Sri Chaitanya IIT Academy., India.: Key Sheet

Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Jr. Super60 Jee-Main Date: 04-12-2021
Time: 09.00Am to 12.00 WTM-16 Max.Marks:300
Key Sheet
PHYSICS
1 3 2 1 3 3 4 1 5 3
6 2 7 1 8 1 9 2 10 2
11 1 12 4 13 3 14 2 15 1
16 3 17 1 18 1 19 2 20 2
21 8.00 22 0.67 23 15.00 24 6.00 25 25.00
26 3.00 27 3.00 28 3.00 29 7.00 30 1.4
CHEMISTRY
31 1 32 3 33 2 34 2 35 1
36 4 37 4 38 3 39 1 40 3
41 4 42 1 43 1 44 1 45 3
46 4 47 4 48 1 49 4 50 1
51 32.00 52 2.25 53 0.1 54 2.00 55 5.00
56 9.00 57 2.00 58 5.00 59 5.00 60 4.00
MATHEMATICS
61 2 62 2 63 4 64 3 65 1
66 3 67 3 68 3 69 3 70 2
71 3 72 2 73 4 74 3 75 4
76 1 77 4 78 3 79 3 80 3
81 7.00 82 2.00 83 2.00 84 0 85 0
86 0 87 7.00 88 48.00 89 5.00 90 1.00
Sri Chaitanya IIT Academy 04-12-2021_Jr.Super60_Jee-Main_WTM-16_Key & Sol’s
SOLUTIONS
PHYSICS
1. As all the points on the periphery of either ring are at the same distance from point P,
the potential at point P, the potential at point P due to the whole ring can be calculated
 
as V    GM  / R 2  x 2 where x is the axial distance from the centre of the ring. This
expression is independent of the fact whether the distribution of mass is uniform or
non-uniform.
GM G  2 M GM  1 2 
So, at P,V       
2R 5R R  2 5
2. When rotating from east to west
2 2
Wrel  
1.5 24
24
 T1  h
17
Gm Gm L x  x GmL
3. V  ; V  Gm  ; 
At any point x Lx  xL  x  xL  x
V is max at x = L/2
4.
1 2 GMm 1 2 ve2 GM R 2 w2
5. By conservation of energy, mve   m  Rw   0,   ,
2 R 2 2 R 2
2GM
Ve   R 2 w2
R
10 r 2G m
6. Wext   Fdr   dr  2G m ln 10 
r r
7.
Sec: Jr.Super60 Page 2

8. wag   v p  v  m
 GM 2GM 
   m
 r 2a 
9. In the circular motion around the Earth, the centripetal force on the satellite is a
gravitational force. Therefore, v2 = GM /R, where M is the mass of the Earth, R is the
radius of the orbit of satellite and G is the universal gravitational constant. Therefore,
the kinetic energy increases with the decrease in the radius of the orbit. The
gravitational potential energy is negative and decreases with the decrease in radius.
 T   ab 1 
10. t A B      ae  b 
  ab  4 2 
11. Work done will be zero when displacement is perpendicular to the field. The field
1
makes an angle 1  tan 1   with positive x – axis while the line y  4 x  2 makes an
4
angle
2  tan 1  4  With positive x – axis
 1   2  90

i.e., the line y  4 x  2 is perpendicular to E.
12. At any distance ‘r’ from centre of earth, Let the speed of the body be ‘v’ from
conservation of energy
13. Field is maximum at x = R/ 2

GM 2GM 2 2GM
Potential    2;   
 R 
2
3 3R
2
R  R
 2
 2
14. At maximum separation, speeds of two bodies are same.
Conserving the linear momentum
v
2v0  v0  2v1 ; v1  0 ....1
2

15. If the body is just able to reach the point at which the net gravitational field is zero,
then it will reach the other planet.
8R
Let r be the distance from m at which field is zero. r   2R
9M
1
M
Applying conservation of energy
1 2 GMm 9GMm GMm 9GMm
mv    
2 R 7R 2R 6R
4GM
v
7R
2 2 2 2
16. Gravitational pressure inside the earth is P  G   R  r  ,  is density of earth
3
and R is radius of earth.
Substitute r=R/2
17.
v2 gR
18. h  R
v2 2g  g
2g 
R
19.
Conceptual
20.
21. Given V0  Ve
2
1 1
2 2
 GM  1  2GM 
    
 Rh 2 R 
On solving h = R
From law of conservation of energy
GMm 1 2 GMm
  mv 
Rh 2 R
1 2 GMm GMm GMm
mv   
2 R 2R 2R
1
GM
V
R
 gR  10  6.4 106  2

3
 8 10 m / sec  8 km / sec
22.
Equivalent Grauss law,  EdA  4Gm
2Er 2  4G  r 2 t  
E  2  Gt
GM G  4  4GR
E earth  2  2  R 3  
R R  3  3
4R
So t 
6
1 1  2GM  GMm GMm
23. m.  
  
2 4  R  R Rh
R
h
15
24. COAM  mvR = mv1 3R …(i)
v
3R E R
1 GMm 1 GMm v1
COE  mv 2   mv '2  …(ii)
2 R 2 3R
3 GM
 v
2 R
25. The potential energy at depth is given by
GM  2 R2  11GMm
U1  V1m    3R  4  m   8 R
2R3  
GMm
The energy of satellite at a height R/2 is given by E 2  
3R

25GMm
 The work required = E2  U1 =
24 R
26.
1  GM  GMm 3GMm
27. Erequired   mx   
2  2R  R ; 4R
A A A
28. A1  0  0  0
2 4 4
A A 3A t2
A2  0  0  0 t1 
2 4 4 ; 3
29.
30. In the tunnel, motion of the particle is simple harmonic with angular frequency
g g
 . Just before collision, V0  A  R  gR
R R
Just after collision, v  eV0  gR / 5
Let new amplitude be A | , then
v gR / 5 R
A1   
 g/R 5
7R
Net distance  R   R / 5    R / 5  
5
CHEMISTRY
31. N 2O4  2 NO2
Initial 1 0
At equilibrium 1-x 2x
D
So  (1  x )  0
d
32. 2 SO2  O2  2 SO3
Initial 2 1 0
Final 2-2x 1-x 2x
As n   , we can calculate the value of x as 0.5
1 1
So K p  2
1 1 0.5
H

33. K  A'e RT
H 1
Log K = Log A - .
2.303R T
H
So slope =  Tan 45  1
2.303R
H  2.303  2 Cal
34. 2NO2  N 2O4
1 -
1  /2
MI
M eq 
1  ( n  1)
46
60 
1 
1    1 
2 
60  30  46
14

30
 14
No. of moles of N 2O4  
2 60
16 32
No. moles of NO2  
30 60
14 14
X N 2O4  
60 46
14  32
60
35. When both the flasks are connected, the initial partial pressure of both the gases will
change according to the equation : PV 1 1  PV
2 2

For No: 0.46  250  PNO  350  PNO  0.328 atm
For O2 : 0.86  100  PO2  350  PO2  0.246 atm
Now, 2NO O2  2NO2  N 2O4
Initial par. 0.328 – 0.328 0.246 atm 0 0
Pressure
Final par 0.3328 – 0.328 0.246 – 0.164 (0.328 – 2x) atm x atm
Pressure =0 = 0.082 atm
No is limiting reagent for the first reaction
From question, total final pressure = 0.37 atm
Or. 0.082 + (0.328 – 2x) + x = 0.37
Or x = 0.04
P x 0.04
Now, K p K p for the equilibrium reaction  N2 2O4  2

P NO2 (0.328  2 x) (0.328  2  0.04) 2
 0.65 atm 1
36. A  nB
0.6 0
0.6-x nx
From the diagram at equilibrium
( B)  nx  0.6 and [ A]  0.6  x  0.3
So n = 2 and x = 0.3
[ B]2 0.6  0.6
KC    1.2
[ A] 0.3
37. Conceptual
38. Conceptual
39. oG  2.303 RT logK
40. A( s )  B( g )  C( g )
P1 P1 x  P1 ( P1  P2 ).........(1)
D( s)  C( g )  E ( g ) K P2  y  PC .PE
P2 P2 y  ( P1  P2 )( P2 )...........(2)
Adding 1 and 2
X + y = ( P1  P2 ) 2
Now total pressure
PT  PC  PB  PE
 ( P1  P2 )  P1  P2  2( P1  P2 )
PT  2( x  y )
41. NH 4 HS( s )  NH 3( g )  H 2 S( g )
0.1 mol 0 0
0.1 (1   ) 0.1 0.1
  0.03
0.06  0.082  600
P  0.984 atm
3
0.984
PH 2S  PNH 3   0.492
2
K P  PNH3 .PH 2S  0.492  0.492  0.242 atm 2
K P  0.242
42. Equilibrium T  320
Above 320k forward reaction is favour.
below 320k backward reaction is favour.
43. Conceptual
44. Conceptual
45. N 2 ( g )  3H 2 ( g )  2 NH 3 ( g )
Initial moles 1 2 0
At eqm 1–x 2 – 3x 2x
Where x = 0.5
2
1
 
KC  4  256
3
 0.5  0.5 
  
 4  4 
Equilibrium constant for the reaction
1 3
NH 3 ( g ) N 2 ( g )  H 2 ( g )
2 2
1 1
KC1  
KC 16
46. LiCl.3 NH 3 ( s )  LiCl.NH 3 ( s )  2 NH 3 ( g ) ;
[ K P  9 atm 2 ]
Therefore,
LiCl . NH 3 ( s )  2 NH 3 ( g )  LiCl .3 NH 3 ( s );
Initial moles 0.1 a 0
Final moles at eqm 0 (a – 0.2) 0.1
 1 2 
 K 'P  9 ( atm ) 
Let initial moles of NH 3 is a for completion of reaction
1 1 1
At eqm K 'P  2
or 
( P ' NH3 ) 9 ( P ' NH3 ) 2
 P ' NH3  3 atm
 PV  nRT  3  5  n  0.0820  310
 n  0.59 i.e., (a  0.2)  0.59
 initial moles of NH 3  0.79
47. 6HCHO  C16 H 12O6
C
Conc. At eqm C (1   )
6

Oserved moles concentration M T
=
Initial moles concentration MO
M T = Theoretical molar mass of HCHO
C
C (1   ) 
6  M T  30
C M O 150
   0.96
48. 2 A( g )  B( g )  C( g )  D( g )
Initial moles 1 1 7 3
At eqm 2 – 2x 1- x 7+x 3+x
Due to very high value of KC we can assume that reactant almost converted into
products so
1  x  y ; 2  2x  2 y  x  1
8 4
1012 
(2 y ) 2 y
 y 3  8  1012
 equilibrium concentration of
A  2 y  4  104
rmix M SO2
49. 
rSO2 M mix
64
 2.56 
M mix
 M mixture  25
Let mole fraction of F2 is x
38  x  (1  x)  19
25 
1
x  0.315 ;
P 2 (0.685 P ) 2
 KP  F   1.49 atm
PF2 (0.315 P )
50. Go  H o  T S o
 RT lnk  H o  T S o
S o
2
R
51. Ptotal  PHNO3  PNO2  PH 2O  PO2
 PNO2  4 PO2 and PH 2O  2 PO2
 Ptotal  PHNO3  7 PO2
 30  2  PO2  7
28
 PO2  4
7

4
PNO .PH 2O .PO2
KP  2
4
PHNO3
(4  4) 4  (2  4) 2  4
 4
 220
2

K P  K C ( RT ) ng  K C (0.08  400)3
220
 KC   32
(32)3
52. 2 NOBr ( g )  2 NO ( g )  Br2 ( g )
Initial pressure P 0 0
At eqm P – 2x 2x x
Where 2 x  0.40 P
 x  0.20 P;
 1.20 P  6
 P  5 atm
2
PNO .PBr2 2 2  1
KP  2
 2
PNOBr 3
 KP for the reaction
2 NO ( g )  Br2 ( g )  2 NOBr ( g )
32
Is  2.25
22
53. 2 SO3 ( g )  2 SO2 ( g )  O2 ( g )
Moles at eqm 1 – 2x 2x x
Only SO2 will oxidized
So equivalent of SO2 = equivalent of KMnO4
2 x  2  0.2  5
 2 x  0.5
2
 0.5   0.25 
   
 2   2 
KC  2
 0.125
 0.5 
 
 2 
54. A( s )  B( g )  2C( g )
B and C produced in 2:1 ratio so, then partial pressures are P and 2P
K P  4 P3
P2
55. D C 100
CB 1/ 2
1
B A
10
D A KC  5
56. SO2  NO2  SO3  NO
3 4 1 4
3-2 4-2 1+2 4+2
1 2 3 6
63
KC   9 K P  KC
2
KP  9
57. 2HI  H 2  I 2
1 - -
1–0.8 0.4 0.4
0.4  0.4
KC  4
(0.2)2
H 2  I 2  2 HI
2 2 -
2-x 2-x 2x
2
1 (2 x)

4 (2  x)2
1 2x

2 2 x
2  x  4x
x  0.4
Iodine left in the vessel = 2 – 0.4 = 1.6
No. of eq.w I2 = no. of eq Na2S2O3
1.6  2  V  1.6  1
V  2 Lit
58. Ag   Fe 2  Fe 3  Ag
500x0.9 500x1
450 500 - -
450-x 500-x x x
(500  x)
 30  25  0.06  5
1000
x  250
[ Ag  ]  0.2
[ Fe 2 ]  0.25
[ Fe 3 ]  0.25
0.25
KC  5
0.2  0.25
59. nCO2  nCaCO3 require
nCO2  [CO2 ]  V  0.05
wCaCO3  n  100
= 0.05 x 100 = 5g

60. H 2  I 2  2 HI
1 3
x x
1 3 x
2 2
4 x2
KC 
(2  x)(6  x)
H 2  I 2  2 HI
3 3
3  x 3  x 2x
4 x2
KC 
(3  x)2
4 x2 4 x2

(12  8 x  x 2 ) 9  6 x  x 2
12  8x  x2  9  6x  x2
2 x  3 , x  1.5
4  (1.5)2
KC  4
(3  1.5)2
MATHEMATICS
61. r b b r b .b  0  r .b
= r .b  b  b .b  r  0  r .b
 0r
62.       a  d   0
GE  d . a c d  b  a . b c  d  d . b a d  c  b .c
 a c d  d .b  b a d  d .c  0
   
  
  
  
a c d  d .b  a b d  d .c
 d .b  d .c    d. b  c  0
d b c
63. d  1  GE max  pmax  qmax  3 2  2  4 2
1 2 1
abc   2 1 2 =  1  2 0  11  0 ( a , b , c are coplanar)
 
1 1 1
i j k
pmax  1 2 1  909  3 2
2 1 2
i j k
qmax  2 1 2  1  0 1  2
1 1 1
2
64. GE  2 a b a b   2 a  b  2 4  4  1  18

65.  a b c   0
x2  x  6  0
   
66. Value =  a b c   b c a   c a b   3  a b c   3  4   12
a.a a.b a.c
2
67.  abc   b.a b.b b.c
 
c.a c.b c.c
1 3
1
2 2
1 1
 1
2 2
3 1
1
2 2
2 3 1 2 32 2
  
4 2 2 4 2
3 2

2 2
2
68.  a b c 
2
  
 a b sin .cos 0 
 3 
3 2
  a1  a22  a32  b12  b22  b32 
4
 
    
69. r = ( a × b ) sin x + ( b × c ) cos y + 2 ( c × a )

  
r . (a + b + c) = 0

 [a b c] ( sin x + cos y + 2) = 0

[a b c]  0  sin x + cos y = –2
this is possible only when sin x = – 1 and cos y = –1
for x2 + y2 to be minimum x = –  and y = 
2
5 2
 minimum value of (x2 + y2 ) is = 2 + 2=
4 4

70. AB equation r  a  s b  a  
Also a  s b  a .b  a   0
2
 a. b  a  s b  a  0
 
a. b  a
s  2
b a
a. b  a  b  a 
 Foot  a  2
b a


 a. b  a
 1  2
  a   a.b  a  b
2
 b  a   b a 
   
    1
71. Equation of plane containing the line
  
r  a  kb
And

perpendicular to the plane
r .n  q
72. Equation of line joining
  
73.  a  2b  3c  . b  2c  3a    c  2a  3b   36
    
  a  2b  3c  .b  c  3a  c  2b  a  4c  a  6c  b  9a  b   36

 18a.  b  c   36

 a.  b  c   2
  
a.a a.b a.c
      2
Also a.b b .b b .c   a , b , c   2 2  4
  
a.c c .b c .c
2 2 2   
74.   
 2 a  b  c  2 a.b  b.c  c.a  9 
      3
a.b  b.c  c.a 
2
  2 2 2 2   
a  b  c  a  b  c  2 a.b  b.c  c.a  0  
    
 
 2a  5 b  c  2a  5a  3

       2
75. b  c  a  a b c   a.a  a
 
   2 2
Similarly a b c   b  c
 
     
 a  b  c  a b c 
 
        2
Now b  c c  a a  b   a b c 
   
     2
 a b c   a b c 
   
  
But a b c   0
 
   
So a b c   1
 
  
Hence a  b  c  1

76. Let r  xiˆ  yjˆ  zkˆ
So, 2y  z  0, 5x 12y  1, 3x  4z  2
7
Solving, z 
2

77. Angle between the line and normal to the plane  
2
1 
 Angle between i  2 j  k ,
3
i  3 j  k  is  
2
1  6 1 6
cos 900      sin  
6 11 11

78. Given plane passes through a & b containing the line is

 AP AB c   0
 
  
 r  a   b  a  c  0
 r  b  c  c  a   a b c 
a b c 
length of  r from the origin 
b c  c a
  
79.  a  b   c  d     a  d   0,
       
   acd  b  bcd  a    a  d   0
    
  acd  bad   0
   
 either c and b must lie in the plane of a and d .
     
80. considers OABC, OA   , OB   , OC  
And OA, BC as a pair of opposite edges.
 
OA  a , BC  b
 
Equation of OA  r  O  t 

  
Equation of BC is r    s     
    abd sin 
d V
    sin  6
81. d  x b  c  y c  a   z a  b
   
d .a
x etc…….
a b c 
 
11 19 4
x , y , z
5 5 5
1 34
GE   7
5 5
82. a . c  b  a .b c  a .c  b  b . c a
   
 a .b  c  b .c  a  a || c    2
 c  2a 
O
A a
a
3
83. B C
2
 a 2 2
Side =a, height = a     a
 3 3
2
 height  62
3
84. c  a b
 a b  c  0
 a b c   0
85. Let p  q  r
 a  b  c  b c  a   c  a b
   
 a .c  b  a .b  c b .a  c  b .c  a  c .a   c .a  b  0
 GE  123 p q r   c 0  0

86. taking dot product with a  abc   p  q cos   r cos     (1)

taking dot product with c  abc   p cos   q cos   r    (2)
From (1) and (2) p  r .

87. The distance of the point ‘a’ from the plane r.n  q measured in the direction of the unit
 
q  a .n
vector b is  

b.n
 
Here a  i  2j  3k,
 n  i  j  k and q = 5

2i  3j  6k 2i  3j  6k
Also b  
 2  2   3 2   6  2 7
 The required distance

5  i  2j  3k . i  j  k
  

1  
7
 2i  3j  6k .i  j  k 
5  1  2  3
7
1
 2  3  6 
7
      
88.      
a  a  b  a.b a  a.a b
2
= a b
Continuing in the same manner
   2
C  a   a   a b 
  
 2
 a
2
 a b 
4
 a b
 4 
C  a b  2 4  3  48
  
89. a  b  1.a.b  0
          
    
Let p  a  b  a  2b  a  b  a  2 a  b  b   
 2      2  
   
= a b  ab a  2 ab b  2 b a  b  2a
    2
 
 2a  b . p  2 a  b  5
90.    2  cos ec  1

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Sri Chaitanya IIT Academy., India.: Key Sheet

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Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

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13. Field is maximum at x = R/ 2

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 The required distance

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