SURYADATTA NATIONAL SCHOOL

A.Y. 2022- 23
STANDARD XII CHEMISTRY JOURNAL

INDEX
EXPT TITLE OF EXPERIMENT DATE PAGE NO
NO
6 To identify the functional group present in given organic
sample (A)
7 To identify the functional group present in given organic
sample (B)
8 To identify the functional group present in given organic
sample (C)
9 To identify the functional group present in given organic
sample (D)
10 To identify the functional group present in given organic
sample (E)
TEST FOR FUNCTIONAL GROUP

EXPERIMENT NO 6

AIM : To identify the functional group present in given organic sample (A)

OBSERVATION TABLE :

EXPERIMENT OBSERVATION INFERENCE

TEST FOR UNSATURATION :

Dissolve organic compound in No observation Unsaturation absent.

2 ml of CCl4 then add bromine
water dropwise

TEST FOR CARBOXYL GROUP:

Take given compound in dry Effervescence of CO2 Carboxyl group is present.

test tube. Add a pinch of
sodium Bicarbonate Na2HCO3

EQUATION : WRITE IT FROM TEXT BOOK.

RESULT :

The given organic compound contains Carboxyl functional group.

EXPERIMENT NO 7

AIM : To identify the functional group present in given organic sample (B)

OBSERVATION TABLE :

EXPERIMENT OBSERVATION INFERENCE

TEST FOR UNSATURATION :

Dissolve organic compound in No observation Unsaturation absent.

2 ml of CCl4 then add bromine
water dropwise

TEST FOR CARBOXYL GROUP:

Take given compound in dry No effervescence of CO2 Carboxyl group is absent.

test tube. Add a pinch of
sodium Bicarbonate Na2HCO3

TEST FOR PHENOLIC GROUP :

Take given compound in dry Violet green colour Phenolic group is present.
test tube. Add 2 ml alcohol. obtained
Shake well. Then add 2-3 ml
neutral FeCl3

EQUATION : WRITE IT FROM TEXT BOOK.

RESULT :

The given organic compound contains Phenolic functional group.

EXPERIMENT NO 8

AIM : To identify the functional group present in given organic sample (C)

OBSERVATION TABLE :

EXPERIMENT OBSERVATION INFERENCE

TEST FOR UNSATURATION :

Dissolve organic compound in 2 No observation Unsaturation absent.

ml of CCl4 then add bromine
water dropwise

TEST FOR CARBOXYL GROUP:

Take given compound in dry test No effervescence of CO2 Carboxyl group is absent.
tube. Add a pinch of sodium
Bicarbonate Na2HCO3

TEST FOR PHENOLIC GROUP :

Take given compound in dry test No observation Phenolic group is absent.

tube. Add 2 ml alcohol. Shake
well. Then add 2-3 ml neutral
FeCl3

TEST FOR CARBONYL GROUP :

(1) Take given compound in dry Orange-yellow colour

test tube. Add 2,4 dinitrophenyl ppt is observed.
Carbonyl group is present.
hydrazine. Shake well.

(2) Take given compound in dry

test tube. Add 1 ml NaOH and 2
ml sodium nitroprusside solution. Red colour is observed.
Shake well

EQUATION : WRITE IT FROM TEXT BOOK.

RESULT : The given organic compound contains Carbonyl functional group.

EXPERIMENT NO 9

AIM : To identify the functional group present in given organic sample (D)

OBSERVATION TABLE :

EXPERIMENT OBSERVATION INFERENCE

TEST FOR UNSATURATION :

Dissolve organic compound in 2 No observation Unsaturation absent.

ml of CCl4 then add bromine
water dropwise

TEST FOR CARBOXYL GROUP:

Take given compound in dry test No effervescence of CO2 Carboxyl group is absent.
tube. Add a pinch of sodium
Bicarbonate Na2HCO3

TEST FOR PHENOLIC GROUP :

Take given compound in dry test No observation Phenolic group is absent.

tube. Add 2 ml alcohol. Shake
well. Then add 2-3 ml neutral
FeCl3

TEST FOR CARBONYL GROUP :

(1) Take given compound in dry

test tube. Add 2,4 dinitrophenyl
No observation Carbonyl group is absent.
hydrazine. Shake well.

(2) Take given compound in dry

test tube. Add 1 ml NaOH and 2
ml sodium nitroprusside solution.
Shake well

TEST FOR ALDEHYDE GROUP

Take small amount of given Appearance of silver Aldehyde group is present.

organic compound in a dry test mirror on the sides of
tube. Add 1 ml of Tollen’s the test tube.
reagent. Keep the test tube in
water bath for 2-3 minutes.

EQUATION : WRITE IT FROM TEXT BOOK.

RESULT : The given organic compound contains Aldehyde functional group

EXPERIMENT NO 10

AIM : To identify the functional group present in given organic sample (E)

OBSERVATION TABLE :

EXPERIMENT OBSERVATION INFERENCE

TEST FOR UNSATURATION :

Dissolve organic compound in 2 No observation Unsaturation absent.

ml of CCl4 then add bromine
water dropwise

TEST FOR CARBOXYL GROUP:

Take given compound in dry test No effervescence of CO2 Carboxyl group is absent.
tube. Add a pinch of sodium
Bicarbonate Na2HCO3

TEST FOR PHENOLIC GROUP :

Take given compound in dry test No observation Phenolic group is absent.

tube. Add 2 ml alcohol. Shake
well. Then add 2-3 ml neutral
FeCl3

TEST FOR BASE

Take small amount of given Soluble Base is present.

organic compound and add dilute
HCl to it

TEST FOR AMINO GROUP :

Take small amount of given

organic compound in a dry test
Orange or red dye is Amino group is present.
tube. Add 1ml of dil.HCl. Cool the
obtained
solution. Add 2 ml 10% aqueous
NaNO2 solution to it. Shake well.
Add 2 ml alkaline solution of β-
napthol.

EQUATION : WRITE IT FROM TEXT BOOK.

RESULT : The given organic compound contains Amino functional group.

Note: you can refer following link for equations and additional information
http://amrita.olabs.edu.in/?sub=73&brch=8&sim=141&cnt=1