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2. What is the frequency of the photon emitted when an electron in an n = 2 orbit drops
to an n = 1 orbit?
3. An electron typically spends about 108 s in an excited state before it drops to a lower
state by emitting a photon. How many revolutions does an electron in an n = 2 Bohr
orbit make in 1.00 x 108 s?
4. What is the shortest wavelength present in the Brackett series of spectral lines?
5. What is the shortest wavelength present in the Paschen series of spectral lines?
7. How much energy is required to remove an electron in the n = 2 state from a hydrogen
atom?
8. Find the wavelength of the spectral line that corresponds to a transition in hydrogen
from the n = 10 state to the ground state. In what part of the spectrum is this?
12. If an electron is in 4d level for hydrogen, calculate the magnitude of orbital angular
momentum along with its possible angular momentum and along with its possible z-
components?
13. For a d state-electron, obtain the values of L, S, and J.
16. Jika medan magnet diberikan pada arah sumbu-z, maka Sz adalah …
a) (mz + 1)
b) mz
c) mz/
d) mz2
17. The energy needed to detach the electron from a hydrogen atom is 13.6 eV, but the
energy needed to detach an electron from a hydrogen molecule is 15.7 eV. Why do you
think the latter energy is greater?
18. Consider the hydrogen molecule H2 as a rigid rotor with distance of separation
of H-atoms r = 1.0 A˚. Compute the energy of J = 2 rotational level.
19. The carbon monoxide (CO) molecule has a bond length R of 0.113 nm and the masses
of the 12C and 16O atoms are respectively 1.99 x 10-26 kg and 2.66 x 10-26 kg.
Find :
(a) the energy
(b) the angular velocity of the CO molecule when it is in its lowest rotational state.
20. When CO is dissolved in liquid carbon tetrachloride, infrared radiation of frequency
6.42 x 1013 Hz is absorbed. Carbon tetrachloride by itself is transparent at this
frequency, so the absorption must be due to the CO.
(a) What is the force constant of the bond in the CO molecule?
(b) What is the spacing between its vibrational energy levels?