p n bi 1:

Andotetroz duy nht cho sn phm quang hot khi b oxy ha bi axit nitric l:

A cho B v C khi x l vi HCN tip theo l Ba(OH)
2


Cc - andolacton tng ng D v E l:

Hn hp trn em x l vi Na Hg pH = 3,5 cho sn phm:



p n bi 2:


p n bi 3:
- A l ng khng kh nn cc monosaccarit u khng cn nhm OH semiaxetal
- A b thy phn bng enzym -Glucozidaza th thu c disaccarit B v D-arabinose chng t A c
lin kt -Glycozit vi D-arabinose
- T dy bin ha trn th C, D s l D-Mannose v D-Glucose .
- Cho sn phm ete ha thy phn trong mi trng axit thu c 2,3,4,6-tetra-O-metyl ca mt
D-andohexose (C), 2,4,6-tri-O-metyl ca D- andohexose (D) v 2,3,4-tri-O-metyl-D-arabinose. Nn
trnh t cc monosaccarit trong A l: D-mannose lin kt vi D-glucose bng lin kt 1,3-glycozit v
D-glucose lin kt vi D-arabinose bng lin kt-1,1-glycozit.
Cu trc ca A
O
OH
OH
OH
CH
2
OH
O
CH
2
OH
O
OH OH
O
O
OH
OH
OH

Cc chuyn ha tng ng
CHO
HO
OH
CH
2
OH
OH
HO
OH
CH
2
OH
OH
HO
OH
CH
2
OH
OH
HO
CN
CN
OH
H
3
O
+
HO
OH
CH
2
OH
OH
COOH
OH
H
3
O
+
HO
OH
CH
2
OH
OH
HO
COOH
t
o
HO
O
CH
2
OH
OH
C
OH
O
t
o
HO
O
CH
2
OH
OH
HO
C
O
Na(Hg)
HO
OH
CH
2
OH
OH
CHO
OH
Na(Hg)
HO
OH
CH
2
OH
OH
HO
CHO