FOOD TECHNOLOGY

CARBOHYDRATES
FORMULA FOR CARBOHYDRATES
 CxH2Oy

Carbohydrates can be split up into:

Sugars Monosaccharides Glucose

Fructose

Disaccharides Maltose
Sucrose
Lactose
Non Sugars Simple Starch
Polysaccharides Cellulose
Glycogen

Complex Pectin
Polysaccharides Gums
MONOSACCHARIDES
 These contain 2-7 carbon atoms.

 Most common Monosaccharide in food contain 6

carbon atoms (called hexoses) therefore their
formula is C6H12O6 .
GLUCOSE
 Found in large amounts of grapes and smaller
amounts in carrots and peas.
 Glucose syrup which is used in commercial
manufacture is not pure glucose, but a mixture of
other carbohydrates, glucose and water.
Formula for Glucose
Alpha Beta
Glucose Glucose
GLUCOSE CONT.
 There are two forms of glucose alpha and beta.
 It‟s important to remember that the only difference
in the two is that in alpha glucose, the hydroxyl
group (OH), is at the bottom of the structure and in
Beta glucose, the OH is at the top.
 Glucose is a reducing sugar, this means it has the
ability to break down Fehling‟s solutions to form a
brick red coloured precipitate.
 Fehling‟s solution is a mixture of 2 solutions which
have to be mixed at the time of carrying out the test
for reducing sugar.
FRUCTOSE
 Fructose is one and a half times sweeter than
glucose.
 An equal mixture of fructose and sucrose is called
invert sugar – found in honey, made when making
jam.
 The structure of Fructose changes depending on if
it is found in its own or whether it is joined with
other sugars.
FRUCTOSE STRUCTURE
 Fructose in the free state:

 Fructose when it is joined with other sugars:

GALACTOSE
 This doesn‟t occur in foods but it is formed when
lactose if broken down during digestion.
DISACCHARIDES
 Disaccharides have the formula C12H22O11.
 These sugars are formed when two
Monosaccharides join together during a
condensation reaction (when water is eliminated).
LACTOSE
 This sugar is found only in milk.
Cow‟s milk – 4 to 5%
Human milk – 6 to 8%
 This reducing sugar is formed by joining together
Glucose and Galactose.
MALTOSE
 Is formed when two Glucose units join together.
 When the two units join, water is eliminated and the
remaining O2 atom forms a bridge between the two
glucoses.
 This bridge is called a Glycosidic Link.

 Maltose is a reducing sugar. During digestion starch

is broken down by the enzyme amylase (this
enzyme is present in our saliva).
SUCROSE
 Sucrose is not a reducing sugar.
 Sucrose is formed by 1 glucose unit joined with 1
fructose unit.
 Ordinary sugar is almost pure sucrose (caster
sugar/ sugar in tea etc).

RECAP
Glucose + Glucose = Maltose
Glucose + Fructose = Sucrose
Glucose + Galactose = Lactose
HYDROLYSIS
 It s the chemical breakdown of a molecule when it
combine with water and produces two smaller
molecules.

C12 H22 O11 + H2O = 2C6 H12 O6

Hydrolysis of different disaccharides:
Glucose
Maltose + Water -> Glucose + Glucose
Fructose
Sucrose + Water -> Glucose + Fructose
Galactose
Lactose + Water -> Glucose + Galactose
SIMPLE POLYSACCHARIDES
 Long chains of 1 type of monosaccharide joined
together.
 Usually insoluble in water.

 Most polysaccharides usually have a 1-4 Glycosidic

link, but sometimes 1-6 link, a 1-2 link or a 1-3 link.
 The general formula for simple polysaccharides is
(C6H10O5)n.
 „n‟ here represents many thousands of
monosaccharide units.
STARCH
Types of starch
 Amylase: Consists of between 50 – 500 glucose
units joined in a straight chain.

 Amylopectin: This molecule consists up to 100,000

glucose units joined in a branched-chain structure.
PROPERTIES OF STARCH
 Appearance and Solubility:
Starch is a white powder which is insoluble in cold
water.
Hydrolysis breaks down starch:
Starch -> Dextrins -> Maltose -> Glucose
PROPERTIES OF STARCH CONT.
 Effect of Heat
Gelatinization (with water):
 Water penetrates the outer layers of granules and
the granules begin to swell when the temperature
rises from 60 C to 80 C.
 Granules swell up to 5x the original size – mixture
becomes viscous (thick).
 At 80 C the starch granules break up and disperse
throughout the water.
 Long chain molecules unfold and the starch/water
mixture becomes more viscous – forms a sol.
 On cooling, starch molecules form a network with
the water and produce a gel.
CELLULOSE
 Insoluble
 Long chain of glucose units – are the building
blocks of plants being found in cell walls.
 Cellulose is important for providing fibre (NSP) in
the diet.
 Non-starch polysaccharides (NSP) is necessary for
efficient passage of food through the alimentary
canal and regular emptying of the bowel.
GLYCOGEN
 Carbohydrate only found in animals
 Animals store glycogen in muscles and liver and
when required, it converts it to glucose which is
broken down to provide energy.
 Glycogen, like Amylopectin, is composed of
branched chains of glucose units.
COMPLEX POLYSACCHARIDES
 These are long chains of different
monosaccharide's joined together and often with
branches.
PECTIN
 Complex mixture of polysaccharides found in many
fruits and some root vegetables.
 Apples and the peel of citrus fruits are particularly
rich in pectin.
 Main importance: Gelling Agent (e.g. jam making)

 Pectin is broken down in fruit as fruit ripens – Jam

will not gel well if made from over ripe fruit.
 For pectin to form a really good gel, 65% of it needs
to be sugar.
 pH affects gel strengths (pH 3.0-3.5). Lemon juice
lowers this setting.
GUMS
 Tragacanth, arabic and guar – Produced by plants
and are used in food manufacturing as thickeners,
stabilizers and gelling agents in foods.
 E.g. Ice cream, salad dressing and fruit pie fillings.

 Certain seaweed extracts are used in a similar

manner.
 These include carrageenan (Irish Moss), alginates
e.g. sodium alginate and agar (agar-agar).
 Agar is also used in the preparation of
microbiological media.
THE PROPERTIES OF CARBOHYDRATES
 Sugar
The effect of heat:
Melting point of sucrose is 160 C to 161 C.
After sugar is melted and cooled slowly, it forms an
amorphous (shapeless) sugar sometimes called
“barley sugar”.
If sucrose is heated above melting point, brownish-
coloured substances called caramel is formed.
Maltose melts at about 100 C, therefore it
decomposes more easily by heat than sucrose.
THE PROPERTIES OF CARBOHYDRATES CONT..
Aeration:
A soufflé will rise because of the trapped air in the
egg whites – adding sugar will make the egg whites
more stable.
The sugar interacts with the whipped foam structure
to make the foam more elastic so that the air cells
can expand and take up more air and therefore
rise.
MODIFIED STARCH
 Also a „novel food‟
 It is classified as a smart food and is used by
manufacturers in a variety of products.
 Pizza Toppings – topping thickens when heated in
the oven and will not run off the pizza.
 Sauce/ Gravy granules – boiling water can be
added to thicken without the sauce going lumpy.
MODIFIED STARCH CONT..
 Modified starch is used as a fat replacer in low-fat
meals.
 The noodles in „pot snacks‟ are pre-gelatinised; so
boiled water will reheat and „cook‟ them.
 Modified starch is used in „cup-a-soups‟ to improve
mouth-feel, thicken then drink/soup when the boiled
water is added, and blend uniformly without lumps.
 Modified starches allow sauces to be reheated by
syneresis*. This is useful in dishes that are cooked
from frozen e.g. Lasagne.

*When a sauce that has cooled and solidified is reheated, often

goes lumpy and a watery liquid may separate from it.