NME-Laporan 2 - Kelompok 25 - MR CP Polimer 2 Reaksi

A.
Perhitungan Cp Menggunakan Metode Estimasi
Unsur Δe (J/moloK)_x000D_ (Perry, 1999)

C 10.89
H 7.56
O 13.42
Cl 24.69
Na 26.19
1. Selulosa (C6H10O5)n
4. Na-CMC (C8H11O7Na)n
n = 1000
MR = 162000 g/mol 162 kg/mol
nE ΣnE ΣΔE
C= 6 6000 65340
H= 10 10000 75600
O= 5 5000 67100
208040
CpSelulosa =_x000D_ 208040 J/mol.K 1284.1975 J/kg.K CpNa-CMC =_x000D_
2. Hemiselulosa(C5H8O4)n 5. Na-MCA
n= 175
MR = 23100 g/mol 23.1 kg/mol
nE ΣnE ΣΔE
C= 5 875 9528.75
H= 8 1400 10584
O= 4 700 9394
29506.75
CpHemiselulosa =_x000D_ 29506.75 J/mol.K 1277.3485 J/kg.K CpNa-MCA =_x000D_
6. Na-Glikolat (OHCH2COON
3. Lignin (C9H10O2)n
)
n= 10
MR = 1500 g/mol 1.5 kg/mol
nE ΣnE ΣΔE
C= 9 90 980.1
H= 10 100 756
O= 2 20 268.4
2004.5
Cplignin =_x000D_ 2004.5 J/mol.K 1336.3333 J/kg.K CpNa-Glikolat =_x000D_
Na = 1 0 0 0
4. Na-CMC (C8H11O7Na)n 7. Selulosa-Na ( (C6H9O5Na)n)
n= 1000 n=
MR = 242000 g/mol 242 kg/mol MR =
nE ΣnE ΣΔE
C= 8 8000 87120 C=
H= 11 11000 83160 H=
O= 7 7000 93940 O=
Na = 1 1000 26190 Na =
290410
CpNa-CMC =_x000D_ 290410 J/mol.K 1200.0413 J/kg.K CpSelulosa =_x000D_
ClCH2COONa_x000D_
nE ΣnE ΣΔE
Cl = 1 1 24.69
C= 2 2 21.78
H= 2 2 15.12
61.59
CpNa-MCA =_x000D_ 61.59 J/molK 733.21429 J/kg.K
6. Na-Glikolat (OHCH2COONa
)
nE ΣnE ΣΔE
C= 2 2 21.78
H= 3 3 22.68
O= 3 3 40.26
Na = 1 1 26.19
110.91
CpNa-Glikolat =_x000D_ 110.91 J/molK 1131.7347 J/kg.K
C6H9O5Na)n)
1000
184000 g/mol 184 kg/mol
nE ΣnE ΣΔE
6 6000 65340
9 9000 68040
5 5000 67100
1 1000 26190
200480
200480 J/mol.K 1089.5652 J/kg.K

B. Perhitungan Cp Menggunakan Appendix Yaws
Gas Cp = A+BT+CT2+DT3+ET4_x000D_ (Yaws)

Solid Cp = A+BT+CT 2_x000D_
Liquid Cp = A+BT+CT2+DT3_x000D_
GAS
1. H2O_x000D_
MR = 18 g/mol
T= 298.15 K
A B C D E Cp (J/mol.K)
H2O(g)_x000D_ 33.933 -0.008419 0.000029906 -1.7825E-08 3.6934E-12 9973.677017
O2_x000D_ 33.933 -0.008419 0.000029906 -1.7825E-08 3.6934E-12 0
N2_x000D_ 33.933 -0.008419 0.000029906 -1.7825E-08 3.6934E-12 0
SOLID LIQUID
1. NaOH 1. H2O_x000D_
MR = 40 g/mol MR =
T= 298.15 K T=
A B C Cp (J/mol.K) A
NaOH 51.234 0.013088 2.336E-05 16063.501318 H2O(l)_x000D_ 92.053
2. Asam Monokloroasetat (MCA) C2H3ClO2_x000D_ 3. H2O2_x000D_

MR = 94.497 g/mol MR =
T= 298.15 K T=
A B C Cp (J/mol.K) A
MCA -55.75 0.59859 9983.4943871 H2O2_x000D_ -15.248
3. NaCl
MR = 58.5 g/mol
T= 298.15 K
A B C Cp (J/mol.K)
NaCl 41.293 0.033607 -1.393E-05 13682.19015
LIQUID
18 g/mol
298.15 K
B C D Cp (J/mol.K)
-0.039953 -0.000211 5.347E-07 24861.758278
34 g/mol
298.15 K
B C D Cp (J/mol.K)
0.67693 -0.001495 1.202E-06 14709.4417028
Kapasitas Produksi : 6000 ton/tahun
Masa Aktif Produksi : 330 hari
Temperatur Referensi : 25 C_x000D_
o
: 298 K
Basis Perhitungan : kg/jam
Bahan Baku : Bagasse_x000D_
Produk : Carboxymethyl Cellulose (CMC)_x000D_
Kapasitas Perancangan Pabrik CMC

Kapasitas Produksi = 757.5758 kg/jam 757.575757575758
Basis Perancangan = 786.474 kg/jam
26. Rotary Reactor (R-101)

Fungsi : Reaksi karboksimetilasi
Asumsi : 1. Konversi reaksi 80%
2. Basis F36 =_x000D_ 441.4876
3. Udara keluar F48 membawa 1% produk hasil reaksi_x000D_
4. Rasio Selulosa : MCA adalah 1:1,2
5. Rasio MCA : NaOH adalah 1:1,7
Data aliran 36 F36 =_x000D_ 441.4876 kg/jam

Komponen w F (kg/jam) Mr (kg/kmol) N (kmol) N (mol)
Selulosa 0.95 419.4132 162000 0.002588971 2.58897058935239
H2O_x000D_ 0.05 22.0744 18 1.22635449 1226.35448969324
1.22894346 1228.94346028259
1.200000 1.7
Konversi = 0.8
(C6H10O5) + 2NaOH + ClCH2COOH
mula 2.5889705893524 + 5.282 + 3.107
reaksi 2.0711764714819 + 4.142352942964 + 2.07117647148191
sisa 0.5177941178705 + 1.139 + 1.036
Konversi = 0.8
ClCH2COOH + 2NaOH → OHCH2COONa
mula 1.036 + 1.139 →
reaksi 0.455658823726 + 0.911317647452 → 0.455658823726021
sisa 0.580 + 0.228 → 0.455658823726021
Komponen Mr (kg/kmol) w F (kg/jam) X mol

Selulosa 162000 0.138 83.882647 0.000410 0.517794
Selulosa-Na 184000 0.000 0.000000 0.000000 0.000000
MCA 94.497 0.000 0.054802 0.000459 0.579929
MCA-Na 84 0.000 0.000000 0.000000 0.000000
NaOH 40 0.000 0.009113 0.000180 0.227829
CMC 242000 0.824 501.224706 0.001640 2.071176
Na-Glikolat 98 0.000 0.044655 0.000361 0.455659
NaCl 58.5 0.000 0.147820 0.002000 2.526835
H2O_x000D_ 18 0.037 22.624088 0.994950 1256.893765
1 607.987830 1.000000 1263.272988
Masuk
Komponen
F36
N36
F40
N40
F44
Selulosa 419 0.002589
Selulosa-Na
MCA 0.294 0.003
MCA-Na
NaOH 0.21
CMC
Na-Glikolat
NaCl
H2O_x000D_ 22 1.22635449 0.08 0.004600256 0.39
O2
N2
Total 441 1 0 0 1
27. Heater (E-204)

F masuk F keluar N masuk N keluar
Komponen Mr
46 48 46 48
Selulosa 162000.0 83.0438 83.0438 0.0005 0.0005
Selulosa-Na 184000.0 0.0000 0.0000 0.0000 0.0000
MCA 94.5 0.0543 0.0543 0.0006 0.0006
MCA-Na 84.0 0.0000 0.0000 0.0000 0.0000
NaOH 40.0 0.0090 0.0090 0.0002 0.0002
CMC 242000.0 496.2125 496.2125 0.0021 0.0021
Na-Glikolat 98.0 0.0442 0.0442 0.0005 0.0005
NaCl 58.5 0.1463 0.1463 0.0025 0.0025
H2O_x000D_ 18.0 22.3978 22.3978 1.2443 1.2443
Total 588393.0 601.9080 601.9080 0.0010 0.0010
28. Aging vessel (V-103)

F in F out N in N out
Komponen Mr
48 49 N48 N49
Selulosa 162000.0 83.0438 83.0438 0.0005 0.0005
Selulosa-Na 184000.0 0.0000 0.0000 0.0000 0.0000
MCA 94.5 0.0543 0.0543 0.0006 0.0006
MCA-Na 84.0 0.0000 0.0000 0.0000 0.0000
NaOH 40.0 0.0090 0.0090 0.0002 0.0002
CMC 242000.0 496.2125 496.2125 0.0021 0.0021
Na-Glikolat 98.0 0.0442 0.0442 0.0005 0.0005
NaCl 58.5 0.1463 0.1463 0.0025 0.0025
H2O_x000D_ 18.0 22.3978 22.3978 1.2443 1.2443
Total 588393.0 601.9080 601.9080 0.0010 0.0010
29. Cooler (E-205)

Masuk Keluar Masuk Keluar
Komponen Mr
F49 F50 N49 N50
Selulosa 162000.0 83.044 83.044 0.000512616 0.00051261617669177
Selulosa-Na 184000.0 0.000 0.000 0 0
MCA 94.5 0.054 0.054 0.00057413 0.00057413011789479
MCA-Na 84.0 0.000 0.000 0 0
NaOH 40.0 0.009 0.009 0.000225551 0.00022555111774438
CMC 242000.0 496.212 496.212 0.002050465 0.0020504647067671
Na-Glikolat 98.0 0.044 0.044 0.000451102 0.00045110223548876
NaCl 58.5 0.146 0.146 0.002501567 0.00250156694225586
H2O_x000D_ 18.0 22.398 22.398 1.244324827 1.24432482720494
Total 588392.997 601.908 601.908 1.251 1.251
30. Cyclone (CY-301)

Masuk Keluar Masuk
Komponen Mr
F47 F51 F52 N47
Selulosa 162000 0.839 0.0084 0.8304 0.000005
Selulosa-Na 184000 0.000 0.0000 0.0000 0.000000
MCA 94.497 0.001 0.0000 0.0005 0.000006
MCA-Na 84 0.000 0.0000 0.0000 0.000000
NaOH 40 0.000 0.0000 0.0001 0.000002
CMC 242000 5.012 0.0501 4.9621 0.000021
Na-Glikolat 98 0.000 0.0000 0.0004 0.000005
NaCl 58.5 0.001 0.0000 0.0015 0.000025
H2O_x000D_ 18 0.226 0.0023 0.2240 0.012569
O2 32 -162.984 -162.9836 -5.093237
N2 14 -268.244 -268.2438 -19.160272
Total 588439 -425.15 -431.17 6.019 -24.24
588439 -425.15 -425.15 -24.24
31. Cyclone (CY-302)

Masuk Keluar Masuk
Komponen Mr
F51 F53
F
54
N51
Selulosa 162000 0.0084 0.0001 0.0083 0.0000001
Selulosa-Na 184000 0.0000 0.0000 0.0000 0.0000000
MCA 94.5 0.0000 0.0000 0.0000 0.0000001
MCA-Na 84 0.0000 0.0000 0.0000 0.0000000
NaOH 40 0.0000 0.0000 0.0000 0.0000000
CMC 242000 0.0501 0.0005 0.0496 0.0000002
Na-Glikolat 98 0.0000 0.0000 0.0000 0.0000000
NaCl 58.5 0.0000 0.0000 0.0000 0.0000003
H2O_x000D_ 18 0.0023 0.0000 0.0022 0.0001257
O2 32 -162.9836 -162.9836 -5.0932368
N2 14 -268.2438 -268.2438 -19.1602719
Total 588438.997 -431.167 -431.227 0.060 -24.253
32. Silo (TK-107)

Masuk Keluar
Komponen Mr
F
50
F52 F54
F55
Selulosa 162000 83.0438 0.8304 0.0083 83.8826
Selulosa-Na 184000 0.0000 0.0000 0.0000 0.0000
MCA 94.497 0.0543 0.0005 0.0000 0.0548
MCA-Na 84 0.0000 0.0000 0.0000 0.0000
NaOH 40 0.0090 0.0001 0.0000 0.0091
CMC 242000 496.2125 4.9621 0.0496 501.2242
Na-Glikolat 98 0.0442 0.0004 0.0000 0.0447
NaCl 58.5 0.1463 0.0015 0.0000 0.1478
H2O_x000D_ 18 22.3978 0.2240 0.0022 22.6241
Total 601.9080 6.0191 0.0602 607.9872
607.9872 607.9872
33. Rotary Dryer (RD-301)

Masuk Keluar
Komponen Mr
F
55
F57
F58
F59
Selulosa 162000 83.88 83.883
Selulosa-Na 184000 0.00 0.000
MCA 94.497 0.05 0.055
MCA-Na 84 0.00 0.000
NaOH 40 0.01 0.009
CMC 242000 501.22 501.224
Na-Glikolat 98 0.04 0.045
NaCl 58.5 0.15 0.148
H2O_x000D_ 18 22.62 22.172 0.452
O2 32 79.20 79.204
N2 14 130.36 130.357
Total 608 210 231.732 585.816
818 818
34. Heater (E-301)

Komponen Mr F56 F57 N56 N57
O2 32 79.204 79.204 2.475 2.475
N2 14 130.357 130.357 9.311 9.311
Total 46 210 210 12 12
36. Cooler (E-302)

Komponen Mr
F59 F60 N59 N50
Selulosa 162000 83.883 83.883 0.0005 0.00051779360007636
Selulosa-Na 184000 0.000 0.000 0.0000 0
MCA 94.497 0.055 0.055 0.0006 0.00057992883208552
MCA-Na 84 0.000 0.000 0.0000 0
NaOH 40 0.009 0.009 0.0002 0.0002278291840336
CMC 242000 501.224 501.224 0.0021 0.00207117440030544
Na-Glikolat 98 0.045 0.045 0.0005 0.0004556583680672
NaCl 58.5 0.148 0.148 0.0025 0.00252683276837264
H2O_x000D_ 18 0.452 0.452 0.0251 0.0251378501591943
Total 588392.997 585.816 585.816 0.03152 0.03152
33. Ball mill (BM-301)

Komponen Mr
F60 F61 N50 N61
Selulosa 162000 83.88 83.88 0.000517794 0.00051779360007636
Selulosa-Na 184000 0.00 0.00 0 0
MCA 94.497 0.05 0.05 0.000579929 0.00057992883208552
MCA-Na 84 0.00 0.00 0 0
NaOH 40 0.01 0.01 0.000227829 0.0002278291840336
CMC 242000 501.22 501.22 0.002071174 0.00207117440030544
Na-Glikolat 98 0.04 0.04 0.000455658 0.0004556583680672
NaCl 58.5 0.15 0.15 0.002526833 0.00252683276837264
H2O_x000D_ 18 0.45 0.45 0.02513785 0.0251378501591943
Total 588392.997 586 586 0.031517067 0.031517067312135
37. Product Tank (TK-108)

Komponen Mr
F61 F62 N61 N62
Selulosa 162000 83.88 83.88 0.00052 0.00052
Selulosa-Na 184000 0.00 0.00 0.00000 0.00000
MCA 94.497 0.05 0.05 0.00058 0.00058
MCA-Na 84 0.00 0.00 0.00000 0.00000
NaOH 40 0.01 0.01 0.00023 0.00023
CMC 242000 501.22 501.22 0.00207 0.00207
Na-Glikolat 98 0.04 0.04 0.00046 0.00046
NaCl 58.5 0.15 0.15 0.00253 0.00253
H2O_x000D_ 18 0.45 0.45 0.02514 0.02514
Total 588392.9970 585.8156 585.8156 0.03152 0.03152
1. Roll crusher (RC-101)

Komponen Mr
F1 F2 N1 N2
Selulosa 162000 413.934 413.934 0.002555146 0.00255514619883041
Hemiselulosa 23100 206.967 206.967 0.008959604 0.0089596035543404
Lignin 1500 206.967 206.967 0.137977895 0.137977894736842
827.867 827.867 0.149492644 0.149492644490013
2. Vibrating screen (VS-101)

Masuk Keluar Masuk
Komponen Mr
Komponen Mr
F2 F3 F4 N2
Selulosa 162000 413.934 20.697 393.237 0.00255514619883041
Hemiselulosa 23100 206.967 10.348 196.619 0.0089596035543404
Lignin 1500 206.967 10.348 196.619 0.137977894736842
827.867 41.393 786.474 0.149492644490013
827.867 827.867 0.149492644490013
3. Silo 1 (TK-101)
Komponen Mr
F4 F5 N4 N5
Selulosa 162000 393.237 393.237 0.002427389 0.00242738888888889
Hemiselulosa 23100 196.619 196.619 0.008511623 0.00851162337662338
Lignin 1500 196.619 196.619 0.131079 0.131079
786.474 786.474 0.142018012 0.142018012265512
4. Steam Explosion Tank (V-101)

Masuk Keluar Masuk
Komponen Mr
5 6 7 5
Selulosa 162000 393.237 393.237 0.00242738888888889
Hemi 23100 196.619 58.986 0.00851162337662338
Hemi aq 23100 137.633
Lignin 1500 196.619 196.619 0.131079
H2O g 18 1258.358
H2O l 18 1572.948 314.590
786.474 1572.948 2359.422 0.142018012265512
2359.422 2359.422 87.5280180122655
5. Flash Tank (V-102)

Masuk Keluar Masuk
Komponen Mr
7 8 9 7
Selulosa 162000 393.237 393.237 0.00242738888888889
Hemi 23100 58.986 58.986 0.00255348701298701
Hemi aq 23100 137.633 137.633 0.00595813636363636
Lignin 1500 196.619 196.619 0.131079
H2O g 18 1258.358 1258.358 69.9088
H2O l 18 314.590 314.590 17.4772
2359.422 1101.064 1258.358 87.5280180122655
2359.422 2359.422 87.5280180122655
6. Heater (E-101)
Komponen Mr
F8 F10 N8 N10
Selulosa 162000 393.237 393.237 0.002427389 0.00242738888888889
Hemi 23100 58.986 58.986 0.002553487 0.00255348701298701
Hemi aq 23100 137.633 137.633 0.005958136 0.00595813636363636
Lignin 1500 196.619 196.619 0.131079 0.131079
H2O l 18 314.590 314.590 17.4772 17.4772
1101.064 1101.064 17.61921801 17.6192180122655
7. Mixer (M-101)
Masuk Keluar Masuk
Komponen Mr
F12 F13 F14 N12
NaOH 40 1101.064 1101.064 27.52659
H2O 18 1101.064 3303.191 4404.254 61.1702
2202.127 3303.191 5505.318 88.69679
5505.318 5505.318 272.20739
8. Heater (E-102)
Komponen Mr
14 15 14 15
NaOH 40 1101.064 1101.064 27.52659 27.52659
H2O 18 4404.254 4404.254 244.6808 244.6808
5505.318 5505.318 272.20739 272.20739
9. Delignification Tank (DT-101)

Masuk Keluar Masuk
Komponen Mr
F8 F15 F16 N8
Selulosa 162000 393.237 393.237 0.00242738888888889
Hemi 23100 58.986 0.00255348701298701
Hemi aq 23100 137.633 196.619 0.00595813636363636
Lig 1500 196.619 9.831 0.131079
Lig aq 1500 186.788
H2O l 18 314.590 4404.254 4718.844 17.4772
NaOH 40 1101.064 1101.064
1101.064 5505.318 6606.382 17.6192180122655
6606.382 6606.382 289.826608012266
10. Expansion Valve (EV-101)

Komponen Mr
16 17 16 17
Selulosa 162000 393.237 393.237 0.002427389 0.00242738888888889
Hemi aq 23100 196.619 196.619 0.008511623 0.00851162337662338
Lig 1500 9.831 9.831 0.00655395 0.00655395
Lig aq 1500 186.788 186.788 0.12452505 0.12452505
H2O l 18 4718.844 4718.844 262.158 262.158
NaOH 40 1101.064 1101.064 27.52659 27.52659
6606.382 6606.382 289.826608 289.826608012266
11. Cooler (E-103)
Komponen Mr
17 18 17 18
Selulosa 162000 393.237 393.237 0.002427389 0.00242738888888889
Hemi aq 23100 196.619 196.619 0.008511623 0.00851162337662338
Lig 1500 9.831 9.831 0.00655395 0.00655395
Lig aq 1500 186.788 186.788 0.12452505 0.12452505
H2O l 18 4718.844 4718.844 262.158 262.158
NaOH 40 1101.064 1101.064 27.52659 27.52659
6606.382 6606.382 289.826608 289.826608012266
12. Heater (E-104)

Komponen Mr
19 20 19 20
H2O 18 13212.763 13212.763 734.0424 734.0424
13212.763 13212.763
13. Rotary Filter (RF-101)

Masuk Keluar
Komponen Mr
18 20 22 21
Selulosa 162000 393.237 393.237
Hemi aq 23100 196.619 196.619
Lig 1500 9.831 9.831
Lig aq 1500 186.788 186.788
H2O l 18 4718.844 13212.763 358.632 17572.975
NaOH 40 1101.064 1101.064
6606.382 13212.763 761.700 19057.445
19819.145 19819.145
14. Heater (E-105)

Komponen Mr
23 24 23 24
H2O2 34 228.510 228.510 6.720882962 6.72088296176471
228.510 228.510
15. Heater (E-106)

Komponen Mr
25 26 25 26
H2O 18 2466.082 2466.082 137.0045419 137.004541852941
2466.082 2466.082
16. Bleaching Tank (BT-101)

Masuk Keluar
Komponen Mr
21 24 26 27
Selulosa 162000 393.237 393.237
Lig 1500 9.831
Lig aq 1500 9.831
H2O l 18 358.632 2466.082 2824.714
H2O2 34 228.510 228.510
761.700 228.510 2466.082 3456.292
3456.292 3456.292
17. Heater (E-107)

Komponen Mr
28 29 28 29
H2O 18 6912.584 6912.584 384.032427 384.032427005882
6912.584 6912.584
18. Rotary Filter (RF-102)

Masuk Keluar
Komponen Mr
27 29 30 31
Selulosa 162000 393.237 393.237
Lig aq 1500 9.831 9.831
H2O l 18 2824.714 6912.584 9542.552 194.746
H2O2 34 228.510 228.510
3456.292 6912.584 9780.893 587.983
10368.876 10368.876
19. Rotary RD (RD-101)

Masuk Keluar
Komponen Mr
31 33 34 35
Selulosa 162000 419.413 419.413
H2O 18 194.746 172.672 22.074
O2 32 24.835 24.835
N2 14 40.874 40.874
614.159 65.709 238.381 441.488
679.868 679.868
20. Heater (E-108)

Komponen Mr
32 33 32 33
O2 32 24.835 24.835 0.776093035 0.776093035211066
N2 14 40.874 40.874 2.919588085 2.91958808484163
40.874 40.874
21. Cooler (E-201)

Komponen Mr
35 36 35 36
Selulosa 162000 419.413 419.413 0.002588971 0.00258897058935239
H2O 18 22.074 22.074 1.22635449 1.22635448969324
441.488 441.488 1.22894346 1.22894346028259
22. Mixer (M-201)

Masuk Keluar Masuk
Komponen Mr
38 39 40 38
MCA 94.497 0.294 0.294 0.00310676470722287
H2O 18 0.002965454 0.079839145756 0.083 0.00016474744362427
0.296545399 0.079839145756 0.376 0.00327151215084714
0.376 0.376 0.00770702024842349
23. Heater (E-202)

Komponen Mr
39 40 39 40
MCA 94.497 0.294 0.294 0.003106765 0.00310676470722287
H2O 18 0.083 0.083 0.004600256 0.00460025554120062
0.376 0.376 0.00770702 0.00770702024842349
24. Mixer (M-202)

Masuk Keluar Masuk
Komponen Mr
42 43 44 42
NaOH 40 0.211 0.211 0.00528150000227888
H2O 18 0.211 0.18 0.392 0.0117366666717308
0.42252 0.181080000078 0.6036 0.0170181666740097
0.604 0.604 0.0270781666783505
25. Heater (E-203)

Masuk Keluar
Komponen Mr
43 44 43 44
NaOH 40 0.211 0.211 0.0052815 189.340149497021
H2O 18 0.392 0.392 0.021796667 0.0217966666760716
0.604 0.604 0.027078167 189.361946163697
Data Aliran 40 F40 =_x000D_ 0.3763845443 kg/jam
Komponen w F (kg/jam) Mr (kg/kmol) N (kmol)
MCA 0.78 0.29357994454 94.497 0.003
H2O_x000D_ 0.22 0.08280459974 18 0.00460025554
0.008
→ (C8H11O7Na) + NaCl + 2H2O

→ + + 1252.751
→ 2.0711764714819 + 2.07117647148 + 4.14235294296
→ 2.0711764714819 + 2.07117647148 + 1256.89376485
+ NaCl
+ 2.0711764714819
+ 0.455658823726
+ 2.5268352952079
F (kg/jam) mol F (kg/jam) mol

83.043821 0.000513 0.838826 0.000005
0.000000 0.000000 0.000000 0.000000
0.054254 0.000574 0.000548 0.000006
0.000000 0.000000 0.000000 0.000000
0.009022 0.000226 0.000091 0.000002
496.212459 0.002050 5.012247 0.000021
0.044208 0.000451 0.000447 0.000005
0.146342 0.002502 0.001478 0.000025
22.397847 1.244325 0.226241 0.012569
601.907952 1.250640 6.079878 0.012633
Keluar
N44
F45
N45
F 46
N 46
F47
83.043821 0.000513 0.838826
0.000000 0.000000 0.000000
0.054254 0.000574 0.000548
0.000000 0.000000 0.000000
0.005 0.009022 0.000226 0.000091
496.212459 0.002050 5.012247
0.044208 0.000451 0.000447
0.146342 0.002502 0.001478
0.0217966666761 22.397847 1.244325 0.226241
-162.98 -5.093236846648 -162.984
-268.24 -19.16027194692 -268.244
0 -431 -24 602 1.251 -425
11.240 -22.989780 176.760
165.52022932
Fungsi : Meningkatkan suhu keluaran dari rotary reactor

Asumsi : 1. Tidak terjadi perubahan massa
Fungsi : Pematangan produk

Kondisi : T = 55 o
C_x000D_ kg/jam
t= 8 jam
Fungsi : Menurunkan suhu dari aging vessel
Keluar Fungsi : Memisahkan produk dari udara

N51 N52 Asumsi : 1. 1% produk terbawa udara
0.000000 0.000005
0.000000 0.000000
0.000000 0.000006
0.000000 0.000000
0.000000 0.000002
0.000000 0.000021
0.000000 0.000005
0.000000 0.000025
0.000126 0.012443
-5.093237
-19.160272
-24.25 0.013
-24.24
Keluar Fungsi : Memisahkan produk dari udara

N53
N
54
Asumsi : 1. 1% produk terbawa udara
0.0000000 0.0000001
0.0000000 0.0000000
0.0000000 0.0000001
0.0000000 0.0000000
0.0000000 0.0000000
0.0000000 0.0000002
0.0000000 0.0000000
0.0000000 0.0000003
0.0000013 0.0001244
-5.0932368
-19.1602719 0.0000000
-24.254 0.000
N50 N52 N54 N55

0.0005126161767 5.126161767E-06 5.126161767E-08 0.0005177936
0 0 0 0
0.0005741301179 5.741301179E-06 5.741301179E-08 0.00057992883
0 0 0 0
0.0002255511177 2.255511177E-06 2.255511177E-08 0.00022782918
0.0020504647068 2.050464707E-05 2.050464707E-07 0.0020711744
0.0004511022355 4.511022355E-06 4.511022355E-08 0.00045565837
0.0025015669423 2.501566942E-05 2.501566942E-07 0.00252683277
1.2443248272049 0.012443248272 0.000124432483 1.25689250796
1.2506402585018 0.012506402585 0.000125064026 1.2632717251
1.263272 1.2632717251
N Fungsi : Mengurangi kadar air

55 57 58 59 Asumsi : 1. Efisiensi 95%
0.0005177936001 0.0005177936
0 0
0.0005799288321 0.00057992883
0 0
0.000227829184 0.00022782918
0.0020711744003 0.0020711744
0.0004556583681 0.00045565837
0.0025268327684 0.00252683277
1.2568925079597 1.231754657801 0.02513785016
2.4751240594673 2.475124059467
9.3111809856149 9.311180985615
1.2632717251127 11.786305045082 13.01805970288 0.03151706731
13.0495767701948 13.0495767701948
Fungsi : Memperkecilkan ukuran prduk
Asumsi : tidak teriadi perubahan massa
85.560058844478
Fungsi : Mencacah Bagasse menjadi 2 mm

Asumsi : 1. Efisiensi Roll crusher 95%
2. Aliran F3 dimasukkan kembali kedalam roll crusher
asumsi F1 = 827.867
Feed = 786.474 kg bagasse
Keluar Fungsi : Untuk Screening bagasse yang memenuhi ukuran

N3 N4 Asumsi : 1. Aliran 3 adalah 5% dari aliran 2
0.0001277573099 0.0024273888889
0.0004479801777 0.0085116233766
0.0068988947368 0.131079
0.0074746322245 0.1420180122655
0.149492644490013
Fungsi : Untuk menyimpan bagasse sementara

Asumsi : tidak ada perubahan massa
Masuk Keluar Fungsi : Melunakan serta mengurangi ukuran partikel dan kandungan hem
6 7 Asumsi : 1. Aliran keluar tangki dalam keadaan saturated pada tekanan at
0.0024273888889 2. Adiabatic expansion process
0.002553487013 3. 70% hemiselulosa terpisahkan dari bagasse
0.0059581363636 4. Rasio saturated steam terhadap bagasse 1:2
0.131079
69.9088 y= 0.8000
87.386 17.4772 x= 0.2000
87.386 87.528018012266
87.5280180122655 87.528018012266
Keluar Fungsi : Untuk melepaskan uap air sisa steam explotion tank
8 9 Asumsi : 1. semua uap terlepas ke aliran 9
0.0024273888889
0.002553487013
0.0059581363636
0.131079
69.9088
17.4772
17.619218012266 69.9088
87.5280180122655
Fungsi : Untuk meningkatkan suhu keluaran dari flash tank (V-102) dari 100C menjadi 150C
Asumsi : 1. Menggunakan steam suhu
karena tidak ada perubahan massa masuk dan keluar maka nilai F8 = F10
Masuk Keluar Fungsi : Untuk mengencerkan NaOH 50% menjadi 20%
N13 N14 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah
27.52659 F11= 1101.275
183.5106 244.6808 1101.275
183.5106 272.20739 2202.550
272.20739 272.20739
Fungsi : Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)

karena tidak ada perubahan massa masuk dan keluar maka nilai F14 = F15
Masuk Keluar Fungsi : Untuk memecahkan ikatan lignin

N15 N16 T= 150
0.0024273888889 P= 7
Asumsi : 1. rasio bagasse : cairan NaOH adalah 1:5
0.0085116233766 2. menghilangkan lignin sebesar 95%
0.00655395 3. melarutkan hemiselulosa yang masih tersisa dari dalam bagass
0.12452505
244.6808 262.158
27.52659 27.52659
272.20739 289.82660801227
289.826608012266 289.82660801227
Fungsi : Untuk menurunkan tekanan keluaran dari tangki delignifikasi (DT-101)

Asumsi: 1. Tidak ada perubahan masa
2. Tekanan diturunkan dari 7 menjadi 1 bar
Fungsi : Untuk mendinginkan keluaran dari tangki delignifikasi
Asumsi: 1. tidak ada perubahan massa
2. medinginkan dari suhu 150 ke suhu 80
Fungsi : Untuk meningkatkam suhu air pencucian yang akan masuk kedalam rotary filter 1
Asumsi: 1. Tidak ada perubahan massa
2. Meningkatkan suhu air dari 30 menjadi 80
3. Rasio air yang digunakan untuk pencucian 2 : 1
Masuk Keluar Fungsi : Untuk memisahkan selulosa dari

18 20 22 21 Asumsi : 1. Efisiensi rotary filter 98%
0.0024273888889 0.002427388889 2. Rasio Air pencucian dan pulp 2
0.0085116233766 0.00851162338
0.00655395 0.00655395
0.12452505 0.12452505
262.158 734.0424 19.924008 976.276392
27.52659 27.52659
289.82660801227 734.0424 19.93298933889 1003.9360187
1023.86900801227 1023.86900801227
Fungsi : Untuk meningkatkan suhu H2O2 yang akan masuk kedalam tangki bleaching
Asumsi : 1. Tidak ada perubahan massa
2. Suhu dinaikkan dari 30 menjadi 80
3. H2O2 yang akan digunakan adalah 30% dari aliran 21
Fungsi : Untuk meningkatkan suhu air yang akan digunakan pada proses bleaching
Asumsi : 1. Tidal terjadi perubahan massa
Masuk Keluar Fungsi : Untuk menghilangkan sisa lignin
21 24 26 27 Asumsi : 1. Melarutkan sisa lignin yang ad
0.0024273888889 0.00242738889 2. Air yang digunakan untuk kons
0.00655395
0.00655395
19.924008 137.0045418529 156.928549853
6.7208829617647 6.72088296176
19.932989338889 6.7208829617647 137.0045418529 163.658414154
163.658414153595 163.65841415
Fungsi : Untuk meningkatkan suhu air pencucian yang akan digunakan pada rotary filter 2
Asumsi : 1. Tidal terjadi perubahan massa
3. Rasio air yang digunakan untuk pencucian 2 : 1
Masuk Keluar Fungsi : Untuk memisahkan selulosa dari

27 29 30 31 Asumsi : 1. Rasio Air pencucian dan pulp 2
0.0024273888889 0.00242738889 355.868141331
0.00655395 0.00655395
156.92854985294 384.03242700588 530.1417573216 10.8192195372
6.7208829617647 6.720882961765
163.6584141536 384.03242700588 536.8691942334 10.821646926
547.690841159477 547.690841159477
Masuk Keluar Fungsi : Untuk mengurangi kadar air

31 33 34 35 Asumsi : 1. Efisiensi rotary dryer 95%
0.0025889705894 0.00258897059 2. Rasio Air pencucian dan pulp 2
10.819219537177 9.592865047483 1.22635448969
0.7760930352111 0.776093035211
2.9195880848416 2.919588084842 8.5835889694
10.821808507766 3.6956811200527 13.28854616754 1.2289434603 51.910276148
14.5174896278185 14.5174896278185
Fungsi : Untuk meningkatkan suhu udara pengering

Fungsi : Untuk menurunkan suhu selulosa keluaran rotary dryer (RD-101)

2. Suhu diturunkan dari 90 menjadi 35
Masuk Keluar Fungsi : Untuk mengencerkan MCA 99% menjadi 78%

39 40 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah
0.0031067647072 F40 = 0.37638454428
0.0044355080976 0.0046002555412
0.0044355080976 0.0077070202484
00770702024842349 0.0077070202484
Fungsi : Untuk meningkatkan suhu MCA

Masuk Keluar Fungsi : Untuk mengencerkan NaOH 50% menjadi 35%

43 44 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah
0.0052815000023 F41 = 0.60360000026 kg/jam
0.0100600000043 0.0217966666761
0.0100600000043 0.0270781666784
0270781666783505 0.0270781666784
Fungsi : Untuk meningkatkan suhu NaOH

Data Aliran 44 F44 =_x000D_ 0.60360000026
N (mol) Komponen w F (kg/jam) Mr (kg/kmol)
3.107 NaOH 0.35 0.2112600001 40
4.600 H2O_x000D_ 0.65 0.3923400002 18
7.707
N47
0.000005
0.000000
0.000006
0.000000
0.000002
0.000021
0.000005
0.000025
0.012569
-5.093237
-19.160
-24.241
-22.990236
gurangi kadar air
nuhi ukuran
partikel dan kandungan hemiselulosa bagasse
saturated pada tekanan atmosfer
explotion tank
delignifikasi : Bagasse adalah 5 : 1
ih tersisa dari dalam bagasse

k memisahkan selulosa dari sisa black liquor
siensi rotary filter 98%
sio Air pencucian dan pulp 2 : 1
k menghilangkan sisa lignin dan sisa blackliquor
elarutkan sisa lignin yang ada
yang digunakan untuk konsistensi pulp 15%
k memisahkan selulosa dari sisa lignin dan bleaching agent

k mengurangi kadar air

siensi rotary dryer 95%

kg
N (kmol) N (mol)
0.005 5.282
0.02179666668 21.797
0.027 27.078
Komponen
x36_x000D_ N36_x000D_
Selulosa 0.00 0.0026
MCA
NaOH
Na-Glikolat
CMC
NaCl
H2O_x000D_ 1.00 1.2264
Total 1.0000 1.2289

Masuk Keluar
x 40_x000D_
N
40_x000D_
x44_x000D_ N44_x000D_
x 45_x000D_
N 45_x000D_
x
46_x000D_
N46_x000D_
x47
0.0004 0.5126162 -0.0002
0.4031084 0.003 0.0005 0.5741301 -0.0002
0.0002 0.2255511 -0.0001

0.20 0.0053 0.0004 0.4511022 -0.0002
0.0016 2.0504647 -0.0009
0.0020 2.5015669 -0.0010
0.60 0.0046 0.80 0.0217967 0.9950 1244.3248 -0.5185
-0.661383 0.0273
1.0000 0.0077 1.0000 0.0271 0.0000 -0.661 1.0000 1250.6403 -0.4938
1 1263
1262
uar
N47
0.0051779
0.0057993
0.0022783
0.0045566
0.0207118
0.0252684
12.568938
-0.661383
11.97
63
26. Rotary Reactor (R-101)
Reaksi Alkalisasi (C_6 H_10 O_5 )n+NaOH →(C_6 H_10 O_5 Na)+H_2 O
Reaksi Eterifikasi ClCH_2 COOH+NaOH →ClCH_2 COONa+H_2 O
(C_6 H_10 O_5 Na)+ClCH_2 COONa →C_5 H_7 O_4 CH_2 OCH_2 COONa+NaCl
Reaksi Samping ClCH_2 COONa+NaOH →OHCH_2 COONa+NaCl
Neraca Energi Total : Qumpan + Qreaksi = Qproduk + Qloss
a. Panas Umpan
T36 = 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
T44 = 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qumpan = 6338.180658695 + 147.391427371562 N O2
b. Panas Reaksi Standar

Reaksi beroperasi pada 35oC
Data ΔHf0 masing komponen pada 25oC (298 K) :
Komponen ΔHf (kj/mol) ΔHf (kj/kmol)

Selulosa -74.764 -74764
Selulosa-Na -161.075 -161075
MCA -435.2025997143 -435202.5997143
MCA-Na -59.888 -59888
NaOH -147.456 -147456
CMC -198.038 -198038
Na-Glikolat -30.954 -30954
NaCl -250.267 -250267
H2O -285 -285000
Reaksi Utama
(C_6 H_10 O_5 )+NaOH+ClCH_2 COOH →(C_8 H_11 O_7 Na)+" " NaCl+ 2H_2 O
T = 308.15 Tref = 298.15
Komponen Mr (kg/mol) N (mol) F (kg) A
Selulosa 162000 2.588971 419413.235475088
MCA 94.497 3.106765 293.57994453844
CMC Err:509
NaOH 40 5.281500 211.260000091155 51.234
NaCl 58.5 41.293
H2O 18 1252.751412 22549.5254143892 92.053
ΔHR0 = Σ ΔHf produk - Σ ΔHf reaktan ΔHR =

ΔHR = -213.4264002857 kJ/mol
0
ΔHR =
ΔHR0 = -213426.4002857 kJ/kmol ΔHR =
=
Reaksi samping
ClCH_2 COOH+NaOH →ClCH_2 COONa+ H_2 O
T = 308.15 Tref = 298.15

Komponen Mr (kg/kmol) N (kmol) F (kg) A
MCA 94.497 1 97.8599815128132 -55.75
NaOH 40 1.139147059315 45.5658823726021 51.234
Na-Glikolat 98
H2O 18 0 92.053
ΔHR0 = Σ ΔHf produk - Σ ΔHf reaktan ΔHR =

ΔHR0 = 266.7045997143 kJ/mol ΔHR =
ΔHR =
=
c. Q Produk
(ΔH47)
T= 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
CMC
Na-Glikolat
H2O 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
NaCl 41.293 0.033607 -0.000013927
Q produk = 2350.90352561 + 23.7465002586894 +
d. Qloss
0,25 dari Qudara di aliran 48
Qloss = 0.25 X ( 147.3914273716
Qloss = 36.84785684289 N O2 + 36.341979849
Qumpan = 6338.180658695 + 147.391427371562 N O2

Qreaksi = -8384.978348392
Qproduk = 2350.90352561 + 23.7465002586894 +
Qloss = 36.84785684289 N O2 + 136.715067051
Qumpan + Qreaksi = Qproduk + Qloss

6338.18065869489 + 147.3914273716 N O2 +
6338.18065869489 +
Qloss = -883.9970791885 kJ/jam

Qudara 46 = -3.54E+03 kJ/jam
Qudara 48 = -7073.438953132 kJ/jam
Masuk
Komponen
36 40 44 45
Selulosa 5386.094414089
Selulosa-Na
MCA 4
MCA-Na
NaOH 3.0288616704041
Na-Glikolat
CMC
NaCl
H2O_x000D_ 925.236347386 3 16.4447298314238
O2 -750.699448769
N2 -2785
Total 6311.330761475 7.376305718326 19.4735915018279 -3535.98831675
Reaksi -8384.9783483922
Qloss
-5582.8
Heater (E-204)
(ΔH46)
T= 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
CMC
Na-Glikolat
H2O 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
NaCl 41.293 0.033607 -0.000013927
Aging Vessel (V-103)

T= 55 C = 328.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Cooler (E-205)
T= 55 C = 328.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Cyclone (CY-101)
Tref = 25 C = 298.15 K
T48 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Cyclone (CY-102)
Tref = 25 C = 298.15 K
T52 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Silo (TK-107)
Tref = 25 C = 298.15 K
T51 = 35 C = 308.15 K
T53 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Rotary Dryer (RD-102)

Tref = 25 C = 298.15 K
T57 = 35 C = 308.15 K
T59 = 150 C = 423.15 K
T60 = 100 C = 373.15 K
a. menentukan % relative humidity
T udara awal = 30 C
P= 1 atm
PA = 2.97 kPa
P uap air = 4.246 kPa (Appendix A.2-9 Geankoplis 1993:857)
100 𝑥 𝑃𝐴/(𝑃𝑢𝑎𝑝 𝑎𝑖𝑟)

HR = = 69.9481865284974
H= 0.019 kg uap air/kg udara kering (perry's 7th ed gambar 12-3 hal 12-6)
H2 = 0.019 (diasumsi kan tidak berubah)
b. Menentukan wet bulb (Tw)
Ww = 0.0646
Wg = 0.019
tw = 123.8 F = 51
0.0456 = 0.00023 196.2
0.0456 = 0.04563
c. Menentukan suhu udara keluar (TG1)
exp(1,5) = 150-51
4.48169 = 99
99 = 4.48169
99 = 4.48169
327.56614 = 4.48169
TG1 = 73.1
= 346.2
d. Menentukan panas umpan masuk (Q57)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
e. menentukan panas produk keluar (Q60 dan Q61)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
4456.355649538 + 294.93738 N O2
f. Qloss
Qloss = 0,25 x Panas udara masuk
Qloss = 0.25 x ( 3737.70020
Qloss = 934.4250489227 N O2 + 912.0466488625
Panas masuk = Panas keluar

Q55 + Q57 = Q58 + Q59 + Qloss
2691.93267 + 3737.70020 N O2 +
2691.93267 + 3737.70020 N O2 +
2691.933 +
17461.83072 N O2 -
45912.1300117382 45912.13001174
Q55 = 2691.93 45912.13

Q57= 43220.19734096 kj/jam 45912.13
Q58 = 7893.78443 kj/jam
Qloss = 10805.04933524 kj/jam
Masuk Keluar
Komponen
Komponen
55 57 58 59
Selulosa 1077.21781 3770.26
Selulosa-Na 0.00000 0.00
MCA 0.72904 2.70
MCA-Na 0.00000 0.00
NaOH 661.63873 2315.74
CMC 2.29714 21052.14
Na-Glikolat 0.50537 1.77
NaCl 1.26849 4.47
H2O_x000D_ 948.27608 4456.35565 66.22
O2 9251.272 730.00661
N2 33968.926 2707.422
2691.933 43220.197 7893.784 27213.296
Qloss 10805.04934
Total 45912.130 45912.130
Heater (E-301)
Tref = 25 C = 298.15 K
Komponen A B C D
O2 29.526 -0.0088999 0.000038083 -3.2629E-08

N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Masuk Keluar
Komponen
58 59
Udara 1718.359 43220.197
Qsteam 41501.838
43220.197 43220.197
Cooler (E-302)
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Masuk Keluar
Komponen
59 60
Selulosa 3770.262 1077.218
Selulosa-Na 0.000 0.000
MCA 2.704 0.729
MCA-Na 0.000 0.000
NaOH 0.460 0.131
CMC 21052.142 185349.069
Na-Glikolat 1.769 15.573
NaCl 4.467 1.268
H2O_x000D_ 66.217 18.966
24898.021 186462.953
Qsteam 161564.933
total 186462.953 186462.953
Ball Mill (BM-301)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Roll Crusher (RC-101)

Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Komponen Cp (kj/kg) 1 2
N (kmol) NCpdT N (kmol)
Selulosa 1040200 0.002555146199 2657.86307602339 0.002555146199
Hemiselulosa 147533.75 0.008959603554 1321.84391088517 0.008959603554
Lignin 10022.5 0.137977894737 1382.88345 0.137977894737
5362.59043690856
Vibrating Screen (VS-101)

Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Kelua
Selulosa 1040200 0.002555146199 2657.86307602339 0.00012775731
Hemiselulosa 147533.75 0.008959603554 1321.84391088517 0.000447980178
Lignin 10022.5 0.137977894737 1382.88345 0.006898894737
5362.59043690856
5362.59043690856
Silo 1 (TK-101)
Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Selulosa 1040200 0.002427388889 2524.96992222222 0.002427388889
Hemiselulosa 147533.75 0.008511623377 1255.75171534091 0.008511623377
Lignin 10022.5 0.131079 1313.7392775 0.131079
5094.46091506313
Steam Explosion Tank (V-101)

Data Steam
P= 1002.7 kPa P=
T =_x000D_
6
453.15 K T =_x000D_
7
Vspecific =_x000D_ 193.8 cm3/g Vspecific =_x000D_

Hvap = 2776.3 kj/kg Hvap =
Hliq = 763.1 kj/kg Hliq =
Q= 0 diasumikan proses adibatik

r= 0 diasumsikan tidak ada panas tergenerasi
T =_x000D_
5
303.15 K
T6=_x000D_ 453.15 K
T =_x000D_
7
373.15 diasumsikan aliran keluar proses dalam keadaan setimbang pada tekanan atmos
T = _x000D_
ref
298.15 K
1. Menghitung Usaha (W)

𝑊=−∫_(𝑣_1^𝑡)^(
𝑣_2^𝑡)▒ 〖𝑃 P1.3 hal 9 van ness et al (2005) introduction of chemical engineering thermody
𝑑𝑉 ^𝑡 〗
Adiabatic expansion process berlaku persamaan 𝑃𝑉^𝛾=𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
γ= 1.32
Vin = 2631.542004 m3/jam
Vout = 304.8373224 m3/jam
K = 3313500.572382 kJ/m3
W= -827438.6720435 kj/jam
2. Menghitung Entalpi Aliran Input

Komponen Cp m m.Cp.dT (kJ/kg)
Selulosa 6420.987654321 393.237 2524.97

Hemiselulosa 6.386742424242 196.6185 1.26
Lignin 6.681666666667 196.6185 1.3137
H2O 4366976
4369503.072
W+ 〖∆ H 〗 _input− 〖∆ H 〗 _output =0
W+ 〖∆ H 〗 _input−( 〖∆ H 〗 _Selulosa+ 〖∆ H 〗 _Hemiselulosa+ 〖∆ H 〗 _Hemiselulosa(aq) +
〖∆ 〖
W+ H〗∆ H_Lignin+ 〖∆〖
〗 _input−( H∆〗H_(H_2 O(g) )+ 〖〖
〗 _Selulosa+ ∆∆HH〗〗_(H_2 O(l))) =0
_Hemiselulosa+
〖∆ H 〗 _(Hemiselulosa(aq))+ 〖∆ H 〗 _Lignin) = 〖∆ H 〗 _(H_2 O)
∆H2O = 2251.8 kj/jam
4. Menghitung fraksi uap dan cair dari steam
y= fraksi uap
P6.73a hal 219 van ness et al (2005) intr
y= 0.8120
1-y= 0.1880
3367367.0784 kj/jam
131844.50136 kj/jam
Masuk Keluar
Komponen 5 6 7
Q Q Q
Selulosa 2524.9699 37.875
Hemiselulosa 1.2558 5.6509
Hemiselulosa (aq) 13.1854
Lignin 1.3137 19.7061
H2O (g) 4366975.5324 3367367.0784
H2O (l) 131844.50136
2528 4366975.5 3499288
W -827438.67
3542064.40 3499288.00
Cp (kj/kg)
Flash Tank (V-102)
Cp (kj/kg)
Tref = 25 C = 298.15 K
T7 = 100 C = 373.15 K
T8= 100 C = 373.15 K
T9 = 100 C = 373.15 K
7
Komponen Cp
N N.Cp.dT
Selulosa 15603000 0.002427388889 37874.549
Hemiselulosa 2213006.25 0.002553487013 5650.883
Hemiselulosa (aq) 2213006.25 0.005958136364 13185.393
Lignin 150337.5 0.131079 19706.089
H2O (g) 3367367.078
H2O (l) 131844.501
3575628.493
3575628.493
Heater (E-101)
Tref = 25 C = 298.15 K
T8 = 100 C = 373.15 K
T10= 150 C = 423.15 K
Masuk Keluar
Komponen 8 10
Cp N N.Cp.dT Cp
Selulosa 15603000 0.002427388889 37874.55 26005000
Hemiselulosa 2213006.25 0.002553487013 5650.8827 3688343.75
Hemiselulosa (aq) 2213006.25 0.005958136364 13185.3930 3688343.75
Lignin 150337.5 0.131079 19706.0892 250562.5
H2O 131844.5014
208261.4151 259206.024236578
Qsteam 50944.6092
259206.024
Mixer (M-101)
Tref = 25 C = 298.15 K T13= 30 C =
T12 = 30 C = 303.15 K T14= 30 C =
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Heater (E-102)
Tref = 25 C = 298.15 K
T14 = 30 C = 303.15 K
T15= 150 C = 423.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
Delignification Tank (DT-101)

Tref = 25 C = 298.15 K
T10 = 150 C = 423.15 K
T15= 150 C = 423.15 K
T16= 150 C = 423.15 K
Komponen A B C D
Selulosa
Hemi
Hemi aq
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Expansion Valve (EV-101)

Tref = 25 C = 298.15 K
T16 = 150 C = 423.15 K
T17 = 150 C = 423.15 K
Komponen A B C D
Selulosa
Hemi aq
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Cooler (E-103)
Tref = 25 C = 298.15 K
T17 = 150 C = 423.15 K
T8 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Hemi aq
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Qcw
Heater (E-104)
Tref = 25 C = 298.15 K
T19 = 30 C = 303.15 K
T20 = 80 C = 353.15 K
Komponen A B C D
H2O 92.053 -0.039953 -0.00021103 0.00000053469

Qsteam
Rotary Filter (RF-101)

Tref = 25 C = 298.15 K
T18 = 80 C = 353.15 K
T20 = 80 C = 353.15 K
T21 = 80 C = 353.15 K
T22 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Hemiselulosa(aq)
Lgnin
Lignin (aq)
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
Heater (E-105)
Tref = 25 C = 298.15 K
T23 = 30 C = 303.15 K
T24 = 80 C = 353.15 K
Komponen A B C D
H2O2 -15.248 0.67693 -0.0014948 0.0000012018

Qsteam
Bleaching Tank (BT-101)

Tref = 25 C = 298.15 K
T21 = 80 C = 353.15 K
T24 = 80 C = 353.15 K
T26 = 80 C = 353.15 K
T27 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Lig
Lig aq
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
H2O2 -15.248 0.67693 -0.0014948 0.0000012018
Heater (E-106)
Tref = 25 C = 298.15 K
T25 = 30 C = 303.15 K
T26 = 80 C = 353.15 K
Komponen A B C D
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
Heater (E-107)
Tref = 25 C = 298.15 K
T28 = 30 C = 303.15 K
T29 = 80 C = 353.15 K
Komponen A B C D
Komponen A B C D
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
Rotary Filter (RF-102)

Tref = 25 C = 298.15 K
T27 = 80 C = 353.15 K
T29 = 80 C = 353.15 K
T30 = 80 C = 353.15 K
T31 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Lignin (aq)
H2O (l) 92.053 -0.039953 -0.00021103 0.00000053469
H2O2 -15.248 0.67693 -0.0014948 0.0000012018
Rotary Dryer (RD-101)

Tref = 25 C = 298.15 K
T31 = 80 C = 353.15 K
T33 = 200 C = 473.15 K
T35 = 90 C = 363.15 K
a. menentukan % relative humidity
T udara awal = 30 C
P= 1 atm
PA = 2.97 kPa
P uap air = 4.246 kPa (Appendix A.2-9 Geankoplis 1993:857)
100 𝑥 𝑃𝐴/(𝑃𝑢𝑎𝑝 𝑎𝑖𝑟)

HR = = 69.9481865284974
H= 0.019 kg uap air/kg udara kering (perry's 7th ed gambar 12-3 hal 12-6)
H2 = 0.019 (diasumsi kan tidak berubah)
b. Menentukan wet bulb (Tw)

Ww = 0.0646
Wg = 0.019
tw = 123.8 F = 51
0.0456 = 0.00023 196.2
0.0456 = 0.04563
c. Menentukan suhu udara keluar (TG1)
exp(1,5) = 200-51
4.48169 = 149
149 = 4.48169
149 = 4.48169
377.56614 = 4.48169
TG1 = 84.2
= 357.4
d. Menentukan panas umpan masuk

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Qumpan masuk = 63309.590 + 5612.45127847
e. menentukan panas produk keluar

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Qproduk = 31954.3182096 + 1825.70095
f. Qloss
Qloss = 0,25 x Panas udara masuk
Qloss = 0.25 x ( 5612.45127847
Qloss = 1403.112819618 N O2 + 1290.957471715
Panas masuk = Panas keluar
Q31 + Q33 = Q34 + Q35 + Qloss
63309.59037 + 5612.45128 N O2 +
63309.59037 + 5612.45128 N O2 +
63309.590 +
25038.28752 -
Q33= 19432.04055751 kj/jam

Q34= 38434.2734604 kj/jam
Qloss = 4858.010139377 kj/jam
Heater (E-108)
Tref = 25 C = 298.15 K
T32 = 30 C = 303.15 K
T33 = 200 C = 473.15 K
Komponen A B C D
O2 29.526 -0.0088999 0.000038083 -3.2629E-08

N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Qsteam
Cooler (E-201)
Tref = 25 C = 298.15 K
T36 = 90 C = 363.15 K
T37 = 35 C = 308.15 K
Komponen A B C D
Komponen A B C D
Selulosa
H2O l 92.053 -0.039953 -0.00021103 0.00000053469
Qcw
Heater (E-202)
Tref = 25 C = 298.15 K
T32 = 30 C = 303.15 K
T33 = 35 C = 308.15 K
Komponen A B C D
MCA -55.75 0.59859

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qsteam
heater (E-203)
Tref = 25 C = 298.15 K
T44 = 30 C = 303.15 K
T45 = 35 C = 308.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359

H2O l 92.053 -0.039953 -0.00021103 0.00000053469
Qcw
Mixer (M-102)
Tref = 25 C = 298.15 K
T37 = 30 C = 303.15 K
T38= 30 C = 303.15 K
T39= 30 C = 303.15 K
Komponen A B C D
MCA -55.75 0.59859

H2O 92.053 -0.039953 -0.00021103 0.00000053469
Mixer (103)
Tref = 25 C = 298.15 K
T41 = 30 C = 303.15 K
T42= 30 C = 303.15 K
T43= 30 C = 303.15 K
Komponen A B C D
NaOH 51.234 0.013088 0

H2O 92.053 -0.039953 -0.00021103
Total steam = 3360.235432 kg/jam

3.360235431678 ton/jam
Total cw = 30928.85524557 kg/jam
30.92885524557 ton/jam
Total udara = kg/jam
ton/jam
OCH_2 COONa+NaCl
T40 =
Tref =
Cp (J/mol ) N (mol) Q (J/jam) Komponen
2080400 0.00259 5386.09441408872 MCA
754.460765759055 1 925.236347386016 H2O
6311.33076147473
T45 =
Tref =
Cp (J/mol ) N (mol) Q (J/jam) Komponen
573.485121480108 0.0052815000023 3.0288616704041 O2
754.460765759055 0.0217966666761 16.4447298314238 N2
19.4735915018279
+ 145.36792 N N2
B C D Cp (J/mol) ΔH (kj/jam)
2080400 5386094.4140887
2004800 6228441.8850404
290410 0
0.013088 0.000023359 573.485121480108 3028.8616704041
0.033607 -0.000013927 502.009557710092 0
-0.039953 -0.00021103 0.00000053469 754.460765759055 945151.78953574
12562716.950335
ΔHR0 + [ΔH produk - ΔH reaktan]
-213.42640028575 + -3793.9260391537
-4007.3524394395 kJ/mol
-8299.9340855027 kJ/jam
B C D Cp (kJ/kmol) ΔH (kj/jam)
0.59859 1257.125585 1301.864466675
0.013088 0.000023359 61.59 70.160067383214
110.91 0
-0.039953 -0.00021103 0.00000053469 754.460765759055 0
ΔHR0 + [ΔH produk - ΔH reaktan]

266.704599714255 + -453.34481924095
-186.64021952669 kJ/mol
-85.044262889498 kJ/jam
(ΔH48)
T=
Tref =
Cp (J/mol) N (mol) Q (J/jam) Komponen
208040 0.000513 1066.44669398957 Selulosa
200480 0.000000 0 Selulosa-Na
1257.125585 0.000574 0.7217536603246 MCA
61.59 0.000000 0 MCA-Na
290410 0.000226 655.023001041455 CMC
110.91 0.002050 2.27417040627539 Na-Glikolat
754.460765759055 0.000451 0.34033893802247 H2O
573.485121480108 0.002502 1.43461142177022 NaOH
502.009557710092 1.244325 624.662956152838 NaCl
2350.90352561025 O2
N2
294.937383716924 N O2 + 290.771081870133 N N2
N O2 + 145.36792 N N2 )
N N2
+ 546.86026820407 N O2
294.937383716924 N O2 + 1093.85311751145 N O2
N O2
546.860268204066 N O2 + -8384.9783483922 =
694.251695575628 N O2 + -8384.9783483922 =
-2046.7976896973 + 694.251695575628 N O2 =
694.251695575628 N O2 =
-868.10172954666 N O2 =
N O2 =
F O2 =
F O2 =
N N2 =
F N2 =
F N2 =
Udara =
=
Keluar
46 47
1066.44669398957 10.772188828178
0 0
0.7217536603246 0.0072904410134
0 0
655.023001041455 6.6163939499137
2.27417040627539 0.0229714182452
0.34033893802247 0.0034377670507
1.43461142177022 0.0144910244623
624.662956152838 6.3097268298267
-1502.185950201
-5571.253002931
2350.90352561025 -7049.692452873
-883.997079188482
-5582.786
(ΔH48)
T=
Tref =
Cp (J/mol.K) N (kmol) Q (kj/jam) Komponen
2080400 0.00 1066.45 Selulosa
2004800 0.00 0.00 Selulosa-Na
1257.13 0.00 0.72 MCA
615.90 0.00 0.00 MCA-Na
2904100 0.00 655.02 CMC
1109.10 0.00 2.27 Na-Glikolat
754.46 0.00 0.34 H2O
573.49 0.00 1.43 NaOH
502.01 1.24 624.66 NaCl
2350.90
T=
Tref =
Cp N (kmol) Q (kj/jam) Komponen
6241200 0.0005 3199.3 Selulosa
6014400 0.0000 0.0 Selulosa-Na
3950.9538 0.0006 2.3 MCA
1847.7000 0.0000 0.0 MCA-Na
1728.7473 0.0002 0.4 NaOH
8712300 0.0021 17864.3 CMC
3327.3000 0.0005 1.5 Na-Glikolat
1513.5080 0.0025 3.8 NaCl
2258.6647 1.2443 2810.5 H2O_x000D_
23882.062
T=
Tref =
Cp (J/kg K) N (kmol) Q (kj/jam) Komponen
6241200 0.0005126161767 3199.3400819687 Selulosa
6014400 0 0 Selulosa-Na
3950.9538 0.0005741301179 2.268361545155 MCA
1847.7 0 0 MCA-Na
1728.7473 0.0002255511177 0.38992089211681 NaOH
8712300 0.0020504647068 17864.263664767 CMC
3327.3 0.0004511022355 1.50095246814175 Na-Glikolat
1513.5080 0.0025015669423 3.78614146982167 NaCl
2258.6647 1.2443248272049 2810.51253088582 H2O_x000D_
23882.0617
T52 = 35 C =
T53 = 35 C =
47 51
E
Cp N (kmol) Q (kj/jam) Cp
2080400 5.1779411787E-06 10.7721888281774 2080400
2004800 0 0 2004800
1257.125585 5.7992941201E-06 0.0072904410133798 1257.125585
615.9 0 0 615.9
573.48512148011 2.2782941186E-06 0.00130656777939 573.48512148011
2904100 2.0711764715E-05 60.1490359083063 2904100
1109.1 4.5565882373E-06 0.0050537120139453 1109.1
502.00955771009 2.5268352952E-05 0.0126849546895358 502.00955771009
754.46076575906 0.01256893764853 9.48277032309133 754.46076575906
8.8607E-12 294.93738371693 -5.0932368466484 -1502.18595020112 294.93738371693
2.5935E-13 290.77108187013 -19.160271946916 -5571.25300293057 290.77108187013
-6993.00862239662
-6993.00862239662
T54 = 35 C =
T55 = 35 C =
51 53
E
2080400 5.1779411787E-08 0.1077219 2080400.00
2004800 0 0.0000000 2004800.00
1257.125585 5.7992941201E-08 0.0000729 1257.13
615.9 0 0.0000000 615.90
573.48512148011 2.2782941186E-08 0.0000131 573.49
2904100 2.0711764715E-07 0.6014904 2904100.00
1109.1 4.5565882373E-08 0.0000505 1109.10
502.00955771009 2.5268352952E-07 0.0001268 502.01
754.46076575906 0.00012568937649 0.0948277 754.46
8.8607E-12 294.93738371693 -5.0932368466484 -1502.186 294.94
2.5935E-13 290.77108187013 -19.160271946916 -5571.253 290.77
-7072.63
-7072.63
T55 = 35 C = 308.15
T56 = 35 C = 308.15
50 52
Cp N (kmol) Q (kj/jam) Cp N (kmol)
2080400 0.001 1066.447 2080400.00 0.00001
2004800 0.000 0.000 2004800.00 0.00000
1257.125585 0.001 0.722 1257.13 0.00001
615.9 0.000 0.000 615.90 0.00000
573.485121480108 0.000 0.129 573.49 0.00000
2904100 0.002 5954.755 2904100.00 0.00002
1109.1 0.000 0.500 1109.10 0.00000
502.009557710092 0.003 1.256 502.01 0.00003
754.460765759055 1.244 938.794 754.46 0.01244
7962.603
s 1993:857)
y's 7th ed gambar 12-3 hal 12-6)

C = 324.15 K
/ TG1 - 51
/ TG1 - 51
(TG1- 51)
TG1 - 228.566142587241
TG1
C
K
T57 = 35 C = 308.15 K T59 = 150C =

55 57
E
Cp (kj/kg) N (kmol) Q (kj/jam) Cp (kj/kg)
2080400 0.00052 1077.22 26005000
2004800 0.00000 0.00 25060000
1257.12559 0.00058 0.73 20016.43544
615.90 0.00000 0.00 7698.75000
2904100 0.00023 661.64 36301250
1109.10 0.00207 2.30 36301250.00
1109.10000 0.00046 0.51 13863.75000
502.00956 0.00253 1.27 6447.97094
754.46077 1.25689 948.28 9469.49572
8.8607E-12 3737.70020
2.5935E-13 3648.18660
2691.93
T60=73,1C = 346.25 K T61 = 60 C =

58 59
E
Cp (kj/kg) N (kmol) Q (kj/jam) Cp (kj/kg)
7281400
7016800
4661.82267
2155.65000
10164350
10164350
3881.85000
1767.92043
3617.89227 1.23175465780052 4456.35564953779 2634.16638
8.8607E-12 294.93738 ? ?
2.5935E-13 290.77108 ? ?
+ 290.77108 N N2
N O2 + 3648.18660 N N2 )
N N2
3648.18660 N N2 = 4456.35564953779 +
13724.13053 N O2 = 4456.35564953779 +
17461.831 N O2 = 5754.248 N O2
5754.248 N O2 = 31669.652 -
11707.583 N O2 = 28977.719
N O2 = 2.475 kmol/jam
F O2 = 79.204 kg/jam
F O2 = 0.079 ton/jam
N N2 = 9.311 kmol/jam
F N2 = 130.357 kg/jam
F N2 = 0.130 ton/jam
Udara = 209.561 kg/jam

udara = 0.210 ton/jam
T56 = 30 C = 303.15 K T57 = 150C =
56 57
E
8.8607E-12 147.39142737156 2.47512405946725 364.812068046572 3737.7001956907
2.5935E-13 145.36791939602 9.31118098561491 1353.5470069986 3648.18659545
1718.35908
T59 = 60 C = 333.15 K T60 = 35C = 308.15

59 60
Cp (J/mol.K) N (kmol) Q (kj/jam) Cp (kj/kg) N (kg)
7281400 0.00052 3770.26232 2080400 0.00052
7016800 0.00000 0.00000 61777912 0.00000
4661.82267 0.00058 2.70353 1257.12559 0.00058
2155.65 0.00000 0.00000 18978.96 0.00000
2019.32444 0.00023 0.46006 573.48512 0.00023
10164350 0.00207 21052.14152 89489842 0.00207
3881.85 0.00046 1.76880 34176.92 0.00046
1767.92043 0.00253 4.46724 502.00956 0.00253
2634.16638 0.02514 66.21728 754.46077 0.02514
24898.02
T60 = 60 C = 308.15 K T61 = 35C = 308.15
59 60
Cp (J/mol.K) N (kmol) Q (kj/jam) Cp (kj/kg) N (kg)
2080400 0.00052 1077.21781 2080400 0.00052
2004800 0.00000 0.00000 2004800 0.00000
1257.12559 0.00058 0.72904 1257.12559 0.00058
615.90 0.00000 0.00000 615.90 0.00000
573.48512 0.00023 0.13066 573.48512 0.00023
2904100 0.00207 6014.89758 2904100 0.00207
1109.10 0.00046 0.50537 1109.10 0.00046
502.00956 0.00253 1.26849 502.00956 0.00253
754.46077 0.02514 18.96552 754.46077 0.02514
7113.71
K
Keluar
2
NCpdT
2657.86307602339
1321.84391088517
1382.88345
5362.59043690856
K
Keluar
3 4
NCpdT N (kmol) NCpdT
132.89315380117 0.0024273888889 2524.96992222222
66.0921955442584 0.0085116233766 1255.75171534091
69.1441725 0.131079 1313.7392775
268.129521845428 5094.46091506313
5362.59043690856
K
Keluar
5
NCpdT
2524.96992222222
1255.75171534091
1313.7392775
5094.46091506313
101.3 kPa
373.15 K
1673 cm3/g
2676 kj/kg
419.1 kj/kg
aan setimbang pada tekanan atmosfer
of chemical engineering thermodynamic'
P3.29c hal 75 van ness et al (2005) introduction of chemical engineering thermodynamic'
3. Menghitung Entalpi Aliran output

Komponen Cp m N.Cp.dT
Selulosa 96.314814814815 393.237 37.8745

Hemiselulosa 95.801136363636 58.98555 5.6509
Hemiselulosa(aq) 95.801136363636 137.63295 13.1854
Lignin 100.225 196.6185 19.7061
H2O (g)
H2O (l)
76.4169
Hemiselulosa(aq) +
a hal 219 van ness et al (2005) introduction of chemical engineering thermodynamic'

8 9
Cp Cp
N N.Cp.dT N
15603000 0.0024273888889 37874.5488
2213006.25 0.002553487013 5650.8827
2213006.25 0.0059581363636 13185.3930
150337.5 0.131079 19706.0892
131844.5014
208261.4151
T steam = 170
P steam =
Keluar Q (kj/jam) Hv (kJ/kg)
10 50944.6092 2767.1
N N.Cp.dT
0.00242738888889 63124.248055556
0.00255348701299 9418.1378650568
0.00595813636364 21975.655018466
0.131079 32843.4819375
131844.5014
259206.024236578
259206.0
303.15 K
303.15 K
Masuk
12 13
Cp N N.Cp.dT Cp N
286.401928718804 27.52659 7883.66846705175 286.401928718804
377.486381588157 61.1702 23090.9174590239 377.486381588157 183.5106
30974.5859260757
Masuk Keluar
14 15
Cp N N.Cp.dT Cp N
286.401928718804 27.52659 7883.66846705175 7377.8588557201 27.52659
377.486381588157 244.6808 92363.6698360956 9469.49571881325 244.6808
2419843.74557193
2520091.08387508
Masuk
10 15
Cp N N.Cp.dT Cp N
26005000 0.0024273888889 63124.2480555556
3688343.75 0.002553487013 9418.13786505682
3688343.75 0.0059581363636 21975.6550184659
250562.5 0.131079 32843.4819375
131844.5014 9469.49571881325 244.6808

7377.8588557201 27.52659
259206.024236578
Masuk Keluar
16 17
Cp N N.Cp.dT Cp N
26005000 0.0024273888889 63124.2480555556 26005000 0.0024273888889
3688343.75 0.0085116233766 31393.7928835227 3688343.75 0.0085116233766
250562.5 0.00655395 1642.174096875 250562.5 0.00655395
250562.5 0.12452505 31201.307840625 250562.5 0.12452505
2448848.2894358
7377.8588557201 27.52659 203087.295799277 7377.8588557201 27.52659
2779297.10811166
Masuk Keluar
17 18
Cp N N.Cp.dT Cp N
26005000 0.0024273888889 63124.2480555556 11442200 0.0024273888889
3688343.75 0.0085116233766 31393.7928835227 1622871.25 0.0085116233766
250562.5 0.00655395 1642.174096875 110247.5 0.00655395
250562.5 0.12452505 31201.307840625 110247.5 0.12452505
2448848.2894358 4136.37124570978 262.158
7377.8588557201 27.52659 203087.295799277 3188.85429699435 27.52659
2779297.10811166 1228200.16790158
1551096.94021008
2779297.10811166
Masuk Keluar
19 20
Cp N N.Cp.dT Cp N
377.486381588157 734.0424 277091.009508287 4136.37124570978 734.0424
2759180.86698351
3036271.87649
Masuk
18 20
Cp N N.Cp.dT Cp N
11442200 0.0024273888889 27774.6691444444
1622871.25 0.0085116233766 13813.26886875
110247.5 0.00655395 722.556602625
110247.5 0.12452505 13728.575449875
4136.37124570978 262.158 1084382.81303278 4136.37124570978 734.0424
3188.85429699435 27.52659 87778.2848031016
1228200.16790158
Masuk Keluar
23 24
Cp N N.Cp.dT Cp N
429.072591260699 6.7208829617647 2883.74666796427 4845.31001 6.7208829617647
29681.0148505524
32564.7615185167
Masuk
22 24
Cp N N.Cp.dT Cp N
11442200 0.0024273888889 27774.6691444444
110247.5 0.00655395 722.556602625
4136.37124570978 19.924008 82413.0937904915

4845.31001414227 6.7208829617647
110910.319537561
Masuk Keluar
25 26
Cp N N.Cp.dT Cp N
377.486381588157 137.00454185294 51717.3487652101 4136.37124570978 137.00454185294
514984.298686937
566701.6475
Masuk Keluar
28 29
Cp N N.Cp.dT Cp N
377.486381588157 384.03242700588 144967.011282969 4136.37124570978 384.03242700588
1443533.6772043
1588500.68848727
Masuk
27 29
Cp N N.Cp.dT Cp N
11442200 0.0024273888889 27774.6691444444
110247.5 0.00655395 722.556602625
4136.37124570978 156.92854985294 649114.741242639 4136.37124570978 384.03242700588
4845.31001414227 6.7208829617647 32564.7615185167
710176.728508225
s 1993:857)
y's 7th ed gambar 12-3 hal 12-6)

C = 324.15 K
/ TG1 - 51
/ TG1 - 51
(TG1- 51)
TG1 - 228.566142587241
TG1
C
K
T31 = 80 C = 353.15 K T33 = 200C =

31 33
E
Cp.dT N N.Cp.dT Cp.dT
11442200 0.00259 29623.51928
3113.53984 10.81922 33686.07109
8.8607E-12 5612.4512784701
2.5935E-13 5163.8298868604
63309.59037
N O2 + 5163.82989 N N2
T34=84,2C = 357.4 K T35 = 90 C =

34 35
E
13522600
3331.05053 9.59286504748324 31954.318209601 3620.2694043095
8.8607E-12 1825.70095 ? ?
2.5935E-13 1734.16294 ? ?
N O2 + 1734.16294 N N2 +
N O2 + 5163.82988686043 N N2 )
N N2
5163.82989 N N2 = 31954.318209601 +
19425.83624 N O2 = 31954.318 +
25038.28752 N O2 = 71403.666 +
14609.02865 N O2 = 71403.666 -
10429.25886 N O2 = 8094.075
N O2 = 0.776 kmol/jam
F O2 = 24.835 kg/jam
= 0.025 ton/jam
N N2 = 2.920 kmol/jam
F N2 = 40.8742331877828 kg/jam
= 0.0408742331877828 ton/jam
udara = 65.709 kg/jam
= 0.0657092103145369 ton/jam
Masuk Keluar
E 32 33
8.8607E-12 151.82534 0.77609303521107 117.830591239324 5612.4512784701
2.5935E-13 145.95382 2.91958808484163 426.125026618749 5163.8298868604
14650.1311832081
15076.2562098268
Masuk Keluar
35 36
Cp.dT N N.Cp.dT Cp.dT N
75549427.85 0.0025889705894 195595.246746051 97.5754691358025 0.0025889705894
4888.78746034047 1.2263544896932 5995.38645114454 754.460765759055 1.2263544896932
201590.633197195
200665.144229789
201590.633197195
Masuk Keluar
39 40
621.0804175 0.0031067647072 1.92955072143625 1257.125585 0.0031067647072
377.486381588157 0.0046002555412 1.73653381862869 754.460765759055 0.0046002555412
3.71022117826152
7.37630571832646
Masuk Keluar
43 44
286.401928718804 0.0052815000023 1.51263178718104 573.485121480108 0.0052815000023
377.486381588157 0.0217966666761 8.22794483423343 754.460765759055 0.0217966666761
9.73301488041345
19.4735915018279
Masuk
37 38
Cp (kJ/kg) N mCpdT Cp (kJ/kg) N
0 0.2935799445384 0
Err:509 0.0029654539852 Err:509 Err:509 0.0798391457564
Err:509
Masuk
41 42
Cp (kJ/kg) m (kg) mCpdT Cp (kJ/kg) m (kg)
Err:508 0.2112600000912 Err:508
Err:509 0.2112600000912 Err:509 Err:509 0.18
Err:508
35 C = 308.15 K
25 C = 298.15 K
A B C D Cp (J/mol.K) N (mol)
-55.75 5.99E-01 1257.126 0.00311
92.053 -0.039953 -0.00021103 0.00000053469 754.461 0.00460
30 C = 303.15 K
25 C = 298.15 K
A B C D E Cp (J/mol)
29.526 -0.0088999 0.000038083 -0.000000032629 8.8607E-12 147.39143
29.342 -0.0035395 0.000010076 -4.3116E-09 2.59E-13 145.36792
292.7593467676
35 C = 308.15 K
25 C = 298.15 K
A B C D E Cp (J/mol)
208040
200480
-55.75 0.59859 1257.125585
61.59
290410
110.91
92.053 -0.039953 -0.00021103 0.00000053469 754.4607657591
51.234 0.013088 0.000023359 573.4851214801
41.293 0.033607 -0.000013927 502.0095577101
29.526 -0.0088999 0.000038083 -0.000000032629 8.8607E-12 294.9373837169
29.342 -0.0035395 0.000010076 -4.3116E-09 2.5935E-13 290.7710818701
…...(1)
…...(2)
…...(3)
…...(4)
2350.90352561025 + 23.7465002586894 + 294.9373837169 N O2

2350.90352561025 + 23.7465002586894 + 1562.353425122 N O2
2374.65002586894 + 1562.35342512228 N O2
2374.650 - -2046.7976896973
4421.448
-5.0932 mol/jam
-162.9836 kg/jam
-0.1630 ton/jam
-19.2 kmol/jam
-268.2438 kg/jam
-0.3 ton/jam
-431.2 kg/jam
-0.4 ton/jam
55 C = 328.15 K
25 C = 298.15 K
A B C D Cp (J/mol K) N (kmol)
62412000 0.00051
60144000 0.00000
-55.75 0.59859 3950.95376 0.00057
18477.00000 0.00000
87123000 0.00023
33273.00000 0.00205
92.053 -0.039953 -0.00021103 0.00000053469 2258.66467 0.00045
51.234 0.013088 0.000023359 1728.74733 0.00250
41.293 0.033607 -0.000013927 1513.50796 1.24432
Qsteam =
55 C = 328.15 K
25 C = 298.15 K
A B C D Cp N (kmol)
6241200 0.000512616177
6014400 0
-55.75 0.59859 3950.9538 0.000574130118
1847.7000 0
51.234 0.013088 0.000023359 1728.7473 0.000225551118
8712300 0.002050464707
3327.3000 0.000451102235
41.293 0.033607 -0.000013927 1513.5080 0.002501566942
92.053 -0.039953 -0.00021103 0.00000053469 2258.6647 1.244324827205
35 C = 308.15 K
25 C = 298.15 K
A B C D Cp (J/kg K) N (kmol)
2080400 0.000512616177
2004800 0
-55.75 0.59859 1257.1256 0.000574130118
615.9000 0
51.234 0.013088 0.000023359 573.4851 0.000225551118
2904100 0.002050464707
1109.1000 0.000451102235
41.293 0.033607 -0.000013927 502.0096 0.002501566942
92.053 -0.039953 -0.00021103 0.00000053469 754.4608 1.244324827205
308.15 K
308.15 K
51 52
N (kmol) Q (kj/jam) Cp N (kmol) Q (kj/jam)
5.1779411787E-08 0.107722 2080400 5.126161767E-06 10.6644669399
0 0.000000 2004800 0 0
5.7992941201E-08 0.000073 1257.125585 5.741301179E-06 0.007217536603
0 0.000000 615.9 0 0
2.2782941186E-08 0.000013 573.485121480108 2.255511177E-06 0.001293502102
2.0711764715E-07 0.601490 2904100 2.050464707E-05 59.54754554922
4.5565882373E-08 0.000051 1109.1 4.511022355E-06 0.005003174894
2.5268352952E-07 0.000127 502.009557710092 2.501566942E-05 0.012558105143
0.00012568937649 0.094828 754.460765759055 0.012443248272 9.38794261986
-5.0932368466484 -1502.19
-19.160271946916 -5571.25
-7072.63 79.6260
-6993.0086
308.15 K
308.15 K
53 54
N (kmol) Q (kj/jam) Cp N (kmol) Q (kj/jam)
0.000000 0.0010772 2080400.000 5.126161767E-08 0.1066447
0.000000 0.0000000 2004800.000 0 0.0000000
0.000000 0.0000007 1257.126 5.741301179E-08 0.0000722
0.000000 0.0000000 615.900 0 0.0000000
0.000000 0.0000001 573.485 2.255511177E-08 0.0000129
0.000000 0.0060149 2904100.000 2.050464707E-07 0.5954755
0.000000 0.0000005 1109.100 4.511022355E-08 0.0000500
0.000000 0.0000013 502.010 2.501566942E-07 0.0001256
0.000001 0.0009483 754.461 0.0001244324827 0.0938794
-5.093237 -1502.19
-19.160272 -5571.25
-7073.43 0.7963
-7072.63
K
K
52 54 55
Q (kj/jam) Cp N (kmol) Q (kj/jam) Cp N (kmol)
10.664 2080400.00 0.0000 0.106645 2080400.00 0.001
0.000 2004800.00 0.0000 0.000000 2004800.00 0.000
0.007 1257.13 0.0000 0.000072 1257.13 0.001
0.000 615.90 0.0000 0.000000 615.90 0.000
0.001 573.49 0.0000 0.000013 573.49 0.000
59.548 2904100.00 0.0000 0.595475 2904100.00 0.002
0.005 1109.10 0.0000 0.000050 1109.10 0.000
0.013 502.01 0.0000 0.000126 502.01 0.003
9.388 754.46 0.0001 0.093879 754.46 1.257
79.626 0.79626
8043.025
423.15 K
57
N (kmol) Q (kj/jam)
? ?
? ?
333.15 K
59
N (kmol) Q (kj/jam)
0.00 3770.262319596
0.00 0
0.00 2.703525377853
0.00 0
0.00 2315.735566732
0.00 21052.14151574
0.00 1.768797436082
0.00 4.467239272988
0.03 66.2172796512
Q59 = 27213.296
294.93738 N O2 + 290.77108 N N2 +
294.937 N O2 + 1093.853 N O2 +
+ 31669.652
2691.933
423.15 K T steam = 170 C
57 P steam = kPa
N (kmol) Q (kj/jam) Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg)
2.47512405946725 9251.27168143 41501.838 2767.1 719.1
9.31118098561491 33968.92565953
43220.197
41501.838
K
60 T CW in = 30 C 303.15
Q (kj/jam) T CW out = 49 C 323.15
1077.22 Q Cp
0.00 161564.933 1505.5337126063
0.73
0.00 Q = N.Cp.dT
0.13 N = Q/(Cp.dT)
185349.07 N = 107.31405828428 kmol/jam
15.57 F Cw = 1931.653049117 kg/jam
1.27 F Cw = 1.931653049117 ton/jam
18.97
186462.95
161564.933
K
60
Q (kj/jam)
1077.22
0.00
0.73
0.00
0.13
6014.90
0.51
1.27
18.97
7113.71
9
N.Cp.dT
3367367.0784
3367367.0784
3575628.4935
C 443.15 K
kPa
Hl (kJ/kg) λs (Kj/kg) m (kg/jam) m (ton/jam)
719.1 2047.9 24.877 0.025
Keluar
13 14
N.Cp.dT Cp N N.Cp.dT
286.4019287188 27.52659 7883.6684670518
69272.7523770717 377.4863815882 244.6808 92363.669836096
69272.7523770717 100247.33830315
100247.338303147 100247.33830315
T steam = 170 C 443.15
P steam = kPa
luar Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
15 2419843.7456 2767.1 719.1 2047.9
N.Cp.dT
203087.295799277
2317003.7880758
2520091.08387508
Keluar
15 16
N.Cp.dT Cp N N.Cp.dT
26005000 0.0024273888889 63124.248055556
3688343.75 0.0085116233766 31393.792883523

250562.5 0.00655395 1642.174096875
250562.5 0.12452505 31201.307840625
2317003.7880758 2448848.2894
203087.295799277 7377.85885572 27.52659 203087.29580
2520091.08387508 2779297.11
2779297.10811166 2779297.11
luar
17
N.Cp.dT
63124.2480555556
31393.7928835227
1642.174096875
31201.307840625
2448848.2894358
203087.295799277
2779297.10811166
T CW in = 30 C 303.15
T CW out = 49 C 322.15
luar Q Cp.dT
18 1551096.94021008 1094.5901651511
N.Cp.dT
27774.6691444444 Q = N.Cp.dT
13813.26886875 N = Q/(Cp.dT)
722.556602625 N = 1417.0572599618 kmol/jam
13728.575449875 F Cw = 25507.030679312 kg/jam
1084382.81303278 F Cw = 25.507030679312 ton/jam
87778.2848031016
.16790158
.94021008
2779297.10811166
T steam = 100 C 373.15

P steam =
20 2759180.8670 2676 419.1 2256.9
N.Cp.dT
3036271.87649179
3036271.87649
Keluar
20 21 22
N.Cp.dT Cp N N.Cp.dT Cp N
11442200 0.002427388889
1622871.25 0.0085116233766 13813.26886875
110247.5 0.00655395
110247.5 0.12452505 13728.575449875
3036271.87649179 4136.37124571 976.276392 4038241.5957341 4136.37124571 19.924008
3188.854296994 27.52659 87778.284803102
3036271.87649179 4153561.7248558
4264472.04439337
T steam = 100 C 373.15
P steam = kPa
24 29681.0149 2676 419.1 2256.9
N.Cp.dT
32564.7615185167
32564.7615185167
suk Keluar
24 26 27
11442200 0.002427388889
110247.5 0.00655395
4136.37124571 137.004541852941 566701.64745215 4136.37124571 156.9285498529
32564.7615185167 4845.310014142 6.720882961765
32564.7615185167 566701.64745215
710176.73
T steam = 100 C 373.15

P steam =
26 514984.2987 2676 419.1 2256.9
N.Cp.dT
566701.647452148
566701.6475
T steam = 100 C 373.15

P steam =
29 1443533.6772 2676 419.1 2256.9
N.Cp.dT
1588500.68848727
1588500.69
Keluar
29 30 31
11442200 0.002427388889
110247.5 0.00655395 722.556602625
1588500.68848727 4136.37124571 530.141757321647 2192863.1211353 4136.37124571 10.81921953718
4845.310014142 6.72088296176471 32564.761518517
1588500.68848727 2226150.4392565
2298677.4
473.15 K
33
N N.Cp.dT
? ?
? ?
363.15 K
35
N N.Cp.dT
0.00 35009.61369158
1.23 4439.733637874
39449.347
39449.347
1825.70094952626 N O2 + 1734.1629409247 N N2 +
1825.701 N O2 + 6523.756 N O2 +
14609.029 N O2
63309.590
T steam = 220 C
P steam =
Keluar Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg)
33 14650.1312 2799.9 943.7
N N.Cp.dT
0.77609303521107 4355.784347682
2.91958808484163 15076.25620983
15076.256
T CW in = 30 C 303.15
T CW out = 49 C 323.15
luar Q Cp
36 200665.144229789 1094.5901651511
N.Cp.dT
0.25262001983486 Q = N.Cp.dT
925.236347386016 N = Q/(Cp.dT)
925.48896740585 N = 183.32445386269 kmol/jam
F Cw = 3299.8401695284 kg/jam
144229789 F Cw = 3.2998401695284 ton/jam
201590.633197195
T steam = 55 C 328.15
P steam =
40 3.7102 2601 230.2 2370.8
N.Cp.dT
3.9055934000249
3.47071231830156
7.37630571832646
suhu steam = 55 C

44 9.7330 2601 230.2 2370.8
N.Cp.dT
3.0288616704041
16.4447298314238
19.4735915018279
Keluar
38 39
mCpdT Cp (kJ/kg) N mCpdT
0 0.29357994453844 0
Err:509 Err:509 0.0828045997416 Err:509
Err:509 Err:509
Err:509 Err:509
Keluar
42 43
mCpdT Cp (kJ/kg) m (kg) mCpdT
Err:508 0.2112600000912 Err:508
Err:509 Err:509 0.3923400001693 Err:509
Err:509 Err:508
Err:509 Err:508
Q (J/jam)
3.905593400025
3.470712318302
7.376305718326
N (mol) Q (J/jam)
? ?
? ?
? ?
N (mol) Q (J/jam)
0.0000 10.772188828
0.0000 0
0.0000 0.007290441
0.0000 0
0.0000 6.6163939499
0.0000 0.0229714182
0.0000 0.0034377671
0.0000 0.0144910245
0.0126 6.3097268298
? ?
? ?
23.746500259
+ 1093.8531175 N O2 + 36.8478568429 N O2
T steam = 75 C 348.15
P steam = kPa
Q (kj/jam) Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
31993.401 51252.32 2635.4 313.9 2321.5
0.000
2.26836
0.00000
19650.690
68.22511
1.01889
4.32458
1883.29553
53603.2233
51252.32
Q (kj/jam)
3199.340081969
0
2.268361545155
0
0.389920892117
17864.26366477
1.500952468142
3.786141469822
2810.512530886
23882.062
T CW in = 30 C 303.15
T CW out = 49 C 323.15
Q (kj/jam) Q Cp.dT N
1066.44669399 15919.4589 1505.53371261
0
0.721753660325 Q = N.Cp.dT
0 N = Q/(Cp.dT)
0.12935021016 N = 10.5739637565 kmol/jam
5954.754554922 F Cw = 190.331347616 kg/jam
0.500317489381 F Cw = 0.19033134762 ton/jam
1.255810514264
938.794261986
7962.6027
15919.4589
55
Q (kj/jam)
1077.2178
0.0000
0.7290
0.0000
0.1307
6014.8976
0.5054
1.2685
948.2761
8043.025
8043.025
27213.296 + 934.425048922676 N O2 + 912.046648863
27213.296 + 934.425 N O2 + 3431.033
443.15 K
atm
λs (Kj/kg) m (kg/jam) m (ton/jam)
2047.9 20.266 0.020
K
K
K
m (kg/jam) m (ton/jam)
1181.6220 1.1816220253
K
K
m (kg/jam) m (ton/jam)
1222.5534 1.2226
22
N.Cp.dT
27774.66914444
722.556602625
82413.09379049
110910.3195376
4264472.044393
K
m (kg/jam)
13.151232
Keluar
27
N.Cp.dT
27774.66914444
722.556602625
649114.7412426
32564.76151852
710176.7285082
710176.7285082
m (kg/jam)
228.182152
m (kg/jam)
639.609055
31
N.Cp.dT
27774.66914444
44752.3085946
72526.97773904
2298677.4
39449.34732945 + 1403.11281961752 N O2 + 1290.95747172
39449.347 + 1403.113 N O2 + 4856.459
493.15 K
λs (Kj/kg) m (kg/jam) m (ton/jam)

1856.2 7.893 0.008
K
K
K
m (kg/jam)
0.001565
m (kg/jam)
0.004105
+ 136.7150671 N O2
K
atm
m (kg) (ton/jam)
22.077 0.022077243
K
K
Ball Mill (BM-101)
Tref = 25 C
T56 = 35 C
T57 = 35 C
Komponen A B
Selulosa
MCA
CMC
Na-Glikolat
H2O 51.234 0.013088
NaOH 0 0
NaCl 0 0
N N2
N O2
N N2
N O2
298.15 K
308.15 K
308.15 K
56 57
C D Komponen
Cp (kj/kg) m (kg) Q (kj/jam) Cp (kj/kg) m (kg) Q (kj/jam)
2080.4 0.00052 1.0772178 ### 0.00052 1.0772178 Selulosa
1.2571256 0.00058 0.000729 1.25713 0.00058 0.000729 MCA
0.5734851 0.00023 0.0001307 0.57349 0.00023 0.0001307 NaOH
2904.1 0.00207 6.0148976 ### 0.00207 6.0148976 CMC
2.336E-05 1.1091 0.00046 0.0005054 1.10910 0.00046 0.0005054 NaGlikolat
0 0.5020096 0.00253 0.0012685 0.50201 0.00253 0.0012685 NaCl
0.7544608 1.25689 0.9482761 0.75446 1.25689 0.9482761 H2O_x000D_
8.043025 8.043025
Masuk Keluar
56 57
1.07722 1.07722
0.00073 0.00073
0.00127 0.00127
0.00013 0.00013
6.01490 6.01490
0.94828 0.94828
0.00051 0.00051
8.043 8.043
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW)
E-103 H1 150 80 0 0 70 0.000000000
E-109 H2 90 35 0 0 55 0.000000000
E-113 H3 55 35 0 0 20 0.000000000
E-115 H4 60 35 -161564.933 -44.8791479 25 -1.795165918
E-101 C1 100 150 -50944.6092 -14.1512803 50 -0.283025606
E-102 C2 30 150 2419843.75 672.178818 120 5.601490152
E-104 C3 30 80 2759180.87 766.43913 50 15.328782594
E-105 C4 30 80 29681.0149 8.24472635 50 0.164894527
E-106 C5 30 80 514984.299 143.051194 50 2.861023882
E-107 C6 30 80 1443533.68 400.981577 50 8.019631540
E-108 C7 30 200 14650.1312 4.06948088 170 0.023938123
E-110 C8 30 35 3.71022118 0.00103062 5 0.000206123
E-111 C9 30 35 9.73301488 0.00270362 5 0.000540723
E-112 C10 35 55 51252.3198 14.2367555 20 0.711837775
E-114 C11 30 150 41501.8383 11.5282884 120 0.096069070
H1 H2 H3
200 50 200-150
150 10 150-140
140 40 140-100 0
100 20 100-80 0
80 10 80-70 0 0
70 15 70-55 0
55 5 55-50 0
50 5 50-45 0
45 10 45-35 0 0
35 5 35-30 0 0
30 5 30-25 0 0
25 5 25-20
20 20 20-0
T QH initial Pass Final pass

QH=0 Qh min
200 0 273.120493
-1.196906
150 -1.19690614 271.923587
-54.38472
140 -55.5816235 217.53887
-217.5389
100 -273.120493 0
-114.4299
80 -387.55044 -114.429947
-320.9583
70 -708.508739 -435.388246
-481.4374
55 -1189.94619 -916.825694
-164.0383
50 -1353.98453 -1080.86403
-173.0142
45 -1526.99869 -1253.8782
-346.0283
35 -1873.02703 -1599.90654
-169.4587
30 -2042.48574 -1769.36525
-8.97583
25 -2051.46157 -1778.34108
-8.97583
20 -2060.4374 -1787.31691
Qc
H1 150
H2 90
H3 55
H4 60
-14.15128 kW 0
100
C1 150
280.07451 kW
C2 150
C3 80
273.12049
C4 80
C5 80
C6 80
2.3938123 kW
C7 200
C8 35
C9 35
C10 55
4.8034535 Kw
C11 150
Beban Heater = 273.1204931

Stream Ts Tt Tadj adjusted T
Ts Tt
ceklis H1 150 80 10 140 70
ceklis H2 90 35 10 80 25
ceklis H3 55 35 10 45 25
ceklis H4 60 30 10 50 20
ceklis C1 100 150 100 150
ceklis C2 30 150 30 150
ceklis C3 30 80 30 80
ceklis C4 30 80 30 80
ceklis C5 30 80 30 80
ceklis C6 30 80 30 80
ceklis C7 30 200 30 200
ceklis C8 30 35 30 35
ceklis C9 30 35 30 35
ceklis C10 35 55 35 55
ceklis C11 30 150 30 150
H4 C1 C2 C3 C4 C5 C6 C7
0.0239381
-0.283026 5.6014902 0.0239381
-0.283026 5.6014902 0.0239381
5.6014902 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166 5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166 5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166 5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166
-1.795166
QH min = 273.12049
Qc min = -1787.317
T pinch hot = 110 C
T pinch cold = 100 C
C Q
110 0 0 0
110 0
110 0
110 -1.795165917595
kW
C
100 -0.283025606392 -14.15128
100 5.601490151787 280.07451

100 15.32878259435
100 0.164894526948
100 2.8610238815941
100 8.0196315400239
100 0.023938122848 2.3938123
100 0.000206123399
100 0.000540723049
100 0.711837774873
100 0.09606907006 4.8034535

C8 C9 C10 C11 delta H sigma C
-0.023938 -1.196906142419
0.0960691 -5.438472 -54.38471738303
0.0960691 -5.438472 -217.5388695321
0.0960691 -5.721497 -114.4299468939
0.0960691 -32.09583 -320.9582988761
0.0960691 -32.09583 -481.4374483142
0.7118378 0.0960691 -32.80767 -164.0383383124
0.7118378 0.0960691 -34.60283 -173.0141679004
0.7118378 0.0960691 -34.60283 -346.0283358008
0.000206 0.000541 0.0960691 -33.89174 -169.4587132583
-1.795166 -8.975829587976
-1.795166 -8.975829587976
Ch > Cc
6.7248349 kW
#DIV/0! C
110
H
E
1.675669 kW
#DIV/0!
110
90
110
55
110
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
766.4391297 kW
C #DIV/0! C
14.236755 kW
#DIV/0! C
8.244726 kW 143.05119408 kW
64.592737789 C 144.27963
Beban Cooler = #DIV/0!
400.981577 kW
#DIV/0! C
392.10431 kW
#DIV/0! C
0.0010306 kW
C 144.28020472 C
C
80 0
#DIV/0! kW
35 0
#DIV/0! kW
35 0
0.0027036 Kw
144.28171 C
30 -1.7951659176
-205.1546 kW
100 -0.28302560639
30 5.601490151787
30 15.32878259435
30 0.1648945
30 2.861023881594
30 8.019631540024
30 0.023938122848
30 0.000206
30 0.000541
35 0.711837774873
30 0.09606907006
Q
-53.8549775
392.1043106
766.4391297
8.244726
143.0511941
400.981577
1.675668599
0.001030617
0.002703615
14.2367555
6.724834904
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW)
E-103 H1 150 80 0 0 70 0.000000000
E-109 H2 90 35 0 0 55 0.000000000
E-113 H3 55 35 0 0 20 0.000000000
E-115 H4 60 35 -161564.933 -44.8791479 25 -1.795165918
E-101 C1 100 150 -50944.6092 -14.1512803 50 -0.283025606
E-102 C2 30 150 2419843.75 672.178818 120 5.601490152
E-104 C3 30 80 2759180.87 766.43913 50 15.328782594
E-105 C4 30 80 29681.0149 8.24472635 50 0.164894527
E-106 C5 30 80 514984.299 143.051194 50 2.861023882
E-107 C6 30 80 1443533.68 400.981577 50 8.019631540
E-108 C7 30 200 14650.1312 4.06948088 170 0.023938123
E-110 C8 30 35 3.71022118 0.00103062 5 0.000206123
E-111 C9 30 35 9.73301488 0.00270362 5 0.000540723
E-112 C10 35 55 51252.3198 14.2367555 20 0.711837775
E-114 C11 30 150 41501.8383 11.5282884 120 0.096069070
H1 H2 H3
200 50 200-150
150 10 150-140
140 5 140-135
135 35 135-100 0
100 20 100-80 0
80 5 80-70 0
75 5 75-70 0 0
70 5 70-65 0 0
65 10 65-55 0
55 5 55-50 0
50 5 50-45 0
45 5 45-40 0
40 5 40-35 0 0
35 5 35-30 0 0
30 5 30-25 0 0
25 5 25-20 0 0
20 5 20-15
15 15 15-0
T QH initial Pass Final pass

QH=0 Qh min
200 0 273.120493
-1.196906
150 -1.19690614 271.923587
-54.38472
140 -55.5816235 217.53887
-27.19236
135 -82.7739822 190.346511
-190.3465
100 -273.120493 0
-114.4299
80 -387.55044 -114.429947
-160.4791
75 -548.029589 -274.909096
-160.4791
70 -708.508739 -435.388246
-160.4791
65 -868.987888 -595.867395
-320.9583
55 -1189.94619 -916.825694
-164.0383
50 -1353.98453 -1080.86403
-164.0383
45 -1518.02286 -1244.90237
-173.0142
40 -1691.03703 -1417.91654
-173.0142
35 -1864.0512 -1590.93071
-169.4587
30 -2033.50991 -1760.38942
-8.97583
25 -2042.48574 -1769.36525
-8.97583
20 -2051.46157 -1778.34108
-8.97583
15 -2060.4374 -1787.31691
Qc
H1 150
H2 90
H3 55
H4 60
-14.15128 kW 0
100
C1 150
280.07451 kW
C2 150
C3 80
273.12049
C4 80
C5 80
C6 80
2.3938123 kW
C7 200
C8 35
C9 35
C10 55
4.8034535 Kw
C11 150
Beban Heater = 273.1204931

Stream Ts Tt Tadj adjusted T
Ts Tt
ceklis H1 150 80 15 135 65
ceklis H2 90 35 15 75 20
ceklis H3 55 35 15 40 20
ceklis H4 60 30 15 45 15
ceklis C1 100 150 100 150
ceklis C2 30 150 30 150
ceklis C3 30 80 30 80
ceklis C4 30 80 30 80
ceklis C5 30 80 30 80
ceklis C6 30 80 30 80
ceklis C7 30 200 30 200
ceklis C8 30 35 30 35
ceklis C9 30 35 30 35
ceklis C10 35 55 35 55
ceklis C11 30 150 30 150
H4 C1 C2 C3 C4 C5 C6 C7
0.0239381
-0.283026 5.6014902 0.0239381
-0.283026 5.6014902 0.0239381
-0.283026 5.6014902 0.0239381
5.6014902 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166 5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166 5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166 5.6014902 15.328783 0.16489453 2.8610238815941 8.0196315 0.0239381
-1.795166
-1.795166
-1.795166
QH min = 273.12049
Qc min = -1787.317
T pinch hot = 115 C

T pinch cold = 100 C
C Q
115 0 0 0
115 0
115 0
115 -1.795165917595
kW
C
100 -0.283025606392 -14.15128
100 5.601490151787 280.07451
100 15.32878259435
100 0.164894526948
100 2.8610238815941
100 8.0196315400239
100 0.023938122848 2.3938123
100 0.000206123399
100 0.000540723049
100 0.711837774873
100 0.09606907006 4.8034535
C8 C9 C10 C11 delta H sigma C
-0.023938 -1.196906142419
0.0960691 -5.438472 -54.38471738303
0.0960691 -5.438472 -27.19235869151
0.0960691 -5.438472 -190.3465108406
0.0960691 -5.721497 -114.4299468939
0.0960691 -32.09583 -160.4791494381
0.0960691 -32.09583 -160.4791494381
0.0960691 -32.09583 -160.4791494381
0.0960691 -32.09583 -320.9582988761
0.7118378 0.0960691 -32.80767 -164.0383383124
0.7118378 0.0960691 -32.80767 -164.0383383124
0.7118378 0.0960691 -34.60283 -173.0141679004
0.7118378 0.0960691 -34.60283 -173.0141679004
0.000206 0.000541 0.0960691 -33.89174 -169.4587132583
-1.795166 -8.975829587976
-1.795166 -8.975829587976
-1.795166 -8.975829587976
Ch > Cc
6.7248349 kW
#DIV/0! C
115
H
E
1.675669 kW
#DIV/0!
115
90
115
55
115
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
766.4391297 kW
C #DIV/0! C
14.236755 kW
#DIV/0! C
8.244726 kW 143.05119408 kW
64.592737789 C 144.27963
Beban Cooler = #DIV/0!
400.981577 kW
#DIV/0! C
392.10431 kW
#DIV/0! C
0.0010306 kW
C 144.28020472 C
C
80 0
#DIV/0! kW
35 0
#DIV/0! kW
35 0
0.0027036 Kw
144.28171 C
30 -1.7951659176
-205.1546 kW
100 -0.28302560639
30 5.601490151787
30 15.32878259435
30 0.1648945
30 2.861023881594
30 8.019631540024
30 0.023938122848
30 0.000206
30 0.000541
35 0.711837774873
30 0.09606907006
Q
0
-53.8549775
392.1043106
766.4391297
8.244726
143.0511941
400.981577
1.675668599
0.001030617
0.002703615
14.2367555
6.724834904
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW/C)
E-103 H1 150 80 0 0.00000 70 0.000000
E-109 H2 90 35 0 0.00000 55 0.000000
E-113 H3 55 35 0 0.00000 20 0.000000
E-115 H4 60 35 -161565 -44.87915 25 -1.795166
E-101 C1 100 150 50944.61 14.15128 50 0.283026
E-102 C2 30 150 2419844 ### 120 5.601490
E-104 C3 30 80 2759181 ### 50 15.328783
E-105 C4 30 80 ### 8.24473 50 0.164895
E-106 C5 30 80 514984.3 ### 50 2.861024
E-107 C6 30 80 1443534 ### 50 8.019632
E-108 C7 30 200 14650.13 4.06948 170 0.023938
E-110 C8 30 35 3.71022 0.00103 5 0.000206
E-111 C9 30 35 9.73301 0.00270 5 0.000541
E-112 C10 35 55 51252.32 14.23676 20 0.711838
E-114 C11 30 150 41501.84 11.52829 120 0.096069
Hot Stream
Interval Tstart Tend ΔT H1 H2 H3 H4 sum C ΔH (kW)
1 150 90 60 0.000000 0 0
2 90 80 10 0.000000 0.000000 0 0
3 80 60 20 0.000000 0 0
4 60 55 5 0.000000 -1.795166 -1.795166 -8.97583
5 55 35 20 0.000000 0.000000 -1.795166 -1.795166 -35.90332
Cold Stream
Interval Tstart Tend ΔT C1 C2 C3 C4 C5 C6
1 200 150 50
2 150 100 50 0.283026 5.601490
3 100 80 20 5.601490
4 80 55 25 5.601490 ### 0.164895 2.861024 8.019632
5 55 35 20 5.601490 ### 0.164895 2.861024 8.019632
6 35 30 5 5.601490 ### 0.164895 2.861024 8.019632
Hot Cold 250

T ΔH T ΔH
150 0 200 0
200
90 0 150 1.196906
80 0 100 301.4231
60 0 80 415.853 150
55 -8.97583 55 1218.249
35 -44.87915 35 1874.402
100
30 2034.885
50
0
-500 0 500 1000 1500
100
50
0
-500 0 500 1000 1500
Hot Cold
T ΔH T ΔH Penentuan Pinch
150 23.3 200 0 250
90 23.3 150 1.196906
80 23.3 100 301.4231 200
60 23.3 80 415.853
55 14.32417 55 1218.249 150
Suhu (C)
35 -21.57915 35 1874.402
30 2034.885 100
Tpinch hot = 100 C 50

Tpinch cold = 100 C 301.4231 kW
0
-500 0 500 1000 1500 2
Entalpi (ΔH)
Hot Cold
T ΔH T ΔH T ΔH T ΔH
150 26.26 200 0 110 0 200 301.423054
250
90 26.26 150 1.196906 110 1.196906 150 301.423054
80 26.26 100 301.4231 110 301.4231 100 301.423054
200
60 26.26 80 415.853 110 415.853 80 301.423054
55 17.28417 55 1218.249 110 1218.249 55 301.423054
150
35 -18.61915 35 1874.402 110 1874.402 35 301.423054
Suhu (C) f(x) = − 0.0
30 2034.885 110 2034.885 30 301.423054
100
Qhmin = 26.26 kW f(x) = 1.336
Qcmin = -2053.504 kW 50
Tpinch hot = 110 C
Tpinch cold = 100 C 0
-500 0
Hot
Linear (Cold)
Hot Cold
T ΔH T ΔH T ΔH T ΔH
150 27.764 200 0 115 0 200 301.423054 250
90 27.764 150 1.196906 115 1.196906 150 301.423054
80 27.764 100 301.4231 115 301.4231 100 301.423054 200
150
Suhu (C)
f(x) = − 0.06
100
f(x) = 1.3369
250
200
60 27.764 80 415.853 115 415.853 80 301.423054
55 18.78817 55 1218.249 115 1218.249 55 301.423054 150
Suhu (C)
f(x) = − 0.06
35 -17.11515 35 1874.402 115 1874.402 35 301.423054
100
30 2034.885 115 2034.885 30 301.423054 f(x) = 1.3369
50
Qhmin = 27.764 kW
Qcmin = -2052 kW 0
-500 0 50
Tpinch hot = 115 C
Tpinch cold = 100 C
Hot
Linear (Cold)
C7 C8 C9 C10 C11 sum C ΔH (kW)
0.023938 0.023938 1.196906
0.023938 0.096069 6.004523 300.2261
0.023938 0.096069 5.721497 114.4299
0.023938 0.096069 ### 802.3957
0.023938 0.711838 0.096069 ### 656.1534
0.023938 0.000206 0.000541 0.096069 ### 160.4829
1000 1500 2000 2500

1000 1500 2000 2500
enentuan Pinch
Hot
Cold
1000 1500 2000 2500

Entalpi (ΔH)
ΔTmin = 10
x pada 100C = 301.4231
250
y pada pinch -768.5756
200
150
f(x) = − 0.0631884606450732 x + 145.628613800973
100
f(x) = 1.3369237776166 x + 55.2257149331214
50
0
-500 0 500 1000 1500 2000 2500
Entalpi (kW)
Hot Linear (Hot) Cold

Linear (Cold) delta Tmin = 10 pinch
ΔTmin = 15
250
x pada 100C = 301.4231
200 y pada pinch -763.5656
150
f(x) = − 0.0631884606450732 x + 145.628613800973
100
f(x) = 1.3369237776166 x + 53.214981571586
ΔTmin = 15
250
200
150
f(x) = − 0.0631884606450732 x + 145.628613800973
100
f(x) = 1.3369237776166 x + 53.214981571586
50
0
500 0 500 1000 1500 2000 2500
Entalpi (kW)
Hot Linear (Hot) Cold

Linear (Cold) delta T min 15 pinch
1 2 3 4 5 6
Selulosa 413.9337 413.93368421 20.69668 393.237 393.237
Hemiselulosa 206.9668 206.96684211 10.34834 196.6185 196.6185
Lignin 206.9668 206.96684211 10.34834 196.6185 196.6185
MCA
NaOH
CMC
Na-Glikolat
NaCl
H2O 1179.711
H2O2
Udara
Total 827.8674 827.86736842 41.39337 786.474 786.474 1179.711
Suhu (K)
Tekanan (bar)
Laju Panas (kj/jam) 5362.59 5362.5904369 268.1295 5094.461 5094.461 4366976
0 #DIV/0!
0 0
0 0 0 0
0 0 0 0
0 0 0
0 0 0 0
0 0 0
F (kg)
0 0.0000
0 0.0000
0 0.0000
0 0.0000
0 0.0000
26.206 0.0000
26.206 0.00
#DIV/0!
0 0 0.35
#DIV/0! #DIV/0!
#DIV/0! 0
#DIV/0! 0 0
#DIV/0! 0
#DIV/0!
#DIV/0!
#DIV/0! 0
#DIV/0! 0
#DIV/0! 0
#DIV/0! 26.206
#DIV/0! 0 26.206
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.000
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
0.000 0
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.000
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
0 0
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.000
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
0 0
0.00
#DIV/0!
#DIV/0! 0
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0! #DIV/0!

#DIV/0! 0 #DIV/0! 0.0000 #DIV/0! 0.000
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
0 0 #DIV/0! 0.0000 #DIV/0! 0.000
0 0.0000
7 8 9 10 11 12 13 14 15 16
393.237 393.237 393.237 393.237
196.6185 196.6185 196.6185 196.6185
196.6185 196.6185 196.6185 196.6185
1101.357 1101.064 1101.064 1101.064 1101.0636
1572.948 314.5896 1258.358 314.5896 1101.064 3303.191 4404.254 4404.254 4718.844
2359.422 1101.064 1258.358 1101.064 1101.357 2202.127 3303.191 5505.318 5505.318 6606.3816
3499288 208261.4 3367367 259206 Err:509 30974.59 69272.75 100247.3 2520091 ###
26.206
0 0
0 26.206
26.206
0
26.206
0 0
0 #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.00
0.000
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
17 18 19 20 21 22 23 24 25 26
393.237 393.237 393.237
196.6185 196.6185 196.6185
196.6185 196.6185 9.830925 186.7876
1101.064 1101.064 1101.064
4718.844 4718.844 13212.76 13212.76 358.6321 17572.98 2466.082 2466.082

228.51 228.51
6606.382 6606.382 13212.76 13212.76 761.7001 19057.44 228.51 228.51 2466.082 2466.082
2779297 1228200 277091 3036272 4153562 110910.3 2883.747 32564.76 51717.35 566701.6
0
27 28 29 30 31 32 33 34 35 36
393.237 393.237 419.4132 419.4132
9.830925 9.830925
2824.714 6912.584 6912.584 9542.552 194.746 173 22 22

228.51 228.51
40.87423 40.87423 40.87423
3456.292 6912.584 6912.584 9780.893 587.983 40.87423 40.87423 213.5458 441.4876 441.4876
710176.7 144967 1588501 2226150 72526.98 426.125 15076.26 #NAME? #NAME? 201590.6
37 38 39 40 41 42 43 44 45 46
0.000513
0.21126 0.29358 0.29358 0.000574

0.29358 0.005282 0.005282
0.000451
0.00205
0.002502
0.21126 0.18108 0.08 0.08 0.002965 0.079839 0.021797 0.021797 1.244325
883.7822
0.42252 0.18108 0.376385 0.376385 0.296545 0.079839 0.027078 0.027078 883.7822 1.250415
Err:509 Err:509 3.666085 7.376306 Err:509 Err:508 9.740577 19.47359 -2785.289 2350.904
47 48 49 50 51 52 53 54 55 56
5.178E-06 0.000513 0.000513 0.000513 0.008388 0.830438 0.000084 0.00830 83.88 83.88
5.799E-06 0.000574 0.000574 0.000574 5.48E-06 0.000543 0.000000 0.00000 0.05 0.05
4.557E-06 0.000451 0.000451 0.000451 4.465E-06 0.000442 0.000000 0.00000 0.04 0.04
2.071E-05 0.00205 0.00205 0.00205 0.050122 4.962125 0.000000 0.00000 501.22 501.22
2.527E-05 0.002502 0.002502 0.002502 1.478E-05 0.001463 0.000501 0.04962 0.15 0.15
0.012569 1.244325 1.244325 1.244325 -268.2438 0 0.000000 0.00000 22.62 22.62
883.7822 883.7822
883.7948 1.250415 1.250415 1.250415 615.5969 5.795011 0.000585 0.057931 607.9781 607.9781
-7049.692 0 #NAME? 0 #NAME? #NAME? #NAME? #NAME? #NAME? 8.043025

57 58 59 60 61
0 83.88 83.88
0 0.05 0.05
0 0.04 0.04
0 501.22 501.22
0 0.15 0.15
22.17158 0.45 0.45
1215.956 1215.956 1215.956

1215.956 1215.956 1238.128 585.8065 585.8065
1718.359 33968.93 7893.784 27213.3 186463

NME-Laporan 2 - Kelompok 25 - MR CP Polimer 2 Reaksi

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NME-Laporan 2 - Kelompok 25 - MR CP Polimer 2 Reaksi

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A.

Perhitungan Cp Menggunakan Metode Estimasi

Unsur Δe (J/moloK)_x000D_ (Perry, 1999)

CpSelulosa =_x000D_ 208040 J/mol.K 1284.1975 J/kg.K CpNa-CMC =_x000D_

CpHemiselulosa =_x000D_ 29506.75 J/mol.K 1277.3485 J/kg.K CpNa-MCA =_x000D_

CpNa-CMC =_x000D_ 290410 J/mol.K 1200.0413 J/kg.K CpSelulosa =_x000D_

CpNa-MCA =_x000D_ 61.59 J/molK 733.21429 J/kg.K

200480 J/mol.K 1089.5652 J/kg.K

Gas Cp = A+BT+CT2+DT3+ET4_x000D_ (Yaws)

2. Asam Monokloroasetat (MCA) C2H3ClO2_x000D_ 3. H2O2_x000D_

Kapasitas Perancangan Pabrik CMC

26. Rotary Reactor (R-101)

Data aliran 36 F36 =_x000D_ 441.4876 kg/jam

Komponen Mr (kg/kmol) w F (kg/jam) X mol

27. Heater (E-204)

28. Aging vessel (V-103)

29. Cooler (E-205)

30. Cyclone (CY-301)

31. Cyclone (CY-302)

32. Silo (TK-107)

33. Rotary Dryer (RD-301)

34. Heater (E-301)

36. Cooler (E-302)

33. Ball mill (BM-301)

37. Product Tank (TK-108)

1. Roll crusher (RC-101)

2. Vibrating screen (VS-101)

4. Steam Explosion Tank (V-101)

5. Flash Tank (V-102)

9. Delignification Tank (DT-101)

10. Expansion Valve (EV-101)

12. Heater (E-104)

13. Rotary Filter (RF-101)

14. Heater (E-105)

15. Heater (E-106)

16. Bleaching Tank (BT-101)

17. Heater (E-107)

18. Rotary Filter (RF-102)

19. Rotary RD (RD-101)

20. Heater (E-108)

21. Cooler (E-201)

22. Mixer (M-201)

23. Heater (E-202)

24. Mixer (M-202)

25. Heater (E-203)

→ (C8H11O7Na) + NaCl + 2H2O

F (kg/jam) mol F (kg/jam) mol

Fungsi : Meningkatkan suhu keluaran dari rotary reactor

Fungsi : Pematangan produk

Keluar Fungsi : Memisahkan produk dari udara

Keluar Fungsi : Memisahkan produk dari udara

N50 N52 N54 N55

N Fungsi : Mengurangi kadar air

Fungsi : Mencacah Bagasse menjadi 2 mm

Keluar Fungsi : Untuk Screening bagasse yang memenuhi ukuran

Fungsi : Untuk menyimpan bagasse sementara

Fungsi : Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)

Masuk Keluar Fungsi : Untuk memecahkan ikatan lignin

Fungsi : Untuk menurunkan tekanan keluaran dari tangki delignifikasi (DT-101)

Masuk Keluar Fungsi : Untuk memisahkan selulosa dari

Masuk Keluar Fungsi : Untuk memisahkan selulosa dari

Masuk Keluar Fungsi : Untuk mengurangi kadar air

Fungsi : Untuk meningkatkan suhu udara pengering