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FIITJEE

ALL INDIA TEST SERIES


FULL TEST – X

JEE (Advanced)-2019
PAPER – 2

TEST DATE: 05-05-2019

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A

1. C, D
Sol. From initial to final instant v  2gh
Conservation of momentum gives : v
v
mv = 2mv
(i) (f)
2gh
 v 
2
Work energy theorem on block + Plank:
1  2gh  1 mgh
Wf  (2m)    m(2gh)  
2  4  2 2
Work energy theorem on block:
1  2gh  1 3
Wf  (2m)    2 m(2gh)   4 mgh
2  4 
mgh  3  mgh
  Wf plank      mgh   
2  4  4

2. C
Sol. Conservation of momentum give: 
Mv  m(v r cos60  v)
v
mvr cos60
v …(i) 60
(m  M) m
Energy conservation vr

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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2

3 1 1
mgR  Mv 2  m (v r cos 60  v)2  (v r sin60)2  …(ii)
2 2 2
Solve (i) and (ii) for v

3. B, C, D
Sol. Based on blackbody radiation.

4. A, B, C
G(2M1 ) M2 GM1M2 M2, R2 M2
Sol. FN   dFcos    dA cos   dm = dA = dA
R 22 2R 22 R 22 dF 2R22

GM1M2 dF cos 
 The force extended by half shell (M1, R1) will be
2R 22 2M1, R1
So, A, B, C are Correct.

5. A, B, D
Sol. Based on magnetism

6. B, C, D
Sol. From the concept of power in A.C. circuit.

7. C
Sol. Equations are : a1
f1  f2  MaC …(i) M
2F
MR2 f1
(f1  f2 )R   …(ii) f1
2 M
2F  f1 = Ma1 …(iii)
aC
3F  f2 = 2Ma2 …(iv) R 
Constraints are
Lower point: R  aC = a2 …(v) f2
Upper point : R + aC = a1 …(vi) f2
3F
Solve for required quantities. 2M
a2

8. B
Sol. KVL in L1 and L2 gives C1 Q Q
M
 Q  Q1  Q1 (Q  Q1) (Q  Q1) C2
E  …(i)
 C1  C2
Q1
Q Q1 (1) C2 (2)
E  …(ii) Q1
C2 C2
Solving above
N
 C  C1  E E
VMN  E  2 
 2C2  C1 

9. C
Sol. Draw FBD and use LOM to solve

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3 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

10. D
Sol. From Work energy theorem, A
Wgas   P0 Adx   kxdx  0
1 2
 Wgas  P0 V  kx  90 J , where x = 0.1 m
2
Using Q = U + W gas
P
= nCv T  Wgas P0
3 dx
= PV  P0 V0   Wgas
2
3
 PV  P0 V0   Wgas  2010  90  2100J
2
Calculate the other values similarly

SECTION – D

11. 00001.00
Sol. Use constraint that length of thread is constant always.

12. 00000.01
Sol. 1  angular velocity of lamina about ICM. ICM
2  angular velocity of axis ICM.
 2
dL  
  2  L
dt

dL 1
  12ICM
dt

13. 00000.50
Sol. Using  =  T
For no displacement, compare the stress on both side of section.

14. 00000.02
3 P
Sol. At P, sinr  60
2
Q
3 3 r
 3 du 60 y
 dr  2
2 2 cosr O

In OPQ,
y 3
 …(i)
sinr sin(150  r)
Differentiate (i) and put r = 30 for  = 3
2
 |dy| = d = 0.2133
3

15. 00001.33
3R
Sol. For K;   (z  b)
4

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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4

8R
K;   (z  b)
9
8
3/ 2
K 9 4 1
    n = 1.33
K 3 3 2
4

16. 00016.67
  
Sol. F  q(v  B)
(3iˆ  4ˆj)  1010  2  109 (x ˆi  yj)
ˆ  3  103 kˆ
400 300 100
Solve: x   ; y  |x + y| =  16.67
6 6 6

17. 00001.76
Sol. mg sin   f = ma …(i)

2
fr  mr 2  …(ii) 
5 
5 mg sin 
 a  gsin 
7 f a
5  5g 
For small ; a  g   x
7  7(R  r)  mg
7(R  r)
 T  2
5g

18. 00312.50
dP dV dP R  dP 
Sol. B    dR  
dV / V V B 3  B 
3 50 1
dR     312.5 Å
100  3 8  10 3 2  109

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5 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Chemistry PART – II

SECTION – A
19. B
PKa1  PKa2
Sol. pH 
2
2.4  14  4.6 

2
= 5.9

20. A, B, D

21. A, B, C, D
Sol. Properties of Baryllium.

22. A, B, D
Sol. P4  3NaOH  3H2O 
 PH3  2NaH2PO2
 White 
23. A

24. B, C
Δ
Sol. NH4 2 Cr2O7   N2  4H2 O  Cr2 O3
Δ 3
2CrO3   Cr2O3  O2
2
Δ 3
2K 2 Cr2O7   2K 2 CrO 4  Cr2 O3  O2
2
Al2O3  Cr  No reaction

25. B
Sol. (P) [Ni(CN)4]2–
O. S of Ni is +2
Ni2  3d8  Paramagnetic

3d 4s
In presence of ligand
Ni2  3d8  Diamagnetic

3d 4s 4p
dsp2
(Q) K3[Fe(CN)6]
Oxidation state of Fe = +3
Fe3  3d5 4s0  Paramagnetic

3d 4s
In presence of ligand

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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6

Paramagnetic low spin


3d 4p
4s
d2 sp3

(R) Ni2  

3d 4s
In presence of ligand

Paramagnetic

sp3
(S) [Ni(NH3)6]SO4
In presence of ligand

sp3 d2 paramagnetic
26. A
Sol. Ag+ - Ag2S 
- AgI  yellow
- 1st group
Zn - 4th group
2+

- ZnS 
- Soluble in KI
- form Amphoteric Oxide
Pb2+ - Pbs 
- PbI2  yellow
- 1st and 2nd group
- form Amphoteric oxides
Bi3+ - Bi2S3 
- BiI3  Black
- BiO+X– (white ppt on dilution with water)
nd
- 2 group
27. D
Sol. P – Chiral, G. I., 2 chiral centers
Q – Chiral, G.I., 2 chiral centers
R – Chiral, G. I., 3 chiral centers
S – Achiral, G. I., plane of symmetry
28. A
Sol. (P)
CHCl3 CHCl3

KOH

KOH

Cl Cl
(Q) Cl

CHClBr2

KOH

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7 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

(R) Cl

CHCl2Br2

KOH

(S) Cl

CHCl3

KOH

SECTION – D
29. 00042.22
Sol. For n mole
 n2 a 
 P  2   V  nb   nRT for negligible volume b  0
 V 
PV – nRTV + n2a = 0
2

Quadratic in V thus,
nRT  n2R 2 T 2  4an2P
V
2
V has one value at given pressure and temperature thus discriminant = 0
n2R2T2 = 4a n2P
P = 42.22 atm.
30. 00046.06
Sol. Meq of H2SO4 = Meq of NaOH
84.6
N of H2SO4 =
5
84.6
Weight of H2SO4 in 1 lit =  49
5
84.6  49
Weight of H2SO4 in 1 ml =
5  1000
84.6  49  100
Purity =  46.06%
5  1.8  1000

31. 00008.50
h 6.6  10 34
Sol. u  27 9
 4.125  104 m / s
mλ 1.6  10  0.01 10
QV = 1/2 mu2
Putting all values we get V
V = 8.50 volt.
32. 00003.82
Sol. Equivalent of oxygen = Equivalent of metal
20 80

8 E
E = 32
64
N.f = 2
32
2F charge is required for 64 gm metal

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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8

1F charge is required for 32 gm metal


60  60  3.2 32  60  60  3.2
Coulomb charge is required for gm metal
96500 96500
= 3.82 gm

33. 00062.10
Sol. A  g  B  g  C  g
At time t  0 p 0 0
At time t  20 min px x x
At time t   0 p p
p + x = 300
2p = 500
p = 250
x = 50
2.303
K log1.25
20
0.693
t1/2   62.10 min
K

34. 00001.43
Sol. HCl + NH4OH  NH4Cl + H2O H = –12.27
H+ + Cl– + NH4OH  NH4 + Cl– + H2O H = –12.27 …1
 –
NH4OH  NH + OH H = x4 …2
From equation (1) and (2)
H+ + OH–  H2O H = –12.27 – x
We know that
–12.27 – x = –13.7
X = 1.43 Kcal

35. 00073.75
Sol. 
PCl5 
 PCl5  Cl2
1 0 0
1 α α α
Meq 1

Minitial 1 α
208.5
 1 α
120
 = 0.7375
Or 73.75%

36. 00344.80
Sol. Work is done against constant pressure and thus irreversible.
V = 4 lit
P = 1 atm
w = –1  4 lit-atm = - 1 × 4 × 101.3 = - 405.2 Joule
 E  a  w
 E  750  405.2
E  344.80 J

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9 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Mathematics PART – III

SECTION – A

37. A, D
Sol. f(x) = 3(x – 1)(x + 1)
 f is strictly non-decreasing in (–, –1] and [1, ) and non-increasing in [–1, 1]
f(–1) = 3, f(1) = –1, f(2) = 3
f(x) = 0 has three distinct roots x 1, x2, x3 i.e. –2 < x1 < –1 < x2 < 1 < x3 < 2
So f(x) = x1 has one solution
f(x) = x2 = has 3 solution
f(x) = x3 has 3 solution

38. A, C
Sol. =0
cos  sin  cos 
 sin  cos  sin   0
cos  sin   cos 
 cos ·cos 2 = 0
  3 5 3 7
  , , , , ,
4 2 4 4 2 4
 3 5 7
But   , , , (rejected)
4 4 4 4
Because line are parallel, so system is inconsistent

39. A, C
4 9x 2 35x 2 35
Sol. (i) We have u    1  = 1
4  x 2 9x 2  1 9x 4  37x 2  4  2
2

37    3x    12 
 x 
 
 1  1  12 2
Since x   2,     , 2  . So u reaches minimum value , when x  
 2  2  5 3
(ii) Using A.M. and G.M.
4 9
u2 
4  x 9  y2
2

12 12 12 12
 =  
2 2
36  9x  4y   xy 
2 2
37  9x  4y 2 2 5
37  2 36  xy 

40. A, B
1 1  1 D
Sol. AD  BC  AC  sin 45º   VABCD 
3 2  6
AC C
So, AD  BC  1
2 45º
AC AC
3  AD  BC   3 AD  BC  3 A
2 2
AC
Equality holds if and only if AD = BC = 1 B
2

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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10

So AD is perpendicular to the face ABC. DC  AD2  AC2  3

41. A, B, C, D
2 n 2 2
Sol. (2x + 1) = 1996(1997) + 1997 for n = 1, we get (2x + 1) = 1997
So 2x + 1 =  1997  x = 998, –999

42. A, B
n
 3
Sol. Tr   cot 1  r 2  
r 1  4
 
4 
1  1
 1 
Tr  tan  2   tan  
 4r  3   r 2  3 
 4
 
 1 
Tr  tan1  
  2 1
 1  r  4  
  
 1  1
Tr  tan1  r    tan1  r  
 2   2 
 1   1 
Sn  tan1  n    tan1  
 2 2
 1  1
lim Sn  tan1   tan1   =  tan1 = tan–1 2
n   2 2 2

43. C
3
Sol. e x  e x  x
3 3
Let f  x   e x  e x  f   x   e x  3x 2  e  x  0
f(–) = , f() = 0  f(x) = x has one solution
sin5 x  sin2 x; cos3 x  cos2 x
 sin5 x + cos3 x  sin2 x + cos2 x  sin5 x + cos3 x  1
Equality holds if sin5 x = sin2 x and cos3 x = cos2 x
 sin x = 0, cos x = 1 or sin x = 1, cos x = 0

 x  , 2
2

44. A
1  17 17  1
Sol. f  x   f x 
2x 2x 2

45. B
9
Sol. Length of common chord = 2 9  3 3
4
 9  9  9  2
Angle between circles =   cos1  
 233  3

46. B

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11 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

 /2
n n 1
Sol. Let In   sin xdx  In   In2
0
n
 /4
n 1
Let Pn   tan xdx  Pn  Pn 2 
0
n 1
1
n 1 1
Let In   x 1  x  dx  In  
0
n 1 n  2

SECTION – D

47. 00002.00
f  x
Sol. g() = g() = g() = 0  g(x) = a(x – )3(x – ) and lim 0
x  g x
4
 f(x) = b(x – )
d
h(x) = f(x)g(x) + g(x)f(x) =  f  x  g x 
dx
d
=
dx
 7
 7 6
ab  x     x    = ab((x – ) + 7(x – )(x – ) )

= ab(x – )6(x –  + 7x – 7) = ab(x – )6(8x –  – 7)


 h(x) has two different real solutions

48. 00002.00
Sol. A(3, 1, 0) inside cube B
B(1, 1, 1) outside cube
C(2, 1, 3) outside cube
Number of intersection point is 2
A

49. 00006.00
Sol. |A| = –18
A adj(A) = –18 I
 a11 a12 a13   5 1 7   18 0 0 
 a21 a22 a 23   1 7 5   0 18 0 
a31 a32 a33   7 5 1  0 0 18 
1
 3 aij  3 18    aij  6
3

50. 00007.00
sin 1º sin 2º sin 3º ..... sin 179º
Sol. = sin 1º sin 3º sin 5º ..... sin 179º
sin 2º sin 4º ..... sin 178º
2
 1 1 
 44  sin2º sin 4º.....sin88º 
 2 2  1
=   = 89
 sin2º sin 4º.....sin88º 2 289

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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12

51. 00036.00
2
 x  3 2  y  2 
Sol. C1 :  1
9 4
 A1 = (6, 2), A2 = (0, 2)
(0, 2) (3, 2) A(6, 2)
 PA 1  PA 2  3 2
Clearly locus of P is hyperbola for which
A1A2 = 2ae = 6 and 2a  3 2  e  2
 Locus of P is rectangular hyperbola
2 2 9
Equation of conic C2 : (x – 3) – (y – 2) =
2
Now D1 = 2ae = 6 P
2 9
D2 = b =
2 Q
O
9 3
D3 : L  9  
2 2
2 Auxiliary circle of C1
D D 
  1 2 2   36 Auxiliary circle of C2
 D3 

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2
 2  10 
Sol.  y    2 x  
 3  9 
Clearly for three distinct normal x-coordinate > 2a
10 1 19
 x  2  h   [h]least = 2
9 2 9

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Sol. x = 6q + r where 0  r  5
x x x  r   r  9 r
        
2 3 7  2 3  7 7
for r = 0, we get q = 0  x = 0
for r = 1, we get q = 1  x = 7
for r = 2, we get q = –5  x = –28
for r = 3, we get q = 3  x = 21
for r = 4, we get q = –3  x = –14
for x = 5, we get q = –2  x = –7
N
 N = sum of all value = –21  3
7
or Put x = 7k where k  I

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sin x   x cos x  sin x  x  tan x   
Sol. f  x  for x   0,  ; f(x) = 2
= cos x  2   ve for x   0, 
x  2 x  x   2
 
 f(x) is decreasing function for x   0, 
 2
2
  x sin x  2x cos x  2sin x 
f   x    
 x3 

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13 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Let h(x) = –x2 sin x – 2x cos x + 2 sin x


2  
h(x) = –x cos x = –ve for x   0, 
 2
   
 h(x) is decreasing function for x   0,  ; h(x) < h(0) for x   0, 
 2  2
2  
 –x sin x – 2x cos x + 2 sin x < 0  x   0, 
 2
   
 f(x) < 0  x   0,   f(x) is concave down on  0, 
 2  2
 
 for any x1, x2, x3   0, 
 2
 x  x 2  x3 
f  x1   f  x 2   f  x 3 
We can write f  1 
 3  3
x1 = A. x2 = B, x3 = C
 A  B  C  sin A sinB sinC
sin    
 3  A B C
A BC 3
3
9  sin A sinB sinC 9 3  2M  
sin    , M    3 3   5
 3 A B C 2  3 

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