate its empirical and molecular formulas.

A) CH, C2H2 B) CH2, C2H4 C) CH2, C3H6 D) CH3, C2H6 E) CH4, CH4

15. Magnesium metal (0.100 mol) and a volume of aqueous hydrochloric acid that

contains 0.500 mol of HCl are combined and react to completion. How many liters of

hydrogen gas, measured at STP, are produced?

Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

A)2.24 L of H2 B)4.48 L of H2 C)5.60 L of H2 D)11.2 L of H2 E)22.4 L of H2

16. Small quantities of hydrogen can be prepared by the addition of hydrochloric acid

to zinc. A sample of 195 mL of hydrogen was collected over water at 25°C and 753

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torr. What mass of hydrogen was collected? (Pwater = 24 torr at 25°C)

A) 0.00765 g B) 0.0154 g C) 0.0159 g D) 0.0164 g E) 0.159 g

17. Hydrochloric acid is prepared by bubbling hydrogen chloride gas through water.

What is the concentration of a solution prepared by dissolving 225 L of HCl(g) at

37°C and 89.6 kPa in 5.25 L of water?

A) 1.49 M B) 1.66 M C) 7.82 M D) 12.5 M E) 16.6 M

18. A 1.00-L sample of a pure gas weighs 0.785 g and is at 0.965 atm and 29.2°C.

a. What is the molar mass of the gas?

b. If the volume and temperature are kept constant while 0.400 g of the same gas are

added to that already in the container, what will the new pressure be?

19. A 3.60-L gas sample is at a pressure of 95.5 kPa and a temperature of 25.0°C.

a. Calculate the volume occupied by the gas at STP, assuming it behaves ideally.

b. If the gas sample weighs 6.10 g, calculate the molar mass of the gas.