15/07/2020 Chemical Kinetics-Test

NEET- JEE Academy

Chemical Kinetics-Test
15 Jul 2020

1) The rate of a first-order reaction is 0.04 mol l−1 s−1 at 10 6) The given plots represent the variation of the concentration of a
seconds and 0.03 mol l−1 s−1 at 20 seconds after initiation of reactant R with time for two different reactions (i) and (ii). The
the reaction. The half-life period of the reaction is (Given log respective orders of the reactions are
4=0.602 and log 3=0.477)
(1) 54.1 s
(2) 24.1 s
(3) 34.1 s (1) 0, 1

(4) 44.1 s (2) 0, 2

2) The half-life period of a first order reaction is 15 minutes. The (3) 1, 0

amount of substance left after one hour will be:

(4) 1, 1

(1) 1
of the original amount 7) N O2 required for a reaction is produced by the decomposition of
16
N2 O5 in CCl4 as per the equation
(2) 1
of the original amount 2N2 O5 (g) → 4N O2 (g) + O2 (g) The initial concentration of
8
N2 O5 is 3.00 molL −1
and it is 2.75 mol L−1 after 30 minutes the
(3) 1
of the original amount
32
rate of formation of N O2 is
(1)
−3 −1 −1
(4) 1
of the original amount
2.083 × 10 molL min

4
(2) 8.333 × 10
−3
molL
−1
min
−1

3) For the chemical reaction N2 (g) + 3H2 (g) ⇌ 2NH3 (g)

(3) 4.167 × 10
−3
molL
−1
min
−1

the correct option is :

(4) 1.667 × 10
−2
molL
−1
min
−1

(1) 1 d [H2 ] 1 d [NH3 ]

−
3 dt
= −
2 dt
8) During nuclear explosion, one of the products is 90 Sr with half
life of 6.93 years. If 1 μg of 90 Sr was absorbed in the bones of a
(2) d [N2 ] d [NH3 ]
−
dt
= 2
dt
newly born baby in place of Ca, how much time, in years , is
required to reduce it by 90% if it is not lost metabolically______ .
(3) d [N2 ] 1 d [NH3 ]
− =
dt 2 dt (1) 62.32
(4) d [N2 ] d [NH3 ] (2) 15.12
3 = 2
dt dt
(3) 23.03
4) For the reaction, 2A + B→ products, when the concentrations of
(4) 21.02
A and B both wrere doubled, he rate of the reaction increased
9) The reaction 2X → B is a zeroth order reaction. If the initial
from 0.3 mol L−1 s−1 to 2.4 mol L−1 s−1 . When the
concentration of X is 0.2 M, the half-life is 6 h. When the initial
concentration of A alone is doubled, the rate increased from 0.3
concentration of X is 0.5 M, the time required to reach its final
molL−1 s−1 to 0.6 mol L−1 s−1
concentration of 0.2 M will be :-
Which one of the following statements is correct ?
(1) 18.0 h
(1) Order of the reaction with respect to B is 2
(2) 7.2 h
(2) Order of the reaction with respect to A is 2
(3) 9.0 h
(3) Total order of the reaction is 4
(4) 12.0 h
(4) Order of the reaction with respect to B is 1
10) Which one of the following statements, about molecularity of a
5) For the reaction 2A + B → C, the values of initial rate at
reaction, is incorrect ?
different reactant concentrations are given in the table below.
The rate law for the reaction is: (1) It depends on the rate determining step.

[A] (mol L−1 ) [B] (mol L−1 ) Initial Rate(mol L−1 s−1 ) (2) It may be either a whole number or fractional

0.05 0.05 0.045 (3) It is the number of molecules of reactants taking part as
per balanced chemical equation.
0.10 0.05 0.090
0.20 0.10 0.72 (4) It may or may not be equal to the order of reaction

(1) Rate = 2
k[A] [B]
2

(2) Rate = 2
k[A] [B]

(3) Rate = k[A][B]

(4) Rate = k[A][B]

2
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15/07/2020 Chemical Kinetics-Test

11) Some statements are give below 13) For the reaction A + B → products ,it is observed that
A) Molecularity is always a whole number (a) as doubling the concentration of A done rate of reaction
B) Molecularity reveals some basic facts about reaction doubled
mechanism. (B) on doubling the concentration of both A & B rate of reaction
C) Molecularity and order of a reaction is always same. doubled
D) A bimolecular reaction confirms to 1st order kinetics when The rate law for the reactions is
any one reactant is taken in large excess. (1) r = K [A] [B]
Among the above the false statements is/are
(2) r = K [A]
(1) C and D
(3) r = K [B]
(2) A and B
(4) r = K [A]2 [B]
(3) Only C 14) 99% of a first order reaction was completed in 32 min. When
(4) A and C will 99.9% of the reaction be complete?
12) Assertion: Molecularity has no meaning for a complex reaction. (1) 48 min
Reason: The overall molecularity of a complex reaction is equal
(2) 46 min
to the molecularity of the slowest step
(3) 50 min
(1) Both assertion and reason are true and the reason is the
(4) 45 min
correct explanation of the assertion
15) For a first order reaction the time for half change and time for
(2) Both assertion and reason are true but reason is not the
90% change are t1 and t2 respectively. Then the ratio t2 /t1 is
correct explanation of the assertion.
nearly equal to
(3) Assertion is true but reason is false
(1) 1.1
(4) Assertion and reason both are false.
(2) 4.4
(3) 3.3
(4) 2.2