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This scheme of work suggests possible teaching and learning activities for each section of
the specification. There are far more activities suggested than it would be possible to teach.
It is intended that teachers should select activities appropriate to their students and the
curriculum time available. The first two columns summarise the specification references,
whilst the Learning Outcomes indicate what most students should be able to achieve after
the work is completed. The Resources column indicates resources commonly available to
schools, and other references that may be helpful. The timings are only suggested, as are
the Possible Teaching and Learning activities, which include references to experimental
work. Resources are only given in brief and risk assessments should be carried out.
Many centres will have access to a Virtual Learning Environment (VLE), and Key Stage 4
related science materials. In the resources, reference is made to VLE and interactive
software. Most VLE software providers have similar presentations on the topics. Before
using any presentation, teachers are reminded that they should decide in advance which
slides are most suitable to achieve the learning objectives and edit the presentation
accordingly before the lesson.
Throughout this specification students will be expected to write word equations and write and
balance symbol equations for reactions specified.
Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
Spec Reference
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.1.1b Evidence for the Students should be familiar 1 Demo; Show suitable examples of
existence of particles with simple diffusion diffusion experiments or other
can be obtained from experiments such as experiments to show that matter is
simple experiments. Br2 /air,NH3 /HCl,KMnO4 /water. made from particles.
3.1.2 A simple model of the atom
3.1.2a All substances are Know that substances are 2 Activity: Use the Periodic Table to Periodic Table for
made of atoms. A made of atoms. State that elicit answers about: chemistry.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
substance that is made substances made of only list of known elements (about 100)
Information about the
of only one sort of one sort of atom are called location of non-metals and metals
Periodic Table can be
atom is called an elements. groups and periods
found on the BBC website
element. There are idea of atoms.
at
about 100 different Know that elements are use of symbols and rules for their
http://www.bbc.co.uk/educ
elements. Elements found in the Periodic Table. use
ation by searching for
are shown in the State where metals and proton number, mass number.
‘Periodic Table’.
Periodic Table. non-metals appear in the Task: Students make notes on their
Periodic Table. VLE/Interactive software,
Periodic Table, and in books.
eg Periodic Table slides.
3.1.2c Atoms have a small Know the structure of an Task: Students view/draw diagrams of VLE/Interactive software,
central nucleus, which atom. basic atomic structure naming sub- eg The Atom.
is made up of protons atomic particles.
and neutrons, and
around which there are
electrons.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.1.2d The relative electrical Know the charges on sub- Discuss: charges on sub-atomic View the Atomic structure .
charges are as shown: atomic particles. particles, and produce chart in books. PowerPoint presentation at
Proton – charge of +1 www.iteachbio.com/Chemi
Neutron – no charge stry/Chemistry/Atomic%20
Electron – charge of -1 Structure.ppt
3.1.2e In an atom, the Task: Work out number of electrons,
number of electrons is protons and neutrons in first ten
equal to the number of elements of Periodic Table. Results as
protons in the nucleus. diagrams or chart in books.
Atoms have no overall
electrical charge.
3.1.2j The relative masses of Discuss: Give the students the mass Know the
protons, neutrons and numbers for elements numbers 1-10. difference
electrons are: Ask them to find the pattern between between atomic
Name of particle Mass the mass numbers and sub-atomic number and mass
Proton 1 particles. number.
Neutron 1
Electron Very small
timing (lessons)
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Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.1.2l The relative atomic Students will not be Discuss: Why does chlorine have an
mass of an element expected to calculate Ar of 35.5? Introduce idea of average
(Ar) compares the relative atomic masses value for mass number, and relate to
mass of atoms of the from isotopic abundances. 12
C isotope.
element with the 12C
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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isotope. It is an
average value for the
isotopes of the
element.
3.1.2i Electrons occupy Students may answer 1 Review atomic structure, nucleus and Electron shell diagram Note: They do not
particular energy questions in terms of either electron cloud. sheet with elements have full outer
levels. Each electron in energy levels or shells. placed in same position as shells, except for
Explain: Introduce idea of shells within
an atom is at a Students should be able to Periodic Table, elements He and Ne. From
the cloud, and filling numbers and
particular energy level represent the electronic 1–20. Ne onwards they
order. Use electron shell sheet to
(in a particular shell). structure of the first 20 have eight
complete them. Teacher completes VLE/Interactive software,
The electrons in an elements of the electrons in their
elements 1,2,3,7 and 11, students eg Periodic Table slides.
atom occupy the Periodic Table in the outer shell.
complete others.
lowest available following forms: View the electron shell
energy levels PowerPoint presentation at
(innermost available http://education.jlab.org/jsa
shells). t/powerpoint/chembond.pp
t
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
3.2.1 Chemical bonds: ionic, covalent and metallic and 3.2.2 How bonding and structure are related to the properties of substances
3.2.1a Compounds are 1 Discuss the differences between
substances in which sodium (a highly reactive metal) and
atoms of two or more chlorine (a toxic gas), and the
elements are compound they form, sodium chloride
chemically combined. (a white, crystalline food flavouring and
preservative).
3.2.1c When atoms form Students should know that Ionic bonding Periodic Table. Know that the
chemical bonds by metals form positive ions, charge on an ion
Activity: Draw out ideas of electron View the bonding
transferring electrons, whereas non-metals form is related to its
shells, and noble gas configuration as PowerPoint presentation at
they form ions. Atoms negative ions. group in the
being unreactive. http://education.jlab.org/jsa
that lose electrons Students should be able to t/powerpoint/chembond.pp Periodic Table.
become positively Task: Students draw diagrams to Use their Periodic
represent the electron t
charged ions. Atoms explain how Na donates/transfers Table list to check
arrangement of ions in the VLE/Interactive software,
that gain electrons electron to Cl, so both achieve noble the charge on
following form: eg bonding part 1.
become negatively gas electronic structure. each ion.
charged ions. Ions Students attempt another single
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
Use Periodic Table to write 1 Explain: Teacher to explain method Periodic Table. Remember the
correct formula for ionic for writing formulae. formula multiplies
VLE/Interactive software
compounds. everything inside
Task: Students work out formulae for eg bonding part 1.
the brackets by
named compounds using Periodic
the number
Table for charges. At first concentrate
outside, when
on simple compounds with only two
dealing with
elements in them. Move on to more
molecular ions.
complex ones (acid radicals/molecular
ions etc) requiring the use of brackets Be careful to use
when students are confident about only subscript
simple balancing of charges. numbers to avoid
confusion with the
Homework: More examples of
charge. Never
formulae.
change the
subscript number,
instead they
should bracket
the polyatomic ion
and put a fresh
subscript outside
the bracket.
timing (lessons)
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3.2.2a Ionic compounds have Describe the NaCl crystal Discuss: Why are ionic compounds NaCl lattice model.
regular structures lattice and why it doesn’t hard to melt? Relate this to regular
View the bonding
(giant ionic lattices) in conduct electricity and is structure of sodium chloride crystal
PowerPoint presentation at
which there are strong hard to melt. structure, leading to idea of crystal
http://education.jlab.org/jsat/
electrostatic forces of formation from solution in regular way.
powerpoint/chembond.ppt
attraction in all Knowledge of the
Task: Students could make their own
directions between structures of specific ionic VLE/Interactive software,
model from marshmallows and
oppositely charged compounds other than eg bonding part 1.
spaghetti (or similar).
ions. sodium chloride is not Marshmallows (breakfast
These compounds required. Students draw diagrams to explain size) and spaghetti.
have high melting properties of sodium chloride.
points and high boiling Explain: consequences of how these
points because of the lattices result in high melting and
large amounts of boiling points, and inability to conduct
energy needed to electricity. Students make notes.
break the many strong
bonds.
3.2.2b When melted or Explain the electrical Explain: how ionic substances, when
dissolved in water, conductivity of ionic dissolved in water, can conduct
ionic compounds substances. electricity (and why as solids they
conduct electricity cannot). Students make notes.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
3.2.1g When atoms share Students should be able to Discuss: Bonding in non-metal View the bonding
pairs of electrons, they represent the covalent compounds. Teacher led discussion PowerPoint presentation at
form covalent bonds. bonds in molecules such as into properties of non-metal http://education.jlab.org/jsat
These bonds between water, ammonia, hydrogen, compounds, relating to the electronic /powerpoint/chembond.ppt
atoms are strong. hydrogen chloride, arrangements of non-metals and that
VLE/Interactive software,
Some covalently methane and oxygen in the electron shells are nearly full.
eg Bonding part 2.
bonded substances, following forms:
Task: Students to show/draw
such as H2, Cl2, O2, Molymods.
structures of, H2, Cl2, O2, HCl, H2O,
HCl, H2O, NH3 and
NH3 and CH4.
CH4, consist of simple
Students draw diagrams to explain
molecules. Others,
covalent bonding. Students should do
such as diamond and
some of these themselves as they
silicon dioxide, have
Students, given appropriate demonstrate understanding.
giant covalent
information, should be able
structures
to draw or complete
(macromolecules).
diagrams to show how
elements form covalent
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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compounds by sharing
electrons.
Students should be able to
recognise other simple
molecules and giant
structures from diagrams
that show their bonding.
3.2.2d Substances that Students need to Task: Students make notes, or answer
consist of simple understand that questions from DART worksheet,
molecules have only intermolecular forces are including questions about unknown
weak forces between weak compared with substances and their structures.
the molecules covalent bonds.
Homework: Past paper question on
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.2.2f Atoms that share Recognise diamond and 1 Task: Use a DART worksheet with DART worksheet, and Know that
electrons can also graphite from their some teacher input and access to models and diagrams of graphite is similar
form giant structures or structures. models of diamond, graphite and diamond, graphite and to metals in that it
macromolecules. silicon dioxide to allow students to fullerenes. has delocalised
Students should be able to
Diamond and graphite explore and understand how the electrons.
recognise other giant VLE/Interactive software,
(forms of carbon) and structure of each substance relates to
structures or molecules eg bonding. Be able to
silicon dioxide (silica) its properties.
from diagrams showing recognise other
are examples of giant their bonding. Students annotate diagrams and make giant structures or
covalent structures notes to explain structures and macromolecules
(lattices) of atoms. All properties. from diagrams
the atoms in these showing their
Provide students with diagrams for
structures are linked to bonding.
labelling, particularly of fullerenes.
other atoms by strong Concentrate on
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.2.1i Metals consist of giant 1 Demo: Show metal lattice structure, View the bonding
structures of atoms demonstrate how atoms can slide over PowerPoint presentation at
arranged in a regular each other and relate to properties. http://education.jlab.org/jsat
pattern. /powerpoint/chembond.ppt
timing (lessons)
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Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
by strong electrostatic
attractions. The
View the bonding
bonding in metals is PowerPoint presentation at
represented in the http://education.jlab.org/jsat
following form: /powerpoint/chembond.ppt
3.2.2g Metals conduct heat Explain the flow of an Discuss how atoms in a metal are
and electricity because electric current in terms of really ions in a sea of electrons and
of the delocalised delocalised electrons. this allows electrons to flow (electrical
electrons in their conductivity). Students make notes.
Students should know that
structures. conduction depends on the
ability of electrons to move
throughout the metal.
timing (lessons)
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3.2.3c In graphite, each Students should be able to Activity: Investigate the properties of Graphite, apparatus to
carbon atom bonds to explain the properties of graphite, including leaving marks on investigate electrical
three others, forming graphite in terms of weak paper, conduction of electricity, high conductivity, test tubes
layers. The layers are forces between the layers. melting point. and Bunsen burner.
free to slide over each
other because there
are no covalent bonds
between the layers
and so graphite is soft
and slippery.
timing (lessons)
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3.2.3e Carbon can also form Students are only required Research fullerenes, models of
fullerenes with different to know that the structure of fullerenes and their uses.
numbers of carbon fullerenes is based on
atoms. Fullerenes can hexagonal rings of carbon
be used for drug atoms.
delivery into the body,
in lubricants, as
catalysts, and in
nanotubes for
reinforcing materials,
eg in tennis rackets.
3.2.4 Nanoparticles
3.2.4a Nanoscience refers to Students should know what 1 Task: Students use internet and other View the ‘nanoscience Be able to
structures that are 1– is meant by nanoscience resources to find out about uses’ PowerPoint describe why a
100 nm in size, of the and nanoparticles and nanoscience, and nanoparticles, and presentation at named and
order of a few hundred should consider some of their current applications. http://nanosense.sri.com/a explained
atoms. Nanoparticles the applications of these ctivities/sizematters/applic nanoparticle
Task: In groups produce mini project/
show different materials, but do not need ations/SM_AppSlides.ppt would be useful in
poster.
properties from those to know specific examples a particular
for the same materials or properties. Alternatively groups give class application.
presentation on one use of
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.3.1 Metals
3.3.1a Metals are useful 1
Demo: Show metal lattice structure,
materials as they are
demonstrate how atoms can slide over
good conductors of
each other and relate to properties,
heat and electricity.
using e.g. polystyrene balls.
They can also be bent
or hammered into
shape because the
layers of atoms in
metals are able to slide
over each other.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.3.1b An alloy is a mixture of Students may be given Demo: Insert a different-sized ball to
at least two elements, information on the show alloy effects make sliding harder
at least one of which is composition of specific to achieve.
a metal. Alloys often alloys so that they can
Task: Students draw diagrams to
have properties that evaluate their uses.
explain metal and alloy structure and
are different from the
properties.
metals they contain.
This makes them more Demo: Compare samples of pure
useful than the pure metals with alloys, eg copper and
metals alone. Steels brass, iron and steel.
are a mixture of iron
with carbon and
sometimes other
metals.
• it is a good
conductor of heat
and electricity
• it can be bent but
is hard enough to
be used to make
pipes or tanks
• it does not react
with water.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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be able to do Homework Students should:
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aqueous solution and to write the ionic metals and the metals. zinc sulfate, test tubes or
establish positions equations. dropping tiles, foils of Cu,
Students should report their findings
within the reactivity Zn, and Mg, iron filings.
Students should be aware and:
series.
that copper can be For the demo. This is a
• describe the pattern using the dangerous demo, which
obtained from solutions of
reactivity series from last lesson you should carry out only if
copper salts by
• write ionic equations for the you are confident and
displacement using scrap reactions
iron. competent to do so.
Demo: If time (and nerves) permit, Dry iron(III) oxide,
demonstrate a thermite reaction eg aluminium powder.
iron oxide with aluminium using a magnesium ribbon,
magnesium ribbon fuse. crucible, bucket of sand.
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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3.3.2c During electrolysis, Know positively charged Discuss: Relating to ions, movement
positively charged ions ions move to the negative and attraction to the positive and
move to the negative electrode, and negative negative electrodes. Students draw
electrode the cathode), ions to the positive diagrams to explain.
and negatively electrode.
Demo: If there is time, demonstrate
charged ions move to
Predict the products of movement of ions, eg the electrolysis
the positive electrode
electrolysing solutions of of a crystal of KMnO4 on filter paper
(the anode).
ions. dampened with sodium chloride
solution.
3.3.2f Reactions at Students should be able to Use half equations to show electron
electrodes can be write half equations for the transfers.
represented by half reactions occurring at the
equations, for electrodes during
example: electrolysis, and may be
required to complete and
2Cl → Cl2 + 2e
- -
balance supplied half
or equations.
2Cl - 2e → Cl2
- -
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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3.3.2h Electrolysis is used to Know what electroplating is 1 Activity: electroplating copper foil with Copper electrode, nickel
electroplate objects. and how it works. nickel (using nickel sulfate solution). electrode, power pack and
-3
This may be for Students report their experiment. wires, 1 mol dm NiSO4
3
reasons such as solution and 100 cm
Discuss: Uses of electroplating
appearance, durability beaker.
including silver and copper. Explore
and prevention of
what is happening in terms of electrons
corrosion. It includes
at both electrodes. Students draw
copper plating and
diagrams to explain.
silver plating.
3.3.2i Aluminium is Students should 1 Task: Explore the extraction of VLE/Interactive software, Remember that
manufactured by the understand why cryolite is aluminium, as either video or eg Useful materials from the only reason
electrolysis of a molten used in this process. worksheet, or use RSC Alchemy, or metal ores. that cryolite is
mixture of aluminium mini-project. needed for the
Students should be aware Visit the RSC Alchemy for
oxide and cryolite. process is to
that large amounts of Do students know that in the 1850s more information on
Aluminium forms at the reduce the
energy are needed in the aluminium was the most expensive Aluminium at
negative electrode and melting point of
extraction process. metal in the world (it was extracted www.rsc.org/Education/Te
oxygen at the positive aluminium oxide
from its ore by a thermite reaction achers/Resources/Alchem
electrode. The positive to less than
using sodium metal)? Now, with y/index.htm
electrode is made of 1000°C and save
electrolysis, it is cheap enough to
carbon, which reacts
make cans from. money/reduce
with the oxygen to
energy costs.
produce carbon
dioxide.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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timing (lessons)
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www.rsc.org/Education/Te
Discuss: Why hydrogen is formed.
achers/Resources/Alchem
Relate to reactivity series position of
y/index.htm
sodium, and industrial uses of sodium
chloride. Students make notes.
3.4 Chemical Analysis
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
the substances in a
mixture by physical
methods, including
distillation, filtration
and crystallisation.
3.4.1d Paper chromatography Students should be able to Activity: Using paper Food dyes or inks, filter
can be used to describe how to carry out chromatography. The Rf value for each paper/chromatography
analyse substances paper chromatography of the dyes used should be calculated. paper, pipettes and 250
3
present in a solution, separations and how the cm beaker.
eg food colourings and components of a mixture
inks/dyes. can be identified using Rf
values. They have to be
aware that solvents other
than water can be used.
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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result in a green
flame.
3.4.3b Aluminium, calcium Students should be able to 1 Discuss: Teacher-led discussion Test tubes, NaOH (aq),
and magnesium ions recognise the presence of about another method of identifying pipettes, solutions of:
form white precipitates these ions in water by this metal ions, this time using sodium
CuSO4
with sodium hydroxide test. hydroxide.
solution but only the AlCl3
Activity: Adding sodium hydroxide
aluminium hydroxide
solution to solutions of metal ions. FeSO4
precipitate dissolves in
Students should add small amounts of
excess sodium FeCl3
sodium hydroxide and observe what
hydroxide solution.
happens after each addition. Students MgCl2
3.4.3c Copper(II), iron(II) and should be warned that adding more to
one solution will produce a further CaCl2
iron(III) ions form
coloured precipitates change. NB: FeSO4 must be freshly
with sodium hydroxide Task: Students prepare and complete produced.
solution. Copper (II) results chart. Remind them that each
forms a blue solid that appears is a precipitate.
precipitate, iron(II) a
green precipitate and
iron(III) a brown
precipitate.
3.4.3d Carbonates react with Recognise the presence of 1 Demo: Teacher-led demonstration of Test tubes and racks,
dilute acids to form these ions in water by effect on acid on carbonates, and silver nitrate solution,
carbon dioxide. these tests. limewater test as a revision and dilute nitric acid, dilute
Carbon dioxide introduction to testing halide and hydrochloric acid, barium
produces a white sulfate ions. chloride, solution, solutions
precipitate with of sodium, sulfate, sodium
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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limewater, which turns Activity: Test halide ions, and then chloride, sodium bromide
limewater cloudy sulfate ions. and sodium iodide.
white.
Task: Students prepare a results chart
and complete it:
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.5.1b Acids react with bases Know that acid + alkali Activity: making a salt by
to form salts. These makes salt + water. neutralisation of an alkali, eg NaCl (pH
reactions are called sensors could be used here instead of
neutralisation indicator paper or solution to be able to
reactions. crystallise the salt without the need for
boiling with carbon).
+
3.5.1f Hydrogen ions, H (aq), Students should be familiar Homework: Students draw diagrams
make solutions acidic, with the pH scale from 0 to to explain the method.
and hydroxide ions, 14, and know that pH 7 is a Use symbol equation with state
-
OH (aq), make neutral solution. symbols to describe reaction (and
solutions alkaline. The Students should be able to should use state symbols hereafter
pH scale is a measure describe the use of when completing symbol equations).
of the acidity or universal indicator to
alkalinity of a solution. measure the approximate
pH of a solution.
3.5.1d Ammonia dissolves in Activity: ammonia as an alkaline
water to produce an solution in water and how it can
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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3.5.1c The particular salt Know which acid makes 1 Revise all reactions to make salts so VLE/Interactive software, Be able to state
produced in any which salt, and which metal far, include writing word and symbol eg chemical reactions. the substances
reaction between an makes which salt. equation (if not already done) for each needed to make
acid and a base or one, including the state symbols. the salt and name
Students should be able to
alkali depends on: the salt, given the
suggest methods to make a Task: Students to come up with rules
• the acid used named soluble salt. for making soluble salts, eg nitric acid names of the
(hydrochloric acid makes nitrates etc. Students make metal and acid
produces chlorides, notes. used.
nitric acid produces
Task: Making a salt. Students to be
nitrates, sulfuric
given list of salts to make, and they
acid produces
should state the chemicals needed and
sulfates)
the method to use to make each salt. A
• the metal in the card game could be produced with
base or alkali. names of salts, acids, ions, and
possible ingredients. Students produce
word equation of the reaction needed
to make each salt, add the method of
production, then attempt to write
balanced symbol equation.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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reacted to produce soluble salt from an by class titration practical to establish measuring cylinder / Note: It should be
3
a salt solution. insoluble base. idea that the volumes of acid and alkali 25cm pipette, conical highlighted that
can be measured using a suitable flask, white tile clamp and averaging out
indicator. Whilst universal indicator will stand solutions of results can give
-3
work, better to use phenolphthalein as 0.5 mol dm , hydrochloric more reliable
the indicator as it gives a definite end acid, sodium hydroxide, results.
3
point. 250cm beakers and
phenolphthalein.
Task: Students draw equipment and
record their results. Calculate the
mean for the titration and then
compare their results.
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.6.1c No atoms are lost or Know that all atoms 1 Tasks: Students carry out and report Balances, boiling tubes, Be able to
3
made during a involved in a reaction must precipitation reaction experiments such 25cm measuring calculate the
chemical reaction so be accounted for. as lead nitrate and potassium iodide to cylinders, lead nitrate mass of a
-3
the mass of the Students should be able to observe there is no change in mass on solution 1 mol dm , reactant or
products equals the calculate the mass of a forming products. potassium iodide product from
–3
mass of the reactants. reactant or product from Homework: Students do calculations 1 mol dm information about
information about the the masses of the
using mass of reactants and products
masses of the other other reactants
to find mass formed of one product or
reactants and products in and products in
mass needed of one reactant.
the reaction and the the reaction.
balanced symbol equation.
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.6.1e Even though no atoms 1 Discuss: Class discussion about Calculation worksheets. Be able to
are gained or lost in a result of the experiment from last evaluate and
chemical reaction, it is lessons, and why results are not VLE/Interactive software, make judgements
not always possible to always correct. eg quantitative chemistry. for the data in the
obtain the calculated question.
Include reference to yield, and
amount of a product
percentage yield. Students make notes
because:
on yield and percentage yield.
• the reaction may
not go to
completion
because it is
reversible
• some of the
product may be
lost when it is
separated from the
reaction mixture
• some of the
reactants may
react in ways
different from the
expected reaction.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
3.6.2c The empirical formula Students should be able to 2 Activity: Finding the formula of Magnesium, crucible and Be able to work
of a compound can be calculate empirical magnesium oxide. Students report lid, balance, crucible out the formula of
calculated from the formulae from given their experiment. tongs, spills and matches, a compound from
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
masses or information. Explain: Teacher led explanation of tripod, gauze, and Bunsen the reacting
percentages of the how to make the calculation using burner. masses provided
elements in a either the graph method or from mass in the question.
Graph paper.
compound. readings. Students find the formula
using chosen method. VLE / Interactive software,
You could use either a graphical eg quantitative chemistry.
method where each group plots their
result on a graph to establish best fit
line to get answer from, or calculate
mean for the class to process using
atomic masses.
You could also use both methods to
see which gives result closest to the
true value.
Homework: Give a formula
calculation from reacting masses for
another compound. Make sure
students know the method from the
experiment.
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.6.3c The relative formula Students are expected to Explain: Show how to make the
mass of a substance, use the relative formula calculation for simple, then more
in grams, is known as mass of a substance to complex formulae.
one mole of that calculate the number of
Task: Students do examples of
substance. moles in a given mass of
calculations with increasing
that substance and vice
complexity.
versa.
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
number of moles
concentration �mol/dm3 �=
volume �in dm3 �
3.6.4b The volumes of acid Students should be able to 2 Required practical: Establish the
and alkali solutions carry out titrations using concentration of an unknown strong
that react with each strong acids and strong acid through titration with a strong
other can be measured alkalis only (sulfuric, base.
by titration using a hydrochloric and nitric acids
suitable indicator. only).
3.6.4c If the concentration of Students should know how Remind students about relative
one of the reactants is to carry out a titration and molecular mass (Mr). Remind them
known, the results of a be able to calculate the that the Mr in grams if dissolved in
titration can be used to chemical quantities in water provides a concentration unit
find the concentration titrations involving that we can use to compare different
of the other reactant. concentrations (in moles solutions.
3
per dm ) and masses (in
Task: Students make brief notes on
molecules and how dissolving different
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
3
grams per dm ). proportions of the Mr produces
solutions of different concentrations.
Explain: Using last time’s results,
show how to work out the
concentration of the acid assuming
–3
1 mol dm sodium hydroxide was
used.
Tell students they need the balanced
equation to work out reacting amounts
and to work out the unknown using the
equation:
Conc of acid x volume used
conc of alkali x volume used
=
no of acid molecules in equation
no of alkali molecules in equation
Give students other examples to
calculate the answers for. One should
also involve using grams instead of
moles.
3.6.4d The molar gas volume Students are expected to 1 Explain: Show how to do the
at room temperature be able to calculate the calculations for simple, then more
and pressure is amount of gas in a reaction complex examples. Include mixed
3
assumed to be 24 dm calculations involving masses of
by using molar amounts of
reactants or products as well as gas
gases and their volumes. volumes.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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be able to do Homework Students should:
3.7 Periodicity
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
• form hydroxides
that dissolve in
water to give
alkaline solutions.
3.7.1d In Group 7, the further Know that the further down Demo: Students make list of halogens, Samples of chlorine, Be able to write
down the group an the group: their colours and their state at room bromine and iodine in and balance
element is: temperature. Remind students of sealed containers. symbol equations.
• the less reactive the colour of chlorine (seen with NaCl
• the less reactive element is reaction). Show samples of other
the element • the higher its melting halogens if possible, if not use halogen
• the higher its point and boiling point. waters from the class experiment to
melting point and show their colour when dissolved in
boiling point. water.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.7.1e A more reactive Know that a more reactive Activity: Displacement reactions – Aqueous solutions of
halogen can displace a halogen can displace a less Students add chlorine water to each of chlorine, and bromine, and
less reactive halogen reactive halogen from an the three compounds and observe iodine solution (iodine in
from an aqueous aqueous solution of its salt. results. Add bromine water to fresh potassium iodide).
solution of its salt. samples of the compounds and Pipettes, test tubes, test
observe results. Add iodine solution to tube racks, solutions of
fresh samples of the compounds and sodium chloride, sodium
observe results. iodide, and sodium
Discuss: Findings from results chart. bromide (alternatively
these could be potassium
Conclude that halogens higher in the compounds).
Group displace halogens that are
lower from their compounds.
Task: Write symbol equations and
balance for one reaction. All reactions
standard.
3.7.1f The trends in reactivity Students should be able to 1 Discussion on reactivity in Group 7 Explain the
within groups in the explain the relative and Group 1. This should be in terms reactivity trends
Periodic Table can be reactivities of the elements of ease of losing/gaining outer within both Group
explained because the in Group 1 and 7. electrons. 1 and Group 7 in
higher the energy level terms of the
Metals easier to lose from outside as
of the outer electrons: distance of the
less attracted to nucleus further down
• the more easily the group. outer electron
electrons are lost from the central,
Non-metals easier to gain up the group positively charged
• the less easily due to stronger attraction from nucleus
electrons are nucleus, and the
as fewer electron shells. attraction of the
gained.
nucleus to those
outer electrons.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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timing (lessons)
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and with sufficient Know that for a reaction to test out theory to see if it explains how
energy. The minimum happen particles have to rates of reaction change.
amount of energy collide with sufficient
Homework: Explain the difference
particles must have to energy to react, and that
between a guess, hypothesis, and
react is called the this amount of energy is
theory.
activation energy. called the activation
energy.
Know that a hypothesis has
to be successfully tested
before it becomes accepted
scientific knowledge.
3.8.1f Increasing the surface Know how particle size 1 Demo: Use decreasing mass method Large and small marble Note: Allow
area of solid reactants affects rate of reaction. to investigate reacting equal masses of chips, balance, dilute students to ‘do‘
3
increases the large chips and small chips of marble hydrochloric acid, 250 cm the experiment
Use collision theory to
frequency of collisions with dilute hydrochloric acid. conical flask, cotton wool, themselves. A
and so increases the explain the change in rate stopwatch.
in terms of particle Students describe the experiment. video camera
rate of reaction. showing the
behaviour. Graph paper.
Students plot graph of results, and use balance, and stop
the hypothesis of collision theory to VLE/Interactive software, watch, connected
explain the results. eg Rates. to a projector
Discuss: Discussion on why every allows students to
particle doesn’t react at once to get take
idea of minimum (activation) energy measurements
required for a collision to cause a themselves.
reaction. Students make notes.
3.8.1e Increasing the Know how concentration 1 Activity: Disappearing cross method. Sodium thiosulfate Always remember
concentration of affects rate of reaction. solution, hydrochloric acid, to mention how
Task: Students investigate sodium
reactants in solutions conical flasks, the particle speed
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
increases the Use collision theory to thiosulfate solution and dilute stopwatches, graph paper. and/or numbers
frequency of collisions explain the change in rate hydrochloric acid. Can be done with and/or
Laminated, photocopied
and so increases the in terms of particle datalogging or by eye. temperature
crosses on paper are a
rate of reaction. behaviour. accounts for the
Use different methods to obtain good idea, to give a
Know that collision theory results/instrumentation. Students standard image for viewing observed change,
has now been successfully explain the results again in terms of through the flask. when asked why
tested. the hypothesis. Teacher-led a rate changes.
discussion, should we make this a
theory rather than hypothesis?
Homework: Students plot graph of
results and interpret it.
3.8.1d Increasing the Use the collision theory to 1 Consolidation lesson on collision VLE/Interactive software
pressure of reacting explain how the change in theory, rates of reaction and activation eg rates.
gases increases the conditions affects the rate energy.
frequency of collisions of any reaction, in terms of
Task: Students could draw particle
and so increases the particle behaviour.
diagrams to show how each change in
rate of reaction.
Know how gas pressure conditions affects the particle mixture
affects rate of reaction. in the reaction and how this relates to
the theory.
Homework: Make a prediction on the
effect of altering the pressure on a gas
reaction.
timing (lessons)
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3.8.1g Catalysts change the Know that catalysts change 1 Discuss: Why do cars have catalysts Manganese (IV) oxide Note: In
rate of chemical the rate of a chemical in their exhaust system? What do they /liver/potato spatula, 20 vol questions
reactions but are not reaction. This is important do? hydrogen peroxide, involving industry
used up during the in industry to reduce costs. balance, measuring and catalysts,
Activity: Investigating effect of
reaction. Different cylinder and boiling tube. students should
catalysts. Use one or more of these
reactions need be given
catalysts on hydrogen peroxide: liver, VLE/Interactive software,
different catalysts. information that
potato, manganese(IV) oxide. Students eg transition metals.
report their experiment. they need to
3.8.1h Catalysts are important Describe the benefit of
in increasing the rates evaluate eg Why
using a catalyst for a given Explain: Develop idea of catalysts
of chemical reactions is a catalyst used
process to the industry helping the reaction to take place. You
used in industrial that reduces the
involved. may wish to mention how catalysts
processes to reduce reacting
work, active sites, forming
costs. temperature?
intermediates etc.
Because reducing
Explain: The value to industry of using the temperature
catalysts in terms of reducing costs will save energy
etc. Students make notes. and make the
Homework: Past paper question on process cheaper.
rates.
3.8.2 Factors affecting equilibrium
3.8.2a When a reversible 1 Demo: Show effect of adding acid, VLE / Interactive software, Note: Dynamic
reaction occurs in a then alkali, to bromine water to reversible reaction equilibrium is just
closed system, demonstrate what we mean by an like the latest ride
equilibrium is reached equilibrium. Students to make notes on at a theme park.
when the reactions equilibrium and the use of the symbol There’s always
occur at exactly the to represent reversible reactions. the same number
same rate in each on the ride; it is
Discuss: How equilibrium is only
direction. just that at the
reached when the products are being
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
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be able to do Homework Students should:
the conditions of the reaction or process. water into one cylinder. Transfer water
reaction. from one cylinder to the other using a
finger over the end of each tube in turn
(keep the tubes in the same cylinder)
3.8.2c If the temperature is until the level in each cylinder does not
lowered, change any more.
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.8.2f Sulfuric acid is Students should be able to 1 Discuss: How we can make the most Resources and a video on
produced industrially describe the stages in the sulfuric acid, as cheaply as possible, sulfuric acid can be found
using the contact contact process and also to and as environmentally friendly as on the RSC Alchemy
process. It is a three- explain why a catalyst, a possible. website at
stage process, which high temperature and www.rsc.org/Education/Te
incorporates a atmospheric pressure result Explain: Use resources from Royal
achers/Resources/Alchem
reversible process and in more yield of sulfur Society of Chemistry (RSC) Alchemy
to explain and provide activities for y/index.htm
the use of a catalyst. trioxide in Stage 2.
students to understand the basics of
Stage 1: Sulfur is the Contact process. Watch video clip.
burned in air to
produce sulfur dioxide
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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3.9.1d In some chemical Explain what is meant by a 1 Task: Students carry out circus of Test tube, copper sulfate,
reactions, the products reversible reaction, and its reversible reactions: spatulas, stand and clamp,
3
of the reaction can symbol. pipette and 100cm
copper sulfate hydration/
react to produce the beaker.
Name a reversible reaction. dehydration
original reactants.
heating ammonium chloride in a VLE/Interactive software,
Such reactions are
test tube eg reversible reactions.
called reversible
adding alkali and acid alternately
reactions and are
to bromine water or to
represented as follows:
potassium chromate solution
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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3.9.1e If a reversible reaction Realise that in a reversible 1 Activity: Students should investigate Copper sulfate, spatula,
is exothermic in one reaction the same energy the temperature changes for the test tubes, pipettes, and
3
direction, it is change takes place in reversible reaction: 100 cm beaker.
endothermic in the either direction.
opposite direction. The
same amount of Homework: Students report their
energy is transferred in experiment.
each case. For
example:
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
can be measured by by different fuels given the energy released? balances and samples of calories to joules,
simple calorimetry, eg equation: alcohols for the burners, the conversion
Students list likely variables that will
by heating water in a eg methanol, propanol, factor should be
have impact including:
glass or metal ethanol and butanol. given in
container. This method Q=mc ∆T mass/ volume of water questions.
can be used to temperature rise
compare the amount of how much energy it takes to heat
0
energy produced by the water by 1 C
fuels.
Discuss how these link into the
equation:
3.9.2b Energy is normally Q=mc ∆T
measured in joules (J).
For comparison Activity: Find the amount of energy
purposes, energy produced by different alcohols when
values could be given burned. Suggest alcohol is burned for
in kJ or calories for a two minutes, as a control. Two
given mass or amount practical groups could do each alcohol,
of substance, eg so they can compare their results for
calories per gram, kJ reliability, and analyse errors. Students
per mole or kJ per describe their method and results.
gram. Students should then use their results
to do the calculation and then compare
their results with the other group using
the same alcohol. Students should
discuss causes of error in their
method, and understand the
importance of control variables. They
should jointly produce a list saying how
they could improve their control of the
variables they identify.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.9.2c The amount of energy 1 Activity: Measuring energy changes in Expanded polystyrene
produced by a other reactions. cup, glass rod, measuring
chemical reaction in cylinders, dilute acid and
Students do neutralisation reaction in
solution can be alkali and a thermometer.
expanded polystyrene cup. Measure
calculated from the
temperature rise and calculate using:
measured temperature
change of the solution Q = mc ∆T
when the reagents are
Remind students that energy change is
mixed in an insulated
container. This method measured in joules.
can be used for Discuss: Class discussion on how to
reactions of solids with represent the result in the class
water or for experiment graphically.
neutralisation
reactions.
3.9.2d Simple energy level Students will be expected 1 Task: Draw energy level diagram for Be able to
diagrams can be used to understand simple combustion. calculate the
to show the relative energy level diagrams energy change
Task: Students draw their own energy
energies of reactants showing the relative from an energy
level diagram for their neutralisation
and products, the energies of reactants and level diagram.
reaction.
activation energy and products, the activation
Tip: Subtract the
the overall energy energy and the overall Homework: Students are given five
value for the
change of a reaction. energy change, with a energy level diagrams, and they
reactant line from
curved arrow to show the calculate from the y-axis the energy
the value for the
energy as the reaction change. At least one should be an
product line. If the
proceeds. Students should endothermic reaction.
value is negative,
be able to relate these to
then the reaction
exothermic and
is exothermic,
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.9.2h Catalysts provide a Students should be able to Activity: What happens when we use Test tubes, measuring Understand that
different pathway for a represent the effect of a a catalyst? Using a catalyst, eg MnO2 cylinders, MnO2 powder, lowering the
chemical reaction that catalyst on an energy level with H2O2, simply in terms of rate of spatula and 20 vol H2O2 activation energy
has a lower activation diagram. reaction. reduces costs in
Or
energy. industrial
You could instead demonstrate adding
CuSO4 powder, conical processes.
copper sulfate to already reacting zinc
flask, zinc granules and
granules and hydrochloric acid to see
dilute HCl(aq).
rate increase.
Discuss: The idea of activation energy
as a hurdle of energy that the reacting
particles have to overcome before
collisions become reactions (collision
theory link here).
Activity: Represent the reaction as an
energy level diagram, showing the
uncatalysed reaction with high
activation energy (hurdle), and the
catalysed reaction having a lower
activation energy (hurdle) to pass.
3.9.2e During a chemical Students should be able to 1 Why do chemical reactions have Molymods. Remember to
reaction: calculate the energy energy changes? Use zinc reacting count every bond
CuSO4 powder, conical
transferred in reactions and with hydrochloric acid as example. as the first step in
energy must be flask, zinc granules and
interpret simple energy Make molymods to represent the the calculation.
supplied to break dilute HCl(aq).
level diagrams in terms of atoms and molecules in the balanced Students should
bonds
bond breaking and bond equation (useful to get students to give also remember
energy is released
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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be able to do Homework Students should:
when bonds are formation (including the you the equation first). the need to
formed. idea of activation energy multiply bond
Discuss: The need for energy to break
and the effect on this of energies by the
the bonds in hydrochloric acid. Draw
catalysts). number of each
energy level diagram showing the
atoms separated, then ask if energy is type of bond to
needed to break bonds and what is get the right
produced when bonds form? Add answer.
3.9.2f In an exothermic Students should be able to products to the energy level diagram to
reaction, the energy calculate the energy show the reaction is exothermic.
released from forming transferred in reactions
Task: Students construct molymods to
new bonds is greater using bond dissociation
show breaking bonds and re-forming
than the energy energies supplied.
them, then draw energy level diagram.
needed to break
existing bonds. Task: Students explain how they think
an endothermic reaction happens, and
3.9.2g In an endothermic make notes, and draw energy level
reaction, the energy diagram.
needed to break
existing bonds is Explain: That chemists know how
greater than the much energy is needed to break a
energy released from bond between two atoms. Represent
forming new bonds. how to use these to work out the
energy transferred in one reaction, eg:
2 H2 + O2 2H2O
Homework: For four examples or
more, students use bond energies to
calculate energy transfer, and if a
reaction is endothermic or exothermic
(give them the balanced equation).
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.9.3b Fuel cells produce Students should be able to 1 Task: Students research the
electricity through the compare the advantages advantages and disadvantages of fuel
reaction of a fuel with and disadvantages of the cells with other forms of energy. This
oxygen. Hydrogen- combustion of hydrogen could be set as a homework.
oxygen fuels cells use with the use of hydrogen
hydrogen as their fuel, fuel cells from information
and are useful in cars that is provided.
and spacecraft. Water
Students should know and
is the only waste
understand the benefits
product from a
and disadvantages of
hydrogen-oxygen fuel
hydrogen fuel in terms of:
cell, so they cause less
pollution when in use. storage and use
products of
combustion.
Knowledge of the details of
the reactions in fuel cells is
not required.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
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be able to do Homework Students should:
timing (lessons)
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3.10.1.2 Hydrocarbons
3.10.1 Some properties of Describe the relationship 1 Refer back to the table of results from
.2c hydrocarbons depend between molecule size and the previous lesson.
on the size of their boiling point, viscosity,
molecules. These ease of ignition, and
properties influence flammability.
how hydrocarbons are Knowledge of trends in
used as fuels. properties of hydrocarbons
is limited to:
boiling points
viscosity
flammability.
3.10.1 Most of the Students should know that 1 Demo /Activity: Name each formula VLE/Interactive software,
.2a hydrocarbons in crude in saturated hydrocarbons and draw methane, ethane and eg ‘organic chemistry‘ and
oil are saturated all the carbon–carbon propane as examples of alkanes in ‘useful organic’.
hydrocarbons called bonds are single covalent both forms. Show as models.
Molymods or similar.
alkanes. The general bonds. Elicit general formula for alkanes.
formula for the
homologous series of Discuss: the use of a line as
alkanes is CnH2n+2. representing a single covalent bond.
3.10.1 Alkane molecules can Describe what the Task: Students draw molecular
.2b be represented in the structural formula shows. diagrams adding in notes to the
following forms: diagrams of methane, ethane, and
Know the general formula
propane as alkanes.
C2H6 for alkanes.
or Students should know that
in displayed structures a —
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.10.1 Most fuels, including Students should be able to 1 Demo: Burning a candle, and passing Equipment as in diagram. Know that
.2d coal, contain carbon relate products of exhaust gases through anhydrous products of
VLE/Interactive software
and/or hydrogen and combustion to the elements copper sulfate/cooling U tube and combustion
eg, ‘useful air’ and ‘Earth
may also contain some present in compounds in cobalt chloride paper, then limewater. depend on the
and atmosphere’.
sulfur. The gases the fuel and to the extent of elements present
released into the combustion (whether Access to internet. in the fuel (check
atmosphere when a complete or incomplete). the formula) and
fuel burns may include how much oxygen
No details of how the
carbon dioxide, water candle here is present.
oxides of nitrogen are
(vapour), carbon Carbon monoxide
formed are required, other
is made if there is
monoxide, sulfur than the fact that they are
not enough
dioxide and oxides of formed at high
Draw attention to need for control oxygen present
nitrogen. Solid temperatures.
experiment to compare the results. for complete
particles (particulates) combustion, but
Students label diagram and make
may also be released. results chart. really serious
Solid particles may Note: Soot formation by incomplete shortage of
contain soot (carbon) combustion. oxygen makes
and unburnt fuels. soot (carbon).
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
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3.10.1 Ethanol can be made Students should be able to 2 Discuss: Evaluate the advantages Sugar, yeast, limewater,
3
.2f by reacting ethene with compare the two ways of and disadvantages of making ethanol 250 cm conical flask and
steam. making ethanol in terms of from renewable and non-renewable bung with delivery tube.
C2H4 + H2O → type of raw material, type of sources. test tube, distillation
C2H5OH process, labour, rate of apparatus
Homework: Past paper questions/
Phosphoric acid is reaction, conditions
worksheet on advantages and VLE/Interactive software,
used as a catalyst to needed, purity of product
disadvantages of making ethanol from eg organic chemistry.
increase the rate of the and energy requirements.
renewable and non-renewable
reaction.
Students should know that sources.
This is efficient
ethanol for use as a biofuel
because it is a Activity: Making ethanol with yeast.
is produced from a dilute
continuous process. (You could start the culture and in the
solution of ethanol obtained
However, ethene is a second lesson distil the ethanol.)
by the fermentation of plant
non-renewable
materials at a temperature Students make notes on fermentation
resource which may
between 20 °C and 35 °C. and distillation.
run out one day.
Detailed knowledge of the
Ethanol can also be
methods used to produce
made by fermenting
other biofuels is not
sugar:
required.
C6H12O6 →
2C2H5OH + 2CO2 Students should know and
Enzymes in yeast are understand the benefits
natural catalysts for
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.10.1 Unsaturated Students should know that 2 Discuss: Introduce idea of double Molymods. Remember that
.3c hydrocarbon ‘=’ represents a double bond using structural formula of ethene ‘=’ means a
Bromine water, test tubes,
molecules can be bond in the structure. and propene. double covalent
test tube racks, liquid
represented in the bond, and that ‘–‘
alkanes, eg pentane,
following forms: Students should be able to means a single
hexane, liquid alkenes, eg
recognise alkenes from Required practical: Test for the covalent bond. A
C3H6 or hexene, cyclohexene.
their names or formulae, presence of a double bond in an double bond
but do not need to know the unknown hydrocarbon. means that the
names of individual alkenes compound is
other than ethene and Activity: Class practical testing for unsaturated. A
double bonds using bromine water. single bond
propene. Students should test a range of named means that the
alkenes and alkanes. Students make compound is
notes. saturated.
3.10.1 Alkenes react with Know that the presence of Homework: Students predict reactions
.3d bromine water, turning double bonds in a molecule
of a variety of molecules displaying
it from orange to can be tested for by the
single and double bonds with bromine
colourless. decolourisation of bromine
water.
water.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.10.1 Some of the products Know that cracking Explain: Show with models how
.3e of cracking are useful produces more useful breaking large molecules produces not
as fuels. molecules including only alkenes, but also more fuels like
alkenes and fuels. petrol (octane) and diesel
(dodecanes).
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.10.2 The properties of Know that: 1 Review ideas of polymers. Show Selection of polymers with Be able to explain
b polymers depend on examples of polymers or use circus on different properties why the structure
LD polythene and HD
what they are made properties such as transparency, including LD and HD gives the property
poly(ethene) are made
from and the flexibility, stretching etc. Including LD poly(ethene). or vice versa.
using different catalysts
conditions under which and HD poly(ethene). Ask what causes
and conditions
they are made. For these differences.
the differences in
example, low density polymers’ properties Activity: Identifying LD and HD
(LD) and high density depend on the monomer poly(ethene) using 50 parts ethanol
(HD) poly(ethene) are used and also the and 50 parts water mix.
produced using conditions under which
Discuss: a variety of possible
different catalysts and they are made, as these
monomers, and refer to the differences
reaction conditions. influence the type of
as being due to the structure achieved
structure produced.
when the different monomers
polymerise. Students make notes.
3.10.2 Thermosoftening Students should be able to 1 Demo: Show that there are two types A video on the properties
c polymers consist of explain thermosoftening of polymers, thermosetting and of plastics can be found on
individual, tangled polymers in terms of thermosoftening polymers, by heating the BBC website at
polymer chains. intermolecular forces. in a fume cupboard. Students can see www.bbc.co.uk/learningzo
which of a number of common ne/clips by searching for
Thermosetting
polymers belong to each group. clip ‘903’.
polymers consist of
polymer chains with Task: Students report their More information on
cross-links between experiment. Students suggest possible poly(ethene) can be found
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
them so that they do uses for polymers based on their on the RSC Alchemy
not melt when they are properties. website
heated. www.rsc.org/Education/Te
Explain: Develop explanation of the
achers/Resources/Alchem
difference in the polymers’ behaviour
y/index2.htm
in terms of structure. Students make
notes.
3.10.2 Polymers have many Students should consider 2 Activity: Choose from
d useful applications and the ways in which new
making a polymer from cornstarch
new uses are being materials are being
testing a polymer’s strength, eg
developed. Example developed and used, but
plastic carrier bag testing strength
include: new will not need to recall the
to breaking point (not a Hooke’s
packaging materials, names of specific
Law investigation)
waterproof coatings for examples.
testing waterproofing of different
fabrics, dental Know that we use a wide polymer fabrics
polymers, wound range of polymers investigating the amount of water
dressings, hydrogels developed for specific absorbed by hydrogels.
and smart materials purposes.
Students plan and report their
(including shape
Identify from properties investigation.
memory polymers)
relevant uses for a polymer.
3.10.2 Many polymers are not Realise that polymers are Discuss polymer developments, and
e biodegradable, ie they often hard to dispose of, waste disposal issues.
are not broken down and that biodegradable
Activity: Make notes on need for
by microbes. This can ones offer some solutions
disposal of plastics via recycling and
lead to problems with to these problems.
biodegradability rather than landfill.
waste disposal.
Advantages and disadvantages of
3.10.2 Plastic bags are being Knowledge of specific each disposal method.
f made from polymers named examples is not
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
and cornstarch so that required, but students Homework: Recycling plastics – give
they break down more should be aware of the two advantages and two
easily. Biodegradable problems that are caused in disadvantages of recycling plastics.
plastics made from landfill sites and in litter.
cornstarch have been
developed.
3.10.3.1 Alcohols
3.10.3 Alcohols contain the Students should be able to 1 Activity: Name these compounds: Molymods.
.1a functional group –OH. recognise alcohols from
Diagrams of CH4, C2H6, C3H8.
their names or formulae,
Methanol, ethanol and
but do not need to know Produce a blank chart (like the one
propanol are the first
the names of individual below) only showing the headings for
three members of a
alcohols other than each column (shown in bold).
homologous series of
methanol, ethanol and Complete the first three columns with
alcohols.
propanol. students. Leave the ‘alcohol name’
Alcohols can be column until the task listed below.
represented in the
following forms: number of start alkane alcohol
carbon to name name
atoms in name
CH3CH2OH molecule
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.10.3 Methanol, ethanol and Describe key reactions of 2 Discuss: Why are alcohols useful to Methanol, ethanol, Note: Students
.1b propanol: alcohols, and why alcohols us? propanol, sodium, distilled do not need to
are useful. water, universal indicator, write balanced
dissolve in water to Demo: To show:
form a neutral grass stained fabric, chemical
alcohols dissolve in water to give a crucibles. equations for the
solution
neutral solution reactions of
react with sodium
reactions of alcohols with sodium or alcohols other
to produce
magnesium produce hydrogen gas than combustion
hydrogen
that they burn in air
burn in air reactions.
solvent effect, eg on grass stains.
are used as fuels
and solvents, and
Add acidified potassium dichromate
ethanol is the main
solution to some dilute ethanol solution
alcohol in alcoholic
until next lesson.
drinks.
Demo: Of 50:50 ethanol/water
mixtures burning without damaging
paper. Soak old book/notepad in 50:50
ethanol water, place in enamel tray,
and set it alight. Let it burn for two
minutes so the flames can be seen,
then put heat proof mat over the top to
extinguish fire. Retrieve book/notepad
and show it is damp, but undamaged.
Students report the experiment and
write symbol equation for combustion
of ethanol with air. Mention use of
ethanol as a drink. Mention it is mildly
poisonous and this is why it is
intoxicating, whilst others are highly
poisonous.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.10.3 Ethanol can be Students should be aware Activity: Ask students to safely smell Note: Students
.1c oxidised to ethanoic that vinegar is an aqueous some ethanol, and then the flask with do not need to
acid, either by solution that contains ethanoic acid in from last lesson. Ask write balanced
chemical oxidising ethanoic acid. students what has happened, and to chemical
agents or by microbial tell you what has been made. equations for the
action. Ethanoic acid is reactions of
Discuss: The oxidation of ethanol to
the main acid in carboxylic acids.
ethanoic acid, and use molymods to
vinegar.
show what has happened to the
molecule of ethanol as it has been
oxidised. Students should explain why
brewing wine and beer need to ferment
without oxygen present.
3.10.3.2 Carboxylic acids
3.10.3 Ethanoic acid is a Students should be able to 1 Task: Students can now draw the
.2a member of the recognise carboxylic acids structure and formula of ethanoic acid.
homologous series of from their names or Students name carbon-based
carboxylic acids, which formulae, but do not need compounds, and then draw or make
have the functional to know the names of methanoic acid and propanoic acid.
group –COOH individual carboxylic acids
other than methanoic acid,
The structures of
ethanoic acid and
carboxylic acids can
propanoic acid.
be represented in the
following forms:
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
CH3COOH
or
3.10.3 Carboxylic acids: Students are expected to 2 Demo: To show: Test tubes, ethanoic acid,
.2b write balanced chemical pipettes, sodium
dissolve in water to carboxylic acids dissolve in water to
equations for the reactions hydrogencarbonate,
produce acidic form acidic solutions
of carboxylic acids. spatula, indicator paper,
solutions sodium carbonate produces CO2
react with gas. wooden splints and
carbonates to limewater.
Discuss: Carboxylic acids react like
produce carbon
acids, but have a higher pH, and so Test tubes, ethanoic acid,
dioxide
are weaker acids. This is why it is safe
react with alcohols ethanol, concentrated
to use vinegar in cooking but not H2SO4, pipettes, sodium
in the presence of
hydrochloric acid. hydrogencarbonate,
an acid catalyst to
produce esters Activity: Test dilute ethanoic acid with spatula and indicator
do not ionise indicator paper, sodium paper.
completely when hydrogencarbonate (and test the gas
dissolved in water produced) and magnesium ribbon (and
and so are weak test the gas produced).
acids
Students make notes on these
aqueous solutions
reactions, and use equations.
Spec Reference Summary of the Learning Outcomes Possible teaching and Learning Resource Examination
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
timing (lessons)
Suggested
Specification Content What most students should Activities ‘hints and tips’
be able to do Homework Students should:
3.10.3.3 Esters
3.10.3 Esters have the Students will not be 1 Students make notes on uses of esters
.3a functional group expected to give the names for perfumes and flavourings. Explain
of esters other than ethyl to students that milk goes slightly
–COO–
ethanoate, but should be ‘fruity’ before it goes off because
The structures of able to recognise a esters are produced in the milk by
esters can be compound as an ester from bacteria.
represented in the its name or its structural
following forms: formula.
CH3COOCH2CH3 or