Kendiciya Vidyalaya Bangarch

Monthly Yest -

September 2023

-e-A
1 .
Standard electicode potential of SHE at 298K is
Osmotic Picessure has
2 .
advantage over rest of the
colligative properties .

.
3 ⑯O .
IMAC sol: Will have the highest conductivity at 298K .

strong electrolyte
HCl is a
+

conductivity
stronger the electrolyte &

4 .
K =

3 .
2xT0 Lmas' ; order of the Reaction : end

it'
nth order 1-n
-
K = extration) -

time
Sec .

5 .
A First orders reaction is 50 % completed in 1 .
26x16"s .

⑧ Infinite time would take For 100 % completion of iceaction .

6
i
Y
H
.

- -

, GHs

Bin I

diethyl bicomomethane
⑯ 3-Biomo pentane

7 .

Election displacement through the Sigma bund

:
⑯ Inductive effect .

.
8 & SCN ligand will not show chelation .

.
9 ⑰ Catalyst increases the Rate of Reaction .

lessen activation
⑫ Catalyst provides an alternative pathway
For the completion of chemical reaction
energy
.

⑫ & is the connect explanation of *.

⑨ Both ⑰ & correct x

10 .

A Cusoy can be stored in Zinc vessel .

⑫ In is more Reactive than (u .

& D but ⑫ is correct .

is wizong
11 .
⑰ order of the Reaction can be zero on fractional .

⑫ We cannot determine order from balanced chemical equation .

③ Both ⑰ are connect but ⑫ is not the correct explanation of

->B -

CH2
12 (i) +2 -CHC12 (ii) H22 -

de de
=
UPAC- 1 , 1 - Dichloroethane I
UDAC- 1 ,
2-Dichloroethane
name name
chloicide
Common -
Ethylidene Common -
Ethylene dichloride
name
(gem-dihalide) name (vic-dihalide)

13-

OR

14 .

Synergic Bonding in Metal Carbonyls :

(0) vacant & Orbital of

(i) ligand (lonepains of ->
Metal
M-C 5 band
+
=>

(ii) Filled & orbital of metal -> vacant antibonding

Orbital of CO
band
.

=> M-c +

effect Strengthens the M-CO bond

Synergic
-
:
-C

BI
15
-=H-H3
I
1 methyl-but-2-ene
:

i) Bicomo-2 :
He
t
(ii) chloride :

Its in-in-

(iii) Morphenylmethane Ph-ct-c(or) Csteg--CH2C

:
(02)
at
-

16 .

(OR)
17 .
* Conceptual Question
Cr (NH3) y 2
Bre
,

A B

+ AgNO3 + AgNO3
z
z

Pale-yellow ppt
.

White Precipitate
CAgC1) (AgBre)

I
dil NH3
(NH0H]
+
(NHyH conCYNH3
.

soluble soluble

C (Test

Cl
Fonct)
is ionisable
i e
.

,
C CTest
-

BR is
For Br)
ionisable i e .

is Bi is present
ce present
out side the
out side the

co-ordination sphere co-ordination sphere

[creNRs)n"27 Br
[Cr(NH3yce Bi] cl By
(i) At .

[Ar]' bdY *
us'
(ii) cret in both the cases
S Cre :

3 d 450
E cre+=

(x/xx/xx
IiK
&2543- octahedral geometry .

(iii) no . of unpaired electrom in (r+= 3

... Spin only magnetic moment :

+2) BM

:5 BM
-Pis oxidation state or Mn in (Mn(0)10] :
1 .

(ii) Structure of decacarbonyl di Manganese

CO

0 C -
-
in
IM
"
0 "I- do
[Mn, ]
07 ,

(iii) Oxidation state of pentacarbonyliion -

(iv) ccept :
In metal carbonyls ,

shorten will be
easien the
backbonding=
bonding) the band order
C
CH type CO
i . e more the no .
of i e
.
CO band length
, ,

des of metal .
will increases .

&
-=G
D &
T
inte
-
Back bonding easy

IY
Y
C II

8
e

easier donation of
et
8 O
From Filled & Orbitals of
*
Exr &
metals to vacant i orbital of
*

* 0x B S carom in CO
B c
.

6
stronger (B
. 0M)
t E) Higher required () If M-c band gets
Fou stronger band . X
omd gets weaken
(B 01)
0
.

vice-versa · - .

Just find the no of es of the metal valence shell

Trick :
.
.

moise the no .
of delectron =

trackbanding = 1,0 bondoteden .

(a) [MnCcos]Y :
> Mut :
[An)" us'3d5
Highest d ei
Ars--B <b) [Fecco)s] =1 Fe= Enj' YS3d- Es I co
Baden
<) GreCIO)s] = CR2 :

[AnY' us' 3d5

(1) [rccoss] =S v =
[AnY" us3d
 Section -
E

. It is Found does not

# also that a catalyst change the

equilibizium constant .

The catalyst forms a complex with the reactants and provides an alternate path with the
lower energy of activation for the reaction; the forward and backward reactions are
affected to the same extent.

⑪ These elements belong to the middle part of the periodic table and are present between the
s and p-block elements in the periodic table.
The d-block elements are called transition elements because they exhibit transitional
behaviour between s-block and p-block elements. Their properties are transitional between
highly reactive metallic elements of s-block which are ionic in nature and the elements of p-
block which are covalent in nature. Likewise, we can say that the d-block elements construct
a bridge between the s and p-block elements.

Allylic halide ic halide

⑪ ⑭

-
-

X-X
·

Cty
=

CH-ctG
-

Bir
·

CH=CH-BI

Enthalpy of atomization of transition elements

W Because of large number of unpaired electrons in their atoms, transition elements have
stronger interatomic interaction and hence stronger bonding between atoms resulting in
higher enthalpies of atomization.

⑱ Cu (4s1 3d10) and Zn (4s2 3d10) do not posses any unpaired d electrons, resulting a few
metallic bonding nature and hence called as soft metals.

OR

(1)

(11)
⑳ al
, is The pressure exerted by vapours of liquid on the surface of the liquid when
equilibrium is established between liquid and it's vapour is called vapour pressure of
a liquid.

Azeotropes are the binary mixtures of solution that have the same composition in liquid
(i) and vapour phase and that have constant boiling points throughout distillation.

(b) (d) gmi

Density of the Lake Water 1 25
=
.

Wsolvent :

1kg
g of Nations
92 of water
per kg .

ne

- Y

of thesolute
molality-moles See
Ym (
=

OR
⑧
, is Osmosis: The spontaneous uni-directional flow of the solvent molecules through a semi-
permeable membrane into the solution or flow of solvent to a solution of lower
concentration to a higher concentration, through a semi-permeable membrane is called
osmosis

(ii) A saturated solution is a solution in which the maximum amount of solute is dissolved under the
current conditions.
A saturated solution is a solution that contains maximum amount of the solute that can be
dissolved in a given amount of the solvent at a particular temperature is called a saturated
solution.

(b) cuSis cutas +

saas

[cu2t] (s2]
... Solubility product ,
ksp=
SXS
=
s
=

2
S
ksp
=

I s :
sp
·
t
I
x158
-

2 45
.
moll

(a) 2 45.
x508 M .

-
mon