CHEMISTRY ASSIGNMENT_IONIC EQUILIBRIUM

If pH  3.31 , then find out H  (Approx)


1.
1) 3.39  10 4 2) 5  10 4 3) 3.0  103 4) None

2. Find out pH of solution having 2  10 3 moles of OH ions in 2 litre solution :-

1) pH  3 2) pH  3  log 2 3) pH  3  log 2 4) pH  11

3. pH of tomato juice is 4.4 . Then concentration of H3O will be :-

1) 39  104 2) 3.9  10 5 3) 3.9  10 4 4) 3.9  105
4. Degree of dissociation of 0.1NCH3COOH is : (Dissociation constant  1  10 5 )
1) 10 5 2) 10 4 3) 10 3 4) 10 2
5. The degree of dissociation of acetic acid is given by the expression   0.1  C 1 (where C =
concentration of the acid) What is the pH of the solution :-
1) 1 2) 2 3) 3 4) 4
6. The degree of ionisation of a compound depends upon :
1) Size of the solute molecules 2) Nature of the solute molecules
3) Nature of the container taken 4) The amount of current passed

7. Find out K a for 10 2 MHCN acid, having pOH  10 :-

1) K a  10 4 2) K a  10 2
3) K a  10 5 (4) None of these
8. Ionic product of water will increase, if :-
1) Decrease the pressure 2) Add H
3) Add OH 4) Increase the temperature
9. For water at 25ºC, 2  10 7 moles per litre is the correct answer for which one of the followoing
2
1) H   OH 
 
2) H 
2
4) H   OH 
 
3) OH 

1
10. At 25 C , the dissociation constant for pure water is given by :-

1)  55.4  1014 
1
2) 1  10 14

1  10 14
3) 4) None of these
18
11. Ionic product of water is equal to :-
1) Dissociation constant of water  H2O 2) Dissociation constant of water  H 


3) Product of H2O and H 

 2
4) Product of OH  and H 

12. For pure water, addition of H and OH ion concentrations at 90 C is :-
1) 10 14 2) 10 12
3) 2  10 6 4) 2  10 7
At a certain temperature, pure water has H3O   10 mol L . What is the value of K w at this
 6.7 1
13.
temperature :-
1) 10 6 2) 10 12 3) 10 67 4) 10 13.4
14. Which of the following is not an acidic salt :-
1) NaHSO4 2) HCOONa
3) NaH2PO3 4) None of these
15. Which is a basic salt :-
1) MgCl2 2) KCl 3) NaCl 4) Mg(OH) Cl
16. The mixed salt among the following is :-
C H  OH COONa
|
1) 2) NaKSO4
CH  OH COONa

3) CaCl2 4) All
17. What will be the pH of ammonium formate solution, If K a  1  10 4 acid K b  1  10 5 :-
1) 6.5 2) 7.5 3) 8.0 4) 9.0
18. Which salt will not undergo hydrolysis :-
1) KCl 2) Na 2SO4 3) NaCl 4) All
19. HCOO  H2O  HCOOH  OH
Degree of hydrolysis for above reaction is given by:-
Kh
1) h  K h 2) h 
C

Kh
3) h  4) K h  hc
V

2
20. The highest pH value is of :-
1) 0.1MNaCl 2) 0.1MNH4Cl
3) 0.1MCH3COONa 4) 0.1MCH3COONH4
21. pH of K 2 Ssolution is : 
1) 7 2) Less than 7 3) More than 7 4) 0
22. For anionic hydrolysis, pH is given by:-
1 1 1 1 1 1
1) pH  pK w  pK o  log C 2) pH  pK w  pK a  pK b
2 2 2 2 2 2
1 1 1
3) pH  pK w  pK a  log C 4) None of above
2 2 2
Hydroxyl ion concentration OH  in the case of sodium acetate can be expressed as (where K a

23.
is dissociation constant of CH3COOH and C is the concentration of sodium acetate):-

1) OH    CK w * K z 
1/2
2) OH   C  K w K a


1/2
 C  Kw 
3) OH   

4) OH   C.K a  K w *


 Ka 
24. pH of water is 7 . When any substance Y is dissolved in water then pH becomes 13 . Substance Y is
a salt of :-
1) Strong acid and strong base 2) Weak acid and weak base
3) Strong acid and weak base 4) Weak acid and strong base
25. Given :-
(a) 0.005MH2SO4 b) 0.1MNa 2SO4
c) 10 2 MNaOH d) 0.01MHCl
Choose the correct code having same pH :-
1) a, c, d 2) b, d 3) a, d 4) a, c
26. In the following solutions, the conc. of different acids are given, which mixture of the acid has highest
pH :-
M M M M M M
1) H2SO4 , HNO3 , HClO4 2) H2SO4 , HNO3 , HClO4
10 20 10 20 10 20
M M M M M M
3) H2SO4 , HNO3 , HClO4 (4) H2SO4 , HNO3 , HClO4
20 10 40 20 5 5

27. 10 6 MHCl is diluted 100 times. Its pH is :-

1) 6.0 2) 8.0
3) 6.95 4) 9.5

3
28. In a solution of pH = 5, more acid is added in order to reduce the pH upto 2 . The increase in
hydrogen ion concentration is:-
1) 100 times 2) 1000 times 3) 3 times 4) 5 times
29. The pH of a 0.02M ammonia solution which is 5% ionised will be :-
1) 2 2) 11 3) 5 4) 7
30. Choose the wrong statement :-
1) For a neutral solution : H   OH   K w
 

2) For an acidic solution : H   K w & OH   K w

 

3) For a basic solution : H   K w & OH   K w

 

4) For a neutral solution : H   OH   10 M(atalltemperatures)

  7

31. The conjugate acid of O2 is :-

1) O2 2) H 3) H3O 4) OH
32. Select the species which can function as lewis base, bronsted acid and bronsted base:-
a) H2O b) NH4 c) N3
Correct code is :-
1) Only a 2) a, b 3) a, c 4) b, c
33. Which ion does not show acid behaviour :-
3 3
1)  Al  H2O 6  2) Fe  H2O 6 

3) HPO4 2 4) ClO3
34. Which acts as Lewis base in the reaction
BCl3  : PH3  Cl3 B  PH3
1) PH3 2) BCl3 3) Both 1 & 2 4) None
35. Which acts as Lewis acid in the reaction
SnCl2  2Cl   SnCl 4 
2

1) Cl  2) SnCl2 3) SnCl 4 4) None


36. The conjugate base of  CH3  N H2 is :-
2

1) CH3NH2 2)  CH3 2 N 3)  CH3 2 N 4)  CH3 2 NH

37. In the reaction
HNO3  H2O  H3O  NO3 , the conjugate base of HNO3 is :-
1) H2O 2) H3O
3) NO3 4) H3O and NO3

4
38. The two Bronsted bases in the reaction HC2O4  PO34  HPO42  C2O24 are
1) HC 2O4 and PO24 2) HPO24 and C2O24
3) PO43 and C2O42 4) HC 2O4 and HPO42
39. Which of the following is a base according to Bronsted-Lowry concept :-
1) I 2) H3O
3) HCl 4) NH4
40. Which of the following is not a correct statement
1) Arrhenius theory of acids-bases is capable of explaining the acidic or basic nature of the sub-
stances in the solvents other than water
2) Arrhenius theory does not explain acidic nature of AlCl3
3) The aqueous solution of Na 2CO3 is alkaline although it does not contain OH ions
4) Aqueous solution of CO2 is acidic although it does not contain H ions
41. According to Arrhenius theory, acids are substances that dissociate in water to give ...(X) ... ions and
bases are substances that produce .... (Y)... ions. Here, (X) and (Y) refer to
1) hydronium, hydroxyl
2) hydroxyl, hydrogen
3) hydrogen, hydroxyl
4) hydroxyl, hydronium
42. Which of the following salts will give highest pH in water?
1) KCl 2) NaCl 3) Na 2CO3 4) CuSO4
43. Following solutions were prepared by mixing different volumes of NaOH and HCl of different
concentrations:
M M M M
a. 60mL HCl  40mL NaOH b. 55mL HCl  45mL NaOH
10 10 10 10
M M M M
c. 75mL HCl  25mL NaOH d. 100mL HCl  100mL NaOH
5 5 10 10
pH of which one of them wil be equal to 1?
1) b 2) a 3) d 4) c
The concentration of H  and concentration of OH  of a 0.1 M aqueous solution of 2%
 
44.

ionised weak acid is K w  1  10 

14

1) 0.02  10 3 M and 5  10 11 M 2) 1  10 3 M and 3  10 11 M

3) 2  10 3 M and 5  10 12 M 4) 3  10 2 M and 4  10 13 M
45. What will be the H ion concentration when 4g NaOH dissolved in 1000 mL of water
1) 10 1 2) 10 13 3) 10 4 4) 10 10

5
46. A solution of MgCl2 in water has pH
1) < 7 2) > 7 3) 7 4) 14.2
47. 0.2 M solution of HCOOH is 3.2% ionised then find ionisation constant of acid
1) 4.2  10 4 2) 4.2  10 5 3) 2.1  10 4 4) 2.1  10 5

48. Three reactions involving H2PO4 are given below:

(i) H3PO4  H2O  H3O  H2PO4

(ii) H2PO4  H2O  HPO24  H3O

(iii) H2PO4  OH  H3PO4  O2

In which of the above does H2PO4 act as an acid?

1) (i) only 2) (ii) only 3) (i) and (ii) 4) (iii) only
49. The hydrogen ion concentration of a 10 8 M HCl aqueous solution at 298K  K  10 14  is
w

1) 1.0  10 6 M 2) 1.0525  10 7 M

3) 9.525  10 8 M 4) 1.0  10 8 M
50. Equimolar solutions of the following were prepared in water separately. Which on of the solutions will
record the highest pH?

1) BaCl2 2) MgCl2 3) CaCl2 4) SrCl2

KEY
1) 2 2) 4 3) 2 4) 4 5) 1 6) 2 7) 4 8) 4 9) 1 10) 1
11) 1 12) 3 13) 4 14) 2 15) 4 16) 2 17) 1 18) 4 19) 2 20) 3
21) 3 22) 3 23) 3 24) 4 25) 3 26) 3 27) 3 28) 2 29) 2 30) 4
31) 4 32) 1 33) 4 34) 1 35) 2 36) 4 37) 3 38) 3 39) 1 40) 1
41) 3 42) 3 43) 4 44) 3 45) 2 46) 1 47) 3 48) 2 49) 2 50) 1