-

:
:
(C6H12O6)

:

, 2013. e

1. .......................................................................................................2
1.1.

..................................................................3-4

1.2.

...5

2. . ..........................................................6
2.1.

....................................................................................7-8

3. ...........................................................................................9
4. ...........................................................................................10-12
5. ...............................................................................13
5.1.

.......................................................................14

5.2.

.............................................................................15

6. ......................................................................................16
7. ...............................................................................................17
8. ................................................................................................18

, .
,
.
, .

a
.
, ,
.
. .

.
.
,
.

1.1.

pH-
, pH-
5.0-8.0.

, 2
mg, 2 % ,
.
,
2 mg.
.

15 ml,
, ,
.
15 ml, ,
.

,
40 .
.
.

:

, ,
. .

,
.

1.2.

()

1ml
1 ml , 4 ml

4 ml , 20 ml

2 ml

20 ml ()100 ml

10% ,

100 ml

10% 50 ml( )

50 mg
50 mg , 200 mg
200 mg

100 mg

2. .

.
.

, ,
,
( ),
.
, .
,
. ,
.
, .

.


, .

2.1.
pH-
6.0-7.5.

,
, .

,
40 .
.
.

:

, ,
. .

:

,
. , ,
7

. ,
, .

3.
Cn(H2O)n


. .
. ,
.
. :
, , .
,
. ,
. ( )
,
. .
.
.
, , -
.
,
, .
.

4.
.
. :
, , , , , , , .
(+)-(, ).
.
.
,

.
(+)- C6H12O6.
. (II)- .
- .

1.
:

C=O

C
|

[O]

COOH

C
|

CH2OH

CH2OH

10

[O]

2.
g+ ( )

C=

C
|

COO-NH4+

H C
|

+ 2[g(NH3)2]OH

CH2OH

CH2OH

3+H2O+2Ag

3. Felingova reakcija
Oksidacija monosaharida sa Cu2+ jonima

C=O

H
COOK

+ 2 CHO

Cu
CHO

COONa

OH

COOH

C OH

CH2OH

11

+2Cu2O

CH2OH

CHOH


1.
2.
3.
.
. 80%
.( ) ( ) .

.
.

3.9 6.1 mmol ( ).
,
. .
, ,
. .
.

12

5.

13

5.1.
: Glucosi infundibile 5% ( 5% )

:
:
1. NaOH, 0.1 mol/l
2. 0.05 mol/l
100.0 ml 1.27 g , I2, 2,0 g , KI, .
.
3.H2SO4, 0,5 mol/l
1000.0 ml 25 g Na2H2CO3 0.2 g H2CO3
.

4. -,Na2S2O3, 0.1 mol/l

1000.0 ml 25 g Na2S2O3 i o.2 g Na2CO3
.
5. ()
1.0 g 5 ml 100 ml
100 ml .
.
: 100
mg ( 2 ml), 30 ml NaOH 20 ml .
30 . 10 ml H2SO4
Na2S2O3 . 2 ml

. .
:
0.1 mol/l Na2S2O3, , C6H12O6
Na2S2O3
.
1 ml 0.1 mol/l Na2S2O3 9.01 mg C6H12O.
4.75 5.25% e.

14

5.2.

15

6.
:
V(Na2S2O3)=v(Na2S2O3) V(Na2S2O3)
V(Na2S2O3)=19.5cm3
V1(Na2S2O3)=8.5ml
V2(Na2S2O3)=8.4ml

V3(Na2S2O3)=8.4ml

V(Na2S2O3)=
V(Na2S2O3)=19.5-8.43= 11.07ml
1.0ml 0.1mol/l Na2S2O3

9.01mg

C6H12O6

11.07ml o.1 mol/l Na2S2O3 Xmg C6H12O6

x=
x=99.74 mgC6H12O6=0.09974g C6H12O6

W=
W=

*100%

*100%

W=4.98% C6H12O6

16

7.
% Na2S23.
.
.

17

8.
1. II III -
2. - -
3. - ,

18