IIIITINYIEDUCITIDIIII

JR CHEMlST!~ITITUnONl,lllll
LONG :~~~~rPt.p1msriJ:
What are the postulates of B0 h ' {UC fURE
model to exP run various series of line spec! hy• I;ngcn •lorn? Discuss the importance of this
1 · , · rs model of 1
H
ow arc the quantum numb 1 rn m ,ydrogcn ntom.
quantum numbers. crs 11' nll d m arrived al'/ Explain the significance of all the
PERIODIC TABLE (Classificatio
•••3. Define m and IF Wl . JE 8
of clements & Periodicity in properties)
1
an element. 2· 1y ts ➔ 2 > IE for . atom? Discuss the factors that effect IE of
1 8 given

... 4. What . properties vary in a group and in a period?

is periodic propcrtY?· How the followcng
Explain.

a) Atomic radius b) Electron gain Enthalpy c) Ionisatioh Energy (IE)

~atur~ of oxides e) Electro negativity
i) Metallic and non-metallic nature
•••s. Write an essay on s, p, d and f block elements.
CHEMICAL BONDING AND MOLECULAR STRUCTURE
...6. Give an accout ofVSEPR Theory, and its applications
•••7. Expalin the factors favorable for the formation of Ionic Compounds.
•••s. Discuss Hybridisation with suitable examples?
•••9.Give the Molecular Orbital Energy diagram of (a) N2 and (b) 02, Calculate the respective
bond order. Write the magnetic nature ofN2 and 02 molecules. 1
CHEMICAL EQUILIBRIUM AND ACIDS - BASES
•••to.S1alC and explain [,ecbatlier's prin~iple? Discuss the "!'plication of Lcchallicr's principle for
th industrial synthesis of Amffiorua and sulphur tnoXIde.
e ORGANIC CHEMISTRY
••• ll. Give two methods ~f preparation of acetylene. How does it react with fo11owinp p lbe
correspanding equations
~ Acd,ic acid b) Water c) Hydrogen
:) }lalogeDI e) Hydrogen halide t) Ammonical AgN03 and eu2a 2
••• 2. J)elCribe any two methods of preparation of benzene, with aorreaponding equetfcas
1 Beazcae does not behave like an albnea, why? Explain the baJopnatJ,..._ alkylation.
aeylatloD, nitradOD and sulphonation of benzene,,
•••tJ. Deacribe two methods of preparation of ethylooe. Olvo aquadaa for the...._ of
c,tbylenl with the followinl,
•> OJ011C b) Co~ and d11,alkKMn04 o) Hydropn halldo 4 ) ~ •~--
 .,.,..._." .._e d1ff«enC t,e1wecn
•••14 ~-u•
cMON Pf ELEME R1on1c I JN, 1 01
m,r rror rt, flH II
•• lllftll~aruae ..........-..tun \\ h f r ,tc: 1 q
••
gCMJP'L pQNDJNG AND MOLEC
fontlllion of Coordinate (maknt hond wrlh on ''"'"'.........
da1IIIII nftrOF11 m ammonia is tn p I hybridization, th
1
- ..... ~ o n involved in SI 6 molecule.
. . . . 111e hyt,riclll.lbOn mvolved in PCJ5 molecule.
wa. ■ HydroPD bonding and explain types of Hydrogen bonds.
• &Jin snales and give suitable examples.
.a- dipole moment
a) 8FJ b)BF2 c) NH3 and NF3

STATES OF MATTER: GASES AND LIOIDDS

1
.-X Define (a) rms (b) average and (c) most probable speeds of gas molecules G ve th
M l«msbir and problem.
splaiD Dalton's law of Partial pressures and problem.
• polhdMCS of Kinetic Molecular Theo~"~f ~~·
splaiD Graham's law of Diffusion a n ~

(b) Charle's law c) Graham's Jaw d) Daltons law

fiom kinetic gas equation.
Derive Ideal gas equation.

STOICHIOMETRY
,-mula of a compound having percentage composition:
um (Cr) • 35.36, oxygen(O) 38.07. (Given the atonuc
n. ad 16 re,pecdvely) (Ans: K2er2o7)
 Fe2+ + Cr20J- ➔ Fe3+ +Cr3+

,1" Chemical analysis of a carb d

we1'ght of the elements pres ont comp mm gave the foll •
;;,J-•

Calculate the empirical fo e7' carbon== 10.06%, hydr

rmu a of the compound.
o;m~
percentage composition by
ogcn - 0.84%, chlorine - 89.10%,
(Ans : CHCJ 3)

HYDROGEN AND
''"'"''33. Explain the terms hard
. .
ITS COMPOUNDS
water and soft w t W .
1) rnn - exchange method d .. a er. nte a note on the
···)
111 C lark method an 11) Calgon meth Od 10
c. r the removal of hardness of water.

***34. Wha:
reaction? . of dihydrogen be increased by this
is water-gas shift reaction?· How can the production

***35 . W nte
· a few lines on th ill
***36 Ex . . . e ut ty of hydrogen as a fuel.
. . plam, with s~utable examples, the following :
1) electron - deficient
***37. Write the chemical . . ~ ")
1 electron - precise and iii) electron - rich hydrides
. reaction to JUStify that hydrogen peroxid1canction as on oxidizing as
Well as reducmg agent.

THERMODYNAMICS
***38. State and explain the Hess's law of constant Heat summation.
***39. Explain extensive and intensive properties.
***40. Explain the followings
. J.41lntemal energy b) Enthalpy
d) Gibb's energy
~Entropy

CHEMICAL EQUILIBRIUM AND ACIDS - BASES

***41. Derive the relation between KP and K. for the equilibrium reaction

i) 2S02 + 0 2 ~ 2S03
(g) (g) (g)

ii) N2 + 3H2 ~ 2NH3

***42. Explain the terms: (i) electrolyte (ii) Non - electrolyte
(iii) strong and weak electrolytes (iv) ionic - equilibrium
***43. What is common ion effect? Illustrate.
... 44.~efme conjugate acid and conjugate bas;)Write the conjugate acid and conjugate base of
each of the followmg :
a) Off b) H 0 c) HC03- d) H204
2
***45. Write on (i) Common ion effect.
~ e relation between K,;p and solubil_ity (S) of a spaningly soluble salt BaSo4.
***46. Defme ionic product of water. What 1s 1ts value at room temperature?
***47. Explain Bronsted-Lowery acid base theory?

_S~n~·~c~h~aJ~·tan~Y~a_ _ _ _ _ _ _ _ _ Page3 Hyderabad

 THE S-BLOCK ELEMENTS
~L What do you .know about Castner - Kellner process.? Write
. the pri ·
.._,. WJJathappeDS when ncip 1e involved in•It.
i) Mqnesium is burnt in air? ii) Quick lime is heated wi th ..
UQCblorine reacts with slaked lime? silica;
.Sr) Ctloium nitrate is strongly heated?
Waat is Plaster of Paris? Write a short note on it.
-!IJt:lttir does NaOH reacts with (a) C/2 (b) FeSO◄ (c) NH◄ Cl (d) A/Cl
THE P-~LOCK ELEMENTS (GROUP-I~)
~·~ lq1afn the mucture of diborane.
)'fa-, two methods of preparation of diborane. How does it react with
,. . . __.,."Wi-~~lftr.t,anmonoxide b) Ammonia c) H20 d) CO e) aq.KOH
(GROUP-14)
44epaaation ofH 20 gas. Mention it uses.
tlC>fe on a) silicates b) zeolites c) Fullerenes
is conductor of electricity, whild diamond is not explain.
on the allotropy of carbon.

ORGANIC CHEMISTRY
Which type of compounds reacts with q
each for position and functional isomerism.
• reaction and name the products A,B and C.
AJC~+CH CJ
~.,......,........,--+B, 3 >C

•ODS of methane.
metrical isomerism? Explain the geometrical isomers of

· any two substitution reactions of benzene.

ed in the following reactions. Give the equations for the

•ch is more stable.

·~U'3.II~ book Q No: 31)
 VERY SHORT A l\.T .
~~sWER OUEs
***Ol. What. b ATOMIC STRU IONS (VSAQ)
18 a lack body? · CTURE
***02 . H owman ·
*** y p electrons are re - .
03. What is Zeeman effe t p sent 111 sulphur atom'!
***04. Explain a),,P l"' c and Starck effect?
***0 au t s exclusion princ· l
S. Explain Heisenber , . ip c. b) Aulbau principle c) Ilund's rule
u . g
ncertainty principles uncertamty . .
principle? and Explain the significance of Heisenberg's
PERIODIC TABLE.(Cl . .
. assification of elements & Periodicity in properties)
***06. What
***07 Am are representative
_
elements? Give . valence shell configuration. -
· their -
3
. ong ~ ,o i,F-,Na+,Mg+2 and Al+3
a) What is common in them?
b) Arrange them ih the increasing ionic radil.
c) Define iso electronic series.
. . enthalpyl (IE 1) of O is less than ofN-explain.
***08 • Ioruzat1on
· effect? How is it related to IE?
***09 . What.is screemng
***10. What is diagonal relation? Give one pair of elements, that have this relation.
*** 11. Electron affinity of chlorine is more than that of fluorine - explain.
*** 12. What type of bonds present in NH4Cl.

CHEMICAL BONDING & MOLECULAR STRUCTURE

** * 13. What is Octet rule?
2
***14. Which of the two ions Ca2+ or Zn + is more stable and why?
***15. How many Sigma and Pi bonds are present in (a) C2H2, (b) C2H4 and c) c6H 6 ?
STATES OF MATTER
***16. Define:
a) Isotherms b) Isobars c) Isochores d) compressibility factor
e) Absolute zero
***17. Define
a) Critical temperature b) Critical pressure c) Critical volume

*** 18. Define

a) Critical constant b) Surface tension c) Co-Efficient of viscosity
**(!_2.)What is Boltzman's constant? Give its value.
***20. Calculate kinetic energy of 5 moles of nitrogen at 270c
*** 1. Calculate kinetic energy of 3 moles of CO2 gas al 270c
2
***22. Calculate RMS velocity of CO2 gas at 27°c.
***23. Write Vander Wall's equation.
*"'*Z4.Which gas diffuses faster among N2, o 2 & Cl 14? Why'?

Sri Chititan,,:.y_a___ _;__________ Page S

 ST O lC H IO M ET R \
.. CH . t
la of a co mp ou nd is
***25. Th e em pm ca l for mu 20 . Its mo l ecu 1ar Weight is
of the co mp ou nd . (A n .C 90 . Calculate the
molecular for mu la . s . 3 H6 03 )
-. \ ty of Na 2C O3 in a solution pre pa red by di 1 .
***26. Calculate the mo lan sso vmg Water to form 250 ml
of the sol uti on .
l{ •
"27 . Ho w ma ny nu mb er of mo les of glu co se arc prcscJ • Ill 5 40 gm s 0 f gl uco sc?
**" .
(A ns : 3 mo les ) ,
.
Wh at are dis pro po rli on ali on rea cti on s? Gi ve 1..~xunip/c 1
***28. de rlin ed c/omc n{ . ' '
, '
ox ida tio n nu mb er of Ilic un s eac h of th c 1r:0 11 ow ing and ho w
***29. Wh at arc the 111
• u Jts?
do yo u rat ion ah sc youJ' rcs
c) Na lC~ 04
3 b) H2 ~2 06 c) Fc 30 4
a) KJ.
i) Na BH
~ 07 g) K2 Mn O4 h) K2 Ct 207 4
t) H 2
j) H2 ~2 07
le of sod ium car bo na te. (A
ns : 10 .6 g)
lat e the we igh t of 0.1 mo
•0 30 , Ca lcu

TH ER M O DY NA M IC S
an ex am ple .
0 31 .D cfi ne a sys tem . Gi ve
•
ex pa nsi on of an ide al gas in reversible and irreversible
e in the fre e
•0 32 . What is the wo rkd on
pro ces ses ?
***33. Wh at is the relation
ship be tw een Cp an d Cv.

IU M & AC ID S - BA SE S
CH EM IC AL EQ UI LI BR
l eq uil ibr ium.
.. . 34 .St ate law of ch em ica equilibrium?
tem pe rat ure on a sys tem at
..*35. Wh at is the eff ect of le .
••• 36 . De fin e con jug ate an
d ba se pair. Gi ve n an exa mp
3
ge n ion is 3.8 xlo - M. Wh
at is its pH .
.. .37 .Co nce ntr ati on of hy dro reactions.
at is ho mo ge no us eq uil ibr ium? Write tw o ho mo ge no us
***38. Wh eo us rea cti on s.
at is het ero gen eou s eq uil ibrium? Write tw o he ter og en
••• 39 _ Wh
d Kc·
•••40. Write the relation bet we en KP an
••• 41 , De tm e pH..
~Q. What Hy
is buffer solutions?
drolysis of different salts.
•••43_ Write
•••44. Give the classification of salts.
POUNDS
HYDROGEN AND ITS COM
son s .
45 .The three iostopes of hydrogen dif fer in the ir rat
es of rea cti on . Gi ve the rea
•••
..• 46.Explain the term "SY
NG AS ". ·
· wit h rel eva nt, ba lan ced eq ua tw n.
·•• 47 What·11 meant by coal gas1fucation? Expla in
•

Hyderabad
••• . THE s-BLOCK ELEMENTS
4 &.Wnte the biolo · c ·
***49.Write an tw gi al importance of mg and Ca.
***50 Wh y o uses of caustic soda
* ** · . Y are alkar1 metals not found in a fr .
51. Give the uses of th .c 11 . ee state m nature.
e 10 owmg. ·
a) caustic soda b) sodium
***52 Lithi carbonate c) quicklime d) plast' f ·
· um salts are mostl h dr 1c o pans
***53 What ha y y ated. Why?
***54· . ppens when magnesmm· . burnt in air?
metal lS .
•••ss·:te_the average composition of Portland cement .
· Y 15 gypsum added to cement?
*** 56.What 1s. plaster of paris .
*** 57 .Wnte
. the bioloo-ical rmpo
o" · . rtance of sodium
. and Potassium ions.

THE p-BLOCK ELEMEfilS

***58. Classify the following oxides as neutral, acidic, basic or amphoteric.
a) CO b) B203 c) SiO2 d) CO2

e) Al203 f) PbO2 g) 1120 3

***59. Explain the structure of silica
***60. What is 'producer gas'?
***61. How is water gas prepared?
***62. How is producer gas prepared?
***63. Explain inert pair effect.
***64. Give the formula of borazine. What is its common name?
***65. Give the formulae of a) Borax b) Colemanite
***66.WhY diamond is hard.
*** 7. i) Write two crystallin~ allotropes of ~arbon and mention the hybridisation present in then.
6
***68 ii) What is allotropy? give the crystalline allotropes of carbon.
***69.WhY is carbon monoxide Poisonous
***70.Wb.at borax?
***71. Explain borax bead test with a suitable example.
***72. Give the hybridization of carbon in
a) co;2 b) diamond c) graphite d) fullerene
••*73. Write the use of CO2 in photosynthesis
••*74. Name the two man made silicates
***75. What are silicones and give example.
***76. What is •synthesis gas'?
***77. What is meant by dry ice and its uses.
***78. Graphite is a good conductor - explain.
•**79. Write the uses of carbondioxide
***SO.How does graphite function as a lubricant?

Page7
Sri Chaitanya
 ENVIRONMENTAL CHEMISTRY
,\e
***81. What is PAN? What effect is caused by it?
i.g
***82. What is green house effect? and how is it caused?
***83. Write two adverse effects caused by acid rains. Which oxides cause acid rain? and what is
its pH value?
***84. What is Ozone hole? Where was it first observed? Explain Depletion of Ozone layer.

***85. Define a) Pollutant

b) Contaminant c) Receptor
d) Sink e)1LV
f) COD and BOD
g) Eutrophcation
***86 What is photo chemical Smog.
***87.What is acid rain?
I

ORGANIC CHEMISTRY
***88. Write the structure of: Trichlorothanoic acid, Neopentane, p-nitro benzaldehyde.
***89. Learn the following reactions
a) Wurtz reaction b) Friedalcraft's reactions
c) Polymensation of ak:enes & alkynes d) Ozonolysis of C H , C2H2, C6H6.
2 4
e) Addition ofH20 to C2H2.

***90. Explain a) Crystallisation b) Distillation

CH3
I
HC-C-CH-CH -CH
3 I I 2 3

***91. i) CH3 CH3

ii)
***92. Draw cis and trans isomers of the following compounds. Also write their IUP AC names:
i) CHCl=CHCl ii) C2H5CCH3=CCH3C2H5
***93. Write IUP AC names of :
a) CH 3 -CH 2 -CH 2 -CH= CH
2

~.~-
b) !

c)
~¢ No, NO,

***94. Write structure formulas of the following compounds:

i) 3, 4, 4, 5 -Tetramethylheptane ii) 2, 5-Dimethyhexane
***95. Write IUP AC names of the following compounds:
i) (CH3)J C CH2C(CH3)J ii) (CH3)2 C(C2H5)i
***9~How is Nitrobenzene prepared.
ALL THE BEST
Sri Chaitanya
--- - - - - - - - Page a Hyderabad_