coordinating

Intro
ligands
TUPAC Nonring
Isomerism

Bonding
or
Werner BIFT
Theory rat Band Crystal
They field Theory

HEY two

of Acid mite Base

Substance which is formed by kin

All of the constituents

Gives their identical inte

men
EMEI Afd

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salt which consists of 20h more than 2 compounded

kzsoy.AM 4 3.24t

They gives test of all the constituent Particles

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forks tire

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definate identity in solid state but loses its identity

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when dissolved

solid
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s
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some
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entities

which have their definate identity in Id as well as

insly

does not Give identification

test of all of its constituents
It

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43155 soil
 Ahsou.zuthp
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central Atm

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of the d block cations

And
are
most
cations
good complex forming
Because they have
Small size
y
high charge density
presence of vacant orbitals of low E

Emison
mfs
ligand
species union
donates UP air to metal is called asgard
the atom which donates lone Pair is called as
I ligand
donar Atom

Uassificationofligands
 ontheBasisofchange

cationicligand

Nth nth Hydrazinium

nitrosonium
Not
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of dioxygenium

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of
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mon

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Flexidentateligand
ligands which shows flexible denticity
are called as
flexidentate
 soit Generally
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friendssoy ee CE rs soda
NB

NB
with

NB Bidentate
Mong

me EDTA 2052 no poi

Ambidentate
which have more
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of donor sites
the bonded by using only one

can be
but it at a time
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 NOT nitrite nitwit
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f
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nitrito

which of the following are

Ambidentate
f
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2052
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Chelatingligards
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when any multi
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a
Ray like structure
which is called as
chelatching
and ligand is called as chelating ligand

gym
thy All multidurtate
Had a

mnI chdationutff

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 DG AH T5

FEE
of complexcompounds is compared by
Stability
their formation constants
the value of formation
const Gerety is
highs is

the stability of complex

it is observed that
most of the
Practically more stable than
chelating complexes
are relatively
Non chelating ligands
favour chatty
Bucz thermodynamic factor entropy
called as chelating effect
This Effect is called

A
F
win oh

value of formation
cost form
formation
identification
const and gives
test of all

and does not Give test of of its constituents

its constituents
Kt
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 0550 Kafana

Name of
name of ion in
in Name of ligands None of Ors of metal
ionisation
in Alphabetical metal in Roman no
in
in the
sphere Yonder Bracket
41.7
It D
ligand

Amice rented
cate
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turn
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yungstfag.ae
ite ito
NB Ammine

I co carbonyl
Itnstiontroz
no nitrosyl

use di tri tetra Penta taxa with the name of ligands

Nts a diammina
 nameof ligand
if already includes di tri ete

Bis
This

tetany
p

Do not use Di tri Bis this in comparing

alphabetical ord y

3 tutte o

It ou

tri oxalate Aluminate II

potassium

asia
Inn EchozÉdy beatnioeynato

Ammonium diaquatethathioumatoFerreted

L th to 4 0

2 0
n to

Pten ch
II chloride
bis EthylamediammingPlatinum
 Se 3 M 2

Ti th t 3 Y ed 2

t
V tr to s ly
and pt
2 4
at 3 I 2
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th th 7 ly
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ni
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 someone
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ligands

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iron a tetra ammine iron ion
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coordination Position
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Jochem

fo nasty sod d fo NB a soy

L
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molecular formula But Produces

some
2 complexas having
ions on
ionisation
different isomers of Each other
Those are ionisation
measurements or
can be distinguished by conductivity
Precipitation Ray
 Pt Ints eh Blu CPAs Beda

gÉiÉYÉ amply of which have Ambidentate ligands

MF
Two linkage isomers have
some

with central Natal

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are distinguished

by their
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f ok
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hydrator's m schisms m

some M F But different watch of crystallisation

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They are differentiated by Precipitation meatnod
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 ekeb
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coordinationisomerism t
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fr Ints er 13413 X X
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assisting
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find co
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143
am

ligandisomerism
 NB
NB
nm
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are not actual Isomers

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are identical in tetrahedral

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so tetrahedral complexdoes not show GI

CarusePlanal

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k
what is the shape of
complex
a
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either sqPlanalorode
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ay
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when tetrahedral complex have
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find total
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is Active But
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it

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 157

7014150.130L

Exist in 2
different stereo isomerictoys

1
Ni EDTA
q

EAT
affection
attracted by control metal in
of é which
are
Total no

the Given complex is called

as
Effective Atomics

SAID Atomic No o s t z en

Kutalent
if
u n o o 12 2

2 6 2 E I
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him
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31

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30
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felt I
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Wernestheony Everymetal has a valencies and every metal
has a tendency to satisfy Both of its valencies

MinEEnyunwny at
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Non ionisable
iarisably
Directional
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tool
N 6 4

lock bulb A3 3 not Ayat

N te

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5 NB
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 NB

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or

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NB

Mfrs
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valaureBond Theory I

V BT Explains the formation of coordination compounds

hidden and King
the concept of
by

In the formation of coordination compound Motors

electronsof
vaccaut orbitals for Bonding Because Both the

amend animal
BN DM
 Ist identify the central metal in the complex

write the E configuration of metal and then of its ion

electrons will show Backfiring if is

present studlijad
metal Acc too
Arrange the vacant
orbitals on

vacant orbitals undergoes hybridisation to arrange

themselves for minimumrepulsion

hybrid orbitals overlaps with lone pail containing orbitals of

lizards

write the Geometry of complex Acc to the hybridisation

complex will be Paramagnetic if it has unpaired I

magnetic moment of complex is calculated by

MFtDB
 en
Py EDTA

E ci Bi I
WO

UX 3d

306

EMIRATI

sped
fix
2
s SBd
octahedral
orbital Mnd 0M
outa paramagnetic
low
him M Tty BM
 outa orbital

Hint
us ur s

inner

rid
27 3
I
3d

II
500
3d Us up

desB xxxxxxx die

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inner orbital
lowspin
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I in 5 Riad rest

308

do

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high
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 died
452 308

FETE E

Dixit
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slow spin

I
dsps inn
and
spade onto
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26
Fe

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inner
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En if
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tetrahedral

eat n 3
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 6
to UX 307
3d

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31

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para
metalimwitnontguration
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High
spade
outcome
Oda

insf ceystalfieldfroly
4
 It Explains Properties of coordination compounds

by considering electrostatic interaction btw

metal tar and ligand

Aec to CFT central metal is surrounded

by
suitable no of ligands which contains lonePains_

Acc to Control metal is considered as Pointtivechange

Cft
and Anionic ligands are considered as point Livechange

it
É
Yodo
i
1
t
metal in daydyed on splitting
spherical
ligand

d orbital
field tired
of metal
in Absenceof
lizard field
I
 tf

E
btw d orbitals is called as Crystal field splitting
O Tu E difference
Reason of BackPairing By
the concept of
the
O CFT Explains
Hand PairingEnergy
PE é show BackPairings
if CFSE

a PE é does not show Back Pairing

if FSE

trig ego
du tugegg tag is
dz
dy iT
3
d5 tugs egg
96 tug eg tug ego
da tag eg
d8 tug est
da tug eg tug eg
1ai
Colourationinwordination compounds

Tibet

IIItcomumentroy
matt

Comp Comp2 Comps

B G
Voint
OR
dr
Try to
so or
or

E contra comp Comps

hh

jfÉ no en parents 615 Edta

 on tho evil y on F No52 yet
5 Bit 5

compounds is Explained by CFT

colouration of coordination
the concept of d
d transition
by correspondingto
and egg orbitals is
Energy diff
btw Tag
The complex absorbs
so that
suitable light of visible rage
any transition d d transit
visible light for Ig to ez electronic

and a complimentary
colour is shown by ligand

spectrochemical
And Relative strength of lizards is compared by
A chin

sÉÉ
dig del
D itVy di

Eff Aah
Ddny

A No
Dan
dry dye den
D
due

omfg
attach
 I takes
M case of sq Planar ligand field BackPairing Always
Place Because
oflangevalueofts
Tethahedralstlitting's

F É

t o
t
Aya
bed
drip dot doublydegenerate

Due to very low Value of CFSE Back Pairing is generally not

observed in tetrahedral complex

FactorsoffectifE

Edt
FOEL O.state
Os ti 2 3
I If
will work as
3d o s 3 Everyligand
AE

4th 3d D

f ggy.CO
t
5th yd s

on sa 2 25 D

2nd and sd selfies elements

every ligand
will work as
stray field ligand

Now metal can interact with lizard

Jaffa more strongly USE
At

774

pool
Sunday
E Ee J s Ent
N 6 4 n 6 3

ants eats it

X1
odd
dÉ
duty
a Do
a

A
Octa rates
Er Ning Enid

retro

At Do DSP

DSP 1.3 Do

AT Ya Ao

RIBS Giant5
318
SpPlanet
atte

SEE dst
a DX
D
gigginggoing East Ed

27173790
Acc to spectrochemical suries typeof ligand also affects
Ist
CASE Because lizards which are Placed
are

strong field lizards

cations tho acts as

For most of the 3d
weak field ligand
But in Cots it acts
as SFI
lizard for most of the
Nfb acts as stroy field
3d series cations except Fiat