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Tejas Lakshya JEE (2024)

Practice Sheet (Chemistry)

Biomolecules
Single Correct Type Questions: (1 to 15) 8. Study the structures of α-D-(+) glucopyranose and
1. Which of the following reagents may be used to β -D-(+) glucopyranose and mark the correct
identify glucose? statement.
(1) Neutral FeCl3 Solution
(2) Ammoniacal AgNO3
(3) CHCl3 and KOH (alc.)
(4) NaHSO3

2. Which of the following is a non-reducing sugar?

(1) Glyceraldehyde (2) Glucose
(3) Glactose (4) Sucrose
(1) Structures I and II are enantiomers
(2) Structures I and II are anomers
3. Which of the following carbohydrates is a
monosaccharide? (3) The two structures I and II differ in
(1) Sucrose (2) Maltose configuration of C1 and C4
(3) Fructose (4) Starch
(4) Both the structures I and II give 2, 4-DNP test
4. Glucose is a/an 9. In cellulose, D-glucose units are joined by
(1) Aldohexose (2) Aldopentose (1) α-1, 4-glycosidic linkage
(3) Aldotetrose (4) Ketohexose (2) β-1, 6-glycosidic linkage
(3) β-1, 4 glycosidic linkage
5. Glucose reduces
(4) peptide linkage
(1) Tollen’s reagent
(2) Fehling’s solution
10. The pair of compounds in which both the
(3) Benedict’s solution
compounds give positive test with Tollen’s reagent
(4) All
is
6. Which of the following reagents cannot distinguish (1) glucose and sucrose
between glucose and fructose? (2) fructose and sucrose
(1) Tollen’s reagent (3) acetophenone and hexanal
(2) Fehling’s reagent (4) glucose and fructose
(3) Benedict’ solution
(4) All of these 11. Which of the following statements is not correct?
(1) Only -amino acids are obtained on hydrolysis
7. Osazone formation involves only 2 carbon atoms of of proteins
glucose because of (2) The amino acids which are synthesized in the
(1) chelation body are known as non-essential amino acids
(2) oxidation (3) There are 20 essential amino acids
(3) reduction (4) L-amino acids are represented by writing the –
(4) hydrolysis NH2 group on the left side.
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12. How many number of water molecules are removed 17. Which of the following is reducing sugar ?
from the n number of amino acids during the
formation of peptide bond?
(1) (n – 1) (2) n (1)
(3) (n – 2) (4) (n – 3)

13. Which is a fat soluble vitamin?

(1) Vitamin A
(2) Vitamin B6
(3) Vitamin C
(2)
(4) Vitamin B2

14. Phosphodiester linkage is present between which

carbon atoms of pentose sugars of nucleotides?
(1) 5’ and 3’
(2) 1’ and 5’ (3)
(3) 5’ and 5’
(4) 3’ and 3’

15. Fehling’s solution test is given by

(1) glucose
(2) fructose (4)
(3) lactose
(4) all of these

One or More than One Correct Type Questions: (16 to 18) 18. Which of the following pairs are C-2 epimers?
(1) Allose, Altrose
16. Following are the structure of D-Glucose and D- (2) Glucose, Mannose
Galactose. (3) Gulose, Indose
CHO CHO (4) Galactose, Talose
H OH H OH
Passage Type Questions: (19 to 20)
HO H HO H
H OH HO H
H OH H OH
CH2OH CH2OH
D-Glucose D-Galactose
Which of the following statements are correct about
these compounds?
(1) The are diastereomers
(2) Both are component of lactose One cyclic acetal form of D-galactose is shown
(3) They are C4 epimer above.
(4) Both are optically active
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19. Which atom is the anomeric carbon ? 22. Match the following
(1) Atom A (2) Atom B Column-I Column-II
(3) Atom E (4) Atom F (Structure of (Characteristic property)
protein)
20. Which name most completely describes this cyclic  − Helix The polypeptide chains lie
acetal form ? structure side by side in an open
(1)  -D-Galactofuranose A P structure having inter-chain
(2)  -P- Galactofuranose amide H-bonding that holds
(3)  -D-Galactopyranose the chains together
(4)  -D-Galactopyranose − The polypeptide chain is
Pleated coiled up inti a right handed
Match the Column Type Questions: (21 to 22) sheet spiral structure. It is stabilised
Match the following structure by intra-molecular H-bonding
Column-I Column-II between (C = O) of one amino
(Molecule) (Configuration) B q. acid residue and the (N − H)
of the 4th AA residue in the
chain. This is also called
A p R-(Rectus) 3.613helix, having 3.6 AA in
each turn of the helix and 13-
membered ring.
Parallel This structure has the chains
pleated running in opposite directions.
B q S-(Sinister) sheet The  − C atoms rotate
C structure r. slightly out of the plane of the
sheet to minimise repulsions
between their bulky (R)
groups.
C r D Anti- This structure has chains
parallel running in the same direction;
pleated all with their N-terminal
D sheet s. residue starting at the same
structure end. The (R) groups alternate
D s L
positions below and above the
sheet
A B C D A B C D
(1) p, r q, s q, s p, r (1) p q r s
(2) p, r q, s q s (2) s t q p
(3) q, s q, r r, s r, s (3) p r s q
(4) q, s p, r p, s p, s (4) q p s r
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Integer Type Questions (23 to 25)

23. How many acidic group is present in given amino

acid ?

NH3 CH CH2 CH2 CO2H

CO2

24. How many compound which is given below is

isomer of D-Glucose ?
D-Mannose, D-Fructose, D-Gulose, D-Idose, D-
Galactose, D-Arabinose, D-Ribose.

25. Glucose molecule reacts with ‘X’ number of

molecule of phenylhydrazine to yield osazone. The

value of X is :
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Hints and Solutions

1. (2) 14. (1)
2. (4) 15. (4)
3. (3) 16. (1, 2, 4)
4. (1) 17. (1, 4)
5. (4) 18. (1, 2, 3, 4)
6. (3) 19. (4)
7. (2) 20. (3)
8. (2) 21. (1)
9. (3) 22. (4)
10. (4) 23. (2)
11. (3) 24. (5)
12. (1) 25. (3)
13. (1)

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