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Chemistry past paper Common


Questions By Vasumitra
Gajbhiye
GENERAL

State why two isotopes of have the same chemical properties

same number of electrons

same electronic configuration AND same number of outer shell electrons.

Explain why increasing the temperature increases the rate of reaction.

particles move faster and have more energy

more collisions per second so greater collision rate. frequency of collision


increase

more of the (colliding) molecules / particles have sufficient energy (activation


energy) to react / more of the collisions have sufficient energy (activation
energy) to react

Explain why decreasing the temperature decrease the rate of reaction.

particles have less energy and move slower.

fewer collisions per second so smaller rate of collision. frequency of


collisions decrease.

fewer portion of particles have sufficient energy to react. fewer portion of


particles have energy greater than equal to activation energy.

Give two properties of aluminium that make it suitable for use in overhead
electricity cables.

ductile / malleable

Chemistry past paper Common Questions By Vasumitra Gajbhiye 1


conducts (electricity)

low density

protective oxide layer

What is a saturated solution?

a solution that can dissolve no more solute

at the particular/specific/any given temperature

Why temperature doesn’t increase at boiling or melting?

energy is used to break bonds / overcome attraction

between molecules

Why is cotton wool used in this


experiment?

to allow gas to escape.

to prevent loss of acid.

Why does the graph levels off in


this experiment?

reaction finished

all the nitric acid is used up.

Describe the structure and bonding of metals

(lattice of) positive ions / cations

(delocalised / sea of) electrons

attraction / attract between positive and negative

Why an atom has overall charge 0?

Same number of protons and electrons

Why an ions has a charge of X+?

X more protons than electrons

Why an ions has a charge of X-?

Chemistry past paper Common Questions By Vasumitra Gajbhiye 2


X less protons than electrons

Why using lumps of solids decreases rate of reaction?

(lumps have) smaller surface area OR powder has larger surface area

(lumps have) fewer collisions per unit time / less collision frequency OR
powder has more collisions per unit time / more collision frequency

What is the observation when sodium react with water?

fizz / bubbles

moves

floats

melts / forms a ball

gets smaller / disappears

Why do gases diffuse?


due to random motion of molecules / particles from the region of higher
concentration to lower concentration.

Which element is found in clean dry air?


Argon

Which compound is found in clean dry air?

Carbon dioxide

Why a solid is added in excess to a acid?

to make sure all the acid reacts

If excess calcium metal is added to dilute hydrochloric acid instead of excess


zinc powder, pure calcium chloride crystals do not form. Explain why

Ca will also react with water

Describe how to check if all the water has been given off from a hydrated salt?

heat again and weigh again and repeat

until mass is constant

Why a reaction is exothermic?

Chemistry past paper Common Questions By Vasumitra Gajbhiye 3


more energy released (in bond formation) than used/taken in (in bond breaking)

Which process is used to separate the products of hydrolysis of long chain


carbohydrates.

Chromatography.

Describe how oxides of nitrogen form in a car engine.

nitrogen and oxygen (from the air) react (in the engine)

(due to) high temperatures

Which catalyst is used in catalytic converter?


platinum

What is catalyst?

(a substance which) increases the rate of a reaction

remains unchanged/ unaffected/ unused or without changing mass

From the first 30 elements, which gas diffuses with the slowest rate?
Chlorine

Explain, in terms of particles, why does the rate of reaction decrease as the time
increase?
• concentration of particles decreases
• lower rate of collisions of particles

What are the effects of nitrogen dioxide?

• Respiratory problems
• Acid rain

What is meant by the term redox?

reduction and oxidation occurs simultaneously.

Which gas is used to convert iron to steel?

Oxygen

Describe how solid sodium conducts electricity.

electrons move/mobile/flow

Chemistry past paper Common Questions By Vasumitra Gajbhiye 4


Explain why sodium chloride conducts electricity when molten.

Ions move/are mobile/flow

State how the student decides that a suitable number of results have been
obtained.

at least two results are within 0.2 cm3 or less

What happen to rate of reaction when surface area is increased?

Rate of reaction increase. More collisions per unit time.

When group 1 element react with cold water what is formed?

metal hydroxide

State one observation that indicates the copper(II) oxide is in excess in step 1.
Undissolved solid remains

Why a substance is oxidising agent?

It has gain electrons hence reduced.

Why a substance is reducing agent?


It has lost electrons hence oxidised.

What is the colour of bromine?


Orange - Brown

Suggest the name of the compounds that decompose to give metal oxide?

metal hydroxides, metal carbonates, metal nitrates.

State a pH number that indicates the presence of a strong alkali.

14

State how the energy profile diagram shows this is an exothermic reaction.

energy of products is lower than energy of reactants

BONDING

Why ionic compound X have higher melting point than covalent compound Y?

Chemistry past paper Common Questions By Vasumitra Gajbhiye 5


ionic bond in X

attraction between molecules in Y

weak attraction (between particle) in Y

Describe metallic bonding.

Lattice of (named) metal ions in sea of delocalised electrons

attraction between positive (named metal) ions

and negative electrons

Explain why nitrogen does not conduct electricity.

No mobile electrons OR no ions

Explain, in terms of attractive forces between particles, why nitrogen has a low
melting point.

Weak forces of attraction between molecules

Why ionic compound don’t conduct electricity when solid but conduct when
molten? Explain in terms of structure and bonding.

ions

(ions) are fixed (in a lattice)

ions are mobile

Explain why molten ionic compounds can conduct electricity.


ions can move through the structure

Describe what can be done to any ionic compound to allow it to conduct


electricity.

dissolve it in water

Explain, in terms of attractive forces between particles, why (any covalent


compound) has a low melting point.

forces of attraction between molecules

AND

are weak / need a small amount of energy to break

Chemistry past paper Common Questions By Vasumitra Gajbhiye 6


Why ionic compounds have high melting point?
strong forces of attraction (between oppositely charged ions)

Explain why covalent compounds are non-conductors of electricity?

no moving or flowing or mobile charged particles or ions or electrons

Which type of bond is present in carbon dioxide?

Double covalent bond.

What is ionic bond?

oppositely charged ions

(ions) are attracted

Give physical properties of ionic compounds.

physical constants: high boiling point / melting point

conductivity: conduct (electricity) when aqueous or conduct (electricity)


when molten

solubility: soluble in water

Explain, in terms of particles, why brass is harder than pure zinc.

exists as layers

(alloy) contains different sized (copper) atoms

makes it more difficult for layers (of atoms) to slide over each slip/shift other

State the term used to describe the structure of diamond.

Giant covalent

CONTACT PROCESS

What are the steps in contact process


stage 1 Molten sulfur is burned in air to produce sulfur dioxide gas.
stage 2 Sulfur dioxide is reacted with oxygen to form sulfur trioxide.
stage 3 Sulfur trioxide is combined with concentrated sulfuric acid to form

Chemistry past paper Common Questions By Vasumitra Gajbhiye 7


oleum, H2S2O7.
stage 4 Oleum is added to water to form sulfuric acid

CRYSTALLISATION

Why is the residue rinsed after filtration?

To make sure all the filtrate goes through. no filtrate left behind in the filter paper.
(This will increase yield). To wash-out / dissolve / remove salt

How to obtain pure crystals from a filtrate?

evaporation

the starting of crystallisation

drying the crystals

Why the mass of crystals obtained was less than theoretical mass?

some salt remains in solution / some salts does not form crystals
OR

some of the crystals decomposed


OR

some crystals lost in transfer

State two observations that would indicate that some salts are in excess in step
1.

no more bubbling / fizzing / effervescence

solid or powder stops dissolving/ solid remains.

What evidence would show that the solution was saturated?

when crystals form on a glass rod withdrawn from solution / on a sample of


solution placed on microscope slide etc.

Why should the aqueous saturated salt not be heated to dryness?

(heating to dryness) would remove water of crystallisation to form anhydrous


powder.

Suggest why more crystals of magnesium sulfate appear on cooling.

Chemistry past paper Common Questions By Vasumitra Gajbhiye 8


solubility (of MgSO4 / solid) decreases (as temperature decreases)

ELECTROLYSIS

State what is meant by the term electrolysis

breakdown by (the passage of) electricity

of an ionic compound in molten or aqueous (state)

State and explain what would happen to the mass of the negative electrode
during the electrolysis of concentrated copper(II) chloride.

increases

(solid) copper deposited

What happens to the colour of solution during electrolysis of coloured


compound?

colour fades / becomes pale(r) / becomes colourless / becomes lighter

named anions (ions) removed (from solution)

Give one reason why metal spoons are electroplated with silver.

Improves appearance

prevent / resist corrosion / oxidation

antibacterial

When a gas is formed what is observed?

fizzing/ bubbles/ effervescence

Explain why the ionic compound needs to be aqueous or molten.

So that ions are mobile and can move

Explain why inert electrodes are used.


they do not react

EQUILIBRIUM

Chemistry past paper Common Questions By Vasumitra Gajbhiye 9


State features of equilibrium.

reaction is reversible

rate of forward reaction = rate of reverse reaction.

concentrations of reactants and products are constant

Explain, in terms of particles, why a high temperature increases the rate of


reaction.

particles have more energy (E)

rate of collisions increase/ more collisions per unit time(per second)

a higher proportion of particles have energy greater than activation energy


(E > EA)

If forward reaction is exothermic what happens to the amount of product when


temperature is increased?

less amount of product

equilibrium moves left and because forward reaction is exothermic

If a product (E.g. water) is removed from the RHS what happens to the
mass of other product?

more product

equilibrium moves right to replace (named product which is removed, e.g.


water)

If the pressure is increased, the yield of ammonia increases. Explain why, in


terms of equilibrium.

equilibrium shifts / moves in forwards direction

fewer molecules / moles (of gas) on RHS

Suggest why the position of equilibrium does not change.


same number of gas moles on both sides of the equilibrium / same number of
gas molecules on both sides of the equilibrium

ETHANOIC ACID MAKING

Chemistry past paper Common Questions By Vasumitra Gajbhiye 10


Ethanol will react with hot aqueous potassium manganate(VII) to form ethanoic
acid. State the other condition needed for this reaction to take place.
presence of an acid

ETHANOL MAKING

How ethanol can be made by fermentation.

C6 H12O6 → 2CO2 + 2C2 H5 OH


anaerobic respiration

of yeast

at 30°C

using aqueous glucose

What type of reaction is it when ethene is converted to ethanol?


addition

What are the reagents and conditions required for conversion of ethene to
ethanol?

stem

catalyst

60atm

300 deg C

What are the two products of fermentation?

Carbon dioxide and ethanol

EXTRACTION

Give two reasons for using coke in the blast furnace.

(coke)
releases heat (when it reacts with oxygen or reacts in air)
OR (acts as a) fuel

Chemistry past paper Common Questions By Vasumitra Gajbhiye 11


OR increases temperature (in the furnace) / heats (the furnace)
OR source of energy

(coke or carbon monoxide)


reduces iron oxide
OR is a reducing agent
OR converts iron oxide to iron / removes oxygen from iron oxide

(coke)
reacts with oxygen to form carbon monoxide
OR reacts with carbon dioxide to form carbon monoxide

Name two waste gases that leave the blast furnace during extraction of iron.

Nitrogen

Carbon dioxide

Suggest one benefit to the environment of reducing the operating temperature of


electrolysis of aluminium oxide.
less co2 emission

Explain why the anodes need frequent replacement.

anodes or carbon / graphite react with oxygen / O2

(form) carbon dioxide

HARBER PROCESS

State one source of hydrogen for manufacture of ammonia.


hydrocarbon

Explain why a lower temperature and a higher pressure are not used.
Lower temperature → rate of reaction slower
Higher pressure → expensive/ specialised equipment

MAKING OF ZINC

What is the name of zinc ore?

Chemistry past paper Common Questions By Vasumitra Gajbhiye 12


Zinc blende

Name the main zinc compound that is present in zinc blende.


Zinc sulfide

What is the equation for roasting of zinc?

2ZnS + 3O2 => 2ZnO + 2SO2

What is the equation for reduction of zinc oxide?

ZnO + C => Zn + CO

How zinc is removed from the blast furnace?

distilled

ORGANIC CHEMISTRY

What is meant by unsaturated?


not all c-c bonds are single. contain at least one c=c bond.

What are the reagents and conditions required for conversion of a alkene
to alkane?

hydrogen

catalyst

high temperature.

State what is meant by the term functional group.

the atoms / group of atoms which give (any molecule its) chemical properties

If the number of carbon in the chain increase what happen to it’s boiling point?
boiling point increase

State are general characteristics of a homologous series.

same or similar chemical properties or reactions

same general formula

consecutive members differ by CH2

Chemistry past paper Common Questions By Vasumitra Gajbhiye 13


same functional group

common (allow similar) methods of preparation

physical properties vary in predictable manner / show trends / gradually


change
OR
example of a physical property variation i.e. melting point / boiling point /
volatility

Which process is used to make alkenes?


Cracking

Iron(II) sulfate can be converted to iron(III) sulfate by potassium


manganate(VII) at room temperature. What condition must be used for this
reaction to occur?
presence of acid

PETROLEUM

What are the gases found in refinery gases?


methane, ethane, propane, butane

What happens to viscosity as we move up the fractionating column.


it decrease

What happens to flammability as we move up the fractionating column.


it increase

What difference in the molecules of gasoline and kerosene causes


differences in viscosity and flammability?

kerosene has molecules with a longer carbon chain

POLYMERS

How many molecules of water is formed when one ester link is formed?
1

Chemistry past paper Common Questions By Vasumitra Gajbhiye 14


If in a polymer the colour of all the boxes is same then only one monomer is
used to form that polymer.

What is the process used to make monomers for addition polymers?


cracking

Describe what is meant by the term addition reaction.


(only) one product is formed

Give one condition needed when ethanoic acid reacts with the alcohol to make
this ester.
acid (catalyst)

Name a polyester?
Terylene

What does the term condensation mean when used to describe condensation
polymers?
water is a product (when polymer is made)

PROTECTING IRON

Explain how completely coating an iron object with a layer of zinc prevents
rusting

prevents water or / and oxygen reaching iron

Rusting of iron ships can be prevented by attaching zinc blocks to the hull of the
ship. Explain how this prevents rusting.

zinc more reactive (than iron)

Chemistry past paper Common Questions By Vasumitra Gajbhiye 15


zinc corrodes / oxidises / reacts in preference to iron

Explain how the magnesium blocks prevent iron from rusting

magnesium is more reactive than iron / steel ORA (1)


iron is not oxidised
OR
iron does not lose electrons
OR
magnesium loses electrons more easily than or in preference (to iron) ORA
OR
magnesium is oxidised more easily or reacts with oxygen more easily or
corrodes more easily or in preference (to iron)

SALT PREPARATION

What is meant by the term precipitate?

a solid

which forms when two solutions are mixed / reacted / added

What compounds can be used to make metal salts?


Metal oxide, metal carbonate, metal hydroxide

How precipitation is performed practically?

(add) water (to both salts)

dissolve both salts / make solutions

filter (lead(II) iodide)

wash (residue of lead(II) iodide) with water AND dry e.g. with filter paper /
description of washing and drying

How to make salt crystals from metal carbonate and acid?

add metal carbonate to sulfuric acid until

it stops dissolving or no more effervescence

filter excess metal carbonate

Chemistry past paper Common Questions By Vasumitra Gajbhiye 16


evaporation of filtrate to form dry crystals

State two observations when metal carbonate reacts with acid?

fizzing / effervescence

solid disappears / dissolves

Name the experimental technique used when salts are made by reacting a dilute
acid with an aqueous alkali.
Titration

TEST

Test for oxygen.


glowing splint
relight

Test for hydrogen.


Burning splint
squeaky pop

Test for sulfur dioxide.

acidified aqueous potassium manganate(VII)

purple to colourless

What is produced when iron(II) sulfate (or any other metal) react with ammonia?
Iron (II) hydroxide is formed (or any other metal hydroxide is formed)

Suggest why the green precipitate of iron(II) hydroxide turns red-brown at the
surface.

it (iron(II) hydroxide) is oxidised

to form iron(III) (hydroxide) / (oxide)

by (iron(II) hydroxide reacting with) air / oxygen

Chemistry past paper Common Questions By Vasumitra Gajbhiye 17


TRANSITION & GROUP 1 ELEMENTS

What are the chemical properties of transition metals?

act as catalyst

variable oxidation states

Coloured compounds

What are the physical properties of transition metals?

malleable

good conductors of heat and electricity

high melting point

hard and strong/ tough

high density

What are the difference between physical properties of transition metals and
group 1 elements.

higher melting point

high density

hard

What are the difference between chemical properties of transition metals and
group 1 element.

act as catalyst

have variable oxidation states

form coloured compounds

What are the difference between physical properties of group 1 elements and
transition metals.

low melting point or low boiling point

soft

low density

Chemistry past paper Common Questions By Vasumitra Gajbhiye 18


State physical properties of Group I metals which are similar to those of
transition metals.

shiny / lustrous

conduct electricity

conduct heat

Chemistry past paper Common Questions By Vasumitra Gajbhiye 19

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