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I

nter
nal
Exami
nat
ion-Physi
cal
Chemi
str
y-I(
Topi
cs– Gaseousst
ate,Li
qui
dst
ateandDi
l
ute
sol
uti
on)

Ti
me:60mi
nut
es Max:30mar
ks

Sect
ionA(
Answeral
lquest
ions)

1
.Def
inecol
l
isi
onnumber

2.Def
ineBoyl
eTemper
atur
e

3.Whatar
ecol
l
igat
ivepr
oper
ti
es?

4.Whatar
eisot
oni
csol
uti
ons?

5.Wr
it
ePoi
seui
l
le’sequat
ionandexpl
aint
het
erms

6.Def
ineebul
l
ioscopi
cconst
ant
. (
6x1=6mar
ks)

Sect
ionB(Answerany3quest
ions)

7.Cal
cul
ateRMSvel
oci
tyofhydr
ogenat0°
C.

8.Cal
culat
et henormal
i
tyandmolar
it
yofanaqueoussol
uti
oncont
aini
ng1
5.5g
ofanhydroussodi
um car
bonat
ein2li
ter
s.

9.Howwi
l
lyoucl
assi
fyagasbasedoni
tscompr
essi
bil
i
tyf
act
or?

1
0.Calcul
atet
heosmoti
cpressureofM aqueoussol
uti
onofanor
gani
csol
uteat
-1 -1
17°
C( R=0.0821
Lat
m K mil) .

1
1.Whati
stheef
fectoft
emper
atur
eonvi
scosi
ty? (
3x2=6mar
ks)

Sect
ionC(
Anserany2quest
ions)

1
2.Def
inecr
it
ical
temper
atur
eofagasandexpl
ainhowi
tcanbedet
ermi
ned.

1
3.Additi
onof0.643gofacompoundt o50mlofbenzene(d=0.879g/ml
)lowers
-1
thefreezi
ngpointf
rom 5.
51°
Ct o5.
03°C.I
fKfofbenzeneis5.12Kkgmol,
calcul
atethemolarmassofthecompound.

1
4.Theabsoluteviscosit
yofwat erat293Kis1.
02X10-3Pascalsec.Ti
met akenby
equal
volumesofwat erandchlor
oformtofl
owthroughacapi l
l
arytubeis40
and15secondsr especti
vel
y.Densit
yofwaterandchlor
oform arer
espectivel
y
1.
02X1 03 and1 .
49X1 03kgm-3.Calcul
atet
heabsol
uteviscosi
tyofchl
oroform.
(2x4=8mar ks)

Sect
ionD(
Answerany1quest
ion)

1
5.Whydor eal
gasesdevi
atefrom i
deal
behavi
our
?Howdi
dvanderWaal
accountf
orthi
sdevi
ati
ons?
1
6.(a)Howdoabnor malmol
ecul
armassesari
se?(b)Howwil
lyoudeter
mine
viscosi
tyofl
i
qui
dusingOst
wald’sviscomet
er? ( 1x1
0=1 0marks)

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