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  • Addition If Steam With Alkenes

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    Ahmad Talal
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    1) Reagent Hoeg undergoes addition to alkenes at 350°C and 60 atm of pressure. Phosphoric acid is used as a catalyst. 2) The mechanism involves heterolytic fission of the hydrogen-halogen bond to form carbonium ions and halide ions as intermediates. 3) The addition follows Markovnikov's rule - the hydrogen of the reagent adds to the carbon of the alkene with more hydrogens directly attached. This gives a major symmetric product over an unsymmetric one.

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    Addition if steam with alkenes

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    1) Reagent Hoeg undergoes addition to alkenes at 350°C and 60 atm of pressure. Phosphoric acid is used as a catalyst. 2) The mechanism involves heterolytic fission of the hydrogen-halogen bond to form carbonium ions and halide ions as intermediates. 3) The addition follows Markovnikov's rule - the hydrogen of the reagent adds to the carbon of the alkene with more hydrogens directly attached. This gives a major symmetric product over an unsymmetric one.

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    © All Rights Reserved
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    17 views3 pages

    Addition If Steam With Alkenes

    Uploaded by

    Ahmad Talal
    1) Reagent Hoeg undergoes addition to alkenes at 350°C and 60 atm of pressure. Phosphoric acid is used as a catalyst. 2) The mechanism involves heterolytic fission of the hydrogen-halogen bond to form carbonium ions and halide ions as intermediates. 3) The addition follows Markovnikov's rule - the hydrogen of the reagent adds to the carbon of the alkene with more hydrogens directly attached. This gives a major symmetric product over an unsymmetric one.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 3

    Reagent Hoeg

    Steam
    3 Addition
    of Condition 350 60atm

    CatalystHzPOy

    d d
    Equation
    Iced t Hoo n
    H
    H

    Mechanism

    iced
    µ H

    IE
    Ein'Ematiate

    Its
    Got
    Heterolyticfission

    n lÉ n

    d on

    Symmetric Alkene e.g H H


    n d d n ans IIc cu
    Unsymmetric Alkene e.g

    CH In CA CH I H

    Cha Cha Cha OH Propan l o


    minor product
    CHz Chat H2O less probability
    cg
    CH CH CH3 l
    CH CH CH3
    Propan 2 01
    H major product
    greaterprobability

    Markoniv Kor's rule


    When add to
    an unsymmetrical reagent
    an unsymmetrical alkene hydrogen of reagent goes to
    that carbon of c c having more Hydrogen directly
    attached to it

    Cha II

    Hts
    I 93
    Carbo
    1
    9
    cation
    I p
    Got
    Heterolyticfission

    as 44 H
    OH H

    Propan 2 01

    Reagent Hdcg
    4 Addition of Hydrogen Halides Condition Room
    temp
    gift cuz oh 1 1 H Hag
    _Yemp 413 42 43

    Mechanism

    ÉÉ
    Cuz Cha m a ar
    Enter'm'diate
    É
    f 0

    y
    Gas I
    Ij
    Heterolyticfission H
    a 412

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