ENTROPY CHANGE FOR

AN IDEAL GAS
(REVERSIBLE PROCESS)
Mr. Firas M. Younis
MSc Mechanical Engineering

1-) Constant Volume Process

P
1
𝛿𝑄 = 𝑚 𝑐𝑣 𝑑𝑇

𝛿𝑄
𝑑𝑆 =
𝑇 𝑟𝑒𝑣
2

2 2 v
𝛿𝑄
න 𝑑𝑆 = න
1 1 𝑇 T
𝑟𝑒𝑣
1
2
𝑑𝑇
𝑆2 − 𝑆1 = 𝑚 𝑐𝑣 න
1 𝑇 𝑟𝑒𝑣
2
𝑇2
𝑆2 − 𝑆1 = 𝑚 𝑐𝑣 ln
𝑇1
s

1
2-) Constant Pressure Process
P
𝛿𝑄 = 𝑚 𝑐𝑃 𝑑𝑇

𝛿𝑄 2 1
𝑑𝑆 =
𝑇 𝑟𝑒𝑣

2 2 v
𝛿𝑄
න 𝑑𝑆 = න
1 1 𝑇 T
𝑟𝑒𝑣
1
2
𝑑𝑇
𝑆2 − 𝑆1 = 𝑚 𝑐𝑃 න
1 𝑇 𝑟𝑒𝑣
2
𝑇2
𝑆2 − 𝑆1 = 𝑚 𝑐𝑃 ln
𝑇1
s

3-) Isothermal Process

𝑉2 𝑉2 P
𝑄 = 𝑃𝑉 ln 𝑄 = 𝑚𝑅𝑇 ln
𝑉1 𝑉1
2
𝛿𝑄
𝑑𝑆 =
𝑇 𝑟𝑒𝑣
1
2 2
න 𝛿𝑄 = 𝑇 න 𝑑𝑠 v
1 1
T
𝑄 = 𝑇 (𝑆2 − 𝑆1 )
𝑉2
𝑇 𝑆2 − 𝑆1 = 𝑚𝑅𝑇 ln 2 1
𝑉1
𝑉2 𝑃1
𝑆2 − 𝑆1 = 𝑚𝑅 ln = 𝑚𝑅 ln
𝑉1 𝑃2 s

2
4-) Adiabatic Process (Isentropic Process)
P
𝛿𝑄
𝑑𝑆 =
𝑇 𝑟𝑒𝑣 2
𝑑𝑆 = 0
𝑆2 − 𝑆1 = 0
1
𝑆2 = 𝑆1 v
T
2