Page 1 of 3

HESS'S LAW
( Part - VI )
Date /-

Hes's law donotent heat Aummaton faleoctan

uied Out anone
Atep on Mmultiple atehs dhen he change in_en-halpy n-
bolh the ves e
wie_ the same _paawickdhoet he intual
Nd ina utea _Mahe2ame in_ both Cones Th HeMn_
Kaw.
e an
be bepaned _cnomnban two aay
7 n
i_inedt oudaton dcto O
Cy+9 (a) Co CI); 9H,=
) dint uded to Co and then_ Co uda
do Co
CO+ Cg) Co Cg) h=y

C()dC) 44A=yiz
Ihen aecondina Hed,ow

4H= 4h +4
Theomodynamà euslenaton d ten'a la Bs enthalb
astute cnttzon.ate-
Change(OH) dependn an o the inctal atate ond cenal 2tedtr
T meann thast dhe changg
in enthalb daes nat depend on He
num.be ptenmediodee otegen h a
neactton Theneiane, fa
locacticn a
camued aut by a maresn inaokasn ane
by o nacesn naoKaina
atep on
Tuhe
aleba hhamg
erthaC th
an bethe_Aame mUeithen copet

Thermodynamics
Class - XI
 Page 2 of 3
HESS'S LAW
( Part - VI )
Date SUULr
I-
Appkicatina 4he_Hem ndar

of the hecta oP somotionothecompounda.uhas

Caleukation
hea tamatiencnnet be detamned dinectki The onmactien
many_cmmbardy
of
ucch o
CH4(g)GHLgGHsoH(A)fnon hea comtltucnt
ekementn paaetineR mpoaihle Sa Ge canduaectk detomune
-he hearn canoon ese compau
indinectly b apbing tHenlakas
Howeoen
e/can:/ da a
e Detenmncxtaon ndandReat nmazon GH 4
nom the qouinq insasmoataèn

GHC) 4
2 0) 20 (a) +Ho(2), GH-130okJ.
CO)+O (3) C, C8)
4H=- 393.5 kT.,
H2C3) t (9) Ho( H°= -285 8 k
L
Keienana e2 aget=-

Ond
mutibk e
2C C) 20 () 22C3) H°=287K
(S)
Adduna e(3), G) nd5we obtoin

2 ) H C3) aH=(-285-3
+
Dince eyuoeon ith feamaen a H 1300 -787)
A Hhe Atandand enthalp feamatien GN t227Ky.
t22 2kT.moR
Page No.

Thermodynamics
Class - XI
 Page 3 of 3
HESS'S LAW
( Part - VI )
Date- -1-

2 Detaminateon_oheat tnanaition2 Ha guscn demp

Cmd phesounethe
occuw
zheatof enthaly change hat ahen 1mekedon alRetnpi
canm Cn ekement sadrdoam nto anothea_donm ealled 4he
heat onanaition
Jñansuton don-e alotndbeè canmto: anutheh pueha damond
ogaapbile a bhambk lphn da monoclitalhn edes
asenloc and OH oey_amalllhenefone t camot be
detem.med expennenca 0 Houeue ue Can detenmne gH
hee Hesn'a Lece

S(monodlini) S(hhombic)

S(monoelen)+O2 So GH°-299-2 k moa'.

LO
S(hombe) F0 5 4H° -29 9 kI mar'.
Ea (2) eC)) te jet
S(mmoclinut) Shombt)4H°=(-29F2
+296 9)
-0 3 T mos
3 Deteminaten d heat Áydnat _ft a qioen femb
and_Þaeauethethe change
40 en-heaccampanng tho snmatzone1moke hydnate faom
the anhydnous onm ho Compaud do caLled Äcots Adstron_
a
4hatanáydau Compeuncg
The eod
dnaetaon_aAalcannor be 'detenmines
dine ctkbut can he deteininedy ppRerngHen'a law
T

Thermodynamics
Class - XI