BÀI TẬP HÓA PHÂN TÍCH (CH2113)

SỐ HK231
GVHD: Lâm Hoa Hùng

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Họ tên (MSSV)
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Lớp/Nhóm
Yêu cầu: (i) Viết tay tối đa 6 trang giấy A4 đã được chuẩn bị sẵn; (ii) Trích dẫn Tài liệu tham khảo vào cuối bài; (iii) Nộp file
pdf (từ ảnh chụp) trên BKeL; (iv) Nộp tất cả 03 bài tập (bản cứng viết tay) cho GVHD vào buổi học lý thuyết cuối cùng.
Đề bài:
1/ Cho phản ứng sau:
Na2Cr2O7 + FeCl2 + H2SO4 = Fe2(SO4)3 + Na2SO4 + CrCl3 + HCl + H2O
1.1. Hãy cân bằng phương trình phản ứng trên và cho biết phản ứng này có diễn ra hoàn toàn
trong điều kiện chuẩn hay không ?
1.2. Hãy cho biết cần bao nhiêu g FeCl2.4H2O để pha thành 200 ml dung dịch FeCl 2 0,100 N và
cần bao nhiêu ml dung dịch Na2Cr2O7 0,0500 M để phản ứng vừa đủ 200 ml dung dịch
FeCl2 0,100 N.
1.3. Tính thế của dung dịch thu được ở pH = 0 khi cho 200 ml FeCl2 0,100 N tác dụng vừa đủ
với lượng thể tích Na2Cr2O7 0,0500 M nếu xem như pH không thay đổi trong suốt quá
trình phản ứng
1.4. Tính thế của dung dịch thu được ở pH = 0 khi cho 200 ml FeCl2 0,100 N tác dụng với
V(ml) Na2Cr2O7 0,0500 M nếu xem như pH không thay đổi trong suốt quá trình phản ứng
với V = 50 ml và V = 100 ml.

2/ Cho axit Thiomalic (ký hiệu H3T) là axit ba nấc với k1 = 10-3,20, k2 = 10-4,60 Và k3 = 10-10,45.
2.1. Tính pH của dung dịch 0,010 M axit thiomalic theo phương pháp chính xác
2.2. Tính lại pH của dung dịch 0,010 M axit thiomalic theo phương pháp gần đúng và so sánh
với kết quả câu 2.1
2.3. Tính nồng độ các dạng [H3T], [H2T-], [HT2-] và [T3-] đạt được khi cân bằng nếu hòa tan 0,010
mol muối Trinatri của thiomalic acid (Na3T) vào nước và pha loãng thành 500 ml dung dịch.

3/ Người ta cần oxy hóa Cr3+ trong dung dịch nước thành Cr2O72- ở pH 0 thì nên dùng chất oxy
hóa nào để phản ứng diễn ra hoàn toàn ? SV cần trình bày và giải thích rõ ràng trên cơ sở E o
của các bán cân bằng và K của phản ứng.

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-HẾT-

Phần Xác nhận của các thành viên trong nhóm có tham gia bài tập lớn

1………………………………………….... 6..…………………………………………..
Họ tên (MSSV)
Ký tên: Ký tên:

2..………………………………………….. 7..…………………………………………..
Ký tên: Ký tên:

3..………………………………………….. 8..…………………………………………..
Ký tên: Ký tên:

4..………………………………………….. 9..…………………………………………..
Ký tên: Ký tên:

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