0.

316 (pathlength of cuvette is 1 cm)  Thí nghiệm với dung dich mẫu, độ hấp thu của
dung dịch mẫu Am = 0.316
20 mL quinine(aq) is mixed with 10.00 mL of 25 ppm quinine(aq) to obtain 50.0 mL solution
A. Absorbance of solution A at the same conditions is 0.610. Thí nghiệm với dung dịch
mẫu trộn dung dịch chuẩn, nên mình có thể coi dung dịch mẫu có độ hấp thu Am, dung
dịch chuẩn có độ hấp thu Ac. Độ hấp thu có tính cộng nếu chất trong dung dịch mẫu và
chuẩn không tương tác  Am + Ac = 0.610
Report concentration of quinine (ppm and CM)

Am = abCm
Ac = abCc
Thế dữ liệu thí nghiệm vào ta có:
Am = 0.316 = abCm (1)
Am + Ac = 0.610 = abCm + abCc (2)
Lấy (2)-(1) => Ac = 0.610-0.316 = abCc (3)
***Lưu ý: Cm và Cc trong phương trình Lambert-Beer là nồng độ dung dịch đem đi đo độ hấp
thu, mà dung dịch này đã được pha loãng, nên cần chuyển đổi nồng độ dung dịch.
10 mL dd chuẩn 25 ppm pha thành 50 ml dd đo => C c = Cc,ban đầu *10/50 = 5 ppm
Lấy (1) chia (3) vế theo vế => => C m = 5.37 ppm
20 ml dd mẫu ban đầu pha loãng thành 50 ml dd đo => C = C *50/20= 13.43 ppm
Dissolve 0.5 g impure NH4Cl(solid) to obtain 100.0 mL solution A. Add
NaOH(aq) in excess to 20 mL solution A, heat the mixture to remove
NH3. NH3 released is absorbed into 20 mL of 0.2 N HCl(aq). The
excessive HCl(aq) is titrated with 11.00 of 0.2 M NaOH(aq).
Calculate %w/w NH4Cl.
a. Demonstrate that Cu2+ can be titrated by EDTA in the presence of
[CH3COO-] = 0.17 M and pH 9.5.
b. Weigh 0.5234 g sample and dissolve it to 200.0 mL aqueous
solution. Titration of 10 mL of this solution requires 9.30 mL of 0.01
M EDTA. Calculate %CuSO4.5H2O in the solid sample.
Sn2+ is titrated using Fe3+ in acidic solution with [HCl] = 1M.
a. Calculate conditional standard potential (Eo’) of Fe3+/Fe2+ and
Sn4+/Sn2+ and conditional equivalence point potential, knowing Eo for
these two pairs are 0.77 V and 0.15V respectively and:
• Fe3+ is affected by Cl- with β1,1 = 101.45 and β1,2 = 102.1
• Fe2+ is affected by Cl- with β1,1 = 100.4
• Sn2+ is affected by Cl- with β1,1 = 101.51 and β1,2 = 102.24
b. Calculate titration error if potential at the end point (Ef) is 0.33 V
1.8584 g of steel sample containing Cr is dissolved, oxidized to convert
completely Cr into Cr2O72- (solution A). Then, 16 ml of solution of Mohr
salt [(NH4)2Fe(SO4)2.6H2O] is added to solution A and excess of Mohr
salt solution is titrated by 2.7 ml of KMnO4(aq). Knowing that 1.5 ml of
KMnO4(aq) is equivalent to 1 ml of Mohr salt solution with T = 35.28
mg/ml. Calculate percentage of Cr in steel sample.
The concentration of NO2 in air is determined by passing the sample
through a solution of H2O2, which oxidizes NO2 to HNO3, and titrating
the HNO3 with NaOH. What is the concentration of NO2, in mg/L, if a
5.0 L sample of air requires 9.14 mL of 0.01012 M NaOH to reach the
methyl red end point (0.852 mg NO2/L air)
A mixture of HCl and H3PO4 is titrated with 0.1000 M NaOH. The
first end point (methyl red) occurs at 35.00 mL, and the second
end point (bromthymol blue) occurs at a total of 50.00 mL (15.00
mL after the first end point). Calculate the millimoles HCl and
H3PO4 present in the solution. (H3PO4: 1.5 mmol; HCl: 2 mmol)
A 50.00-mL of Fe3+ and Al3+ (aq) is transferred to a 250-mL Erlenmeyer
flask and buffered to a pH of 2. The solution is titrated with 0.05002 M
EDTA, requiring 24.82 mL to reach the end point. The solution is
buffered to a pH of 5 and 50.00 mL of 0.05002 M EDTA is added. The
excess EDTA is back titrated with 0.04109 M Fe3+, requiring 17.84 mL to
reach the end point. Report the molar concentrations of Fe3+ and Al3+ in
the sample. (0.03536 M)
0.3000 g mineral containing Fe2O3 and Al2O3 is dissolved to 250.0 mL
solution A.
Titration of 25 mL of solution A at pH 2 requires 2.5mL of 0.01 M EDTA.
After end point, 20 mL of 0.01 M EDTA is added to the same conical
flask. Heat the mixture and titrate excessive amount of EDTA at pH 5
with 4.9 mL of 0.01 M Zn2+(aq).
Calculate CM of Fe3+, Al3+ in solution A and %w/wFe2O3, Al2O3 in the
mineral sample.
2.0250 g dolomite (CaO, MgO, CO2) is dissolved to 500 mL solution A.
Titration of 25 mL of solution A requires 20.20 mL of 0.1025 M EDTA at
pH 10. Titration of 25 mL of solution A at pH 12.5 requires 9.625 mL of
0.1025 M EDTA.
Report %w/wCaO, MgO.