-

-
>
>
>
>
*
*

1.


2.

3.

4.

5. 2
(Solution)
6. (O2) (H2)
(CO2) (NO2)
(Cl2) (O3)

 ( Boyles Law )

1
2
3
4
5
6
7
8
9

(V , dm3)
5.00
10.00
15.00
20.00
25.00
30.00
35.00
40.00
45.00

(P , mmHg)
760
380
253
191
151
127
109
95
84

PV
(mmHg. cm3)
3.80 x 103
3.80 x 103
3.80 x 103
3.82 x 103
3.78 x 103
3.81 x 103
3.82 x 103
3.80 x 103
3.78 x 103

(PV)

(Robert Bolye)
.. 1662 (.. 2205)

 1 15 g 10 150 mmHg
50 mmHg

P1
P2
V1
V2
P1V1
150 x 10
V2

=
=
=
=
=
=
=

150 mmHg
50 mmHg
10
?
P2V2
50 x V2

= 30
2 200 mmHg

P1 = 200 mmHg
P2 = ? mmHg
V1 = V1
V2 =
P1V1 = P2V2
200 x V1 = P2 x
P2 =
= 400 mmHg

 ( Charles Law )

Jacques Charles



273OC
273OC
273OC 0 K
K = 273 + t OC

1
2
3
4

t ( OC )

T(K)

V (cm3)

V/T (cm3/K)

10
50
100
200

283
323
373
473

100
114
132
167

0.35
0.35
0.35
0.35

( Jacqes A.C. Charles )
..1778 ( ..2321 )


V T
V = kT
= k
V1 T1
V2 T2
V T
=

P T
P = kT
= k

 3 80 cm3 45OC
0 OC

V1
V2
T1
T2

=
=
=
=

80 cm3
?
273 + 45 = 318 K
273 + 0 = 273 K
=

V2 =
= 68.68 cm
4 30 25 OC
100 OC

V1
V2
T1
T2

=
=
=
=

30
?
273 + 25 = 298 K
273 + 100 = 373 K
=

V2 =
= 37.55

* *

 ( Combined gas law )

-
( Combined Gas Law )
; m
#. m m

( Ideal gas / Perfect gas law )

V 1/P

V T

V n
V nT/ P

; V
P atm
T ( K )
n mol
R ( 0.0821 atm.L/mol.K )
( gas constant, R ) standard condition ( STP )


1)

2)

3)

4)

5)


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5)