‫اﻹﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .

‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫اﻟﻌﻼﻤﺔ‬
‫ﻋﻨﺎﺼر اﻹﺠﺎ�ﺔ‪) :‬اﻟﻤوﻀــوع اﻷول(‬
‫ﻤﺠﻤوع‬ ‫ﻤﺠزأة‬
‫اﻟﺘﻤر�ن اﻷول‪ 07) :‬ﻨﻘﺎط(‬
‫‪-I‬‬
‫‪ (1‬إﯿﺠﺎد اﻟﺼ�ﻐﺔ اﻟﻤﺠﻤﻠﺔ ﻟﻠﻤركب ‪:A‬‬

‫‪m‬‬
‫‪0,25‬‬ ‫‪A: Cn H 2n O‬‬
‫‪0,25‬‬ ‫‪M A =d × 29=1,52×29=44,08 g.mol−1‬‬
‫‪01,00‬‬ ‫‪44-16‬‬
‫=‪12n+2n+16=44 ⇒ n‬‬

‫‪co‬‬
‫‪0,25‬‬ ‫‪=2‬‬
‫‪14‬‬
‫‪0,25‬‬ ‫‪A : C2 H 4O‬‬
‫‪ (2‬اﻟﺼ�ﻐﺔ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟﻠﻤركب ‪.A‬‬

‫‪n.‬‬
‫‪O‬‬
‫‪00,50‬‬ ‫‪0,50‬‬ ‫‪A : CH3 C‬‬
‫‪H‬‬

‫‪io‬‬ ‫‪-II‬‬
‫‪ (1‬إﯿﺠﺎد اﻟﺼ�ﻎ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟﻠﻤرك�ﺎت‪ :‬ﻤن ‪ B‬إﻟﻰ اﻟﻤركب ‪N‬‬
‫‪at‬‬
‫‪B CH3 CH‬‬ ‫‪CH3‬‬ ‫‪C CH3 CH CH3‬‬ ‫‪D‬‬ ‫‪CH3 CH‬‬ ‫‪CH3‬‬
‫‪OMgCl‬‬ ‫‪OH‬‬ ‫‪Cl‬‬
‫‪uc‬‬

‫‪O‬‬ ‫‪O‬‬
‫‪E CH3 CH CH3‬‬ ‫‪F CH3 CH C‬‬ ‫‪G CH3 CH C‬‬
‫‪MgCl‬‬ ‫‪CH3‬‬ ‫‪OMgCl‬‬ ‫‪CH3‬‬ ‫‪OH‬‬

‫‪13‬‬ ‫‪O‬‬ ‫‪O‬‬ ‫‪CH3‬‬ ‫‪CH3‬‬

‫‪ed‬‬

‫‪03,25‬‬ ‫‪H CH3 CH C‬‬ ‫‪C‬‬ ‫‪CH CH3‬‬

‫‪x‬‬ ‫‪CH2‬‬ ‫‪CH CH3‬‬
‫‪CH3‬‬ ‫‪Cl‬‬ ‫‪I‬‬ ‫‪J‬‬
‫‪0,25‬‬
‫‪O‬‬ ‫‪O‬‬
‫‪K CH3 C‬‬ ‫‪L CH3 C‬‬
‫‪-‬‬

‫‪OH‬‬ ‫‪Cl‬‬
‫‪cy‬‬

‫‪CH3‬‬ ‫‪CH3‬‬
‫‪M‬‬ ‫‪CH CH2‬‬ ‫‪C CH3‬‬ ‫‪N‬‬ ‫‪CH CH2‬‬ ‫‪CH CH3‬‬
‫‪CH3‬‬ ‫‪O‬‬ ‫‪CH3‬‬ ‫‪OH‬‬
‫‪en‬‬

‫‪00,25‬‬ ‫‪0,25‬‬ ‫‪ (2‬اﻟوﺴ�ط اﻟﻤﺴﺘﻌﻤﻞ ﻓﻲ اﻟﺘﻔﺎﻋﻠﯿن رﻗم ‪ 8‬و ‪AlCl3 :12‬‬

‫ﺼﻔﺤﺔ ‪ 1‬ﻤن ‪14‬‬

 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫‪ (3‬ﻤﻤﺎﻛ�ﺎت اﻟﻀوﺌ�ﺔ ﻟﻠﻤركب ‪ N‬ﺒﺈﺴﻘﺎط ﻓ�ﺸر‪:‬‬

‫‪CH3‬‬ ‫‪CH3‬‬

‫‪2‬‬ ‫‪HO‬‬ ‫‪H‬‬ ‫‪H‬‬ ‫‪OH‬‬

‫‪00,50‬‬ ‫‪x‬‬
‫‪0,25‬‬

‫‪m‬‬
‫‪CH2‬‬ ‫‪CH2‬‬
‫‪CH(CH3)2‬‬ ‫‪CH(CH3)2‬‬

‫‪co‬‬
‫‪ (4‬أ‪ -‬ﻤﻌﺎدﻻت اﻟﺘﻔﺎﻋﻞ اﻟﻤؤد�ﺔ ﻟﻠﻤركب ‪ Q‬و اﻟﺒوﻟ�ﻤﯿر‪:P‬‬
‫‪H2SO4‬‬
‫‪0,50‬‬ ‫‪CH3 CH CH3‬‬ ‫‪CH3 CH CH2‬‬ ‫‪+ H2O‬‬
‫‪170 oC‬‬ ‫‪Q‬‬
‫‪OH‬‬

‫‪n.‬‬
‫‪01,50‬‬ ‫‪0,50‬‬ ‫‪n CH3 CH CH2‬‬ ‫‪CH CH2‬‬
‫‪P‬‬

‫‪io‬‬ ‫‪CH3‬‬
‫‪n‬‬
‫ب‪ -‬ﻤﻘطﻊ ﻤن اﻟﺒوﻟ�ﻤﯿر‪ P‬ﯿﺘﻛون ﻤن ﺜﻼث وﺤدات ﺒﻨﺎﺌ�ﺔ‪:‬‬
‫‪at‬‬
‫‪0,50‬‬ ‫‪.......‬‬ ‫‪CH CH2 CH CH2 CH CH2 .......‬‬

‫‪CH3‬‬ ‫‪CH3‬‬ ‫‪CH3‬‬

‫اﻟﺘﻤر�ن اﻟﺜﺎﻨﻲ‪ 07):‬ﻨﻘﺎط(‬
‫‪uc‬‬

‫ﻣﻼﺣﻈﺔ‪ :‬ﯾﻤﻜﻦ ﻛﺘﺎﺑﺔ ﺛﻨﺎﺋﻲ اﻟﻐﻠﯿﺴﺮﯾﺪ ‪ A‬ﺑﺎﻟﺮﻣﺰ ‪DG‬‬ ‫‪-I‬‬

‫‪ (1‬ﺤﺴﺎب اﻟﻛﺘﻠﺔ اﻟﻤوﻟ�ﺔ ﻟﺜﻨﺎﺌﻲ اﻟﻐﻠ�ﺴر�د ‪:A‬‬
‫‪ed‬‬

‫‪1 mol de A → 2 mol de KOH‬‬

‫‪M A → 2 × 56,1 de KOH ‬‬ ‫‪2 × 56,1‬‬
‫‪00,25‬‬ ‫‪0,25‬‬ ‫= ‪ ⇒ MA‬‬ ‫‪−‬‬
‫‪536 g.mol−1‬‬
‫=‬
‫‪1g → IS ×10‬‬ ‫‪−3‬‬ ‫‪‬‬
‫‪‬‬
‫‪209,3 ×10‬‬ ‫‪3‬‬
‫‪-‬‬

‫‪ (2‬أ‪ -‬ﺤﺴﺎب اﻟﻛﺘﻠﺔ اﻟﻤوﻟ�ﺔ ﻟﻠﺤﻤض اﻟدﻫﻨﻲ اﻟﻤﺸ�ﻊ ‪:B‬‬

‫‪cy‬‬

‫‪n B = n NaOH‬‬
‫‪0,25‬‬ ‫‪n NaOH = C NaOH × VNaOH =0,5 ×10 ×10−3 =5 ×10−3 mol‬‬
‫‪m‬‬ ‫‪m‬‬ ‫‪1‬‬
‫= ‪n B = B ⇒ MB = B‬‬ ‫‪= 200 g.mol−1‬‬
‫‪en‬‬

‫‪0.25‬‬ ‫‪MB‬‬ ‫‪n B 5 ×10‬‬ ‫‪−3‬‬

‫‪01,00‬‬ ‫ب‪ -‬اﺴﺘﻨﺘﺞ اﻟﺼ�ﻐﺔ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟﻠﺤﻤض اﻟدﻫﻨﻲ اﻟﻤﺸ�ﻊ ‪:B‬‬
‫‪CH 3 - ( CH 2 )X - COOH‬‬
‫‪0,25‬‬ ‫‪200 - 60‬‬
‫=‪15 + 14x + 45 = 200 ⇒ x‬‬ ‫‪=10‬‬
‫‪14‬‬
‫‪0,25‬‬ ‫‪CH 3 - ( CH 2 )10 - COOH‬‬

‫ﺼﻔﺤﺔ ‪ 2‬ﻤن ‪14‬‬

 2019 :�‫ ﺑﻜﺎﻟﻮر‬//‫ ﺗﻘﲏ ر�ﺿﻲ‬:(‫اﻟﺸﻌﺐ)ة‬// ‫ اﻟﻄﺮاﺋﻖ‬.‫ ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‬:‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‬

:‫كﻤﺎ ﺘﻘﺒﻞ اﻹﺠﺎ�ﺔ‬

B: Cn H 2n O 2
M B = 12n + 2n + 32 = 200
200 - 32
n= =12 CH 3 - ( CH 2 )10 - COOH
14

m
Cn:2∆9,12 ‫ ﯿرﻤز ﻟﻪ ﺒ ـ ـ‬C ‫( اﻟﺤﻤض اﻟدﻫﻨﻲ‬3
: C ‫ ﻋدد ذرات اﻟﻛر�ون ﻓﻲ اﻟﺤﻤض اﻟدﻫﻨﻲ‬-‫أ‬

co
A + 2 H 2O → Glycérol + B + C
M A = 536 g.mol−1
M Glycérol = (3 ×12) + (8 ×1) + (3 × 16) = 92 g.mol−1

n.
M B = 200 g.mol−1
M A + 2M H= M Glycérol + M B + M C

io MC =
2O

M A + 2M H2O − M Glycérol − M B
M C = 536 + ( 2 ×18 ) − 92 − 200 = 280 g.mol−1
at
C: C n H 2n-4O 2
12n + 2n - 4 + 32 = 280
uc

280 − 28
01,25 0,25 = n = 18 = n 18
14
:C ‫ اﺴﺘﻨﺘﺎج اﻟﺼ�ﻐﺔ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟﻠﺤﻤض اﻟدﻫﻨﻲ‬-‫ب‬
ed

0,25 CH3 (CH2)4 CH CH CH2 CH CH (CH2)7 COOH

:H2SO4 ‫ اﻟﻤركزة و ﻓﻲ وﺴط‬KMnO4 ‫ ﺒـ ـ‬C ‫ كﺘﺎ�ﺔ ﺘﻔﺎﻋﻞ أﻛﺴدة اﻟﺤﻤض اﻟدﻫﻨﻲ‬-‫ﺠ‬

-

CH3 (CH2)4 CH CH CH2 CH CH (CH2)7 COOH

cy

CH3 (CH2)4 COOH

3 + KMnO4
x HOOC CH2 COOH
H2SO4
en

0,25 +
HOOC (CH2)7 COOH

14 ‫ ﻤن‬3 ‫ﺼﻔﺤﺔ‬
 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫‪ (4‬كﺘﺎ�ﺔ اﻟﺼ�ﻎ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ اﻟﻤﻤكﻨﺔ ﻟﺜﻨﺎﺌﻲ اﻟﻐﻠ�ﺴر�د ‪:A‬‬

‫‪O‬‬
‫‪CH2 O C‬‬
‫‪(CH2 )7 - CH = CH-CH2 -CH=CH - (CH2 )4 - CH3‬‬
‫‪O‬‬
‫‪CH O C‬‬
‫‪(CH2 )10 - CH3‬‬ ‫‪O‬‬
‫‪CH2 O C‬‬

‫‪m‬‬
‫‪CH2 OH‬‬ ‫‪(CH2 )10 - CH3‬‬
‫‪3‬‬ ‫‪O‬‬
‫‪00,75‬‬ ‫‪x‬‬ ‫‪O‬‬ ‫‪CH O C‬‬
‫‪0,25‬‬ ‫‪CH2 O C‬‬ ‫‪(CH2 )7 - CH = CH-CH2 -CH=CH - (CH2 )4 - CH3‬‬

‫‪co‬‬
‫‪(CH2 )10 - CH3‬‬
‫‪CH2 OH‬‬
‫‪CH OH‬‬

‫‪O‬‬

‫‪n.‬‬
‫‪CH2 O C‬‬
‫‪(CH2 )7 - CH = CH-CH2 -CH=CH - (CH2 )4 - CH3‬‬

‫‪ (5‬ﺤﺴﺎب ﻗر�ﻨﺔ اﻟﯿود ‪ Ii‬ﻟﺜﻨﺎﺌﻲ اﻟﻐﻠ�ﺴر�د ‪:A‬‬

‫‪00,25‬‬
‫‪io‬‬ ‫‪1 mol de A ‬‬
‫‪→ 2 mol de I 2‬‬
‫‪→ 2 MI ‬‬
‫‪M A ‬‬
‫= ‪ ⇒ II = 2 × 254 ×100‬‬
‫‪at‬‬
‫‪0,25‬‬ ‫‪2‬‬ ‫‪94,77‬‬
‫‪100 g ‬‬
‫‪→ II‬‬ ‫‪‬‬ ‫‪536‬‬
‫‪‬‬
‫‪-II‬‬
‫‪uc‬‬

‫‪ (1‬ﺘﺼﻨﯿﻒ اﻷﺤﻤﺎض اﻷﻤﯿﻨ�ﺔ‪:‬‬

‫‪3‬‬ ‫‪ Ala‬ﺤﻤض أﻤﯿﻨﻲ ﺨطﻲ �ﺴ�ط‬
‫‪01,50‬‬ ‫‪x‬‬ ‫‪ Asp‬ﺤﻤض أﻤﯿﻨﻲ ﺨطﻲ ﺤﺎﻤﻀﻲ‬
‫‪ed‬‬

‫‪0,50‬‬
‫‪ Tyr‬ﺤﻤض أﻤﯿﻨﻲ ﻋطري‬
‫‪ (2‬أ‪ -‬كﺘﺎ�ﺔ ﺼ�ﻎ اﻟﻤرك�ﺎت ‪:A, B, C‬‬
‫‪-‬‬
‫‪COOH‬‬ ‫‪COO‬‬ ‫‪-‬‬
‫‪-‬‬

‫‪COO‬‬
‫‪+‬‬ ‫‪+‬‬
‫‪cy‬‬

‫‪H3 N CH‬‬ ‫‪H3 N CH‬‬ ‫‪H2 N CH‬‬

‫‪CH2‬‬ ‫‪CH2‬‬ ‫‪CH2‬‬
‫‪3‬‬
‫‪x‬‬
‫‪en‬‬

‫‪0,25‬‬
‫‪OH‬‬ ‫‪OH‬‬ ‫‪OH‬‬
‫‪A‬‬ ‫‪B‬‬ ‫‪C‬‬
‫‪01,25‬‬ ‫‪2‬‬ ‫ب‪ -‬ﺤﺴﺎب ﻗ�ﻤﺔ اﻟـ ‪ pHi‬ﻟﻠﺤﻤض اﻷﻤﯿﻨﻲ اﻟﺘﯿروز�ن‪:‬‬
‫‪x‬‬
‫‪pK a1 + pK a2 2, 2 + 9,11‬‬
‫‪0,25‬‬ ‫=‬‫‪pHi‬‬ ‫=‬ ‫=‬ ‫‪pHi 5,65‬‬
‫‪2‬‬ ‫‪2‬‬

‫ﺼﻔﺤﺔ ‪ 4‬ﻤن ‪14‬‬

 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫‪ (3‬أ‪ -‬كﺘﺎ�ﺔ اﻟﺼ�ﻐﺔ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟﺜﻼﺜﻲ اﻟﺒﺒﺘﯿد ‪Ala-Asp-Tyr‬‬

‫‪O‬‬ ‫‪O‬‬
‫‪0,25‬‬ ‫‪H2 N‬‬ ‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪COOH‬‬

‫‪CH3‬‬ ‫‪CH2‬‬ ‫‪CH2‬‬

‫‪m‬‬
‫‪COOH‬‬

‫‪OH‬‬

‫‪co‬‬
‫بـ‬
‫‪ -‬ﺼ�ﻐﺔ ‪ Ala-Asp-Tyr‬ﻋﻨد ‪pH= 1‬‬
‫‪O‬‬ ‫‪O‬‬

‫‪n.‬‬
‫‪00,75‬‬ ‫‪0,25‬‬ ‫‪H3 N‬‬
‫‪+‬‬
‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪COOH‬‬

‫‪CH3‬‬ ‫‪CH2‬‬ ‫‪CH2‬‬

‫‪io‬‬ ‫‪COOH‬‬

‫‪OH‬‬
‫‪at‬‬
‫‪ -‬ﺼ�ﻐﺔ ‪ Ala-Asp-Tyr‬ﻋﻨد ‪pH= 13‬‬
‫‪O‬‬ ‫‪O‬‬
‫‪-‬‬
‫‪uc‬‬

‫‪0,25‬‬ ‫‪H2 N‬‬ ‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪COO‬‬

‫‪CH3‬‬ ‫‪CH2‬‬ ‫‪CH2‬‬

‫‪-‬‬
‫‪COO‬‬
‫‪ed‬‬

‫‪-‬‬
‫‪O‬‬

‫اﻟﺘﻤر�ن اﻟﺜﺎﻟث‪ 06) :‬ﻨﻘﺎط(‬

‫‪-‬‬

‫‪ (1‬أ‪ -‬ﺤﺴﺎب كﻤ�ﺔ اﻟﺤ اررة ‪ Q‬اﻟﻨﺎﺘﺠﺔ ﻋن اﺤﺘراق كﺘﻠﺔ اﻟﺒرو�ﺎن اﻟﻐﺎزي‪:‬‬
‫‪cy‬‬

‫‪∑ Q = Qcomb + Qeau = 0‬‬

‫‪0,25‬‬ ‫‪∑ Q = Qcomb + mc ΔT = 0‬‬ ‫‪e‬‬ ‫‪⇒ Qcomb = -mceΔT‬‬
‫‪Qcomb = -723×4,185×22‬‬
‫‪en‬‬

‫‪0,25‬‬ ‫‪Qcomb = -66566,6 J‬‬

‫ب‪ -‬ﻗ�ﻤﺔ أﻨطﺎﻟﺒﻲ اﺤﺘراق اﻟﺒرو�ﺎن اﻟﻐﺎزي‪:‬‬
‫‪0,25‬‬ ‫‪m 1.32‬‬
‫=‪n‬‬ ‫=‬ ‫‪= 0.03 mol‬‬
‫‪M 44‬‬
‫‪Q‬‬
‫‪0,50‬‬ ‫‪ΔH°‬‬ ‫==‬ ‫= ‪comb − 66566.6‬‬‫‪−2218.88 kJ.mol-1‬‬
‫‪comb‬‬ ‫‪n‬‬ ‫‪0.03‬‬
‫ﺼﻔﺤﺔ ‪ 5‬ﻤن ‪14‬‬
 2019 :�‫ ﺑﻜﺎﻟﻮر‬//‫ ﺗﻘﲏ ر�ﺿﻲ‬:(‫اﻟﺸﻌﺐ)ة‬// ‫ اﻟﻄﺮاﺋﻖ‬.‫ ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‬:‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‬

:‫ كﺘﺎ�ﺔ ﻤﻌﺎدﻟﺔ اﻹﺤﺘراق اﻟﺘﺎم ﻟﻠﺒرو�ﺎن اﻟﻐﺎزي‬-‫ﺠ‬

02,50 0,50 C3 H8(g) + 5O 2(g) → 3CO 2(g) + 4H 2 O( ℓ )

:‫ ﺤﺴﺎب أﻨطﺎﻟﺒﻲ ﺘﺸكﻞ اﻟﺒرو�ﺎن اﻟﻐﺎزي‬-‫د‬
∆H°comb = ∑ ∆H°produits - ∑ ∆H°reactifs

m
0,25 ΔH°comb = 3ΔH°f ( CO2(g) ) + 4ΔH°f ( H 2O( ) ) - ΔH°f ( C3H8(g) ) - 5ΔH°f ( O2(g) )
ΔH°f ( C3H8(g) ) = 3ΔH°f ( CO 2(g) ) + 4ΔH°f ( H 2O( ) ) -ΔH°comb - 5ΔH°f ( O2(g) )

co
0,25 ΔH°f ( C3H8(g) ) = 3(-393) + 4(-286)- ( -2218,8) - ( 5×0 )
ΔH°f ( C3H8(g) ) = -1179 - 1144 + 2218,8

n.
0,25 ( )
ΔH°f C3H8(g) = -104,2 kJ.mol-1

io :‫( ﺤﺴﺎب أﻨطﺎﻟﺒﻲ ﺘﺸكﻞ اﻟﺒرو�ﺎن اﻟﻐﺎزي ﻤن ﺨﻼل طﺎﻗﺎت اﻟروا�ط‬2

ΔH f
°

(C H )
at
3 8(g)
3C(s) + 4H 2 (g) C3 H8(g)
0,50
uc

01,25 3ΔH °sub ( C ) 4ΔH °d ( H-H ) -8ΔH °d ( C-H )

-2ΔH °d ( C-C )

3C(g) + 8H (g)
ed

0,25 ΔH°f ( C3H8(g) ) = 3ΔH°sub(C) + 4ΔH°d(H-H) - 2ΔH°d(C-C) - 8ΔH°d(C-H)

ΔH°f ( C3H8(g) ) = (3×717) + (4×436) - (2×348) - (8×413)
-

ΔH°f ( C3H8(g) ) = 2151 + 1744 - 696 - 3304

cy

0,25 ΔH°f ( C3H8(g) ) = -105 kJ.mol-1

0,25 ‫ ﻣﺘﻘﺎرﺑﺘﺎن‬ΔHf0 ( C3H8(g) ) ‫ ﻟـ‬-104,2 kJ.mol-1 ‫ و‬-105 kJ.mol-1 ‫اﻟﻘﯿﻤﺘﺎن‬

en

14 ‫ ﻤن‬6 ‫ﺼﻔﺤﺔ‬
 2019 :�‫ ﺑﻜﺎﻟﻮر‬//‫ ﺗﻘﲏ ر�ﺿﻲ‬:(‫اﻟﺸﻌﺐ)ة‬// ‫ اﻟﻄﺮاﺋﻖ‬.‫ ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‬:‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‬

: ΔH 3 ‫ اﺴﺘﻨﺘﺎج أﻨطﺎﻟﺒﻲ ﻫدرﺠﺔ اﻟﺒرو�ن اﻟﻐﺎزي‬-‫أ‬

0
(3
C3H 7Cl ( ) + H 2 (g) → C3H8 (g) + HCl (g) ΔH1° = -52 kJ.mol-1

0,25 C3H 6 (g) + HCl (g) → C3H 7Cl ( ) ΔH°2 = -72 kJ.mol-1
C3H 6 (g) + H 2 (g) → C3H8 (g) ΔH°3 = ΔH1° +ΔH°2

m
0,25 ΔH°3 = -124 kJ.mol-1

( )
. ΔH f C3 H 7 Cl( ) ‫ ﺤﺴﺎب أﻨطﺎﻟﺒﻲ ﺘﺸكﻞ كﻠور اﻟﺒرو�ﺎن اﻟﺴﺎﺌﻞ‬-‫ب‬
°

co
ΔH°r = ∑ ΔH°produits - ∑ ΔH°reactifs

0,25 ΔH1 = ΔH f ( C3H8(g) ) + ΔH f ( HCl(g) ) - ΔH f ( C3H 7 Cl( ) ) - ΔH f ( H 2(g) )

° ° ° ° °

n.
ΔH°f ( C3H 7 Cl( ) ) =ΔH°f ( C3H8(g) ) + ΔH°f ( HCl(g) ) - ΔH1° - ΔH°f ( H 2(g) )

0,25 ΔH f ( C3H 7 Cl( ) ) = -104,1 - 92 + 52 ⇒ ΔH f ( C3H 7 Cl( ) ) = -144,1 kJ.mol

° ° -1

io (
ΔH f C3 H8 (g) = −105 kJ.mole
°
) −1
‫ ﺘﻘﺒﻞ اﻹﺠﺎ�ﺔ ﻓﻲ ﺤﺎﻟﺔ إﺴﺘﻌﻤﺎل‬:‫ﻤﻼﺤظﺔ‬
ΔH°f ( C3H 7 Cl( ) ) = -145 kJ.mol-1 ‫وﺘﻛون اﻟﻨﺘﯿﺠﺔ‬
at
( )
02,25
: ΔH d ( C-Cl ) C-Cl ‫اﻟر�طﺔ‬
‫ ﺤﺴﺎب أﻨطﺎﻟﺒﻲ ﺘﻔكك ا‬-‫ج‬
°
uc

ΔH°f
3C(s) +
7
H +
1
Cl
( C H Cl  )
3 7 ( )
C3H 7 Cl(  )
2 2 (g) 2 2 (g)
0.50
ed

3ΔH °sub( C ) 7 1
ΔH °d ( H-H ) ΔH °d ( Cl-Cl ) -ΔH °vap( C
2 2 3 H 7 Cl )
-2ΔH°d ( C-C )
-

3C(g) + 7H (g) + Cl(g) C3H 7 Cl(g)

cy

°
-7ΔH°d ( C-H ) -ΔH d ( C-Cl )

= 3ΔH°sub(C) + ΔH°d Cl-Cl 

7 1
ΔH°f  ΔH°d(H-H) +
en


 C3H7 Cl( )   2 2 ( )
0,25  

-  2ΔH°d(C-C) + 7ΔH°d(C-H) + ΔH°d(C-Cl) + ΔH°vap C H Cl 

 ( 3 7 )
7 1
ΔH°f  = 3ΔH°sub(C) + ΔH°d(H-H) + ΔH°d Cl-Cl

 C3H7 Cl( )  2 2 ( )
 

-2ΔH°d(C-C) - 7ΔH°d(C-H) - ΔH°d(C-Cl) - ΔH°vap C H Cl

( 3 7 )

14 ‫ ﻤن‬7 ‫ﺼﻔﺤﺔ‬
 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫‪-144,1= (3×717) + ( ×436) + ( ×242) - (2×348) - ( 7×413) - ΔH°d(C-Cl) - 27‬‬

‫‪7‬‬ ‫‪1‬‬
‫‪0,25‬‬ ‫‪2‬‬ ‫‪2‬‬
‫‪ΔH°d(C-Cl) = 2151 + 1526 + 121 - 696 - 2891 + 144,1 - 27‬‬

‫‪m‬‬
‫‪0,25‬‬ ‫‪ΔH°d(C-Cl) = 328,1 kJ.mol-1‬‬

‫وﺘﻘﺒﻞ أ�ﻀﺎ‪:‬‬

‫‪co‬‬
‫‪-144,1= (3×717) + ( ×436) + ( ×242) - (2×348) - ( 7×413) - ΔH°d(C-Cl) - 27‬‬
‫‪7‬‬ ‫‪1‬‬
‫‪2‬‬ ‫‪2‬‬
‫‪ΔHd(C-Cl) = 2151 + 1526 + 121 - 696 - 2891 + 145 - 27‬‬
‫‪°‬‬

‫‪n.‬‬
‫‪ΔH°d(C-Cl) = 329 kJ.mol-1‬‬

‫‪io‬‬
‫‪at‬‬
‫‪uc‬‬
‫‪-‬‬ ‫‪ed‬‬
‫‪cy‬‬
‫‪en‬‬

‫اﻨﺘﻬﻰ ﺘﺼﺤ�ﺢ اﻟﻤوﻀوع اﻷول‬

‫ﺼﻔﺤﺔ ‪ 8‬ﻤن ‪14‬‬

 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫اﻟﻌﻼﻤﺔ‬
‫ﻋﻨﺎﺼر اﻹﺠﺎ�ﺔ )اﻟﻤوﻀــوع اﻟﺜﺎﻨــﻲ(‬
‫ﻤﺠﻤوع‬ ‫ﻤﺠزأة‬
‫اﻟﺘﻤر�ن اﻷول) ‪ 07‬ﻨﻘﺎط(‪:‬‬
‫ﻠﻤرك�ﺎت ‪: F، E ، D ، C ، B ، A‬‬
‫‪ -I‬اﯿﺠﺎد اﻟﺼ�ﻎ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟ ّ‬

‫‪m‬‬
‫‪CH3 CH CH3‬‬

‫‪CH3 CH CH3‬‬ ‫‪CH3 CH CH3‬‬ ‫)‪(C‬‬

‫‪co‬‬
‫‪6‬‬ ‫‪(A) OMgCl‬‬ ‫‪(B) OH‬‬
‫‪03,00‬‬ ‫‪x‬‬
‫‪0,50‬‬
‫‪COOH‬‬ ‫‪COOH‬‬ ‫‪COOH‬‬

‫‪n.‬‬
‫)‪(D‬‬ ‫)‪(F‬‬ ‫)‪(F‬‬

‫‪io‬‬ ‫ﻠﻤرك�ﺎت )‪:(J)، (I) ، (H) ،(G‬‬

‫‪CH3‬‬

‫‪ -II‬إﯿﺠﺎد اﻟﺼ�ﻎ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟ ّ‬

‫‪COOH‬‬
‫‪at‬‬
‫‪NO2‬‬ ‫‪NO2‬‬
‫‪3‬‬
‫‪uc‬‬

‫‪01,50‬‬ ‫‪x‬‬ ‫)‪(G‬‬ ‫)‪(H‬‬ ‫)‪(I‬‬

‫‪0,50‬‬
‫‪NO2‬‬
‫‪0,50‬‬ ‫‪ -III‬أ‪ -‬ﻨوع اﻟﺒﻠﻤرة ‪ :‬ﺒﻠﻤرة �ﺎﻟﺘﻛﺎﺜﻒ‪.‬‬
‫‪ed‬‬

‫ب‪ -‬ﻣﻘﻄﻊ ﻣﻦ وﺣﺪﺗﯿﻦ ﺑﻨﺎﺋﯿﺘﯿﻦ ﻟﻠﺒﻮﻟﯿﻤﯿﺮ‪:‬‬

‫‪O‬‬ ‫‪O‬‬
‫‪....‬‬
‫‪H‬‬ ‫‪NH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪C‬‬ ‫‪....‬‬
‫‪O‬‬
‫‪-‬‬

‫‪O‬‬
‫‪0,50‬‬
‫‪NH C‬‬ ‫‪NH‬‬ ‫‪C‬‬
‫‪cy‬‬

‫‪02,50‬‬
‫ﺠ‪ -‬ﺤﺴﺎب اﻟﻛﺘﻠﺔ اﻟﻤوﻟ�ﺔ اﻟﻤﺘوﺴطﺔ ﻟﻠﺒوﻟ�ﻤﯿر‪:‬‬
‫‪en‬‬

‫‪0,50‬‬ ‫‪M p= n × M m‬‬

‫‪0,25‬‬ ‫) ‪M m = M(C14 H10O 2 N 2‬‬

‫‪0,50‬‬ ‫‪M m = 12 ×14 + 10 + 32 + 28 = 238g.mol−1‬‬

‫‪0,25‬‬ ‫‪M p = 800 × 238 = 190400g.mol−1‬‬

‫ﺼﻔﺤﺔ ‪ 9‬ﻤن ‪14‬‬

 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫اﻟﺘﻤر�ن اﻟﺜﺎﻨﻲ ) ‪ 06‬ﻨﻘﺎط(‪:‬‬

‫ﻣﻼﺣﻈﺔ‪ :‬ﯾﻤﻜﻦ ﻛﺘﺎﺑﺔ ﺛﻨﺎﺋﻲ اﻟﻐﻠﯿﺴﺮﯾﺪ ‪ A‬ﺑﺎﻟﺮﻣﺰ ‪DG‬‬ ‫‪-I‬‬
‫‪ (1‬ﻤﻌﺎدﻟﺔ ﺘﻔﺎﻋﻞ أﻛﺴدة ﺤﻤض اﻷراﺸﯿدوﻨ�ك‪:‬‬
‫= ‪CH 3 − ( CH 2 )4 − ( CH‬‬
‫‪CH − CH 2 )4 − ( CH 2 )2 − COOH‬‬

‫‪m‬‬
‫‪CH 3 − ( CH 2 )4 − COOH‬‬
‫‪3‬‬
‫‪+‬‬ ‫‪KMnO4‬‬
‫‪x‬‬ ‫) ‪3 ( HOOC − CH 2 − COOH‬‬

‫‪co‬‬
‫‪00,75‬‬ ‫‪0,25‬‬ ‫‪H2SO4‬‬
‫‪+‬‬
‫‪HOOC − ( CH 2 )3 − COOH‬‬
‫‪ (2‬اﻟﺼ�ﻎ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ اﻟﻤﻤكﻨﺔ ﻟﺜﻨﺎﺌﻲ اﻟﻐﻠ�ﺴﯿر�د‪:‬‬

‫‪n.‬‬
‫‪O‬‬
‫‪CH2 O C‬‬

‫‪io‬‬ ‫‪CH O‬‬ ‫‪C‬‬

‫‪O‬‬
‫‪(CH2)2-( CH2-CH = CH)4 - (CH2)4- CH3‬‬
‫‪at‬‬
‫‪(CH2)14 - CH3‬‬

‫‪CH2-OH‬‬
‫‪uc‬‬

‫‪O‬‬

‫‪3‬‬ ‫‪CH2 O‬‬ ‫‪C‬‬

‫‪x‬‬ ‫‪(CH2)14 - CH3‬‬
‫‪O‬‬
‫‪ed‬‬

‫‪0,25‬‬
‫‪CH‬‬ ‫‪O C‬‬
‫‪00,75‬‬ ‫‪(CH2)2-( CH2-CH = CH)4 - (CH2)4- CH3‬‬

‫‪CH2-OH‬‬
‫‪-‬‬

‫‪O‬‬
‫‪cy‬‬

‫‪CH2 O‬‬ ‫‪C‬‬

‫‪(CH2)14 - CH3‬‬

‫‪CH-OH‬‬
‫‪en‬‬

‫‪O‬‬
‫‪CH2 O C‬‬
‫‪(CH2)2-( CH2-CH = CH)4 - (CH2)4- CH3‬‬

‫ﺼﻔﺤﺔ ‪ 10‬ﻤن ‪14‬‬

 ‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‪ :‬ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‪ .‬اﻟﻄﺮاﺋﻖ ‪//‬اﻟﺸﻌﺐ)ة(‪ :‬ﺗﻘﲏ ر�ﺿﻲ‪ //‬ﺑﻜﺎﻟﻮر�‪2019 :‬‬

‫‪ (3‬ﺤﺴﺎب ﻗر�ﻨﺔ اﻟﯿود )‪ (Ii‬ﻟﺜﻨﺎﺌﻲ اﻟﻐﻠ�ﺴﯿر�د ‪:A‬‬

‫‪→ Glycérol + C16 : 0 + C20 : 4∆5,8,11,14‬‬
‫‪A + 2H 2O ‬‬
‫‪M A + 2M H‬‬ ‫)‪= M Glycérol + M C20:4∆5,8,11,14 + M(C16:0‬‬
‫‪2O‬‬ ‫(‬ ‫)‬
‫‪M C16:0 =15 + (14 ×14 ) + 45 = 256 g.mol−1‬‬

‫‪m‬‬
‫‪M C20:4∆5,8,11,14 = (12 × 20 ) + 32 + 32 = 304 g.mol−1‬‬
‫(‬ ‫)‬

‫‪co‬‬
‫‪M A = M Glycérol + M C20:4∆5,8,11,14 +M(C16:0) -2M H O‬‬
‫(‬ ‫)‬ ‫‪2‬‬

‫)‪M A = 92+304+256- ( 2 ×18‬‬

‫‪−1‬‬
‫‪00,50‬‬ ‫‪0,25‬‬ ‫= ‪MA‬‬
‫‪616 g.mol‬‬

‫‪n.‬‬
‫‪ -‬ﻤﻼﺤظﺔ‪ :‬ﺘﻘﺒﻞ اﻹﺠﺎ�ﺔ اﻟﺘﺎﻟ�ﺔ ﻟﺤﺴﺎب ‪MA‬‬
‫‪A : C39 H 68O5‬‬

‫‪io‬‬ ‫‪M A = 39 ×12 + 16 × 5 + 68 = 616 g.mol‬‬

‫‪−1‬‬
‫‪at‬‬
‫‪A‬‬ ‫‪4 x I2‬‬
‫‪4 x 254‬‬ ‫‪4x254x100‬‬
‫‪0,25‬‬ ‫‪616‬‬ ‫= ‪Ii‬‬ ‫‪= 164,93‬‬
‫‪100 g‬‬ ‫‪Ii‬‬ ‫‪616‬‬
‫‪uc‬‬

‫‪ (4‬ﻗ�ﻤﺔ ﻗر�ﻨﺔ اﻟﺘﺼﺒن ‪ Is‬ﻟﺜﻨﺎﺌﻲ اﻟﻐﻠ�ﺴﯿر�د‪. A‬‬

‫‪1 mol de A → 2 mol de KOH‬‬
‫‪ed‬‬

‫‪0,25‬‬ ‫‪616 → 2 × 56,1 de KOH ‬‬ ‫‪1× 2 × 56,1‬‬

‫‪00,25‬‬ ‫= ‪ ⇒ IS‬‬ ‫‪−3‬‬
‫=‬
‫‪182,14‬‬
‫‪1g → IS ×10‬‬ ‫‪−3‬‬ ‫‪‬‬
‫‪‬‬ ‫‪616‬‬ ‫×‬ ‫‪10‬‬

‫‪-II‬‬
‫‪-‬‬

‫‪ (1‬أ‪ -‬ﺘﺼﻨﯿﻒ اﻷﺤﻤﺎض اﻷﻤﯿﻨ�ﺔ ‪:‬‬

‫‪cy‬‬

‫‪3‬‬ ‫‪ :Glu‬ﺤﻤض أﻤﯿﻨﻲ ﺨطﻲ ﺤﺎﻤﻀﻲ‪.‬‬

‫‪x‬‬
‫‪0,50‬‬ ‫‪ :Ser‬ﺤﻤض أﻤﯿﻨﻲ ﺨطﻲ ﻫﯿدروكﺴﯿﻠﻲ‪.‬‬
‫‪02,00‬‬
‫‪ :Asn‬ﺤﻤض اﻤﯿﻨﻲ ﺨطﻲ أﻤﯿدي‪.‬‬
‫‪en‬‬

‫ب‪ -‬كﺘﺎ�ﺔ اﻟﺼ�ﻐﺔ ﻨﺼﻒ اﻟﻤﻔﺼﻠﺔ ﻟﺜﻼﺜﻲ اﻟﺒﺒﺘﯿد ‪:Ser-Asn-Glu‬‬

‫‪O‬‬ ‫‪O‬‬
‫‪H2N‬‬ ‫‪CH C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪C‬‬ ‫‪NH‬‬ ‫‪CH‬‬ ‫‪COOH‬‬
‫‪0,50‬‬ ‫‪CH2‬‬ ‫‪CH2‬‬ ‫‪(CH2 )2‬‬
‫‪C NH2‬‬
‫‪OH‬‬
‫‪O‬‬ ‫‪COOH‬‬

‫ﺼﻔﺤﺔ ‪ 11‬ﻤن ‪14‬‬

 2019 :�‫ ﺑﻜﺎﻟﻮر‬//‫ ﺗﻘﲏ ر�ﺿﻲ‬:(‫اﻟﺸﻌﺐ)ة‬// ‫ اﻟﻄﺮاﺋﻖ‬.‫ ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‬:‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‬

:C , B , A ‫ كﺘﺎ�ﺔ اﻟﺼ�ﻎ اﻷﯿوﻨ�ﺔ ﻟ ـ‬-‫( أ‬2

+ + - -
3 H 3N HC COOH H 3N HC COO H 2N HC COO
x
0,25 (A) CH2 (B) CH2 (C) CH2
C NH2 C NH2 C NH2

m
O O O

: pHi ‫ ﺤﺴﺎب ﻗ�ﻤﺔ اﻟـ‬-‫ب‬

pKa1 + pKa 2

co
01,75 2 pHi =
x 2
0,25 2,02 + 8,8
=pHi = 5,41
2

n.
:‫ ﻫﻲ‬pH=8 ‫ اﻟﺼ�ﻎ اﻷﯿوﻨ�ﺔ اﻟﻤﺘواﺠدة ﻋﻨد‬-‫ﺠ‬
+ - -
H3N CH
2
x
0,25
io (B)
CH2
C
COO

NH2
; H2N

(C)
CH

CH2
COO
at
C NH2
O O
uc

:(‫ ﻨﻘﺎط‬07 ) ‫اﻟﺘﻤر�ن اﻟﺜﺎﻟث‬

:(Gly)s ‫ ﻤوازﻨﺔ ﻤﻌﺎدﻟﺔ ﺘﻔﺎﻋﻞ اﺤﺘراق اﻟﻐﻠ�ﺴﯿن اﻟﺼﻠب‬-‫( أ‬1
4
ed

9 5 1
x NH 2 − CH 2 − COOH + O 
→ 2CO + H O + N
2(g) 2 2 () 2 2(g)
∆Hocomb
(s) 4 2(g)
0,25
:25°C ‫∆ أﻨطﺎﻟﺒﻲ ﺘﻔﺎﻋﻞ اﻻﺤﺘراق ﻋﻨد‬Hocomb ‫ ﺤﺴﺎب‬-‫ب‬
:‫ﺒﺘطﺒﯿق ﻗﺎﻨون ﻫ�س‬
-
cy

0,25 ΔH ocomb = ∑ ΔH of (produits) - ∑ ΔH (reactifs)

o
f

 5 1 
0,25 ΔH ocomb =  2×ΔH of (CO 2(g) ) + ×ΔH of (H 2O( ) )+ × ΔH fo (N 2(g) ) 
02,75  2 2 
en

 9 
- ΔH of (Gly(s) ) + × ΔH of (O 2(g) ) 
 4 
 5 
0,25 ΔH ocomb =  2×(-393) + ×(-286)  - (-527,5)
 2 
0,25 ΔH ocomb = -973,5 kJ.mol-1

14 ‫ ﻤن‬12 ‫ﺼﻔﺤﺔ‬
 2019 :�‫ ﺑﻜﺎﻟﻮر‬//‫ ﺗﻘﲏ ر�ﺿﻲ‬:(‫اﻟﺸﻌﺐ)ة‬// ‫ اﻟﻄﺮاﺋﻖ‬.‫ ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‬:‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‬

:25°C ‫ ﻤن اﻟﻐﻠ�ﺴﯿن اﺤﺘراق ﺘﺎم ﻋﻨد‬7,5g ‫ إﯿﺠﺎد كﻤ�ﺔ اﻟﺤ اررة اﻟﻨﺎﺘﺠﺔ ﻋن اﺤﺘراق‬-‫ﺠ‬
0,25 M Gly = 16 + 14 + 32 + 13 = 75g.mol−1

M Gly= 75 

→ ΔH comb = -973,5 kJ
0,25 
=
m 7,5  → Q=?

m
7,5 × ( -973,5 )
0,25 Q= = −97,35 kJ
75
:‫ ﺘﻘﺒﻞ اﻹﺠﺎ�ﺔ اﻟﺘﺎﻟ�ﺔ‬:‫ﻤﻼﺤظﺔ‬

co
M Gly = 16 + 14 + 32 + 13 = 75g.mol−1

Q m( Gly ) 7,5

n.
ΔH ocomb = ⇒n= = = 0,1mol
n M ( Gly ) 75

Q = ΔH ocomb × n =−973,5 × 0,1 =−97,35kJ

io T
:‫ ﺑﺘﻄﺒﯿﻖ ﻗﺎﻧﻮن ﻛﯿﺮﺷﻮف‬60°C ‫( ﺤﺴﺎب أﻨطﺎﻟﺒﻲ اﻟﺘﻔﺎﻋﻞ اﻟﺴﺎﺒق ﻋﻨد‬2
at
333
∆H T =∆H T + ∫ ∆CpdT ∆H =∆H 298 + ∫ ∆C dT
o o o o
0,50 ,
333
p
0
T0 298

01,75
uc

0,25 ∆=
H o333 ∆H o298 + ∆Cp (333 − 298)

0,25 = (2 ) 2 ( ) ( )
∆Cp 2Cp CO2( g ) + 5 Cp H2O(  ) + 1 Cp N2( g ) − 9 Cp O2( g ) −Cp Gly( s )
4 ( ) ( )
ed

     
0,25 ∆Cp = ( 2×37,45 ) +  5×75,24  +  1×29,12  −  9×29,37  − ( 99,20 )
2  2  4 

0,25 ∆Cp =
112, 27 J.mol-1.K -1

0,25 ∆H333
o
−973,5 + 112,27×10−3  (333 − 298) =
= − 969,58 kJ.mol−1
-

 
cy

: ∆H°f (Gly)g ‫( إﯿﺠﺎد أﻨطﺎﻟﺒﻲ ﺘﺸكﻞ اﻟﻐﻠ�ﺴﯿن اﻟﻐﺎزي‬3

Gly(s) → Gly(g) ∆H°sub (Gly) =
147 kJ.mol−1
∆H° (Gly) =∆H° (Gly) − ∆H° (Gly)
en

sub f (g)
f (s)
00,50 0,25
H°f (Gly)(g) ∆H°f (Gly)(s) + ∆H°sub (Gly)
∆=
0,25 ∆H°f (Gly)
= (g) −380,5kJ.mol−1
-527,5 + 147 =

14 ‫ ﻤن‬13 ‫ﺼﻔﺤﺔ‬
 2019 :�‫ ﺑﻜﺎﻟﻮر‬//‫ ﺗﻘﲏ ر�ﺿﻲ‬:(‫اﻟﺸﻌﺐ)ة‬// ‫ اﻟﻄﺮاﺋﻖ‬.‫ ﺗﻜﻨﻮﻟﻮﺟﻴﺎ ﻫـ‬:‫ﺎﺗﺑﻊ ﻟﻺﺟﺎﺑﺔ اﻟﻨﻤﻮذﺟﻴﺔ ﳌﻮﺿﻮع اﺧﺘﺒﺎر ﻣﺎدة‬

: ∆H°  ‫( ﻓﻲ اﻟﻐﻠ�ﺴﯿن‬C-N) ‫( ﺤﺴﺎب أﻨطﺎﻟﺒﻲ ﺘﻔكك اﻟرا�طﺔ‬4

d C− N 
 

ΔH of (Gly)g
2 C(s) + 5/2 H2 (g) + 1/2N2 (g)+ O2 (g) C2 H 5 NO 2 (g)

0,50
5 o 1 o
o
ΔH d(H − H ) ΔH d

m
2ΔHsub(C)
.... (N ≡ N) .... ΔH od(O =O)
-∑ ΔH od
2 2

co
2 C(g) + 5H(g) + N (g) + 2 O (g)

02,00
0,25 ∑ ΔH o
d = ΔH od (C-C) + 2ΔH od (C-H) + 2ΔH od (N-H) + ΔH od (C-N)

n.
+ ΔH od (C=O) + ΔH od (C-O) + ΔH od (O-H)

0,25 ΔH d (C-N)= ∑ ΔH - ( ΔH (C-C)+ 2ΔH od (C-H) +2ΔH od (N-H) )

io
o o
d
o
d

- ( ΔH od (C=O)+ ΔH od (C-O)+ ΔH od (O-H) )

at
5
0,25 ΔH f (Gly)g = 2ΔH sub (C(s) ) + ΔH od (H-H)
o o

2
uc

1
+ ΔH od (O=O) + ΔH od (N ≡ N) - ∑ ΔH od
2
 5 1 
∑ ΔH o
=  2ΔH osub (C(s) ) + ΔH od (H-H) +ΔH od (O=O) + ΔH od (N ≡ N)  - ΔH of (Gly)g
ed

0,25
 
d
2 2

 5 1 
0.25 ∑ ΔH o
d =  2 × 717 + × (436) +(498) + (940)  − ( −380,5 )
 2 2 
-

∑ ΔH o
= 3872,5 kJ.mol-1
cy

ΔH od (C-N) = 3872,5 - ( (348) + 2(413) + 2(391) ) - ( (810) + (351) + (463) )

ΔH od (C-N) =292,5 kJ.mol-1

en

0,25

‫اﻨﺘﻬﻰ ﺘﺼﺤ�ﺢ اﻟﻤوﻀوع اﻟﺜﺎﻨﻲ‬

14 ‫ ﻤن‬14 ‫ﺼﻔﺤﺔ‬