Bohladey kinetie Tieory f Gpses

Postulates
. Molecule Size is negligible
Molecule is assumed to be hand sshene and at collision elastic
No inteeacton among molecutes mhich means, TE k.E +RE = k-E
4.
ollisientine is neglgibe
is neq lected
5. ftet of Goauity on molecle
gas Law V 0RT at veoy hih TT and
ses ebe ys ideal jg
louw P.

at sTP. PV = n RT

>V= 1x 8 |4 x2.73 P= 1atm

|o)3 X I05 T= 273 k
2-24 xIo2mS
22-4L

Byles Lag (Ts onstat)

Boyle's law states that te pre ssure
fred Gmeunt ofa g Vanies invensely
tue. volme ifthe temperoatne is maunteuned lonstent.
Chaeles Lai(P Constent)
States tat te poessure. voemainins canstant, tue veume of a frxed
amount of a qas Varies directy ity its absolute tempenatune

T T2

T
- 23-15
Dalto's Law f rtial ressupe
Tressure eeoted byamtune of non intenachngges
amxtune of
to tue sum patial pressuoe -tence,tur
"asestue torte peessuee f gas is gtven by
|P= +f2+. -- +Po
ENT-T) +. - a )
 Sige
V=,3 whese
tyesu2.
20 seond
=
tione seLond 2l inwadl p.tae Yeueh wil uolecule the
-2mu. -{-mu)
cellision Sne
aftmonentan
er
mu
les=N Lel, uv,w where
hose
meleuse air
poufoy
ate. walss shose Cube holsd atake let's
 (Ie?)
N.Crms Goms N

M M= toted mass

sleles 0

heyolyhawe
haue .E.

kE = nNms -M M Goms

k.E

3RT (:pY=RT )
PV M
Comg=3RT M

# Mean free time, t ne batween tuWo Succesive, Gol lhsiong

Note I¢ TP aoe
nd Vav
V M
’ \ I and Vaw c T
 6*02%xi623

PV=N pT
Mnolerulan masa

Botzrmanns 'enstart

ten seusnd
Momentam traunsfeoned to a lontajner walI
arsea S
per unt f its sunface
av presune P4puons

Mavwllk pistri buion velocltes

A pontiees speed ppobabi lihy distoi bution
Shows how tie Spes of mokculey are
distoi bued tor an:Tdeat gos.

ny= no. o4 molecles peo umit

"f sped.
28T Voms - }RT
VmpM TTM M

Nbe: () T enp in k
M= molecutas ma(Kg)
V= Sped in ms
(2) Vap <Vay <Vems
ue.
(3) Apea Undee cuNe. qives ott no. f mekcats,
:Vavi Vrms = |: |:28 : l224
 Mest prekuble lecity ’is defned as velbtg posessed by the narimun fraction
melecle ctu paroiular tme.
e. Vay2at
nincreasiny T:
incneaies (l More wnaleculeg haNe hýgh speed.

Vstr) V-p)

numbero a mde kut e. can

"fthat malecua.
pudepde in <antriatiy to fhe total M. E.

Vibrati orel Panslational Rotatinal

1. 2 D. 0.F f eah
node
2. Ocurs tveg
wz

Nte!
A) mono'atomie
,Ne,Ar) () Since nale ulas $ize
0s assuned to be zeso

3Pue to translhi nal

# Diate mie (eg Hz, Oz N2) Note:

() Since mole cudes are

f=3+2 = 5 at buytemp.
Wz 1= 3+2+2=7 at ighte.
 Note!

co2j:3t2:s
2)Vibrtonad Dor
will be mentiored

cund atenrel nefy

# uportion af ineg
ig taeml eyuilbeim, the
totad ener1s distributel amauyst alte deqrees f
h deaee of
freedom wity he avg. ereng1 asioctahed wita eae
feedom equal to kT peo mlede or RT per moe

-for n male of gas Ttl tinetic rengy.

# Mxing f Guses
nixed d Same tent

2. mìuse

(Guset
in sudabed vesel U'semaing constant )

veay free podta ()Re foee pd trovesed

Successive callison.
d= dameles of moleule N
f molectes/lune
Node: uing PV= NkT kT
V2Tm'P