JEE (Advanced) Paper-1

SECTION-I : PHYSICS
PART-A (One or More Than One Correct Type)
This section contains 07 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. Two particles A and B located as shown, start moving simultaneously with

velocities v  4iˆ and vB  4jˆ
(A) the shortest distance between them is (4 2) m
(B) the distance between them first decreases and then increases
(C) the distance between them increases from the beginning
(D) the magnitude of relative velocity of A w.r.t. B is 4 m/s
2. The end B of the rod AB is being pulled with constant velocity v 0 as shown. The length of rod is
 . At the instant depicted in picture.

37°
B v0
4
(A) Velocity of end A is v 0 downwards
3
5 v0
(B) The angular velocity of rod is
3 
(C) The angular velocity of rod will remain constant
(D) Speed of point A is more the speed of point B at the instant.
3. A bimetallic strip is formed by two identical strips, one of copper and the other of brass.
The coefficients of linear expansion of the two metals are and On heating, the temperature of the
C B .
strip goes up by and the strip bends to from an arc of radius of curvature R. Then R is
T
(A) proportional to T (B) inversely proportional to
T
(C) proportional to B  C (D) inversely proportional to B  C
4. A circular cylinder of radius R and height H is filled with water to a height
(2/3)H. It starts rotating about its axis with constantly increasing angular
speed. Choose the correct alternatives.
(A) At all speeds, shape of the free surface is paraboloid.
(B) The free surface touches first the brim of cylinder and then the base H
2
of the cylinder. H
3
(C) The free surface cannot touches the base without spilling water.
(D) The free surface touches the brim as well as base at the same
instant.
5. A particle is suspended by two ideal strings as shown in the figure. Now mass m is given a small
displacement perpendicular to the plane of triangle formed. Choose the correct statement(s).
7l

5l
3 2l

M
3 l
(A) The period of oscillation of the system is 2
g
3l
(B) The period of oscillation of the system is 2
g
(C) The period of oscillation of the system is independent of M
(D) If the distance between the suspension points was kept constant and the length of the strings were
quadrupled then the period of the system will be double
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 –2
6. An open container (2 × 2) base × 2m height half full with water is accelerated at 4 m S up a 15° incline
2
(take g = 10 m/sec ). Choose correct option
(A) water will not spill for given acceleration
–1
(B) at acceleration 7.05 m s the water begin to spill
–1
(C) at acceleration 7.05 m s the water doesn‟t spill
(D) water will spill for given acceleration.
7. For any monoatomic gas the quantities independent of the nature of the gas at the same temperature
is/are :
(A) The number of molecules in one mole
(B) The number of molecules in equal volume and pressure
(C) The translational kinetic energy of one mole
(D) The kinetic energy of unit mass

Part–A : (Single Correct Choice Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

8. Two identical containers A and B having same volume of an ideal gas at the same temperature have mass
of the gas as m A and mB respectively. 2mA = 3mB. The gas in each cylinder expand isothermally to double
its volume. If the change in pressure in A is p , find the change in pressure in B
2 4
(A) 2p (B) 3p (C) p (D) p
3 3
9. Two pulses in a stretched string whose centre are initially 8 cm apart are moving towards each other as
shown in the figure. The speed of each pulse is 2cm/s. After 2 sec, the total energy of the pulses will be :

8 cm
(A) zero (B) purely kinetic
(C) purely potential (D) partly kinetic and partly potential
6
10. At t = 0, a transverse wave pulse in a wire is described by the function y  where x and y are in
x 3
2

meter. the function y(x, t) that describes this wave equation if it is travelling in the positive x direction with a
–1
speed of 4.5 ms is:
6 6 6 6
(A) y  (B) y  (C) y  (D) y 
 x  4.5t   x  4.5t   x  4.5t   x  4.5t 
2 2 2 2
3 3 3 3
11. Two waves represented by,


y1  10sin2000t, y  20sin 2000t 
2 
Are superimposed at any point at a particular instant. The amplitude of the resultant wave is :
(A) 200 (B) 30 (C) 10 5 (D) 10 3
12. The string, the spring and the pulley shown in the figure are light. Find the
time period of the mass m.
m m m
(A) 2 (B) 
k k
k
 m m
(C) (D) 2
2 k 2k
13. Suppose two gases (one mono-atomic and other diatomic) are performing adiabatic process, then which
on is correct.

I
II
P

V
(A) i mono atomic and ii diatomic (B) ii mono atomic and i diatomic
(C) both are monoatomic (D) both are diatomic
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 Part – B Numerical based questions

This section contains 5 questions. The answer to each question may be positive or negative numbers
or decimals (e.g. 6.25, 7.00, -0.33, 30.27, -127.30)..

1. A particle executes simple harmonic motion about the point x = 0. At time t = 0 it has displacement x = 2
–1
cm and zero velocity. If the frequency of motion is 0.25 sec . The angular frequency of the particle is
2. A calorimeter contains 50 g of water at 50°C. The temperature falls to 45°C in 10 minutes. When the
calorimeter contains 100 g of water at 50°C, it takes 18 minutes for the temperature to become 45°C. then
the water equivalent of the calorimeter is : (Assume rate of heat transfer to be constant)
1
3. The amplitude of a wave disturbance propagating in the positive x–direction is given by y at t = 0
1  x2
1
and y at t = 2s, where x and y are in meter. Assuming that the shape of the wave
2  x2
disturbance does not change during the propagation, the speed (in m/s) of the wave is

4. The extension in a string, obeying Hooke‟s law, is x. The speed of sound in the stretched string is v. If
the extension in the string is increased to 1.5 x, the speed (in v) of sound will be
5. A 1.00 × 10–20kg particle is vibrating with simple harmonic motion with a period of 1.00 ×10 –5 sec and a
maximum speed of 1.00 × 103m/s. The maximum displacement of the particle is (in mm)

SECTION-II : CHEMISTRY
PART-A (One or More Than One Correct Type)
This section contains 07 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. A sigma bond is formed by overlap of 2 atomic orbitals of atoms A and B. If the bond formed is along the x-
axis, which of the following overlaps is/are acceptable ?
(A) s orbital of A and Pz of B (B) Px of A and Px of B
(C) s of A and Px of B (D) Px of A and s of B
2. Which of the following values of gas constant R is/are correct?
4 o +19 o
(A) 6.24 × 10 mL – mm/ C mole (B) 5.28 × 10 eV / C mole
o o
(C) 0.02 Kcal / C mole (D) 8.21 mL-atm / C mole

3.
NBS
CH 2 - CH = CH 2   Products
Light

The monobromo product(s) formed in the above reaction is/are:

Br Br
(A) CH - CH = CH 2 (B) CH2 - CH - CH 3

Br

(C) CH = CH - CH 2 - Br (D)
CH2 - CH = CH 2

4. Hg OCOCH 
 Q  
3 2
NaBH4
2

,H O B H6 ,THF

NaOH, H2O
 P 
Choose correct statement(s) regarding the products(P) and (Q) in the above reaction?
(A) „P‟ is optically active and „Q‟ is optically inactive
(B) Both „P‟ and „Q‟ display geometrical isomerism
(C) „P‟ forms more number of alkenes than „Q‟ upon dehydration reaction with conc.H 2SO4
(D) „P‟ is a secondary alcohol whereas „Q‟ is a tertiary alcohol

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 d  A  1/ 2
5. For the reaction A B , the rate law expression is  K  A  . If initial concentration of A is Ao, which
dt
of the following statements is/are true regarding this reaction?
(A) The plot of A against „t‟ will be linear

(B) The half life period is t1/ 2 

2 
Ao
2 1 
1/ 2
K
(C) The rate of reaction decreases linearly with time
K
(D) The integrated form of rate expression is t  Ao A 
2
o
6. One mole of an ideal monoatomic gas at 27 C expands adiabatically against a constant external pressure
3 3
of 1 atm from a volume of 10 dm to a volume of 20 dm . Identify the correct statements
(A) W = 1013 J (B)  U  1013J
(C)  H  1688J (D) The final temperature achieved is 29.18 K
7. Which of the following is/are the functional isomer(s) of n-butanol(C4H9OH)?
CH3
(A) CH3CH2OCH2CH3 (B) CH 3 - C - OH
CH3
O
(C) CH3OCH2CH2CH3 (D)
CH 3CCH 2CH 3
Part–A : (Single Correct Choice Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
– – – –
8. In polar aprotic solvents, the nucleophilicity of F , Cl , Br , I will follow the order
– – – – – –– – –
(a) F > Cl > Br > I (b) I > Br > Cl > F
– – – – – – – –
(c) Cl > F > Br > I (d) I > F > Br > Cl
9. The number of structural isomers obtained on monochlorination of 2-methylbutane is “x” and out of them
the number of optically active compounds are “y”. The numbers “x” and “y” respectively are:
(A) 4, 4 (B) 5, 2 (C) 4, 2 (D) 5, 3
10. How many optically active compounds are possible in the following reaction?

 Monochlorination   Pr oduct  s 
Cl2 /h


(A) 2 (B) 4 (C) 6 (D) 8

11. On monochlorination of 2 – methylbutane, the total number of chiral compounds formed is
(A) 2 (B) 4 (C) 6 (D) 8
12. In which of the following cases, the hydrogenation reaction is most exothermic?

(A) (B) (C) (D)

13. The correct stability order of the following resonance structure is

   
H2C  N  N H2 C  N  N H2C  N  N H2C  N  N
I II III IV 
(A) (I) > (II) > (IV) > (III) (B) (I) > (III) > (II) > (IV)
(C) (II) > (I) > (III) > (IV) (D) (III) > (I) > (IV) > (II)

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 Part – B Numerical based questions

This section contains 5 questions. The answer to each question may be positive or negative numbers or decimals
(e.g. 6.25, 7.00, -0.33, 30.27, -127.30)..

1. How many geometrical isomer(s) is/are possible for the following compound ?
C2H5CH = CH – CH = CHC2H5
–8
2. The pH of a 10 molar solution of HCl in water is:

 Product  s 
Anhy.AlCl
3.  CH3CHCH2CH2Cl 
3

CH3
How many organic product(s) is/are formed in the above reaction? (Consider stereoisomers)

1/ 2 3/ 2
 1  Z
4. 2s for hydrogen atom =  a  (2  ) e / 2 . Calculate the distance from nucleus where
 4  2  0
 2Zr

n a0 
a radial node for 2s orbital can be observed. .

5. How many maximum number of cyclic isomer(s) is/are possible with formula C 5H10? (consider
stereoisomers)

SECTION-III : MATHEMATICS
PART-A (One or More Than One Correct Type)
This section contains 07 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. In a triangle the lengths of the two larger sides are 10 and 9, respectively. If the angles are in A.P. then the
length of the third side can be
(A) 5  6 (B) 3 3
(C) 5 (D) 5  6
2. In a triangle ABC, the length of the bisector of angle A is A
2 bc sin(A / 2) 2 bc cos(A / 2)
(A) (B)
bc bc c A/2 A/2 b
abc A 4
(C) cosec (D) cosec
2R (b  c) 2 bc 2 B C
D

 
n
3. Let 1 2  xn  yn 2 , where xn, yn are integers, then

(A) x2  2yn   1

n
(B) xn  2yn  xn1  0
(C) x2  2yn  1 (D) yn1  xn yn
4. A party of 6 persons consist of 2 Indians, 2 Americans and 2 Englishmen. The number of ways they sit
such that no two men of same nationality are next to one another
(A) in a row is 240 (B) at a round table is 32
(C) in a row is 120 (D) at a round table is 16
2 1 20
5. In the expansion of (x + 1 + )
x2
21
(A) number of terms = 3 (B) number of terms = 41
38 38
(C) coefficient of x = 40 (D) coefficient of x = 20
6. The number of ways in which candidates A1, A2,….,A10 can be ranked, so that A1 is always above A2 is

10! 10
(A) (B) 8! C2
2
10
(C) 10 P2 (D) C2

Page : 5
 + 1 = 0, then z can be (here  is
3 2 1985 100
7. If z satisfies both the equations z + 2z + 2z + 1 = 0 and z +z
complex cube roof of unity).
(A)  (B) 
2

(C) –1 (D) 1

Part–A : (Single Correct Choice Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

8. The solution set of the inequation is

 2  2
(A) 2n  , 2n   (B) 2n  , 2n  
 3  3
   
(C)  n  , n  – {n} (D)  n  , n 
 3  3
n
If n be a positive integer, then 1  i   1  i   2 cos
n k
9. , where k is equal to
4
n n
(A) 3 (B) 2
2 2
n 1 n
(C) 1 (D)  1
2 2
6 6  z1  z 
10. If z1, z2, z3 are any three roots of the equation z = (z + 1) , then arg can be equal to
z  
2

  
(A) 0 (B) (C) (D) 
2 4 4
11. The number of selection of four letters taken from the word COLLEGE must be
(A) 22
(B) 20
(C) Coefficient of in the expansion of (1  x  x2 )2 (1  x)3
(D) 32
x the value of a  b c is always greater than
2
12. cos2 2x  cos
If a, b, c and d are the sides of a quadrilateral,
2
then
d2

1
(A) (B) 1
3
(C) 2 (D) none of these

2
  1 xn
n
x2
13. n

The coefficient of x in 1 x    ....  is
 2! 3! n!

 n   2 
n n

(A) (B)
n! n!
1 1
(C) (D) 
n! n!
2 2

Page : 6
 Part – B Numerical based questions

This section contains 5 questions. The answer to each question may be positive or negative numbers
or decimals (e.g. 6.25, 7.00, -0.33, 30.27, -127.30)..
3 2
1. If are the roots of x – 3x + 3x + 7 = 0 and w is a complex cube root of unity, then
1  1  1  1
 is _______
4  1  1  1
6
 5
2. The remainder when   20 C2k 1 is divided by 11 is
 k 1
sin  sin3 sin9  K
3. If K1 = tan27θ – tanθ and K2 =  then the value of 2 is
cos3 cos9 cos 27  K1
 21
4. Let „a‟ be the number of values of x satisfying 2sinx - 42 cos x  6 in x   0, then the value of a/4 is
 2
______.
, , 
5. If x + y + z = 10, where x, y, z  N. Let „a‟ be the number of solutions of unordered triplet (x, y, z) such that
no two variables are equal then the value of a/5 is _________.

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