NARAYANA JUNIOR COLLEGE

Kothapet, Dilsukhnagar, Hyderabad

SR REG SEC 502

CHEMISTRY

DATE : 15-12-2014.

1.

Calculate the normality of the following solution

a) 6.3 gm HNO3 in a litre solution
b) 11.2 gm of KOH in a litre solution

2.

To convert 1 litre of 1.123N solution of an acid into 1N solution. How much volume of
water should be added?
At 500C the vapour presser of H2O is 92 mn Hg. The vapour pressure of a solution
containing 18.1 gm of a non-volatile solute in 100ml H 2O, at the same temperature is
87 mn Hg. Find the M.Wt of the solute.
Calculate the equivalent weight of K2Cr207 in acid medium.

3.
4.
5.

7.

3gm of solute is dissolved in 22gm of water. The depression F.P shown by the solution is
1.45K. Kf for water = 1.86 K. Kgmole1. Calculate molar mass.
X-rays of wavelength equal to 0.134 nm gave a first order diffraction from the surface of
a crystal. The value was found to be 10.5 0. Calculate the distance between the planes
in the crystal. (sin10.50 = 0.182)
Which crystal has 12 as co-ordination number?

8.

Explain Ferromagnetic solid materials?

6.

9.

Calculate the EMF of the galvanic cell

Zn/Zn2+(1.0M)// Cu2+(1.0M)/Cu
E0Zn2+/Zn = - 0.766V
E0Cu2+/Cu = + 0.327V
10. What products are obtained in the electrolysis of fused KCl and aqueous solution of KCl
between platinum electrodes?
11. The specific conductance of 0.1N KCl solution is 0.14807 m 1 . Calculate the equivalent
conductance.
12. Write any two differences between order and molecularity.
13. What is common ion effect?
14. Find the PH of 0.05 M Ba(OH)2 aqueous solution.
15. Find the PH of 10-8M HCl Solution.
16. The solubility of salt AB = 10-1 mole2/litre2. What is the solubility?
17. The equilibrium constant Kc of a reversible reaction in 10. The rate constant after the
reverse reaction is 2.8. What is the rate? Constant for forward reaction.
18. The PH of a buffer prepared by mixing 50ml of 0.2M CH 3COOH and 25ml of CH3COONa is
4.8. If the PKa = 4.8. What is the strength of CH3COONa.
19. What is an emulsion? Give an example.
20. What is auto catalysis? Give an example.
21. What is Gold number?
22. What is Gibbs energy & entropy?
23. H for the reaction H2(a) + cl2(g) 2 HCl (g) is 184.6 KT. What is heat of formation of
HCl.
24. Define following term
(a) Flux
b) Gangue
c) Slag
25. Write the names and formulae of any two ores of silver.