Phenolics-Cumene Doc. No.

: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 1 of 31

Start-up
Transalkylation Reactor Drying
( R-51002)

Name Date Signature

Developed By J.B.Mahadik

Process Trainer Hartono Susanto

SK Operation Specialist Cherian P Ninan

Process Engineer Haridasan

Final Approval:-
Phenolics Operations Department Manager:-
Mr. Khater-Al, Ali Abdullah

Sign. …………………………………………. Date ……………………………….

 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 2 of 31

Record of revision:

Reason of revision : Revise SOP template and content

Name : J.B. Mahadik
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 3 of 31

Content :
1. Purpose:
2. Important system components/ equipment:
3. Potential consequences by failure system:
4. Precautions and Limitations:
5. Special Tools/Equipment:
6. Prerequisites:
7. Process Description:

8. Operating Tasks:
9. Chemical and physical Properties (MSDS):
10. Control system and strategy :
11. Interlocks:
12. Critical safety systems:
13. Safety and Health:
14. Environmental:
15. Quality:
16. Start up Procedure:
17. Table of Critical Operating Limits:
18. Checklist: All
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 4 of 31

References:
P&ID No :
510-25F-2004: Alkylation Reactor Circulation Pump & circulation cooler
510-25F-2005: Alkylation Reactor.
510-25F-2006: Transalkylation Reactor & Feed Heater.
510-25F-2007: Transalkylation reactor start-Up Heater.
510-25F-2009: Benzene Column.
510-25F-2021: Secondary Benzene Treaters.
PFD NO:
510-25F-1001: Cumene area reaction section.

MSDS Nos. Ref. e-SK share folder MSDS plant wise

 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 5 of 31

1. Purpose:
To provide Standard Operating Procedure for Transalkylation reactor drying and associated equipments in
start up service in a safe and efficient manner.

2. Important system components/ equipment:

2.1. Transalkylation Reactor R-51002

2.2. Transalkylation Feed Heater E-51002
2.3. Alkylation Circulation Cooler E-51001
2.4. Benzene Column C-51021
2.5. Benzene Column Reflux Drum V-51021
2.6. Benzene Recycle Surge Drum V-51022
2.7. Benzene Column Reflux Pump P-51021 A/B
2.8. Benzene Column Bottom Pump P-51022 A/B
2.9. Benzene Recycle Pump P-51023 A/B
2.10. Decanted Water Pump P-51024 A/B
2.11. Benzene Column Condenser E-51021
2.12. Benzene Column Reboiler E-51022
2.13. Benzene Contaminated Oily Water Drum V-51055

3. Potential consequences by failure system:

In case of failure of the Transalkylation Reactor drying, plant will have much water in the system and
catalyst life will be shortened and Cumene Plant has to take shut down.
While temperature is not controlled during drying activities, catalyst could be damaged .

4. Precautions and Limitations:

4.1. All personnel are required to wear standard personal protective equipment (PPE).
4.2. Material Safety Data Sheets (MSDS) – All personnel working in the Cumene area must become familiar
with the Benzene MSDS in his assigned work area.
4.3. Ensure all electrical equipment properly grounded.
4.4. Keep all Motor & coupling guard is in place.
4.5. All fire detector & protective system, gas leak detector system is in line & ready for use.
4.6. Establish good communication between Field & Control room persons.
4.7. Safety shower system is operational .
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 6 of 31

5. Special Tools/Equipment:

5.1. Portable gas detector.

5.2. Proper Chemical Suit
5.3. Proper chemical Gloves
5.4. Face shield

6. Prerequisites:

Prerequisite Resp. Date Time Init

6.1. Ensure that the Product storage flushing and hydrocarbon make up is
C.O.
carried out as per procedure.

6.2. Ensure that all Cumene plant battery limit equipments ready for start-
F.O.
up.

6.3. Ensure that Vent collection system and flare systems are operational. C.O.

6.4. Ensure that all utilities and OSBL facilities are operational F.O
F.O.
6.4.1. Nitrogen for inerting
F.O.
6.4.2. Steam systems -all levels.
F.O.
6.4.3. Steam condensate system all levels.
F.O.
6.4.4. Cooling water circulation for coolers and condensers.
F.O.
6.4.5. Potable water for safety showers.
F.O.
6.4.6. Fire water system.
F.O.
6.4.7. UPS and Auxiliary Power system.

6.5. Ensured that all commissioning steps are carried out with respect to
F.O.
mechanical completion.

6.6. All spectacle blinds are in their normal operating positions as per P&ID.
F.O.
Refer checklist for Blinds # 18.5

6.7. Ensure that the Line-up system as per system line-up check list # 18.8 F.O.
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 7 of 31

Prerequisite Resp Date Time Init

6.8. Ensure that the nitrogen blanketing system is in working condition F.O.

6.9. Verify that all control valves have been stroke checked and close in C.O
manual with 0% output and all control valve bypass are close.

6.10. Ensure that the PCS and BZW system has been commissioned and is in
F.O.
operational condition.

6.11. Ensure that fire & Gas detection system in service.

F.O.
Refer checklist for safety devices # 18.1

6.12. All Safety valves have been lined up as per PSV list.
F.O.
Refer checklist for PSVs # 18.2

6.13. All Car Seal Open/Close have been lined up as per checklist.
F.O.
Refer to car seals Checklist # 18.3

6.14. All instrumentation is installed and ready for service.

F.O.
Refer checklist for Instruments # 18.4

6.15. All vents (pressure –vacuum safety valve and emergency relief hatch)
are commissioned and drains on lines and equipment are closed. F.O.
Refer checklist for Vents & Drains # 18.6

6.16. Ensure that the all sample collection valves are closed F.O.

6.17. Ensure all Pump motors are energized. Refer checklist for Electrical #
F.O.
18.7

7. Process Description:

The catalyst in the Transalkylation reactor contains of moisture that is picked up during transportation to site,
during storage on site and when the catalyst is loaded into the reactors. This moisture is extracted from the
catalyst with circulating dry benzene at elevated temperature and is removed from the system via the
Benzene Column Reflux Drum water boot.

8. Operating Tasks:

8.1. Start up of the Transalkylation Reactor Drying

 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 8 of 31

8.2. Taking samples

9. Chemical and physical Properties (MSDS):

9.1. Chemistry
C6H6 Benzene
9.2. Physical properties
Benzene is liquid material, colorless, sweet odor which is extremely hazardous.
As a liquid, vapor, or mist is readily absorbed through the skin, mucous membranes, gastrointestinal and
respiratory tracts, and can cause cancer .

10. Control system and strategy :

Moisture that present in the catalyst and the system to be removed less than 100 wt ppm by
circulating dry benzene at elevated temperature. To avoid catalyst damage during this stage, drying
progress to be controlled in range of temperature difference between circulated benzene and the
top of catalyst bed is less than 28 oC.
Benzene is line up into the start up heater to increase temperature by controlling the outlet
temperature against high pressure steam flow.

510-FIC-051 flow indication control of recycle benzene into transalkylation reactor

510-TIC-050 temperature indication control of recycle inlet of transalkylation reactor , with high
and low alarm temperature on DCS

510-TI-109 temperature indication of alkylation circulation cooler outlet

510-TI-051/052/053/054/055 catalyst bed temperature indication

11. Interlocks:

No. Interlock No. Cause Effect

1. 510-S-002 Low low recycle benzene flow Close FV-008/050, ESV-117, ESD-116

2. 510-I-008 High level of boot V-51021 Start pump P-51024 A/B

3. 510-I-008 Low level of boot V-51021 Stop pump P-51024 A/B

 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 9 of 31

4. 510-S-003 High High Benzene Overhead Column Close 510-ESV-101,FV-015,FV-001,EDV-

112,FV-087,ESV-105,FV-077 and ESV-107

5. 510-S-009 Low low level in V-51021 , ESD Close HV-121 and stop P-51021 A/B
pushbutton on console at UCB or at
field
510-HV-121 not open Stop P-51021 A/B

6. 510-S-014 High high bearing temperature of P- Stop pump P-51023 A/B

51023 A/B
Low low level of V-51022 Close HV-123 and stop P-51023 A/B
ESD pushbutton on console at UCB Close HV-123 and stop P-51023 A/B
7. 510-S-008 522-HV-122 not open Stop P-51024 A/B

ESD pushbutton on console at UCB or Close HV-122 and stop P-51024 A/B
at field

12. Critical safety systems :

12.1. Temperature difference between recycle benzene and top catalyst bed is not more than 28oC
12.2. Reactor outlet moisture content to be less than 100 wt ppm

13. Safety and Health:

13.1. Normal present Hazardous chemical

Benzene Ref. e-SK share folder MSDS plant wise

Flammable, toxic – cancer hazard ( TLV 2.5 ppm), causes skin irritation.
Concentrations in system 99.71 wt %

13.2. Potential presence of Hazardous chemical

Harmful or fatal if swallowed. Flammable liquid and vapor. Harmful if inhaled or absorbed through skin.
Causes irritation to skin, eyes and respiratory tract. Affect central nervous system.

13.3. Potential other Dangers : None

 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 10 of 31

14. Environmental:

14.1. Air :
It will usually either break down or decompose over a few days, with the products eventually ending up
in the air. It can be washed out of the air by rain, but will evaporate and continue to contaminate the air.
It can attach to rain or snow and be carried back down to the ground.

14.2. Waste water and Soil :

Benzene in soil or water will decompose with the presence of oxygen. It does not build up in plant or
animal tissues
Benzene has a high acute toxic effect on aquatic life. Long-term effects on marine life can mean
shortened lifespan, reproductive problems, lower fertility and changes in appearance or behaviour.
Benzene can cause death in plants and roots and damage to the leaves of many agricultural crops.

15. Quality:

15.1. Back ground

Benzene is received from U & O and then sent to Benzene Column after passing Clay Treater to
remove basic nitrogen , and to secondary benzene treater to remove polar nitrogen before delivered to
Alkylation and Transalkylation reactor.

15.2. Quality Specification

Benzene specification as per Cumene Plant Operating Manual
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 11 of 31

16. Starts up Procedure:

Procedure step Resp. Date Time Init.

1. Put pressure controller 510-PIC-060 in the feed line from R-51002 to

C-51021 in service.

1.1. Open the block valves downstream and upstream of 510-PV-

060 of Transalkylation Reactor effluent line to Benzene F.O
column (C-51021).

1.2. Put 510-PIC-060 in Auto mode at 20.0Barg. C.O

2. Line-Up cooling water of E-51001. ( P&ID No. 510-25F-2004)

2.1. Open the vent valve on upstream of the cooling water return
F.O
line block valve.

2.2. Keep cooling water return block valve closed. F.O

2.3. Gradually open the cooling water supply block valve up

F.O
to 25-50%

2.4. Close the vent valve when air is removed and only cooling
F.O
water comes out. Install blind on the vent valve.

2.5. Open the cooling water return block valve gradually. F.O

2.6. Open cooling water supply totally. Check for any leakage F.O

3. Line Up Recycle Benzene From Secondary Benzene Treaters(R-51052A

or B) to Alkylation Circulation Cooler (E-51001).

3.1. Open the first block valve downstream 510-FE-009 in the

start-up benzene filling line 510-P-0015, which comes from R- F.O
51052A or B.

3.2. Open the double block valves in start-up line 510-P-0036

which allows Recycle Benzene to flow into line 510-P-0008 to
F.O
the Benzene Circulation Cooler E-51001 through line 510-P-
0016.

4. Line Up Recycle Benzene From Alkylation Circulation Cooler (E-51001)

to Transalkylator (R-51002).
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 12 of 31

Procedure step Resp. Date Time Init.

4.1. Open the upstream and downstream block valves of 510-TV-

003A at the outlet of Alkylation Circulation Cooler to R-51001 F.O
Line 510-P-0010.

4.2. Open the block valves in line 510-P-0038 downstream of

temperature control valve 510-TV-003A which allows Recycle
C.O
Benzene to flow to the Transalkylator (R-51002) through line
510-P-0017.

4.3. Open the block valve upstream of 510-FO-013 in line 510-P-

F.O
0017.

4.4. Open the First of the double block valves on downstream of

F.O
510-FO-013 on line 510-P-0017.

4.5. Open the block valve on line 510-P-0021 to the top of the
F.O
Transalkylator.

4.6. Set Recycle Benzene flow at 5000 kg/hr on 510-FI-009 by

globe valve in line 510-P-0038 and compare the flow with F.O
510-FI-012.

4.7. Monitor Recycle Benzene temperature on 510-TI-109 on

outlet of Alkylation Circulation Cooler and 510-TIC-050 on
C.O
Transalkylator inlet line. Also monitor 510-TI-051 and 510-TI-
052 on the catalyst bed.

Note:
Monitor the temperatures of the Benzene stream and the Catalyst bed in the
Transalkylator, Differential temperature should not exceed 28°C.

4.8 Gradually increase Recycle Benzene Flow to 20,000 Kg/hr on

510-FI-009 by globe valve in line 510-P-0038 and compare the F.O
flow with 510-FI-012.

5. Line up Recycle Benzene to Feed Heater E-51002.

5.1. Open the upstream and downstream valves of the Benzene

recycle valve 510-FV-051 from R-51052A or B to E-51002. C.O
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 13 of 31

5.2. Override 510-FALL-046 A/B C.O

5.2. Open the inlet and outlet valves of E-51002 and set the Recycle
Benzene flow to 5000 kg/hr on 510-FIC-051 to Transalkylation C.O
Feed Heater E-51002.

5.3. Monitor the mixed stream temperature on 510-TIC-050 on

C.O
Transalkylator top inlet.

Note:
When the Transalkylator bed temperature increases to 70°C, increase the Recycle Benzene flow and temperature.

5.4. Gradually decrease Recycle Benzene Flow on 510-FI-009 to zero

F.O
to alkylation circulation cooler by globe valve in line 510-P-0038.

5.5. Gradually increase Recycle Benzene flow to 20,000 kg/hr on 510-

C.O
FIC-051 to Transalkylation Feed Heater.

Note:
At this point, Recycle Benzene temperature flowing through Transalkylator is 98°C and the bed temperature is 70°C.

WARNING:
THE STEPS 1.6 AND 1.7 REQUIRE HEAT AND HEARING PROTECTION.

Procedure step Resp. Date Time Init.

6. Removal of condensate from steam line and Transalkylation Feed

Heater (E-51002).

6.1. Open the HS bypass-valve 10-15% and ESV-116 downstream

block valve and open 510-FV-050 gradually 10-15% and drain
F.O
the condensate by opening the drain valve upstream of 510-
FV-050. Close the drain valve only if dry steam comes out.

6.2. Open the block-valve upstream of 510-FV-050 and Close the

F.O
bypass valve of main HS block valve.
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 14 of 31

Procedure step Resp. Date Time Init.

6.3. Open the downstream block valve of 510-LV-003 and close

the upstream block-valve. Open the downstream drain valve F.O
of 510-LV-003.

6.4. Open 510-LV-003 and 510-FV-050 gradually 10-15% to heat

C.O
up the Feed-heater E-51002 and the condensate pot V51002.

6.5. Open the upstream HS condensate valve of 510-LV-003.

(Leave the drain downstream 510-LV-003 open). Leave the F.O
upstream valve closed.

7. Heating up the Transalkylation Feed Heater E-51002.

7.1. Open the steam valve 510-FV-050 gradually and start heating
up the Transalkylation Feed Heater. Open the steam in steps
of 3-5% if the temperature in the bottom doesn’t rise.
Repeat this step until the desired temperature and pressure C.O
has been reached. (Condensate is still not aligned to the
condensate header). Keep monitoring the pressures and
temperatures of the Transalkylator.

7.2. Check for external and internal leaks. Take condensate

F.O
sample for lab. Analysis (conductivity).

7.3. Line up the condensate to the header and close the drain: If
the desired temperature and pressure are reached and the
F.O
condensate sample is within the conductivity specification.
Mount the blind to the drain line which were removed.

7.4. Put 510-LIC-003 of the condensate pot in auto 50 % C.O

8. Increasing Transalkylator Temperature.

8.1. Set Transalkylator inlet temperature HS controller 510-TIC-050

C.O
at 110°C in Cascade mode with 510-FIC-050.

8.2. Slowly increase the set point of 510-TIC-050 to 200°C until the
C.O
transalkylator bed temperatures reaches to 175°C.

Note:
Monitor 510-TIC-050 and bed temperatures 510-TI-051,510-TI-052,510-TI-053, 510-TI-054, 510-TI-
055 and adjust the set point if temperature differential is more than 28°C.
 Phenolics-Cumene Doc. No.: SK-Phenolics-SU- 510009
` Rev. No.: 1
Plant Start-Up
System: Alkylation and Transalkylation
Date: Mar 14 ,2010
Subsystem: Transalkylation Reactor
Page 15 of 31

Procedure step Resp. Date Time Init.

9. Take sample of transalkylator effluent for moisture content from

SC0040. The catalyst is dry when water is less than or equal to 100 wt
ppm at 175°C.
F.O
The online analyser 510-AE-002A or B and 510-AE-003A or B can be
used to compare sample analysis and trend the water concentration
in the system.

10. Maintain Benzene Column Boil Up.

10.1. Open flow control valve 510-FV-087 of steam line to Benzene

column reboiler E-51022 through 510-FIC-087 to maintain boil C.O
up and bottom temperature in Benzene column.

10.2. Maintain Benzene Column Reflux Drum V-51021 interface level

C.O
on 510-LIC-022 and decant water regularly.

11. When the Catalyst is dry isolate the following.

11.1. Close 510-FV-050 on steam line of transalkylator Feed Heater. C.O

11.2. Close 510-FV-051 on recycle benzene to Feed heater. C.O

11.3. Stop Benzene recycle flow through E-51002. C.O

11.4. Close the Transalkylator filling line valves, drain and swing the
C.O
spectacle blind in close position.
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 16 of 31

17. Table of Critical Operating Limits:

Process Consequences of
Operating Safe Safe Consequences
Variable deviating outside Safety Systems or
Range Alarms Required Actions Upper Lower of deviating Outside of
(Variable and of normal Required Actions
(Units) Limit Limit Safe Operating Limits
Tag Number) operating range
Reactor Catalyst may get
damaged, maintain 28°C
At low temp.
differential temperature
Reactor Catalyst Maintain 510-TIC-050 Maintain 510-TIC-050
510-TIC-050 175-200°C 207oC 200°C 175°C between Reactor inlet
may not dry temperature. temperature.
510-TIC-050 & Reactor
perfectly
bed temperatures 510-TI-
051 to 510-TI-055.
Reactor Catalyst may get
damaged, maintain 28°C
At low temp.
Maintain 510-TI-051 differential temperature Maintain 510-TI-051 to
Reactor Catalyst
510-TI-051 175-200°C - to 510-TI-055 200°C 175°C between Reactor inlet 510-TI-055
may not dry
temperatures. 510-TIC-050 & Reactor temperatures.
perfectly
bed temperatures 510-TI-
051 to 510-TI-055.
C-51021 will be operated
C-51021 will be
Maintain 510-PIC-060 at higher pressure Maintain 510-PIC-060
510-PIC-060 20.0 bar g 21 barg operated at higher 20.0 bar g -
pressure resulting in benzene pressure
pressure.
going to flare.
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 17 of 31

18. Checklist :
18.1. Safety Devices Checklist:

Item No. Device Resp. Date Time Init.

1. Deluge system in service. L.O

2. Fire Extinguisher in position with valid date. L.O

3. Gas Detectors are in service. L.O

4. Fire Water system in service. L.O

18.2. PSV Checklist:

Item PSV No. Set Pressure P&ID No. Line No. Required Position Resp. Date Time Init.
No.

1. PSV017A 11.0 bar G 510-25F-2004 510-CWR-0009 Open both u/s & d/s valves F.O

2. PSV017B 11.0 bar G 510-25F-2004 510-CWR-0009 Open both u/s & d/s valves F.O

3. PSV011A 40.0 bar G 510-25F-2005 510-P-0159 Open both u/s & d/s valves F.O

4. PSV011B 40.0 bar G 510-25F-2005 510-P-0159 Open both u/s & d/s valves F.O
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 18 of 31

Item PSV No. Set Pressure P&ID No. Line No. Required Position Resp. Date Time Init.
No.

5. PSV015A 40.0 bar G 510-25F-2006 510-P-0160 Open both u/s & d/s valves F.O

6. PSV015B 40.0 bar G 510-25F-2006 510-P-0160 Open both u/s & d/s valves F.O

7. PSV012A 39.0 bar G 510-25F-2006 510-P-0161 Open both u/s & d/s valves F.O

8. PSV012B 39.0 bar G 510-25F-2006 510-P-0161 Open both u/s & d/s valves F.O

9. PSV023 52.20 bar G 510-25F-2006 V-51002 Open both u/s & d/s valves F.O

10. PSV007 39.0 bar G 510-25F-2007 510-P-0026 Open both u/s & d/s valves F.O

11. PSV024 52.0 bar G 510-25F-2009 510-HS-0004 Open both u/s & d/s valves F.O

12. PSV016 29.90 bar G 510-25F-2018 510-CWR-0018 Open both u/s & d/s valves F.O

13. PSV038 5.0 bar g 510-25F-2018 510-P-0394 Open both u/s & d/s valves F.O

14. PSV053 39.30 bar G 510-25F-2021 510-P-0167 Open both u/s & d/s valves F.O

15. PSV054 39.30 bar G 510-25F-2021 510-P-0167 Open both u/s & d/s valves F.O
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 19 of 31

18.3. Car Sealed Valve Checklist:

Item P&ID No. Line No. Car Sealed Valve Location Position Resp. Date Time Init.
No. Description

1. 510-25F-2004 510-CWR-0009 U/S of PSV-017A Open F.O

2. 510-25F-2004 510-WF-0061 D/S of PSV-017A Open F.O

3. 510-25F-2004 510-CWR-0009 U/S of PSV-017B Close F.O

4. 510-25F-2004 510-WF-0061 D/S of PSV-017B Open F.O

Open
5. 510-25F-2005 510-P-0159 U/S of PSV-011A F.O
Open
6. 510-25F-2005 510-WF-0080 D/S of PSV-011A F.O

7. 510-25F-2005 510-P-0159 U/S of PSV-011B Close F.O

8. 510-25F-2005 510-WF-0080 D/S of PSV-011B Open F.O

9. 510-25F-2006 510-P-0160 U/S of PSV-015A Open F.O

10. 510-25F-2006 510-WF-0005 D/S of PSV-015A Open F.O

U/S of PSV-015B
11. 510-25F-2006 510-P-0160 Close F.O
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 20 of 31

Item P&ID No. Line No. Car Sealed Valve Location Position Resp. Date Time Init.
No. Description

12. 510-25F-2006 510-WF-0005 D/S of PSV-015B Open F.O

13. 510-25F-2006 510-P-0161 U/S of PSV-012A Open F.O

14. 510-25F-2006 510-WF-0006 D/S of PSV-012A Open F.O

15. 510-25F-2006 510-P-0161 U/S of PSV-012B Close F.O

16. 510-25F-2006 510-WF-0006 D/S of PSV-012B Open F.O

17. 510-25F-2006 510-HS-0011 U/S of PSV-023 Open F.O

18. 510-25F-2006 510-AV-0001 D/S of PSV-023 Open F.O

19. 510-25F-2007 510-P-0026 U/S of PSV-007 Open F.O

20. 510-25F-2007 510-WF-0008 D/S of PSV-007 Open F.O

21. 510-25F-2009 510-HS-0004 U/S of PSV-024 Open F.O

22. 510-25F-2009 510-AV-0003 D/S of PSV-024 Open F.O

23. 510-25F-2018 510-CWR-0018 U/S of PSV-016 Open F.O

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 21 of 31

Item P&ID No. Line No. Car Sealed Valve Location Position Resp. Date Time Init.
No. Description

24. 510-25F-2018 510-P-0394 U/S of PSV-038 Open F.O

25. 510-25F-2018 510-WF-0104 D/S of PSV-038 Open F.O

26. 510-25F-2021 510-P-0167 U/S of PSV-053 Open F.O

27. 510-25F-2021 510-WF-0015 D/S of PSV-053 Open F.O

28. 510-25F-2021 510-P-0168 U/S of PSV-054 Open F.O

29. 510-25F-2021 510-WF-0016 D/S of PSV-054 Open F.O

18.4. Instrumentation Checklist :

Item P&ID No. Line No. /Eqpt. No. Tag No Service Resp. Date Time Init.
No.

1. 510-25F-2004 510-P-0010 510-TI-109 Yes

2. 510-25F-2005 510-P-0038 510-FI-012 Yes

3. 510-25F-2005 510-P-0015 510-FIC-009 Yes

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 22 of 31

Item P&ID No. Line No. /Eqpt. No. Tag No Service Resp. Date Time Init.
No.

4. 510-25F-2006 510-P-0043 510-TIC-050 Yes

5. 510-25F-2006 R-51002 510-TI-051 Yes

6. 510-25F-2006 R-51002 510-TI-052 Yes

7. 510-25F-2006 R-51002 510-TI-053 Yes

8. 510-25F-2006 R-51002 510-TI-054 Yes

9. 510-25F-2006 R-51002 510-TI-055 Yes

10. 510-25F-2006 510-P-0050 510-PIC-060 Yes

11. 510-25F-2006 517-HS-0010 510-FIC-050 Yes

12. 510-25F-2006 510-HSC-0011 510-LIC-003 Yes

13. 510-25F-2006 510-P-0041 510-FIC-0581 Yes

14. 510-25F-2006 510-P-0050 510-FI-054 Yes

15. 510-25F-2009 510-HS-0008 510-FIC-087 Yes

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 23 of 31

Item P&ID No. Line No. /Eqpt. No. Tag No Service Resp. Date Time Init.
No.

16. 510-25F-2009 510-HSC-0009 510-LIC-011 Yes

17. 510-25F-2018 510-P-0114 510-FIC-082 Yes

18.5. Blind Checklist:

Item No. P&ID No. Line No./Eqpt. No. Location Description. Required Resp. Date Time Init.
Position

1. 510-25F-2004 510-P-0036 On recycle benzene line to E- Open F.O

51001

2. 510-25F-2004 510-P-0010 On E-51001 process outlet Open F.O

3. 510-25F-2005 510-P-0038 On U/S of FE-012 Open F.O

4. 510-25F-2005 510-P-0042 On U/S of block valve to P- Close F.O

51001A or B

5. 510-25F-2006 510-P-0017 On D/S of FO-013 to R-51001 Top Open F.O

6. 510-25F-2006 510-P-0050 On R-51001 bottom to C-51021 Open F.O

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 24 of 31

Item No. P&ID No. Line No./Eqpt. No. Location Description. Required Resp. Date Time Init.
Position

7. 510-25F-2006 510-P-0044 On R-51001 top D/S of block Close F.O

valve to WF

8. 510-25F-2009 510-P-0050 On C-51021 Open F.O

9. 510-25F-2006 510-N-0010 On N2 line to R-51001 bottom Close F.O

10. 510-25F-2006 510-P-0052 R-51001 bottom to Benzene Close F.O

pump out to P-51081

11. 510-25F-2006 510-P-0051 R-51001 bottom to WF Close F.O

12. 510-25F-2006 510-P-0041 On E-51002 process inlet from R- Open F.O

51052A or B

13. 510-25F-2006 510-P-0043 On E-51002 process outlet Open F.O

14. 510-25F-2006 510-P-0043 From E-51002 to R-51002 Open F.O

15. 510-25F-2006 510-N-0012 On N2 line to R-51001 top Close F.O

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 25 of 31

18.6. Vents and Drains Checklist:

Item P&ID No. Line No./Eqpt. No. Location Description Required Resp. Date Time Init.
No. Position

1. 510-25F-2004 510-P-0036 In between the double valve assembly to Closed F.O

BZW

2. 510-25F-2004 510-P-0010 Drain On D/S of 510-TV-003A Closed F.O

3. 510-25F-2005 510-P-0038 Drain On U/S of FE-012 to BZW Closed F.O

4. 510-25F-2005 510-P-0038 Drain On D/S of FE-012 to BZW Closed F.O

5. 510-25F-2006 510-P-0017 Drain On D/S of FO-013 to BZW Closed F.O

6. 510-25F-2006 510-P-0043 Closed & F.O

Vent on R-51002 inlet from E-51002
Blinded

7. 510-25F-2006 510-P-0044 Drain on U/S of Block valve to WF Closed & F.O

Blinded

8. 510-25F-2006 510-P-0044 Drain on D/S of Block valve to WF Closed & F.O

Blinded
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 26 of 31

Item P&ID No. Line No./Eqpt. No. Location Description Required Resp. Date Time Init.
No. Position

9. 510-25F-2006 510-P-0160 Drain valve to WF on U/S of PSV-015A Closed F.O

10. 510-25F-2006 510-WF-0005 Drain valve to WF on D/S of PSV-015A Closed F.O

11. 510-25F-2006 510-P-0160 Drain valve to WF on U/S of PSV-015B Closed F.O

12. 510-25F-2006 510-WF-0005 Drain valve to WF on D/S of PSV-015B Closed F.O

13. 510-25F-2006 R-51002 Drain valve at the bottom of R-51001 Closed & F.O
Blinded

14. 510-25F-2006 510-P-0050 Drain valve to BZW on U/S of block valve Closed F.O
on R-51001 bottom to C-51021

15. 510-25F-2006 510-P-0050 Drain valve to BZW on D/S of block valve Closed F.O
on R-51001 bottom to C-51021

16. 510-25F-2006 510-P-0041 Drain valve to BZW on U/S of 510-FV-051 Closed F.O

17. 510-25F-2006 510-P-0049 Drain valve in between double block Closed F.O
valve assembly to BZW

18. 510-25F-2006 517-HS-0010 Drain valve on D/s of 510-FV-050 Closed & F.O
Blinded
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 27 of 31

Item P&ID No. Line No./Eqpt. No. Location Description Required Resp. Date Time Init.
No. Position

19. 510-25F-2006 517-HS-0010 Drain valve on D/S block valve on D/S of Closed & F.O
510-FV-050 Blinded

20. 510-25F-2006 V-51002 Drain valve on U/S of PSV-023 Closed & F.O
Plugged

21. 510-25F-2006 510-AV-0001 Drain valve on D/S of PSV-023 Closed & F.O
Plugged

22. 510-25F-2006 510-HSC-0021 Drain valve on LG of V-51002 Closed & F.O

Plugged

23. 510-25F-2006 510-HSC-0021 Vent valve on LG of V-51002 Closed & F.O

Plugged

24. 510-25F-2009 510-P-0050 Drain valve to BZW on D/S of 510-PV- Closed F.O
0060

25. 510-25F-2018 510-P-0114 Drain valve to BZW on D/S of 510-FV-082 closed F.O
 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 28 of 31

18.7. Electrical Checklist:

Item P&ID No. Equipment No Energized Resp. Date Time Init.

No.

1. 510-25F-2004 510-PM-51001A Yes F.O

2. 510-25F-2004 510-PM-51001B Yes F.O

3. 510-25F-2018 510-PM-51043A Yes F.O

4. 510-25F-2018 510-PM-51043B Yes F.O

18.8. System Line Up Check List:

Item P&ID No. Line No. Location Description Required Resp. Date Time Init.
No. Position

1. 510-25F-2004 510-P-0036 Double block valve assembly near interconnection Open F.O
of line 510-P-0008

2. 510-25F-2004 510-P-0010 U/S block valve of 510-TV-003A Open F.O

3. 510-25F-2004 510-P-0010 D/S block valve of 510-TV-003A Open F.O

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 29 of 31

Item P&ID No. Line No. Location Description Required Resp. Date Time Init.
No. Position

4. 510-25F-2004 510-P-0010 510-TV-003A Close F.O

5. 510-25F-2004 510-P-0010 Bypass valve of 510-TV-003A Close F.O

6. 510-25F-2005 510-P-0038 Double block valve assembly on U/S of FE-012 Open F.O

7. 510-25F-2005 510-P-0038 Block valve on U/S of FE-012 Open F.O

8. 510-25F-2006 510-P-0017 Block valve on U/S of FO-013 Open F.O

9. 510-25F-2006 510-P-0017 Block valve on D/S of FO-013 Open F.O

10. 510-25F-2006 510-P-0021 Block valve to R-51002 Filling line Open F.O

11. 510-25F-2006 510-P-0050 Double block valve assembly on U/S start up Open F.O
Bypass line

12. 510-25F-2006 510-P-0050 Block valve on D/S of startup bypass line Open F.O

13. 510-25F-2006 510-P-0041 U/S block valve of 510-FV-051 Open F.O

14. 510-25F-2006 510-P-0041 D/S block valve of 510-FV-051 Open F.O

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 30 of 31

Item P&ID No. Line No. Location Description Required Resp. Date Time Init.
No. Position

15. 510-25F-2006 510-P-0041 510-FV-051 Close F.O

16. 510-25F-2006 510-P-0043 Double block valve assembly from E-51002 to R- Open F.O
51001

17. 510-25F-2006 517-HS-0010 U/S block valve of 510-FV-050 Open F.O

18. 510-25F-2006 517-HS-0010 D/S block valve of 510-FV-050 Open F.O

19. 510-25F-2006 517-HS-0010 510-FV-050 Close F.O

20. 510-25F-2006 517-HS-0010 ESV Open F.O

21. 510-25F-2006 517-HS-0010 Main block valve on HS line on U/S of FE-050 Open F.O

22. 510-25F-2006 517-HS-0010 Bypass of Main block valve of HS line on U/S of FE- Close F.O
050

23. 510-25F-2006 510-HSC-0011 U/S block valve of 510-LV-003 Open F.O

24. 510-25F-2006 510-HSC-0011 D/S block valve of 510-LV-003 Open F.O

25. 510-25F-2006 510-HSC-0011 510-LV-003 Close F.O

 Phenolics- Cumene Doc. No.: SK-Phenolics-SU-510009

Rev. No.: 1
Plant Start-Up
System : Alkylation and Transalkylation
Rev. Date: Mar 14, 2010
Subsystem: Transalkylation Reactor
Page 31 of 31

Item P&ID No. Line No. Location Description Required Resp. Date Time Init.
No. Position

26. 510-25F-2006 510-HSC-0011 Bypass valve of 510-LV-003 Close F.O

27. 510-25F-2009 510-P-0050 U/S block valve of 510-PV-060 Open F.O

28. 510-25F-2009 510-P-0050 D/S block valve of 510-PV-060 Open F.O

29. 510-25F-2009 510-P-0050 510-PV-060 Close F.O

30. 510-25F-2009 510-P-0050 Bypass valve of 510-PV-060 Close F.O

31. 510-25F-2018 510-P-0114 U/S block valve of 510-FV-082 Open F.O

32. 510-25F-2018 510-P-0114 D/S block valve of 510-FV-082 Open F.O

33. 510-25F-2018 510-P-0114 510-FV-082 Close F.O

34. 510-25F-2018 510-P-0114 Bypass valve of 510-FV-082 Close F.O