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Sample Problem
If 3.5 L of gas was collected at 2.5 atm, what will be its volume if the pressure was
changed to 1520 torr?
Problem 1.
At 409.5 K a sample of gas has a volume of 34.5 cm3. If the pressure remains
constant, what will be the volume of the same sample of gas at 200C?
Righ Wr
Steps t ong Explanation
P1V1 = P2V2 The formula is inappropriate
for the case because it states
that pressure remains constant,
hence Charles' Law should be
Yes
employed instead:
V1 V2
=
T1 T2
Problem 2
C, what would be the pressure of the gas in torr if the volume remains constant?
Righ Wr
Steps t ong Explanation
P1 = P2 The issue is related to Gay-
T1 T2 Yes Law, Lussac's which states that
the volume is constant.
P1 = 1330 mmHg
T1 = 45 0C
P2 = n
T2 = 90 0C
T2 = 900 C
= 900 C + 273
= 363 K
P2 = P1T2 Although the solution and
T1 answer in mmHg are valid, the
challenge is asking for the
P2 = 1330 mmHg(363 K)
value of the ultimate pressure in
318 K Yes
torr. The solution does not
= 1518.208 mmHg include any conversions.
1518.208 torr is the correct
answer.
Problem 3
P2 = P1V1T2
T1V2
Because the original
P2 = P1V1T2 temperature should be
T1V2 transformed into Kelvin first,
= 2.5 atm(10L) (273K) the solution is erroneous. The
400C (30L) proper response would be:
Yes T 1=40 ℃+273=313 K
= 5.688 atm P1 V 1 T 2
P2=
T1 V 2
( 2.5 atm ) ( 10 L ) ( 273 K )
P2=
( 313 K )( 30 L )
P2=0.727 atm
Problem 4
Six hundred mL of helium under a pressure of 700 torr are placed in a container
under a pressure of 800 mmHg. The temperature remains constant at 273 K.
Would there be a change in volume? If yes, what would be the new volume in
liters?
Righ Wr
Steps t ong Explanation
P1V1 = P2V2 Yes Because the problem states that
temperature is constant, the
formula provided is
appropriate. Boyle's Law fully
matches the situation.
Volume in L = 1,000 mL
= 525 mL
1000 mL
= .525L