Professional Documents
Culture Documents
Solutions
Mrs. Cristina Soriano, RCh and Engr. Gil Stefan Mamaril, M.Sc.
Concentration of
Solution
1
18 Oct 2022
Percent by Mass
Percent by Volume
Ways of Molarity
Expressing
Concentrations Molality
Mole Fraction
Normality
𝑚𝑜𝑙𝑒 𝑠𝑜𝑙𝑢𝑡𝑒
𝑀=
𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
𝑚𝑜𝑙𝑒 𝑠𝑜𝑙𝑢𝑡𝑒 =
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒 𝑜𝑟 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑤𝑒𝑖𝑔ℎ𝑡
𝒎𝒂𝒔𝒔 𝒔𝒐𝒍𝒖𝒕𝒆
𝑴=
(𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒔𝒐𝒍𝒖𝒕𝒆)(𝒍𝒊𝒕𝒆𝒓 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏)
2
18 Oct 2022
Molarity (Prob 1)
1𝐿
𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 = 2000 𝑚𝐿 × = 2 𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛
1000 𝑚𝐿
𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻
𝑀𝑁𝑎𝑂𝐻 =
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻 (𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛)
Molarity (Prob 1)
𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻
𝑀𝑁𝑎𝑂𝐻 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻)(𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛)
8 𝑔 𝑁𝑎𝑂𝐻
𝑀𝑁𝑎𝑂𝐻 = 𝑔
(40 )(2 𝐿 𝑠𝑜𝑙 ′ 𝑛)
𝑚𝑜𝑙
𝑚𝑜𝑙
𝑀𝑁𝑎𝑂𝐻 = 0.1 𝑁𝑎𝑂𝐻 = 0.1 𝑀 𝑁𝑎𝑂𝐻
𝐿
3
18 Oct 2022
Molarity (Prob 2)
𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝐾𝑂𝐻 = 39 1 + 16 1 + 1 1 = 56
𝑚𝑜𝑙
1𝐿
𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛 = 1500 𝑚𝐿 × = 1.5 𝐿 𝑠𝑜𝑙 ′ 𝑛
1000 𝑚𝐿
𝑚𝑎𝑠𝑠 𝐾𝑂𝐻
𝑀𝐾𝑂𝐻 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝐾𝑂𝐻)(𝐿 𝑠𝑜𝑙 ′ 𝑛)
Molarity (Prob 2)
𝑚𝑎𝑠𝑠 𝐾𝑂𝐻
𝑀𝐾𝑂𝐻 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝐾𝑂𝐻)(𝐿 𝑠𝑜𝑙 ′ 𝑛)
𝑔 𝑚𝑜𝑙
𝑚𝑎𝑠𝑠 𝐾𝑂𝐻 = 56 1.5 𝐿 𝑠𝑜𝑙 ′ 𝑛 0.35
𝑚𝑜𝑙 𝐿 𝑠𝑜𝑙 ′ 𝑛
4
18 Oct 2022
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
𝑚𝑜𝑙𝑒 𝑠𝑜𝑙𝑢𝑡𝑒 =
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒 𝑜𝑟 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑤𝑒𝑖𝑔ℎ𝑡
𝒎𝒂𝒔𝒔 𝒔𝒐𝒍𝒖𝒕𝒆
𝒎=
(𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒔𝒐𝒍𝒖𝒕𝒆)(𝒌𝒈 𝒔𝒐𝒍𝒗𝒆𝒏𝒕)
𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻 = 23 1 + 16 1 + 1 1 = 40
𝑚𝑜𝑙
𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻
𝑚𝑁𝑎𝑂𝐻 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻)(𝑘𝑔 𝐻2 𝑂)
10
5
18 Oct 2022
𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻
𝑚𝑁𝑎𝑂𝐻 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝑂𝐻)(𝑘𝑔 𝐻2 𝑂)
4.0 𝑔 𝑁𝑎𝑂𝐻
𝑚𝑁𝑎𝑂𝐻 = 𝑔
(40 )(1.2 𝑘𝑔 𝐻2 𝑂)
Molality (Prob 1) 𝑚𝑜𝑙
𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
𝑚𝑁𝑎𝑂𝐻 = 0.083 = 𝟎. 𝟎𝟖𝟑 𝒎 𝑵𝒂𝑶𝑯
𝑘𝑔 𝐻2 𝑂
11
Molality (Prob 2)
• What is the mass (grams) of H2O needed to prepare 0.44 molal NaCl if 6.5
grams of NaCl crystals is used?
𝑔
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙 = 23 1 + 35. 5 1 = 58. 5
𝑚𝑜𝑙
𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙
𝑚𝑁𝑎𝐶𝑙 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙)(𝑘𝑔 𝐻2 𝑂)
𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙
𝑘𝑔 𝐻2 𝑂 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙)(𝑚𝑁𝑎𝐶𝑙 )
12
6
18 Oct 2022
Molality (Prob 2)
𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙
𝑘𝑔 𝐻2 𝑂 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙)(𝑚𝑁𝑎𝐶𝑙 )
6.5 𝑔 𝑁𝑎𝐶𝑙
𝑘𝑔 𝐻2 𝑂 =
𝑔 𝑚𝑜𝑙
(58. 5 )(0.44 )
𝑚𝑜𝑙 𝑘𝑔 𝐻2 𝑂
𝑘𝑔 𝐻2 𝑂 = 0.253 𝑘𝑔
𝟏𝟎𝟎𝟎 𝒈
𝒈𝒓𝒂𝒎𝒔 𝑯𝟐 𝑶 = 𝟎. 𝟐𝟓𝟑 𝒌𝒈 × = 𝟐𝟓𝟑 𝒈 𝑯𝟐 𝑶
𝟏 𝒌𝒈
13
Additional Problem…
14
7
18 Oct 2022
Additional Problem
15
Additional Problem
𝑚𝑎𝑠𝑠 𝐻𝐶𝑙
𝑀𝐻𝐶𝑙 =
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝐻𝐶𝑙)(𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛)
430.78 𝑔 𝐻𝐶𝑙
𝑀𝐻𝐶𝑙 = 𝑔
(36. 5 )(1 𝐿 𝑠𝑜′ 𝑛)
𝑚𝑜𝑙
𝑚𝑜𝑙
𝑀𝐻𝐶𝑙 = 11.802 𝐻𝐶𝑙 𝑠𝑜𝑙 ′ 𝑛 = 11.802 𝑀 𝐻𝐶𝑙 𝑠𝑜𝑙 ′ 𝑛
𝐿
16
8
18 Oct 2022
Additional Problem
• Another solution! Using dimensional analysis.
𝑚𝑎𝑠𝑠 𝐻𝐶𝑙
%𝑚𝑎𝑠𝑠 𝐻𝐶𝑙 = × 100
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙 ′ 𝑛
17
Additional Problem
𝑚𝑜𝑙 𝐻𝐶𝑙
𝑀𝐻𝐶𝑙 𝑜𝑟
𝐿 𝑠𝑜𝑙 ′ 𝑛
18
9
18 Oct 2022
𝒈
𝒅𝒆𝒏𝒔𝒊𝒕𝒚 𝒊𝒏 𝒎𝑳 𝒎𝒂𝒔𝒔 % (𝟏𝟎)
𝑴𝒐𝒍𝒂𝒓𝒊𝒕𝒚 = 𝒈
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒊𝒏
𝒎𝒐𝒍
19
𝑋𝑠𝑜𝑙𝑢𝑡𝑒 + 𝑋𝑠𝑜𝑙𝑣𝑒𝑛𝑡 = 1
20
10
18 Oct 2022
A solution is prepared by mixing 10g NaCl with 250g of H2O. Determine XNaCl
and Xwater.
𝑔
𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑁𝑎𝐶𝑙 = 23 × 1 + 35.5 × 1 = 58.5
𝑔𝑚𝑜𝑙
𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝐻2 𝑂 = 1.0 × 2 + 16 × 1 = 18
𝑚𝑜𝑙
10 𝑔 𝑁𝑎𝐶𝑙
𝑚𝑜𝑙 𝑁𝑎𝐶𝑙 = 𝑔 = 0.171 𝑚𝑜𝑙
58.5
𝑚𝑜𝑙
21
250 𝑔 𝐻2 𝑂
𝑚𝑜𝑙 𝐻2 𝑂 = 𝑔 = 13.889 𝑚𝑜𝑙
18
𝑚𝑜𝑙
0.171 𝑚𝑜𝑙
𝑋𝑁𝑎𝐶𝑙 = = 0.012
0.171 𝑚𝑜𝑙 + 13.889 𝑚𝑜𝑙
13.889 𝑚𝑜𝑙
𝑋𝐻2 𝑂 = = 0.988
0.171 𝑚𝑜𝑙 + 13.889 𝑚𝑜𝑙
22
11
18 Oct 2022
𝑒𝑞 𝑠𝑜𝑙𝑢𝑡𝑒
𝑁=
𝑙𝑖𝑡𝑒𝑟 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝑒𝑞 𝑠𝑜𝑙𝑢𝑡𝑒 = 𝑒𝑞𝑢𝑖𝑣𝑎𝑙𝑒𝑛𝑡 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
𝑒𝑞 𝑠𝑜𝑙𝑢𝑡𝑒 =
𝐸𝑊 𝑠𝑜𝑙𝑢𝑡𝑒
𝐸𝑊 𝑠𝑜𝑙𝑢𝑡𝑒 = 𝑒𝑞𝑢𝑖𝑣𝑎𝑙𝑒𝑛𝑡 𝑤𝑒𝑖𝑔ℎ𝑡 𝑠𝑜𝑙𝑢𝑡𝑒
23
24
12
18 Oct 2022
25
𝑒𝑞 𝑠𝑜𝑙𝑢𝑡𝑒
𝑁=
𝑙𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
𝑁=
(𝐸𝑊 𝑠𝑜𝑙𝑢𝑡𝑒)(𝑙𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛)
Normality
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
(Normal 𝑁=
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
Solution) 𝑓
𝑙𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛
𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒
𝑁= ×𝑓
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑠𝑜𝑙𝑢𝑡𝑒)(𝑙𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛)
𝑵= 𝑴×𝒇
26
13
18 Oct 2022
Normality (Prob 1)
Calculate the normality of 9.5 grams of barium hydroxide (Ba(OH)2) dissolved in water
to make 950 mL of solution. (Molar mass: Ba = 137 g/mol ; O = 16 g/mol ; H =1 g/mol)
Molar Mass Ba(OH)2
𝑔
= 137 × 1 + 16 × 2 + 1 × 2 = 171 𝑚𝑜𝑙
27
𝑚𝑎𝑠𝑠 𝐵𝑎(𝑂𝐻)2
𝑀=
(𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠)(𝑙𝑖𝑡𝑒𝑟 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛)
9.5 𝑔 𝐵𝑎(𝑂𝐻)2
𝑀= 𝑔 = 0.058 𝑀 𝐵𝑎(𝑂𝐻)2
171 (0.95 𝐿)
𝑚𝑜𝑙
𝑁 = 𝑀𝐵𝑎(𝑂𝐻)2 × 𝑓
𝑒𝑞
𝑁 = 0.058 × 2 = 0.116 𝐵𝑎(𝑂𝐻)2 = 𝟎. 𝟏𝟏𝟔 𝑵 𝑩𝒂(𝑶𝑯)𝟐
𝐿
Normality (Prob 1)
28
14
18 Oct 2022
Normality (Prob 2)
𝑁𝐻3 𝑃𝑂4
𝑀𝐻3 𝑃𝑂4 =
𝑓
0.93 𝑁
𝑀𝐻3 𝑃𝑂4 = = 𝟎. 𝟑𝟏 𝑴 𝑯𝟑 𝑷𝑶𝟒
3
29
Normality (Prob 3)
Calculate the mass of Na2CO3 solute in 2-liters of 0.88 normal Na2CO3 solution.
(Molar Mass: Na = 23 g/mol ; C = 12 g/mol ; O = 16 g/mol)
f for Na2CO3 = 1 × 2 = 2
30
15
18 Oct 2022
Normality (Prob 3)
31
Normality (Prob 3)
𝑚𝑎𝑠𝑠 𝑁𝑎2 𝐶𝑂3 = (𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠)(𝐿𝑖𝑡𝑒𝑟 𝑠𝑜𝑙 ′ 𝑛)(𝑀𝑁𝑎2 𝐶𝑂3 )
𝑔 𝑚𝑜𝑙
𝑚𝑎𝑠𝑠 𝑁𝑎2 𝐶𝑂3 = 106 2.0 𝐿 0.44
𝑚𝑜𝑙 𝐿
32
16
18 Oct 2022
Questions???
https://media.giphy.com/media/acJ6UbGLUB2De/giphy.gif
33
References
• Silberberg (2004). “Chemistry. The Molecular Nature of
Matter and Change, 4th edition” McGraw – Hill
International Edition
34
17
18 Oct 2022
Thank You!
35
18