1.

Chrysanthemic acid
3
HO

2
1

O
4

2.

3.
3.1
3.2
CO2

CHI3

CBr4

CH3COCH2CH3 CH3CH2OH

= 0

CH3COCH2CH3
3.3

HCH HCOH

SCCH121 Homeworks


1.

1-12
HO 1

O
O

8 H

CH3

12

6
O

CH3

H
H O
5

(-)Strychnine

Lovastatin
Blood chloresterol reduction

O
10
O

CH3

CH3

O
CH3

9
OH

OCH3

11
O

Vanillin

2.

CH2

...
CH3
CH3

C
CH3

...

...
3.
CH3

CH2

CH3
CH3

4.

SCCH121 Homeworks

CH

CH3
CH3

CH3

CH2

CH3
B

 ( )
1.
1.1
1.2
1.3

1.4

1.5

1.6

1.8

1.9

CH3
HC

CH2CH2 CH

CH3

1.7

2.
2.1) 2-Bromo-4-methylhexane

2.2) 1-Chloro-2-pentene

2.3) cis-2-Pentene

2.4) 2,5-Dimethyl-3-hexyne

2.5) 4-Bromo-1-methylcyclohexene

2.6) 1,3-Dichloro-2-butene

2.7) 1,1-Dimethylcyclopropane

2.8) 2,2,4-Trimethylhexane

SCCH121 Homeworks

3.
3.1

3.2

3.3

3.4
CH3CH3

CH3C

CCH2CH3

O3 then (CH3)2S

CH3CH2C

3.5

3.6

3.7

3.8

3.9

3.10

3.11

3.12

4.
4.1

4.3

2 HBr

4.2

4.4
CH3

CH3C

CH

CCH3
H

4.5

SCCH121 Homeworks

CH3

CH3
CH3C

4.6

CH3
CHCH3

CH3C

CHCH3


1. C6H14 IUPAC
2. cis trans
2.1
2.2
CH3C

CHCH3

CH3CH

CCH2CH3

CH3

CH3

3.
3.1) 2,3-Dichlorobutane
3.2) 2,4-Dibromo-6-chloroheptane
3.3) 1,1-Dimethylcyclopropane

3.4) 2,3-Dichloro-4-methylpentane

3.5) 2,2-Dibromobutane

3.6) 2,3-Dihydroxypropanal

4.
4.1

4.2

CO2H
H3C

4.3

Br

NH2

H3C

H
CN

4.4
NH2

OH
CH3

HO

4.5

4.6
Cl
H

OH
H3C

CH3
H
Br
CH3

4.7

5.
5.1
CHO
H
OH
Cl
H
CH3

CHO
HO
H
Cl
H
CH3

5.3
H3C

5.2

5.4

C C

Br

SCCH121 Homeworks

NO2
CH3

H3 C

Br

C C

CH3
NO2


1.
1.1
1.2

1.3

1.4

1.6

1.5

2.
2.1) 3-Methyl-1-chlorobenzene
2.2) 4-Nitroaniline

2.3) 3-Chlorophenol

2.4) 4-Nitrotoluene

3.

4.
4.1
4.2

4.3

4.4

4.5

4.6

SCCH121 Homeworks